Salammoniac, also sal ammoniac or salmiac, is a rare naturally occurring mineral composed of ammonium chloride, NH₄Cl. It forms colorless, white, or yellow-brown crystals in the isometric-hexoctahedral class. It has very poor cleavage and is brittle to

conchoidal fracture Conchoidal fracture describes the way that brittle materials break or fracture when they do not follow any natural planes of separation. Mindat.org defines conchoidal fracture as follows: "a fracture with smooth, curved surfaces, typically slig ...

. It is quite soft, with a

Mohs hardness The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. The scale was introduced in 1812 by ...

of 1.5 to 2, and it has a low

specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water at its dens ...

of 1.5. It is water-soluble. Sal ammoniac is also the archaic name for the chemical compound ammonium chloride. Pliny, in Book XXXI of his '' Natural History'', refers to a salt produced in the Roman province of

Cyrenaica Cyrenaica ( ) or Kyrenaika ( ar, برقة, Barqah, grc-koi, Κυρηναϊκή ��παρχίαKurēnaïkḗ parkhíā}, after the city of Cyrene), is the eastern region of Libya. Cyrenaica includes all of the eastern part of Libya between ...

named ''hammoniacum'', so called because of its proximity to the nearby Temple of Jupiter Amun (

Greek Greek may refer to: Greece Anything of, from, or related to Greece, a country in Southern Europe: *Greeks, an ethnic group. *Greek language, a branch of the Indo-European language family. **Proto-Greek language, the assumed last common ancestor ...

Ἄμμων ''Ammon''). However, the description Pliny gives of the salt does not conform to the properties of ammonium chloride. According to Herbert Hoover's commentary in his English translation of Georgius Agricola's '' De re metallica'', it is likely to have been common sea salt. In any case, that salt ultimately gave

ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous ...

and

ammonium The ammonium cation is a positively-charged polyatomic ion with the chemical formula or . It is formed by the protonation of ammonia (). Ammonium is also a general name for positively charged or protonated substituted amines and quaterna ...

compounds their name. The first attested reference to ''sal ammoniac'' as ammonium chloride is in the

Pseudo-Geber Pseudo-Geber (or "Latin pseudo-Geber") is the presumed author or group of authors responsible for a corpus of pseudepigraphic alchemical writings dating to the late 13th and early 14th centuries. These writings were falsely attributed to Jabir ...

work ''De inventione veritatis'', where a preparation of sal ammoniac is given in the chapter ''De Salis armoniaci præparatione'', ''salis armoniaci'' being a common name in the Middle Ages for sal ammoniac. It typically forms as encrustations formed by sublimation around

volcanic A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. On Earth, volcanoes are most often found where tectonic plat ...

vents and is found around volcanic

fumarole A fumarole (or fumerole) is a vent in the surface of the Earth or other rocky planet from which hot volcanic gases and vapors are emitted, without any accompanying liquids or solids. Fumaroles are characteristic of the late stages of volcani ...

guano Guano (Spanish from qu, wanu) is the accumulated excrement of seabirds or bats. As a manure, guano is a highly effective fertilizer due to the high content of nitrogen, phosphate, and potassium, all key nutrients essential for plant growth. G ...

deposits and burning

coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when ...

seams. Associated minerals include sodium

alum An alum () is a type of chemical compound, usually a hydrated double sulfate salt of aluminium with the general formula , where is a monovalent cation such as potassium or ammonium. By itself, "alum" often refers to potassium alum, with the ...

, native

sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formul ...

and other

fumarole mineral Fumarole minerals are minerals which are deposited by fumarole exhalations. They form when gases and compounds desublimate or precipitate out of condensates, forming mineral deposits. They are mostly associated with volcanoes (as volcanic sublimat ...

s. Notable occurrences include

Tajikistan Tajikistan (, ; tg, Тоҷикистон, Tojikiston; russian: Таджикистан, Tadzhikistan), officially the Republic of Tajikistan ( tg, Ҷумҳурии Тоҷикистон, Jumhurii Tojikiston), is a landlocked country in Centr ...

;

Mount Vesuvius Mount Vesuvius ( ; it, Vesuvio ; nap, 'O Vesuvio , also or ; la, Vesuvius , also , or ) is a somma-stratovolcano located on the Gulf of Naples in Campania, Italy, about east of Naples and a short distance from the shore. It is one of ...

Italy Italy ( it, Italia ), officially the Italian Republic, ) or the Republic of Italy, is a country in Southern Europe. It is located in the middle of the Mediterranean Sea, and its territory largely coincides with the homonymous geographical ...

; and

Parícutin Parícutin (or Volcán de Parícutin, also accented Paricutín) is a cinder cone volcano located in the Mexican state of Michoacán, near the city of Uruapan and about west of Mexico City. The volcano surged suddenly from the cornfield of loca ...

, Michoacan, Mexico.

Uses

It is commonly used to clean the

soldering iron A soldering iron is a hand tool used in soldering. It supplies heat to melt solder so that it can flow into the joint between two workpieces. A soldering iron is composed of a heated metal tip (the ''bit'') and an insulated handle. Heating ...

in the soldering of stained-glass windows.

Metal refining

In jewellery-making and the refining of precious metals,

potassium carbonate Potassium carbonate is the inorganic compound with the formula K2 CO3. It is a white salt, which is soluble in water. It is deliquescent, often appearing as a damp or wet solid. Potassium carbonate is mainly used in the production of soap and gl ...

is added to gold and silver in a

borax Borax is a salt (ionic compound), a hydrated borate of sodium, with chemical formula often written . It is a colorless crystalline solid, that dissolves in water to make a basic solution. It is commonly available in powder or granular form ...

-coated crucible to purify iron or steel filings that may have contaminated the scrap. It is then air-cooled and remelted with a one-to-one mixture of powdered

charcoal Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, ...

and sal ammoniac to yield a sturdy ingot of the respective metal or alloy in the case of sterling silver (7.5% copper) or karated gold.

Bakery

Sal ammoniac has also been used in the past in bakery products to give

cookies A cookie is a baked or cooked snack or dessert that is typically small, flat and sweet. It usually contains flour, sugar, egg, and some type of oil, fat, or butter. It may include other ingredients such as raisins, oats, chocolate chi ...

or biscuits their crisp texture, but the application of food grade baking ammonia (

ammonium carbonate Ammonium carbonate is a salt with the chemical formula (NH4)2CO3. Since it readily degrades to gaseous ammonia and carbon dioxide upon heating, it is used as a leavening agent and also as smelling salt. It is also known as baker's ammonia and is ...

or (NH₄)₂CO₃) is generally being substituted with the creation of modern

baking powder Baking powder is a dry chemical leavening agent, a mixture of a carbonate or bicarbonate and a weak acid. The base and acid are prevented from reacting prematurely by the inclusion of a buffer such as cornstarch. Baking powder is used to increas ...

or baking soda (

sodium bicarbonate Sodium bicarbonate ( IUPAC name: sodium hydrogencarbonate), commonly known as baking soda or bicarbonate of soda, is a chemical compound with the formula NaHCO3. It is a salt composed of a sodium cation ( Na+) and a bicarbonate anion ( HCO3− ...

). Sal ammoniac is known, inter alia, by its use in salmiac

liquorice Liquorice (British English) or licorice (American English) ( ; also ) is the common name of ''Glycyrrhiza glabra'', a flowering plant of the bean family Fabaceae, from the root of which a sweet, aromatic flavouring can be extracted. The liqu ...

, for instance salty liquorice or salmiak

pastilles A pastille is a type of sweet or medicinal pill made of a thick liquid that has been solidified and is meant to be consumed by light chewing and allowing it to dissolve in the mouth. The term is also used to describe certain forms of incense. ...

Dyeing

In addition, the mineral or, better, its synthetic counterpart, also serves for the production of cooling baths as well as in

dyeing Dyeing is the application of dyes or pigments on textile materials such as fibers, yarns, and fabrics with the goal of achieving color with desired color fastness. Dyeing is normally done in a special solution containing dyes and particular c ...

and

leather tanning Tanning is the process of treating skins and hides of animals to produce leather. A tannery is the place where the skins are processed. Tanning hide into leather involves a process which permanently alters the protein structure of skin, makin ...

. Sal ammoniac (ammonium chloride) was the electrolyte in

Leclanché cell The Leclanché cell is a battery invented and patented by the French scientist Georges Leclanché in 1866. The battery contained a conducting solution (electrolyte) of ammonium chloride, a cathode (positive terminal) of carbon, a depolarizer of ...

s, a forerunner of the dry battery; a

carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon ma ...

rod and a

zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...

rod or cylinder formed the electrodes.

Medicine

It was also brought into pharmacopeias by Islamic physicians for medicinal purposes.

References

External links

* {{commons category-inline, Salammoniac
Mineral galleries
Ammonium minerals Cubic minerals Minerals in space group 221 Halide minerals