Sodium metasilicate is the
chemical substance
A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., wit ...
with formula , which is the main component of commercial
sodium silicate
Sodium silicate is a generic name for chemical compounds with the formula or ·, such as sodium metasilicate , sodium orthosilicate , and sodium pyrosilicate . The anions are often polymeric. These compounds are generally colorless transparent ...
solutions. It is an
ionic compound
In chemistry, an ionic compound is a chemical compound composed of ions held together by electrostatic forces termed ionic bonding. The compound is neutral overall, but consists of positively charged ions called cations and negatively charged ...
consisting of
sodium
Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...
cation
An ion () is an atom or molecule with a net electrical charge.
The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...
s and the
polymer
A polymer (; Greek '' poly-'', "many" + '' -mer'', "part")
is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...
ic
metasilicate 320 px, Idealized structure of sodium metasilicate.
Metasilicates are silicates containing ions of empirical formula . Common stoichiometries include MSiO3 and MIISiO3. Metasilicates can be cyclic, usually the hexamer or chains .
Common comp ...
anion
An ion () is an atom or molecule with a net electrical charge.
The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...
s
��–sub>''n''. It is a colorless crystalline
hygroscopic
Hygroscopy is the phenomenon of attracting and holding water molecules via either absorption or adsorption from the surrounding environment, which is usually at normal or room temperature. If water molecules become suspended among the substance' ...
and
deliquescent
Hygroscopy is the phenomenon of attracting and holding water molecules via either absorption or adsorption from the surrounding environment, which is usually at normal or room temperature. If water molecules become suspended among the substance' ...
solid, soluble in water (giving an alkaline solution) but not in alcohols.
[Chemical Book]
"Sodium metasilicate"
Accessed on 2018-05-13.
Preparation and properties
The
anhydrous
A substance is anhydrous if it contains no water. Many processes in chemistry can be impeded by the presence of water; therefore, it is important that water-free reagents and techniques are used. In practice, however, it is very difficult to achi ...
compound can be prepared by fusing
silicon dioxide
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
(silica,
quartz
Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical f ...
) with
sodium oxide
Sodium oxide is a chemical compound with the formula Na2 O. It is used in ceramics and glasses. It is a white solid but the compound is rarely encountered. Instead "sodium oxide" is used to describe components of various materials such as gla ...
in 1:1 molar ratio.
[J. F. Schairer and N. L. Bowen (1956): "The system ——". ''American Journal of Science'', volume 254, issue 3, pages 129-195 ]
The compound crystallizes from solution as various
hydrate
In chemistry, a hydrate is a substance that contains water or its constituent elements. The chemical state of the water varies widely between different classes of hydrates, some of which were so labeled before their chemical structure was understo ...
s, such as
* pentahydrate ·5 (CAS 10213-79-3, EC 229-912-9, PubChem 57652358)
* nonahydrate ·9 (CAS 13517-24-3, EC 229-912-9, PubChem 57654617)
[M. F. Bechtold (1955): "Polymerization and Properties of Dilute Aqueous Silicic Acid from Cation Exchange" ''Journal of Physical Chemistry'', volume 59, issue 6, pages 532–541. ]
Structure
In the anhydrous solid, the metasilicate anion is actually polymeric, consisting of corner-shared tetrahedra, and not a discrete SiO
32− ion.
In addition to the anhydrous form, there are hydrates with the formula Na
2SiO
3·''n''H
2O (where ''n'' = 5, 6, 8, 9), which contain the discrete, approximately tetrahedral anion SiO
2(OH)
22− with water of hydration. For example, the commercially available sodium silicate pentahydrate Na
2SiO
3·5H
2O is formulated as Na
2SiO
2(OH)
2·4H
2O, and the nonahydrate Na
2SiO
3·9H
2O is formulated as Na
2SiO
2(OH)
2·8H
2O. The pentahydrate and nonahydrate forms have their own CAS Numbers
10213-79-3an
13517-24-3respectively.
Uses
Sodium Metasilicate reacts with acids to produce
silica gel
Silica gel is an amorphous and porous form of silicon dioxide (silica), consisting of an irregular tridimensional framework of alternating silicon and oxygen atoms with nanometer-scale voids and pores. The voids may contain water or some other l ...
.
* Cements and Binders - dehydrated sodium metasilicate forms cement or binding agent.
* Pulp and Par - sizing agent and buffer/stabilizing agent when mixed with hydrogen peroxide.
* Soaps and Detergents - as an emulsifying and suspension agent.
* Automotive applications - decommissioning of old engines (CARS program), cooling system sealant, exhaust repair.
* Egg Preservative - seals eggs increasing shelf life.
* Crafts - forms "stalagmites" by reacting with and precipitating metal ions. Also used as a glue called "
soluble glass".
*
Hair coloring kits
See also
*
Potassium metasilicate
*
Sodium orthosilicate
*
Sodium pyrosilicate
References
{{Authority control
Inorganic silicon compounds
Sodium compounds
Metasilicates