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A smoke screen is
smoke Smoke is a suspension of airborne particulates and gases emitted when a material undergoes combustion or pyrolysis, together with the quantity of air that is entrained or otherwise mixed into the mass. It is commonly an unwanted by-produc ...
released to mask the movement or location of military units such as
infantry Infantry is a military specialization which engages in ground combat on foot. Infantry generally consists of light infantry, mountain infantry, motorized infantry & mechanized infantry, airborne infantry, air assault infantry, and mar ...
,
tank A tank is an armoured fighting vehicle intended as a primary offensive weapon in front-line ground combat. Tank designs are a balance of heavy firepower, strong armour, and good battlefield mobility provided by tracks and a powerful ...
s,
aircraft An aircraft is a vehicle that is able to flight, fly by gaining support from the Atmosphere of Earth, air. It counters the force of gravity by using either Buoyancy, static lift or by using the Lift (force), dynamic lift of an airfoil, or in ...
, or
ship A ship is a large watercraft that travels the world's oceans and other sufficiently deep waterways, carrying cargo or passengers, or in support of specialized missions, such as defense, research, and fishing. Ships are generally distinguished ...
s. Smoke screens are commonly deployed either by a canister (such as a
grenade A grenade is an explosive weapon typically thrown by hand (also called hand grenade), but can also refer to a shell (explosive projectile) shot from the muzzle of a rifle (as a rifle grenade) or a grenade launcher. A modern hand grenade ge ...
) or generated by a vehicle (such as a
tank A tank is an armoured fighting vehicle intended as a primary offensive weapon in front-line ground combat. Tank designs are a balance of heavy firepower, strong armour, and good battlefield mobility provided by tracks and a powerful ...
or a
warship A warship or combatant ship is a naval ship that is built and primarily intended for naval warfare. Usually they belong to the armed forces of a state. As well as being armed, warships are designed to withstand damage and are usually faster ...
). Whereas smoke screens were originally used to hide movement from enemies' line of sight, modern
technology Technology is the application of knowledge to reach practical goals in a specifiable and reproducible way. The word ''technology'' may also mean the product of such an endeavor. The use of technology is widely prevalent in medicine, scien ...
means that they are now also available in new forms; they can screen in the
infrared Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of Light, visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from ...
as well as
visible spectrum The visible spectrum is the portion of the electromagnetic spectrum that is visible to the human eye. Electromagnetic radiation in this range of wavelengths is called '' visible light'' or simply light. A typical human eye will respond to ...
of light to prevent detection by infrared sensors or viewers, and they are also available for vehicles in a super-dense form used to block laser beams of enemy target designators or range finders.


Technology


Smoke grenades

These are canister-type grenades used as a ground-to-ground or ground-to-air signalling device. The body consists of a steel sheet metal cylinder with a few emission holes on the top and/or bottom to allow smoke release when the
smoke composition A smoke composition is a pyrotechnic composition designed primarily to generate smoke. Smoke compositions are used as obscurants or for generation of signaling smokes. Some are used as a payload of smoke bombs and smoke grenades. Obscurants Smok ...
inside the grenade is ignited. In those that produce colored smoke, the filler consists of 250 to 350 grams of colored (red, green, yellow or violet) smoke mixture (mostly
potassium chlorate Potassium chlorate is a compound containing potassium, chlorine and oxygen, with the molecular formula KClO3. In its pure form, it is a white crystalline substance. After sodium chlorate, it is the second most common chlorate in industrial use. ...
,
sodium bicarbonate Sodium bicarbonate ( IUPAC name: sodium hydrogencarbonate), commonly known as baking soda or bicarbonate of soda, is a chemical compound with the formula NaHCO3. It is a salt composed of a sodium cation ( Na+) and a bicarbonate anion ( HCO3− ...
,
lactose Lactose is a disaccharide sugar synthesized by galactose and glucose subunits and has the molecular formula C12H22O11. Lactose makes up around 2–8% of milk (by mass). The name comes from ' (gen. '), the Latin word for milk, plus the suffix ' ...
and a
dye A dye is a colored substance that chemically bonds to the substrate to which it is being applied. This distinguishes dyes from pigments which do not chemically bind to the material they color. Dye is generally applied in an aqueous solution and ...
). In those that produce screening smoke, the filler usually consists of HC smoke mixture (hexachloroethane/zinc) or TA smoke mixture (terephthalic acid). Another type of smoke grenade is filled with white phosphorus (WP), which is spread by explosive action. The phosphorus catches fire in the presence of air, and burns with a brilliant yellow flame, while producing copious amounts of white smoke (phosphorus pentoxide). WP grenades double as
incendiary grenade A grenade is an explosive weapon typically thrown by hand (also called hand grenade), but can also refer to a shell (explosive projectile) shot from the muzzle of a rifle (as a rifle grenade) or a grenade launcher. A modern hand grenade ge ...
s.


Smoke shell

Artillery Artillery is a class of heavy military ranged weapons that launch munitions far beyond the range and power of infantry firearms. Early artillery development focused on the ability to breach defensive walls and fortifications during si ...
and mortars can also fire smoke generating munitions, and are the main means of generating tactical smokescreens on land. As with grenades, artillery shells are available as both emission type smoke shell, and bursting smoke shell. Mortars nearly always use bursting smoke rounds because of the smaller size of mortar bombs and the greater efficiency of bursting rounds.


Smoke generators

Very large or sustained smoke screens are produced by a smoke generator. This machine heats a volatile material (typically oil or an oil based mixture) to evaporate it, then mixes the vapor with cool external air at a controlled rate so it condenses to a mist with a controlled droplet size. Cruder designs simply boiled waste oil over a heater, while more sophisticated ones sprayed a specially formulated oily composition ("fog oil") through nozzles onto a heated plate. Choice of a suitable oil, and careful control of cooling rate, can produce droplet sizes close to the ideal size for
Mie scattering The Mie solution to Maxwell's equations (also known as the Lorenz–Mie solution, the Lorenz–Mie–Debye solution or Mie scattering) describes the scattering of an electromagnetic plane wave by a homogeneous sphere. The solution takes the ...
of
visible light Light or visible light is electromagnetic radiation that can be perceived by the human eye. Visible light is usually defined as having wavelengths in the range of 400–700 nanometres (nm), corresponding to frequencies of 750–420 t ...
. This produces a very effective obscuration per weight of material used. This screen can then be sustained as long as the generator is supplied with oil, and—especially if a number of generators are used—the screen can build up to a considerable size. One 50 gallon drum of fog oil can obscure of land in 15 minutes. Whilst producing very large amounts of smoke relatively cheaply, these generators have a number of disadvantages. They are much slower to respond than pyrotechnic sources, and require a valuable piece of equipment to be sited at the point of emission of the smoke. They are also relatively heavy and not readily portable, which is a significant problem if the wind shifts. To overcome this latter problem they may be used in fixed posts widely dispersed over the battlefield, or else mounted on specially adapted vehicles. An example of the latter is the M56 Coyote generator. Many
armoured fighting vehicles An armoured fighting vehicle (AFV) is an armed combat vehicle protected by armour, generally combining operational mobility with offensive and defensive capabilities. AFVs can be wheeled or tracked. Examples of AFVs are tanks, armoured c ...
can create smoke screens in a similar way, generally by injecting
diesel fuel Diesel fuel , also called diesel oil, is any liquid fuel specifically designed for use in a diesel engine, a type of internal combustion engine in which fuel ignition takes place without a spark as a result of compression of the inlet air and ...
onto the hot
exhaust Exhaust, exhaustive, or exhaustion may refer to: Law *Exhaustion of intellectual property rights, limits to intellectual property rights in patent and copyright law ** Exhaustion doctrine, in patent law ** Exhaustion doctrine under U.S. law, in ...
.


Naval methods

Warships have sometimes used a simple variation of the smoke generator, by injecting fuel oil directly into the funnel, where it evaporates into a white cloud. An even simpler method that was used in the days of steam-propelled warships was to restrict the supply of air to the boiler. This resulted in incomplete combustion of the coal or oil, which produced a thick black smoke. Because the smoke was black, it absorbed heat from the sun and tended to rise above the water. Therefore, navies turned to various chemicals, such as
titanium tetrachloride Titanium tetrachloride is the inorganic compound with the formula . It is an important intermediate in the production of titanium metal and the pigment titanium dioxide. is a volatile liquid. Upon contact with humid air, it forms thick clouds ...
, that produce a white, low-lying cloud.


Infrared smokes

The proliferation of
thermal imaging Infrared thermography (IRT), thermal video and/or thermal imaging, is a process where a thermal camera captures and creates an image of an object by using infrared radiation emitted from the object in a process, which are examples of infrared ...
FLIR Forward-looking infrared (FLIR) cameras, typically used on military and civilian aircraft, use a thermographic camera that senses infrared radiation. The sensors installed in forward-looking infrared cameras, as well as those of other thermal ...
systems on the battlefields necessitates the use of obscurant smokes that are effectively opaque in the
infrared Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of Light, visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from ...
part of electromagnetic spectrum. This kind of obscurant smoke is sometimes referred to as "Visual and Infrared Screening Smoke" (VIRSS). To achieve this, the particle size and composition of the smokes has to be adjusted. One of the approaches is using an aerosol of burning
red phosphorus Elemental phosphorus can exist in several allotropes, the most common of which are white and red solids. Solid violet and black allotropes are also known. Gaseous phosphorus exists as diphosphorus and atomic phosphorus. White phosphorus Whit ...
particles and
aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It ha ...
-coated glass fibers; the infrared emissions of such smoke curtains hides the weaker emissions of colder objects behind it, but the effect is only short-lived.
Carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon ma ...
(most often
graphite Graphite () is a crystalline form of the element carbon. It consists of stacked layers of graphene. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on la ...
) particles present in the smokes can also serve to absorb the beams of laser designators. Yet another possibility is a water
fog Fog is a visible aerosol consisting of tiny water droplets or ice crystals suspended in the air at or near the Earth's surface. Reprint from Fog can be considered a type of low-lying cloud usually resembling stratus, and is heavily influ ...
sprayed around the vehicle; the presence of large droplets absorbs in infrared band and additionally serves as a countermeasure against
radar Radar is a detection system that uses radio waves to determine the distance (''ranging''), angle, and radial velocity of objects relative to the site. It can be used to detect aircraft, Marine radar, ships, spacecraft, guided missiles, motor v ...
s in 94 GHz band. Other materials used as visible/infrared obscurants are micro-pulverized flakes of
brass Brass is an alloy of copper (Cu) and zinc (Zn), in proportions which can be varied to achieve different mechanical, electrical, and chemical properties. It is a substitutional alloy: atoms of the two constituents may replace each other wi ...
or
graphite Graphite () is a crystalline form of the element carbon. It consists of stacked layers of graphene. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on la ...
, particles of
titanium dioxide Titanium dioxide, also known as titanium(IV) oxide or titania , is the inorganic compound with the chemical formula . When used as a pigment, it is called titanium white, Pigment White 6 (PW6), or CI 77891. It is a white solid that is insolu ...
, or
terephthalic acid Terephthalic acid is an organic compound with formula C6H4(CO2H)2. This white solid is a commodity chemical, used principally as a precursor to the polyester PET, used to make clothing and plastic bottles. Several million tonnes are produced an ...
. Older systems for production of infrared smoke work as generators of
aerosol An aerosol is a suspension of fine solid particles or liquid droplets in air or another gas. Aerosols can be natural or anthropogenic. Examples of natural aerosols are fog or mist, dust, forest exudates, and geyser steam. Examples of anthropogen ...
of
dust Dust is made of fine particles of solid matter. On Earth, it generally consists of particles in the atmosphere that come from various sources such as soil lifted by wind (an aeolian process), volcanic eruptions, and pollution. Dust in ...
with controlled particle size. Most contemporary vehicle-mounted systems use this approach. However, the aerosol stays airborne only for a short time. The
brass Brass is an alloy of copper (Cu) and zinc (Zn), in proportions which can be varied to achieve different mechanical, electrical, and chemical properties. It is a substitutional alloy: atoms of the two constituents may replace each other wi ...
particles used in some infrared
smoke grenade Smoke grenades used at demonstrations in Paris, 2008 upBritish L83A1 Smoke Grenade manufactured in May 2008. This grenade has already been used. A smoke grenade is a canister-type grenade used as a signaling device, target or landing zone mark ...
s are typically composed of 70%
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pink ...
and 30%
zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
. They are shaped as irregular flakes with a diameter of about 1.7 µm and thickness of 80–320 nm. Some experimental obscurants work in both infrared and millimeter wave region. They include
carbon fiber Carbon fiber-reinforced polymers (American English), carbon-fibre-reinforced polymers (Commonwealth English), carbon-fiber-reinforced plastics, carbon-fiber reinforced-thermoplastic (CFRP, CRP, CFRTP), also known as carbon fiber, carbon compo ...
s, metal coated fibers or
glass Glass is a non- crystalline, often transparent, amorphous solid that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most often formed by rapid cooling (quenchin ...
particles, metal microwires, particles of iron and of suitable polymers.


Chemicals used


Zinc chloride

Zinc chloride smoke is grey-white and consists of tiny particles of
zinc chloride Zinc chloride is the name of inorganic chemical compounds with the formula ZnCl2 and its hydrates. Zinc chlorides, of which nine crystalline forms are known, are colorless or white, and are highly soluble in water. This salt is hygroscopic ...
. The most common mixture for generating these is a zinc chloride smoke mixture (HC), consisting of
hexachloroethane Hexachloroethane, also known as perchloroethane is the organochlorine compound with the chemical formula . It is white solid at room temperature with a camphor-like odor. It has been used by the military in smoke compositions, such as base-eject ...
, grained
aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It ha ...
and
zinc oxide Zinc oxide is an inorganic compound with the formula . It is a white powder that is insoluble in water. ZnO is used as an additive in numerous materials and products including cosmetics, food supplements, rubbers, plastics, ceramics, glass, cement ...
. The smoke consists of zinc chloride, zinc oxychlorides, and
hydrochloric acid Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride. It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid. It is a component of the gastric acid in the dige ...
, which absorb the
moisture Moisture is the presence of a liquid, especially water, often in trace amounts. Small amounts of water may be found, for example, in the air (humidity), in foods, and in some commercial products. Moisture also refers to the amount of water vapo ...
in the air. The smoke also contains traces of organic chlorinated compounds,
phosgene Phosgene is the organic chemical compound with the formula COCl2. It is a toxic, colorless gas; in low concentrations, its musty odor resembles that of freshly cut hay or grass. Phosgene is a valued and important industrial building block, esp ...
,
carbon monoxide Carbon monoxide ( chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simpl ...
, and
chlorine Chlorine is a chemical element with the symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine i ...
. Its toxicity is caused mainly by the content of strongly acidic hydrochloric acid, but also due to thermal effects of reaction of zinc chloride with water. These effects cause
lesion A lesion is any damage or abnormal change in the tissue of an organism, usually caused by disease or trauma. ''Lesion'' is derived from the Latin "injury". Lesions may occur in plants as well as animals. Types There is no designated classif ...
s of the
mucous membrane A mucous membrane or mucosa is a membrane that lines various cavities in the body of an organism and covers the surface of internal organs. It consists of one or more layers of epithelial cells overlying a layer of loose connective tissue. It i ...
s of the upper airways. Damage of the lower airways can manifest itself later as well, due to fine particles of zinc chloride and traces of phosgene. In high concentrations the smoke can be very dangerous when inhaled. Symptoms include
dyspnea Shortness of breath (SOB), also medically known as dyspnea (in AmE) or dyspnoea (in BrE), is an uncomfortable feeling of not being able to breathe well enough. The American Thoracic Society defines it as "a subjective experience of breathing di ...
, retrosternal pain, hoarseness,
stridor Stridor (Latin for "creaking or grating noise") is a high-pitched extra-thoracic breath sound resulting from turbulent air flow in the larynx or lower in the bronchial tree. It is different from a stertor which is a noise originating in the pha ...
,
lachrymation Tears are a clear liquid secreted by the lacrimal glands (tear gland) found in the eyes of all land mammals. Tears are made up of water, electrolytes, proteins, lipids, and mucins that form layers on the surface of eyes. The different types of ...
,
cough A cough is a sudden expulsion of air through the large breathing passages that can help clear them of fluids, irritants, foreign particles and microbes. As a protective reflex, coughing can be repetitive with the cough reflex following three ph ...
,
expectoration Sputum is mucus that is coughed up from the lower airways (the trachea and bronchi). In medicine, sputum samples are usually used for a naked eye examination, microbiological investigation of respiratory infections and cytological investigatio ...
, and in some cases
haemoptysis Hemoptysis is the coughing up of blood or blood-stained mucus from the bronchi, larynx, trachea, or lungs. In other words, it is the airway bleeding. This can occur with lung cancer, infections such as tuberculosis, bronchitis, or pneumonia, and ...
. Delayed
pulmonary edema Pulmonary edema, also known as pulmonary congestion, is excessive liquid accumulation in the tissue and air spaces (usually alveoli) of the lungs. It leads to impaired gas exchange and may cause hypoxemia and respiratory failure. It is due ...
,
cyanosis Cyanosis is the change of body tissue color to a bluish-purple hue as a result of having decreased amounts of oxygen bound to the hemoglobin in the red blood cells of the capillary bed. Body tissues that show cyanosis are usually in locations ...
or
bronchopneumonia Bronchopneumonia is a subtype of pneumonia. It is the acute inflammation of the bronchi, accompanied by inflamed patches in the nearby lobules of the lungs. citing: Webster's New World College Dictionary, Fifth Edition, Copyright 2014 It is ofte ...
may develop. The smoke and the spent canisters contain suspected
carcinogen A carcinogen is any substance, radionuclide, or radiation that promotes carcinogenesis (the formation of cancer). This may be due to the ability to damage the genome or to the disruption of cellular metabolic processes. Several radioactive sub ...
s. The prognosis for the casualties depends on the degree of the pulmonary damage. All exposed individuals should be kept under observation for 8 hours. Most affected individuals recover within several days, with some symptoms persisting for up to 1–2 weeks. Severe cases can suffer of reduced pulmonary function for some months, the worst cases developing marked dyspnoea and cyanosis leading to death. Respirators are required for people coming into contact with the zinc chloride smoke.


Chlorosulfuric acid

Chlorosulfuric acid Chlorosulfuric acid (IUPAC name: sulfurochloridic acid) is the inorganic compound with the formula HSO3Cl. It is also known as chlorosulfonic acid, being the sulfonic acid of chlorine. It is a distillable, colorless liquid which is hygroscopic an ...
(CSA) is a heavy, strongly acidic liquid. When dispensed in air, it readily absorbs moisture and forms dense white fog of
hydrochloric acid Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride. It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid. It is a component of the gastric acid in the dige ...
and
sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular fo ...
. In moderate concentrations it is highly irritating to eyes, nose, and skin. When chlorosulfuric acid comes in contact with water, a strong
exothermic In thermodynamics, an exothermic process () is a thermodynamic process or reaction that releases energy from the system to its surroundings, usually in the form of heat, but also in a form of light (e.g. a spark, flame, or flash), electricity ...
reaction scatters the corrosive mixture in all directions. CSA is highly corrosive, so careful handling is required. Low concentrations cause prickling sensations on the skin, but high concentrations or prolonged exposure to field concentrations can cause severe irritation of the eyes, skin, and respiratory tract, and mild cough and moderate
contact dermatitis Contact dermatitis is a type of acute or chronic inflammation of the skin caused by exposure to chemical or physical agents. Symptoms of contact dermatitis can include itchy or dry skin, a red rash, bumps, blisters, or swelling. These rashes are ...
can result. Liquid CSA causes acid burns of skin and exposure of eyes can lead to severe eye damage. Affected body parts should be washed with water and then with
sodium bicarbonate Sodium bicarbonate ( IUPAC name: sodium hydrogencarbonate), commonly known as baking soda or bicarbonate of soda, is a chemical compound with the formula NaHCO3. It is a salt composed of a sodium cation ( Na+) and a bicarbonate anion ( HCO3− ...
solution. The burns are then treated like thermal burns. The skin burns heal readily, while cornea burns can result in residual scarring. Respirators are required for any concentrations sufficient to cause any coughing, irritation of the eyes or prickling of the skin.


Titanium tetrachloride

Titanium tetrachloride Titanium tetrachloride is the inorganic compound with the formula . It is an important intermediate in the production of titanium metal and the pigment titanium dioxide. is a volatile liquid. Upon contact with humid air, it forms thick clouds ...
(FM) is a colorless, non-flammable, corrosive liquid. In contact with damp air it hydrolyzes readily, resulting in a dense white smoke consisting of droplets of hydrochloric acid and particles of titanium oxychloride. The titanium tetrachloride smoke is an irritant and unpleasant to breathe. It is dispensed from aircraft to create vertical smoke curtains, and during World War II it was a favorite smoke generation agent on warships. Goggles and a respirator should be worn when in contact with the smoke, full protective clothing should be worn when handling liquid FM. In direct contact with skin or eyes, liquid FM causes acid burns.


Phosphorus

Red
phosphorus Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Ea ...
and white phosphorus (WP) are red or waxy yellow or white substances. White phosphorus is
pyrophoric A substance is pyrophoric (from grc-gre, πυροφόρος, , 'fire-bearing') if it ignites spontaneously in air at or below (for gases) or within 5 minutes after coming into contact with air (for liquids and solids). Examples are organolith ...
- can be handled safely when under water, but in contact with air it spontaneously ignites. It is used as an incendiary. Both types of phosphorus are used for smoke generation, mostly in artillery shells, bombs, and grenades. White phosphorus smoke is typically very hot and may cause burns on contact. Red phosphorus is less reactive, does not ignite spontaneously, and its smoke does not cause thermal burns - for this reason it is safer to handle, but cannot be used so easily as an incendiary. Aerosol of burning phosphorus particles is an effective obscurant against
thermal imaging Infrared thermography (IRT), thermal video and/or thermal imaging, is a process where a thermal camera captures and creates an image of an object by using infrared radiation emitted from the object in a process, which are examples of infrared ...
systems. However, this effect is short-lived. After the phosphorus particles fully burn, the smoke reverts from emission to absorption. While very effective in the visible spectrum, cool phosphorus smoke has only low absorption and scattering in infrared wavelengths. Additives in the smoke that involve this part of the spectrum may be visible to thermal imagers or IR viewers.


Dyes

Various signalling purposes require the use of colored smoke. The smoke created is a fine mist of dye particles, generated by burning a mixture of one or more dyes with a low-temperature
pyrotechnic composition A pyrotechnic composition is a substance or mixture of substances designed to produce an effect by heat, light, sound, gas/smoke or a combination of these, as a result of non-detonative self-sustaining exothermic chemical reactions. Pyrotechnic s ...
, usually based on
potassium chlorate Potassium chlorate is a compound containing potassium, chlorine and oxygen, with the molecular formula KClO3. In its pure form, it is a white crystalline substance. After sodium chlorate, it is the second most common chlorate in industrial use. ...
and
lactose Lactose is a disaccharide sugar synthesized by galactose and glucose subunits and has the molecular formula C12H22O11. Lactose makes up around 2–8% of milk (by mass). The name comes from ' (gen. '), the Latin word for milk, plus the suffix ' ...
(also known as milk sugar). Colored smoke screen is also possible by adding a colored dye into the fog oil mixture. Typical white smoke screen uses titanium dioxide (or other white pigment), but other colors are possible by replacing titanium dioxide with another pigment. When the hot fog oil condenses on contact with air, the pigment particles are suspended along with the oil vapor. Early smoke screen experiments attempted the use of colored pigment, but found that titanium dioxide was the most light scattering particle known and therefore best for use in obscuring troops and naval vessels. Colored smoke became primarily used for signalling rather than obscuring. In today's military, smoke grenades are found to be non-cancer causing, unlike the 1950s AN-M8 model.


Sulfonic acid

The smoke generator on the Medium Mark B tank used
sulfonic acid In organic chemistry, sulfonic acid (or sulphonic acid) refers to a member of the class of organosulfur compounds with the general formula , where R is an organic alkyl or aryl group and the group a sulfonyl hydroxide. As a substituent, it is k ...


Tactics


History

The first recorded instance of the tactical use of a smoke screen has been at the
Battle of Macau The Battle of Macau in 1622 was a conflict of the Dutch–Portuguese War fought in the Portuguese settlement of Macau, in southeastern China. The Portuguese, outnumbered and without adequate fortification, managed to repel the Dutch in a much-ce ...
by the Dutch. A barrel of damp gunpowder was fired into the wind so that the Dutch could land under the cover of smoke.


Land warfare

Smoke screens are usually used by infantry to conceal their movement in areas of enemy fire. They can also be used by
armoured fighting vehicle An armoured fighting vehicle (AFV) is an armed combat vehicle protected by armour, generally combining operational mobility with offensive and defensive capabilities. AFVs can be wheeled or tracked. Examples of AFVs are tanks, armoured cars, ...
s, such as
tank A tank is an armoured fighting vehicle intended as a primary offensive weapon in front-line ground combat. Tank designs are a balance of heavy firepower, strong armour, and good battlefield mobility provided by tracks and a powerful ...
s, to conceal a withdrawal. They have regularly been used since earliest times to disorient or drive off attackers. A toxic variant of the smokescreen was used and devised by Frank Arthur Brock who used it during the
Zeebrugge Raid The Zeebrugge Raid ( nl, Aanval op de haven van Zeebrugge; ) on 23 April 1918, was an attempt by the Royal Navy to block the Belgian port of Bruges-Zeebrugge. The British intended to sink obsolete ships in the canal entrance, to prevent Germ ...
on 23 April 1918, the British Royal Navy's attempt to neutralize the key Belgian port of Bruges-
Zeebrugge Zeebrugge (, from: ''Brugge aan zee'' meaning "Bruges at Sea", french: Zeebruges) is a village on the coast of Belgium and a subdivision of Bruges, for which it is the modern port. Zeebrugge serves as both the international port of Bruges-Zee ...
. For the crossing of the
Dnieper river } The Dnieper () or Dnipro (); , ; . is one of the major transboundary rivers of Europe, rising in the Valdai Hills near Smolensk, Russia, before flowing through Belarus and Ukraine to the Black Sea. It is the longest river of Ukraine an ...
in October 1943, the
Red Army The Workers' and Peasants' Red Army (Russian language, Russian: Рабо́че-крестья́нская Кра́сная армия),) often shortened to the Red Army, was the army and air force of the Russian Soviet Federative Socialist R ...
laid a smoke screen long. At the Anzio beachhead in 1944, US Chemical Corps troops maintained a "light haze" smokescreen around the harbour throughout daylight hours, for two months. The density of this screen was adjusted to be sufficient to prevent observation by German forward observers in the surrounding hills, yet not inhibit port operations. In the Vietnam War "Smoke Ships" were introduced as part of a new Air Mobile Concept to protect crew and man on the ground from small arms fire. In 1964-65, the "Smoke Ship" was first employed by the 145th CAB using
UH-1B The Bell UH-1 Iroquois military helicopter, first introduced in 1959, is the first production member of the prolific Huey family of helicopters, and was itself developed in over twenty variants, which are listed below. XH-40 and YH-40 The firs ...
.


Naval warfare

There are a number of early examples of using incendiary weapons at sea, such as
Greek fire Greek fire was an incendiary weapon used by the Eastern Roman Empire beginning . Used to set fire to enemy ships, it consisted of a combustible compound emitted by a flame-throwing weapon. Some historians believe it could be ignited on contact w ...
, stinkpots,
fire ship A fire ship or fireship, used in the days of wooden rowed or sailing ships, was a ship filled with combustibles, or gunpowder deliberately set on fire and steered (or, when possible, allowed to drift) into an enemy fleet, in order to destroy sh ...
s, and incendiaries on the decks of turtle ships, which also had the effect of creating smoke. The naval smoke screen is often said to have been proposed by Sir Thomas Cochrane in 1812, although Cochrane's proposal was as much an asphyxiant as an obscurant. It is not until the early twentieth century that there is clear evidence of deliberate use of large scale naval smokescreens as a major tactic. During the
American Civil War The American Civil War (April 12, 1861 – May 26, 1865; also known by Names of the American Civil War, other names) was a civil war in the United States. It was fought between the Union (American Civil War), Union ("the North") and t ...
, the first smoke screen was used by the '' R.E. Lee'', running the blockade and escaping the . The use of smoke screens was common in the naval battles of
World War I World War I (28 July 1914 11 November 1918), often abbreviated as WWI, was List of wars and anthropogenic disasters by death toll, one of the deadliest global conflicts in history. Belligerents included much of Europe, the Russian Empire, ...
and
World War II World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the World War II by country, vast majority of the world's countries—including all of the great power ...
.


See also

*
Early thermal weapons Early thermal weapons, which used heat or burning action to destroy or damage enemy personnel, fortifications or territories, were employed in warfare during the classical and medieval periods (approximately the 8th century BC until the mid-16th ...
*
Military camouflage Military camouflage is the use of camouflage by an armed force to protect personnel and equipment from observation by enemy forces. In practice, this means applying colour and materials to military equipment of all kinds, including vehicles, ...
* PT boat *
Smoke bomb A smoke bomb is a firework designed to produce a large amount of smoke upon ignition. History Early Japanese history saw the use of a rudimentary form of the smoke bomb. Explosives were common in Japan during the Mongol invasions of the 13 ...


References


External links

* * {{DEFAULTSORT:Smoke Screen Weapons countermeasures Smoke Sniper warfare tactics Diversionary tactics