Red beds (or redbeds) are
sedimentary rocks
Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particle ...
, typically consisting of
sandstone
Sandstone is a clastic sedimentary rock composed mainly of sand-sized (0.0625 to 2 mm) silicate grains. Sandstones comprise about 20–25% of all sedimentary rocks.
Most sandstone is composed of quartz or feldspar (both silicat ...
,
siltstone
Siltstone, also known as aleurolite, is a clastic sedimentary rock that is composed mostly of silt. It is a form of mudrock with a low clay mineral content, which can be distinguished from shale by its lack of fissility.Blatt ''et al.'' 1980, ...
, and
shale, that are predominantly red in color due to the presence of
ferric oxide
Iron(III) oxide or ferric oxide is the inorganic compound with the formula Fe2O3. It is one of the three main oxides of iron, the other two being iron(II) oxide (FeO), which is rare; and iron(II,III) oxide (Fe3O4), which also occurs naturall ...
s. Frequently, these red-colored sedimentary strata locally contain thin beds of
conglomerate
Conglomerate or conglomeration may refer to:
* Conglomerate (company)
* Conglomerate (geology)
* Conglomerate (mathematics)
In popular culture:
* The Conglomerate (American group), a production crew and musical group founded by Busta Rhymes
** ...
,
marl,
limestone
Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms w ...
, or some combination of these sedimentary rocks. The ferric oxides, which are responsible for the red color of red beds, typically occur as a coating on the grains of sediments comprising red beds. Classic examples of red beds are the
Permian
The Permian ( ) is a geologic period and stratigraphic system which spans 47 million years from the end of the Carboniferous Period million years ago (Mya), to the beginning of the Triassic Period 251.9 Mya. It is the last period of the Paleo ...
and
Triassic
The Triassic ( ) is a geologic period and system which spans 50.6 million years from the end of the Permian Period 251.902 million years ago ( Mya), to the beginning of the Jurassic Period 201.36 Mya. The Triassic is the first and shortest per ...
strata of the western United States and the
Devonian
The Devonian ( ) is a geologic period and system of the Paleozoic era, spanning 60.3 million years from the end of the Silurian, million years ago (Mya), to the beginning of the Carboniferous, Mya. It is named after Devon, England, wh ...
Old Red Sandstone facies
In geology, a facies ( , ; same pronunciation and spelling in the plural) is a body of rock with specified characteristics, which can be any observable attribute of rocks (such as their overall appearance, composition, or condition of formatio ...
of Europe.
Primary red beds
Primary red beds may be formed by the erosion and redeposition of red soils or older red beds, but a fundamental problem with this hypothesis is the relative scarcity of red-colored source sediments of suitable age close to an area of red-bed sediments in
Cheshire
Cheshire ( ) is a ceremonial and historic county in North West England, bordered by Wales to the west, Merseyside and Greater Manchester to the north, Derbyshire to the east, and Staffordshire and Shropshire to the south. Cheshire's county tow ...
, England. Primary red beds may also form by in situ (early
diagenetic) reddening of the sediment by the dehydration of brown or drab colored ferric hydroxides. These ferric hydroxides commonly include
goethite (FeO-OH) and so-called "amorphous ferric hydroxide" or
limonite. Much of this material may be the mineral
ferrihydrite
Ferrihydrite (Fh) is a widespread hydrous ferric oxyhydroxide mineral at the Earth's surface, and a likely constituent in extraterrestrial materials. It forms in several types of environments, from freshwater to marine systems, aquifers to hy ...
(Fe
2O
3 H
2O).
This dehydration or "aging" process has been found to be intimately associated with
pedogenesis in
alluvial
Alluvium (from Latin ''alluvius'', from ''alluere'' 'to wash against') is loose clay, silt, sand, or gravel that has been deposited by running water in a stream bed, on a floodplain, in an alluvial fan or beach, or in similar settings. ...
floodplain
A floodplain or flood plain or bottomlands is an area of land adjacent to a river which stretches from the banks of its channel to the base of the enclosing valley walls, and which experiences flooding during periods of high discharge.Goudi ...
s and
desert
A desert is a barren area of landscape where little precipitation occurs and, consequently, living conditions are hostile for plant and animal life. The lack of vegetation exposes the unprotected surface of the ground to denudation. About on ...
environments.
Goethite (ferric hydroxide) is normally unstable relative to
hematite
Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
and, in the absence of water or at elevated temperature, will readily dehydrate according to the reaction:
:2FeOOH (goethite)→ Fe
2O
3 (hematite) +H
2O
The
Gibbs free energy
In thermodynamics, the Gibbs free energy (or Gibbs energy; symbol G) is a thermodynamic potential that can be used to calculate the maximum amount of work that may be performed by a thermodynamically closed system at constant temperature an ...
(G) for the reaction goethite → hematite (at 250 °C) is −2.76 kJ/mol and G becomes increasingly negative with smaller particle size. Thus detrital ferric hydroxides, including goethite and ferrihydrite, will spontaneously transform into red-colored hematite pigment with time. This process not only accounts for the progressive reddening of alluvium but also the fact that older desert dune sands are more intensely reddened than their younger equivalents.
Diagenetic red beds
Red beds may form during
diagenesis. The key to this mechanism is the
intrastratal alteration of
ferromagnesian silicates
In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name ...
by oxygenated
groundwater
Groundwater is the water present beneath Earth's surface in rock and Pore space in soil, soil pore spaces and in the fractures of stratum, rock formations. About 30 percent of all readily available freshwater in the world is groundwater. A unit ...
s during burial. Walker's studies show that the
hydrolysis
Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution, elimination, and solvation reactions in which water is the nucleophile.
Biological hydrolysi ...
of
hornblende and other iron-bearing detritus follows
Goldich dissolution series. This is controlled by the
Gibbs free energy
In thermodynamics, the Gibbs free energy (or Gibbs energy; symbol G) is a thermodynamic potential that can be used to calculate the maximum amount of work that may be performed by a thermodynamically closed system at constant temperature an ...
of the particular reaction. For example, the most easily altered material would be
olivine
The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers qui ...
: e.g.
:Fe
2SiO
4 (fayalite) + O
2 → Fe
2O
3 (hematite) + SiO
2 (quartz) with E = -27.53 kJ/mol
A key feature of this process, and exemplified by the reaction, is the production of a suite of by-products which are precipitated as
authigenic
Authigenesis is the process whereby a mineral or sedimentary rock deposit is generated where it is found or observed. Such deposits are described as authigenic. Authigenic sedimentary minerals form during sedimentation by precipitation or rec ...
phases. These include mixed layer clays (
illite –
montmorillonite),
quartz
Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical f ...
,
potassium feldspar and
carbonates as well as the pigmentary
ferric oxide
Iron(III) oxide or ferric oxide is the inorganic compound with the formula Fe2O3. It is one of the three main oxides of iron, the other two being iron(II) oxide (FeO), which is rare; and iron(II,III) oxide (Fe3O4), which also occurs naturall ...
s. Reddening progresses as the diagenetic alteration becomes more advanced, and is thus a time-dependent mechanism. The other implication is that reddening of this type is not specific to a particular
depositional environment. However, the favourable conditions for diagenetic red bed formation i.e. positive
Eh and neutral-alkaline
pH are most commonly found in hot, semi-arid areas, and this is why red beds are traditionally associated with such climates.
Secondary red beds
Secondary red beds are characterized by irregular color zonation, often related to sub-
unconformity
An unconformity is a buried erosional or non-depositional surface separating two rock masses or strata of different ages, indicating that sediment deposition was not continuous. In general, the older layer was exposed to erosion for an interval ...
weathering
Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs '' in situ'' (on site, with little or no movement ...
profiles. The color boundaries may cross-cut lithological contacts and show more intense reddening adjacent to unconformities. Secondary reddening phases might be superimposed on earlier formed primary red beds in the
Carboniferous
The Carboniferous ( ) is a geologic period and system of the Paleozoic that spans 60 million years from the end of the Devonian Period million years ago ( Mya), to the beginning of the Permian Period, million years ago. The name ''Carboniferou ...
of the southern
North Sea
The North Sea lies between Great Britain, Norway, Denmark, Germany, the Netherlands and Belgium. An epeiric sea on the European continental shelf, it connects to the Atlantic Ocean through the English Channel in the south and the Norwegian ...
. Post-diagenetic alteration may take place through reactions such as
pyrite
The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral.
Pyrite's metallic Luster (mineralogy), lust ...
oxidation:
:3O
2 + 4FeS
2→ Fe
2O
3 (hematite) + 8S E = −789 kJ/mol
and
siderite oxidation:
:O
2 + 4FeCO
3 → 2Fe
2O
3 (hematite) + 4CO
2 E = −346 kJ/mol
Secondary red beds formed in this way are an excellent example of
telodiagenesis. They are linked to the
uplift
Uplift may refer to: Science
* Geologic uplift, a geological process
** Tectonic uplift, a geological process
* Stellar uplift, the theoretical prospect of moving a stellar mass
* Uplift mountains
* Llano Uplift
* Nemaha Uplift
Business
* Upli ...
, erosion and surface weathering of previously deposited sediments and require conditions similar to primary and diagenetic red beds for their formation.
See also
*
Red Beds of Texas and Oklahoma
*
Chugwater Formation
*
Red Hills, Kansas
*
Old Red Sandstone
*
New Red Sandstone
The New Red Sandstone, chiefly in British geology, is composed of beds of red sandstone and associated rocks laid down throughout the Permian (300 million years ago) to the end of the Triassic (about 200 million years ago), that under ...
References
{{reflist
External links
Pictures of Permo-Triassic red beds in Palo Duro Canyon
Sedimentary rocks