putty
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Putty is a material with high plasticity, similar in texture to
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay part ...
or dough, typically used in domestic construction and repair as a sealant or filler. Although some types of putty (typically those using
linseed oil Linseed oil, also known as flaxseed oil or flax oil (in its edible form), is a colourless to yellowish oil obtained from the dried, ripened seeds of the flax plant (''Linum usitatissimum''). The oil is obtained by Expeller pressing, pressing, some ...
) slowly polymerise and become stiff, many putties can be reworked indefinitely, in contrast to other types of filler which typically set solid relatively rapidly.


Chemical composition

Putty, or lime putty, is made from a mixture of calcium oxide (CaO) and water (H2O) in proportions of 38% and 62% by weight respectively, as result, the solution forms hydrated lime (Ca(OH)2) which takes up about a half of the weight. The other putty mixture may be a calcium carbonate (CaCO3, 750-850 parts) based with a admixtures of CaO (ash calcium, 120-180 parts), white cement (40-60 parts), and talc powders in much lower concentrations (fractions).


Applications


Use in construction

Putty has been used extensively in glazing for fixing and sealing panes of glass into wooden frames (or sashes), although its use is decreasing with the prevalence of PVC and metal window frames which use synthetic sealants such as silicone. Glazing putty is traditionally made by mixing a base of whiting (finely ground
chalk Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral calcite and originally formed deep under the sea by the compression of microscopic plankton that had settled to the sea floor. Cha ...
) with
linseed oil Linseed oil, also known as flaxseed oil or flax oil (in its edible form), is a colourless to yellowish oil obtained from the dried, ripened seeds of the flax plant (''Linum usitatissimum''). The oil is obtained by Expeller pressing, pressing, some ...
in various proportions. Historically, white lead was sometimes mixed with the whiting.Paul N. Hasluck, Ed.
The Handyman's Enquire Within
Cassel and Co., 1908; page 439.
There are a number of synthetic alternatives such as
polybutene Polybutene is an organic polymer made from a mixture of 1-butene, 2-butene, and isobutylene. Ethylene steam cracker C4s are also used as supplemental feed for polybutene. It is similar to polyisobutylene (PIB), which is produced from essentiall ...
-based putties, where the polybutene is a low
molecular weight A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bioch ...
oligomer In chemistry and biochemistry, an oligomer () is a molecule that consists of a few repeating units which could be derived, actually or conceptually, from smaller molecules, monomers.Quote: ''Oligomer molecule: A molecule of intermediate relat ...
replacing the
linseed oil Linseed oil, also known as flaxseed oil or flax oil (in its edible form), is a colourless to yellowish oil obtained from the dried, ripened seeds of the flax plant (''Linum usitatissimum''). The oil is obtained by Expeller pressing, pressing, some ...
.
Butyl rubber Butyl rubber, sometimes just called "butyl", is a synthetic rubber, a copolymer of isobutylene with isoprene. The abbreviation IIR stands for isobutylene isoprene rubber. Polyisobutylene, also known as "PIB" or polyisobutene, (C4H8)n, is the ...
is also added to the mixture to provide some strength and flexibility. Painter's putty is typically a
linseed oil Linseed oil, also known as flaxseed oil or flax oil (in its edible form), is a colourless to yellowish oil obtained from the dried, ripened seeds of the flax plant (''Linum usitatissimum''). The oil is obtained by Expeller pressing, pressing, some ...
-based product used for filling holes, minor cracks, and defacements in wood only. Putties can also be made
intumescent An intumescent is a substance that swells as a result of heat exposure, leading to an increase in volume and decrease in density. Intumescent materials are typically used in passive fire protection and require listing, approval, and compliance in ...
, in which case they are used for
firestop A firestop or fire-stopping is a form of passive fire protection that is used to seal around openings and between joints in a fire-resistance-rated wall or floor assembly. Firestops are designed to maintain the fire-resistance rating of a wal ...
ping as well as for padding of electrical outlet boxes in fire-resistance rated
drywall Drywall (also called plasterboard, dry lining, wallboard, sheet rock, gypsum board, buster board, custard board, and gypsum panel) is a panel made of calcium sulfate dihydrate (gypsum), with or without additives, typically extruded between thi ...
assemblies. In the latter case, hydrates in the putty produce an
endothermic reaction In thermochemistry, an endothermic process () is any thermodynamic process with an increase in the enthalpy (or internal energy ) of the system.Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).''Principle of Modern Chemistry'', Brooks Cole. ...
to mitigate
heat In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is ...
transfer to the unexposed side. In
woodworking Woodworking is the skill of making items from wood, and includes cabinet making (cabinetry and furniture), wood carving, joinery, carpentry, and woodturning. History Along with stone, clay and animal parts, wood was one of the first mate ...
, water-based putties are more commonly used, as these emit very little odour, are more easily cleaned up and are compatible with water-based and latex sealers.


Polyester based putty

Polyester putty and epoxy putty are plastics that can be molded by hand but become stiff and hard after curing. Pratley Putty is an epoxy putty used primarily for steel bonding. Milliput is another epoxy putty. Bondo is a polyester putty.


Plumber's putty

Plumber's putty is the common name encompassing a variety of products of completely different compositions, all used for making watertight seals in plumbing. It is a pliable substance used to make watertight seals around faucets and drains. The putty is a basic component of a plumber's toolkit and is often used when replacing plumbing fixtures. Plumber's putty formulations vary but commonly include powdered
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay part ...
and
linseed oil Linseed oil, also known as flaxseed oil or flax oil (in its edible form), is a colourless to yellowish oil obtained from the dried, ripened seeds of the flax plant (''Linum usitatissimum''). The oil is obtained by Expeller pressing, pressing, some ...
. Other formulas use
limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms wh ...
, talc, or fish oil. RTV silicone or
epoxy Epoxy is the family of basic components or Curing (chemistry), cured end products of epoxy resins. Epoxy resins, also known as polyepoxides, are a class of reactive prepolymers and polymers which contain epoxide groups. The epoxide functional ...
sealants may be used in place of putty. Plumber's putty contains
mineral oil Mineral oil is any of various colorless, odorless, light mixtures of higher alkanes from a mineral source, particularly a distillate of petroleum, as distinct from usually edible vegetable oils. The name 'mineral oil' by itself is imprecise, ...
s and/or
vegetable oil Vegetable oils, or vegetable fats, are oils extracted from seeds or from other parts of fruits. Like animal fats, vegetable fats are ''mixtures'' of triglycerides. Soybean oil, grape seed oil, and cocoa butter are examples of seed oils, ...
s so it can stain porous materials such as marble or some plastics.


Other uses

Certain types of putty also have use in the field of terminal ballistics, where the putty can accurately represent the average density of the human body. As such it can be used, for instance, to test the penetrative power of projectiles, or the stopping power of body armour. Modeling clay and play putty, such as Plasticine and Silly Putty are common toys. Silly Putty comes packaged in plastic eggs.


See also

* Blu Tack *
Caulk Caulk or, less frequently, caulking is a material used to seal joints or seams against leakage in various structures and piping. The oldest form of caulk consisted of fibrous materials driven into the wedge-shaped seams between boards on ...
* Grain filler * Rope caulk * Spackling paste * Wood putty * Whitewash


References

* {{cite EB1911 , wstitle=Putty , volume=22 , short=x
Putty & Mastic
at wiki.DIY FAQ.org.uk Materials Passive fire protection Firestops