HOME

TheInfoList



OR:

Silicate minerals are rock-forming
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...
s made up of
silicate In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is a ...
groups. They are the largest and most important class of minerals and make up approximately 90 percent of
Earth's crust Earth's crust is Earth's thin outer shell of rock, referring to less than 1% of Earth's radius and volume. It is the top component of the lithosphere, a division of Earth's layers that includes the crust and the upper part of the mantle. The ...
. In
mineralogy Mineralogy is a subject of geology specializing in the scientific study of the chemistry, crystal structure, and physical (including optical) properties of minerals and mineralized artifacts. Specific studies within mineralogy include the proce ...
,
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is ...
(silicon dioxide, ) is usually considered a silicate mineral. Silica is found in nature as the mineral
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical f ...
, and its polymorphs. On Earth, a wide variety of silicate minerals occur in an even wider range of combinations as a result of the processes that have been forming and re-working the crust for billions of years. These processes include partial
melting Melting, or fusion, is a physical process that results in the phase transition of a substance from a solid to a liquid. This occurs when the internal energy of the solid increases, typically by the application of heat or pressure, which in ...
,
crystallization Crystallization is the process by which solid forms, where the atoms or molecules are highly organized into a structure known as a crystal. Some ways by which crystals form are precipitating from a solution, freezing, or more rarely deposi ...
, fractionation,
metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of ch ...
,
weathering Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs '' in situ'' (on site, with little or no movement ...
, and
diagenesis Diagenesis () is the process that describes physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a ...
. Living organisms also contribute to this geologic cycle. For example, a type of
plankton Plankton are the diverse collection of organisms found in water (or air) that are unable to propel themselves against a current (or wind). The individual organisms constituting plankton are called plankters. In the ocean, they provide a cruc ...
known as
diatom A diatom ( Neo-Latin ''diatoma''), "a cutting through, a severance", from el, διάτομος, diátomos, "cut in half, divided equally" from el, διατέμνω, diatémno, "to cut in twain". is any member of a large group comprising se ...
s construct their
exoskeleton An exoskeleton (from Greek ''éxō'' "outer" and ''skeletós'' "skeleton") is an external skeleton that supports and protects an animal's body, in contrast to an internal skeleton ( endoskeleton) in for example, a human. In usage, some of the ...
s ("frustules") from silica extracted from
seawater Seawater, or salt water, is water from a sea or ocean. On average, seawater in the world's oceans has a salinity of about 3.5% (35 g/L, 35 ppt, 600 mM). This means that every kilogram (roughly one liter by volume) of seawater has appro ...
. The frustules of dead diatoms are a major constituent of deep ocean
sediment Sediment is a naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of wind, water, or ice or by the force of gravity acting on the particles. For example, sand ...
, and of
diatomaceous earth Diatomaceous earth (), diatomite (), or kieselgur/kieselguhr is a naturally occurring, soft, siliceous sedimentary rock that can be crumbled into a fine white to off-white powder. It has a particle size ranging from more than 3 μm to l ...
.


General structure

A silicate mineral is generally an
inorganic compound In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemis ...
consisting of subunits with the formula iO2+nsup>2n-. Although depicted as such, the description of silicates as anions is a simplification. Balancing the charges of the silicate anions are metal cations, Mx+. Typical cations are Mg2+, Fe2+, and Na+. The Si-O-M linkage between the silicates and the metals are strong, polar-covalent bonds. Silicate anions ( iO2+nsup>2n-) are invariably colorless, or when crushed to a fine powder, white. The colors of silicate minerals arise from the metal component, commonly iron. In most silicate minerals, silicon is tetrahedral, being surrounded by four oxides. The coordination number of the oxides is variable except when it bridges two silicon centers, in which case the oxide has a coordination number of two. Some silicon centers may be replaced by atoms of other elements, still bound to the four corner oxygen corners. If the substituted atom is not normally tetravalent, it usually contributes extra charge to the anion, which then requires extra
cation An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...
s. For example, in the mineral
orthoclase Orthoclase, or orthoclase feldspar ( endmember formula K Al Si3 O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture," because its two cleavage planes are at right angles ...
, the anion is a tridimensional network of tetrahedra in which all oxygen corners are shared. If all tetrahedra had silicon centers, the anion would be just neutral silica . Replacement of one in every four silicon atoms by an
aluminum Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It ha ...
atom results in the anion , whose charge is neutralized by the
potassium Potassium is the chemical element with the symbol K (from Neo-Latin '' kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmos ...
cations .


Main groups

In
mineralogy Mineralogy is a subject of geology specializing in the scientific study of the chemistry, crystal structure, and physical (including optical) properties of minerals and mineralized artifacts. Specific studies within mineralogy include the proce ...
, silicate minerals are classified into seven major groups according to the structure of their silicate anion:Hurlbut, Cornelius S.; Klein, Cornelis , , 1985). ''Manual of Mineralogy'', Wiley, (20th edition ed.). Note that tectosilicates can only have additional cations if some of the silicon is replaced by an atom of lower valence such as aluminum. Al for Si substitution is common.


Nesosilicates or orthosilicates

Nesosilicates (from Greek 'island'), or orthosilicates, have the orthosilicate ion, which constitute isolated (insular)
tetrahedra In geometry, a tetrahedron (plural: tetrahedra or tetrahedrons), also known as a triangular pyramid, is a polyhedron composed of four triangular faces, six straight edges, and four vertex corners. The tetrahedron is the simplest of all th ...
that are connected only by interstitial
cation An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...
s. The Nickel–Strunz classification is 09.A –examples include: *Phenakite group ** Phenakite – **
Willemite Willemite is a zinc silicate mineral () and a minor ore of zinc. It is highly fluorescent (green) under shortwave ultraviolet light. It occurs in a variety of colors in daylight, in fibrous masses and apple-green gemmy masses. Troostite is a v ...
– *
Olivine The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers qui ...
group ** Forsterite – **
Fayalite Fayalite (, commonly abbreviated to Fa) is the iron-rich end-member of the olivine solid-solution series. In common with all minerals in the olivine group, fayalite crystallizes in the orthorhombic system (space group ''Pbnm'') with cell parame ...
– **
Tephroite Tephroite is the manganese endmember of the olivine group of nesosilicate minerals with the formula Mn2 Si O4. A solid solution series exists between tephroite and its analogues, the group endmembers fayalite and forsterite. Divalent iron ...
– *
Garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. All species of garnets possess similar physical properties and crystal forms, but differ in chemical composition. The different ...
group ** Pyrope – **
Almandine Almandine (), also known as almandite, is a species of mineral belonging to the garnet group. The name is a corruption of alabandicus, which is the name applied by Pliny the Elder to a stone found or worked at Alabanda, a town in Caria in Asi ...
– ** Spessartine – ** Grossular – **
Andradite Andradite is a mineral species of the garnet group. It is a nesosilicate, with formula Ca3Fe2Si3O12. Andradite includes three varieties: * ''Melanite'': Black in color, referred to as "titanian andradite".Uvarovite – **
Hydrogrossular Hydrogrossular is a calcium aluminium garnet series (formula: Ca3Al2(SiO4)3−''x''(OH)4''x'', with hydroxide (OH) partially replacing silica (SiO4)). The endmembers of the hydrogarnet family (grossular, hibschite, and katoite) depend on the deg ...
– *Zircon group **
Zircon Zircon () is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is Zr SiO4. An empirical formula showing some of t ...
– ** Thorite – **
Hafnon Hafnon is a hafnium nesosilicate mineral, chemical formula or . In natural zircon part of the zirconium is replaced by the very similar hafnium and so natural zircon is never pure . A zircon with 100% hafnium substitution can be made synthetical ...
– * group ** Andalusite – **
Kyanite Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure polymorph of andalusite and sillimanite, and the presence of kyanite in metamorphic rocks gener ...
– **
Sillimanite Sillimanite is an aluminosilicate mineral with the chemical formula Al2SiO5. Sillimanite is named after the American chemist Benjamin Silliman (1779–1864). It was first described in 1824 for an occurrence in Chester, Connecticut. Occurrence ...
– ** Dumortierite – **
Topaz Topaz is a silicate mineral of aluminium and fluorine with the chemical formula Al Si O( F, OH). It is used as a gemstone in jewelry and other adornments. Common topaz in its natural state is colorless, though trace element impurities can mak ...
– **
Staurolite Staurolite is a reddish brown to black, mostly opaque, nesosilicate mineral with a white streak. It crystallizes in the monoclinic crystal system, has a Mohs hardness of 7 to 7.5 and the chemical formula: Fe2+2Al9O6(SiO4)4(O,OH)2. Magnesium, ...
– * Humite group – **
Norbergite Norbergite is a nesosilicate mineral with formula Mg3( Si O4)( F, OH)2. It is a member of the humite group. It was first described in 1926 for an occurrence in the Östanmoss iron mine in Norberg, Västmanland, Sweden, for which it is named. ...
– ** Chondrodite – ** Humite – ** Clinohumite – * Datolite – *
Titanite Titanite, or sphene (from the Greek ''sphenos'' (σφηνώ), meaning wedge), is a calcium titanium nesosilicate mineral, Ca Ti Si O5. Trace impurities of iron and aluminium are typically present. Also commonly present are rare earth metals ...
– * Chloritoid – * Mullite (aka Porcelainite) –


Sorosilicates

Sorosilicates (from Greek 'heap, mound') have isolated
pyrosilicate A pyrosilicate is a type of chemical compound; either an ionic compound that contains the pyrosilicate anion , or an organic compound with the hexavalent ≡-O-≡ group. The anion is also called disilicateViktor Renman (2017): "Structural and ...
anions , consisting of double tetrahedra with a shared oxygen vertex—a silicon:oxygen ratio of 2:7. The Nickel–Strunz classification is 09.B. Examples include: *
Thortveitite Thortveitite is a rare mineral consisting of scandium yttrium silicate (Sc,Y)2Si2O7. It is the primary source of scandium. Occurrence is in granitic pegmatites. It was named after Olaus Thortveit, a Norwegian engineer. It is grayish-green, bla ...
– * Hemimorphite (
calamine Calamine, also known as calamine lotion, is a medication used to treat mild itchiness. This includes from sunburn, insect bites, poison ivy, poison oak, and other mild skin conditions. It may also help dry out skin irritation. It is applied ...
) – * Lawsonite – * Axinite – *
Ilvaite Ilvaite is a sorosilicate of iron and calcium with formula: CaFe2+2Fe3+Si2O7O(OH). Both manganese and magnesium substitute in the structure. Ilvaite crystallizes in the monoclinic system in black prismatic crystals and columnar masses. It is black ...
– *Epidote group (has both and groups} **
Epidote Epidote is a calcium aluminium iron sorosilicate mineral. Description Well developed crystals of epidote, Ca2Al2(Fe3+;Al)(SiO4)(Si2O7)O(OH), crystallizing in the monoclinic system, are of frequent occurrence: they are commonly prismatic in ...
– **
Zoisite Zoisite, first known as saualpite, after its type locality, is a calcium aluminium hydroxy sorosilicate belonging to the epidote group of minerals. Its chemical formula is Ca2 Al3( Si O4)(Si2O7)O(O H). Zoisite occurs as prismatic, orthorho ...
– *** Tanzanite – **
Clinozoisite Clinozoisite is a complex calcium aluminium sorosilicate mineral with formula: Ca2Al3(Si2O7)(SiO4)O(OH). It forms a continuous solid solution series with epidote by substitution of iron(III) in the aluminium (m3 site) and is also called ''alumi ...
– **
Allanite Allanite (also called orthite) is a sorosilicate group of minerals within the broader epidote group that contain a significant amount of rare-earth elements. The mineral occurs mainly in metamorphosed clay-rich sediments and felsic igneous rocks. ...
– **
Dollaseite-(Ce) Dollaseite-(Ce) is a sorosilicate end-member epidote rare-earth mineral which was discovered by Per Geijer (1927) in the Ostanmossa mine (Östanmossa gruva), Norberg district, Sweden. Dollaseite-(Ce), although not very well known, is part of a b ...
– *
Vesuvianite Vesuvianite, also known as idocrase, is a green, brown, yellow, or blue silicate mineral. Vesuvianite occurs as tetragonal crystals in skarn deposits and limestones that have been subjected to contact metamorphism. It was first discovered within ...
( idocrase) –


Cyclosilicates

Cyclosilicates (from Greek 'circle'), or ring silicates, have three or more tetrahedra linked in a ring. The general formula is (Si''x''O3''x'')2''x''−, where one or more silicon atoms can be replaced by other 4-coordinated atom(s). The silicon:oxygen ratio is 1:3. Double rings have the formula (Si2''x''O5''x'')2''x''− or a 2:5 ratio. The Nickel–Strunz classification is 09.C. Possible ring sizes include: File:Beryll.ring.combined.png, 6 units , beryl (red: Si, blue: O) File:Benitoid.2200.png, 3 units ,
benitoite Benitoite () is a rare blue barium titanium cyclosilicate, found in hydrothermally altered serpentinite. It forms in low temperature, high pressure environments typical of subduction zones at convergent plate boundaries. Benitoite fluoresces ...
File:Papagoite.2200.png, 4 units , papagoite File:Eudialyte.2200.png, 9 units , eudialyte File:Milarite.png, 6 units, double ring , milarite
Some example minerals are: * 3-member single ring **
Benitoite Benitoite () is a rare blue barium titanium cyclosilicate, found in hydrothermally altered serpentinite. It forms in low temperature, high pressure environments typical of subduction zones at convergent plate boundaries. Benitoite fluoresces ...
– * 4-member single ring ** Papagoite – . * 6-member single ring ** Beryl – ** Bazzite – ** Sugilite – **
Tourmaline Tourmaline ( ) is a crystalline Silicate mineral, silicate mineral group in which boron is compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. Tourmaline is a gemstone and can be found in a wide variety o ...
– **
Pezzottaite Pezzottaite, marketed under the name raspberyl or raspberry beryl, is a mineral species first recognized by the International Mineralogical Association in September 2003. Pezzottaite is a caesium analogue of beryl, a silicate of caesium, beryl ...
– ** Osumilite – **
Cordierite Cordierite (mineralogy) or iolite (gemology) is a magnesium iron aluminium cyclosilicate. Iron is almost always present and a solid solution exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: to . A high-temperat ...
– ** Sekaninaite – * 9-member single ring ** Eudialyte – * 6-member double ring ** Milarite – Note that the ring in axinite contains two B and four Si tetrahedra and is highly distorted compared to the other 6-member ring cyclosilicates.


Inosilicates

Inosilicates (from Greek enitive: 'fibre'), or chain silicates, have interlocking chains of
silicate In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is a ...
tetrahedra In geometry, a tetrahedron (plural: tetrahedra or tetrahedrons), also known as a triangular pyramid, is a polyhedron composed of four triangular faces, six straight edges, and four vertex corners. The tetrahedron is the simplest of all th ...
with either , 1:3 ratio, for single chains or , 4:11 ratio, for double chains. The Nickel–Strunz classification is 09.D – examples include:


Single chain inosilicates

*
Pyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe I ...
group **Enstatite – orthoferrosilite series ***
Enstatite Enstatite is a mineral; the magnesium endmember of the pyroxene silicate mineral series enstatite (MgSiO3) – ferrosilite (FeSiO3). The magnesium rich members of the solid solution series are common rock-forming minerals found in igneous and ...
– *** Ferrosilite – ** Pigeonite – **Diopside – hedenbergite series ***
Diopside Diopside is a monoclinic pyroxene mineral with composition . It forms complete solid solution series with hedenbergite () and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull ...
– ***
Hedenbergite Hedenbergite, Ca Fe Si2 O6, is the iron rich end member of the pyroxene group having a monoclinic crystal system. The mineral is extremely rarely found as a pure substance, and usually has to be synthesized in a lab. It was named in 1819 after M ...
– ***
Augite Augite is a common rock-forming pyroxene mineral with formula . The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees. Characteristics Augite is a solid solution in the pyroxene group ...
– **Sodium pyroxene series ***
Jadeite Jadeite is a pyroxene mineral with composition Na Al Si2 O6. It is hard (Mohs hardness of about 6.5 to 7.0), very tough, and dense, with a specific gravity of about 3.4. It is found in a wide range of colors, but is most often found in shades ...
– *** Aegirine (or acmite) – **
Spodumene Spodumene is a pyroxene mineral consisting of lithium aluminium inosilicate, Li Al( Si O3)2, and is a source of lithium. It occurs as colorless to yellowish, purplish, or lilac kunzite (see below), yellowish-green or emerald-green hiddenite, pri ...
– **
Pyroxferroite Pyroxferroite (Fe2+,Ca)SiO3 is a single chain inosilicate. It is mostly composed of iron, silicon and oxygen, with smaller fractions of calcium and several other metals. Together with armalcolite and tranquillityite, it is one of the three miner ...
- *Pyroxenoid group **
Wollastonite Wollastonite is a calcium inosilicate mineral ( Ca Si O3) that may contain small amounts of iron, magnesium, and manganese substituting for calcium. It is usually white. It forms when impure limestone or dolomite is subjected to high temperature ...
– **
Rhodonite Rhodonite is a manganese inosilicate, (Mn, Fe, Mg, Ca)SiO3 and member of the pyroxenoid group of minerals, crystallizing in the triclinic system. It commonly occurs as cleavable to compact masses with a rose-red color (the name comes from the G ...
– ** Pectolite


Double chain inosilicates

*
Amphibole Amphibole () is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is ...
group **
Anthophyllite Anthophyllite is an orthorhombic amphibole mineral: ☐Mg2Mg5Si8O22(OH)2 (☐ is for a vacancy, a point defect in the crystal structure), magnesium iron inosilicate hydroxide. Anthophyllite is polymorphic with cummingtonite. Some forms of ...
– **Cummingtonite series ***
Cummingtonite Cummingtonite ( ) is a metamorphic amphibole with the chemical composition , magnesium iron silicate hydroxide. Monoclinic cummingtonite is compositionally similar and polymorphic with orthorhombic anthophyllite, which is a much more common fo ...
– *** Grunerite – **Tremolite series ***
Tremolite Tremolite is a member of the amphibole group of silicate minerals with composition: Ca2(Mg5.0-4.5Fe2+0.0-0.5)Si8O22(OH)2. Tremolite forms by metamorphism of sediments rich in dolomite and quartz. Tremolite forms a series with actinolite and fe ...
– ***
Actinolite Actinolite is an amphibole silicate mineral with the chemical formula . Etymology The name ''actinolite'' is derived from the Greek word ''aktis'' (), meaning "beam" or "ray", because of the mineral's fibrous nature. Mineralogy Actinolite is ...
– **
Hornblende Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rock ...
– **Sodium amphibole group *** Glaucophane – *** Riebeckite (
asbestos Asbestos () is a naturally occurring fibrous silicate mineral. There are six types, all of which are composed of long and thin fibrous crystals, each fibre being composed of many microscopic "fibrils" that can be released into the atmosphere b ...
) – *** Arfvedsonite File:Pyroxen-chain.png, Inosilicate, pyroxene family, with 2-periodic single chain ,
diopside Diopside is a monoclinic pyroxene mineral with composition . It forms complete solid solution series with hedenbergite () and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull ...
File:Tremolite-chain.png, Inosilicate, clinoamphibole, with 2-periodic double chains ,
tremolite Tremolite is a member of the amphibole group of silicate minerals with composition: Ca2(Mg5.0-4.5Fe2+0.0-0.5)Si8O22(OH)2. Tremolite forms by metamorphism of sediments rich in dolomite and quartz. Tremolite forms a series with actinolite and fe ...
File:Wollastonite-chain.png, Inosilicate, unbranched 3-periodic single chain of
wollastonite Wollastonite is a calcium inosilicate mineral ( Ca Si O3) that may contain small amounts of iron, magnesium, and manganese substituting for calcium. It is usually white. It forms when impure limestone or dolomite is subjected to high temperature ...
File:Rhodonite-chain.png, Inosilicate with 5-periodic single chain,
rhodonite Rhodonite is a manganese inosilicate, (Mn, Fe, Mg, Ca)SiO3 and member of the pyroxenoid group of minerals, crystallizing in the triclinic system. It commonly occurs as cleavable to compact masses with a rose-red color (the name comes from the G ...
File:Pellyite-chain.png, Inosilicate with cyclic branched 8-periodic chain, pellyite


Phyllosilicates

Phyllosilicates (from Greek 'leaf'), or sheet silicates, form parallel sheets of silicate tetrahedra with or a 2:5 ratio. The Nickel–Strunz classification is 09.E. All phyllosilicate minerals are
hydrate In chemistry, a hydrate is a substance that contains water or its constituent elements. The chemical state of the water varies widely between different classes of hydrates, some of which were so labeled before their chemical structure was understo ...
d, with either
water Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as ...
or
hydroxyl In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry, alcohols and carboxylic acids contain one or more hydrox ...
groups attached. Examples include: *
Serpentine subgroup Serpentine subgroup (part of the kaolinite-serpentine group in the category of phyllosilicates) are greenish, brownish, or spotted minerals commonly found in serpentinite. They are used as a source of magnesium and asbestos, and as decorativ ...
**
Antigorite Antigorite is a lamellated, monoclinic mineral in the phylosilicate serpentine subgroup with the ideal chemical formula of (Mg,Fe2+)3Si2O5(OH)4. It is the high-pressure polymorph of serpentine and is commonly found in metamorphosed serpentini ...
– **
Chrysotile Chrysotile or white asbestos is the most commonly encountered form of asbestos, accounting for approximately 95% of the asbestos in the United StatesOccupational Safety and Health Administration, U.S. Department of Labor (2007)29 C.F.R.&nb ...
– **
Lizardite Lizardite is a mineral from the serpentine group with formula , and the most common type of mineral in the group. It is also a member of the kaolinite-serpentine group. Népouite and lizardite form a series; intermediate compositions are pos ...
– *
Clay minerals Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay minera ...
group **1:1 clay minerals (TO) *** Halloysite – ***
Kaolinite Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahed ...
– **2:1 clay minerals (TOT) ***
Pyrophyllite Pyrophyllite is a phyllosilicate mineral composed of aluminium silicate hydroxide: Al2Si4O10(OH)2. It occurs in two forms (habits): crystalline folia and compact masses; distinct crystals are not known. The folia have a pronounced pearly ...
– ***
Talc Talc, or talcum, is a clay mineral, composed of hydrated magnesium silicate with the chemical formula Mg3Si4O10(OH)2. Talc in powdered form, often combined with corn starch, is used as baby powder. This mineral is used as a thickening agent a ...
– *** Illite – ***
Montmorillonite Montmorillonite is a very soft phyllosilicate group of minerals that form when they precipitate from water solution as microscopic crystals, known as clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite gro ...
(smectite) – ***
Chlorite The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chlorou ...
– ***
Vermiculite Vermiculite is a hydrous phyllosilicate mineral which undergoes significant expansion when heated. Exfoliation occurs when the mineral is heated sufficiently, and commercial furnaces can routinely produce this effect. Vermiculite forms by the we ...
– **Other clay minerals *** Sepiolite – ***
Palygorskite Palygorskite or attapulgite is a magnesium aluminium phyllosilicate with the chemical formula ) that occurs in a type of clay soil common to the Southeastern United States. It is one of the types of fuller's earth. Some smaller deposits of thi ...
(or attapulgite) – *
Mica Micas ( ) are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into extremely thin elastic plates. This characteristic is described as perfect basal cleavage. Mica is ...
group **
Biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron- endmember annite, and the magnesium-endmember phlogopite; more ...
– ** Fuchsite – **
Muscovite Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula K Al2(Al Si3 O10)( F,O H)2, or ( KF)2( Al2O3)3( SiO2)6( H2O). It has a highly perfect basal cleavag ...
– ** Phlogopite – **
Lepidolite Lepidolite is a lilac-gray or rose-colored member of the mica group of minerals with chemical formula . It is the most abundant lithium-bearing mineral and is a secondary source of this metal. It is the major source of the alkali metal rubidium. ...
– ** Margarite – **
Glauconite Glauconite is an iron potassium phyllosilicate ( mica group) mineral of characteristic green color which is very friable and has very low weathering resistance. It crystallizes with a monoclinic geometry. Its name is derived from the Gre ...
File:Muskovite.sheet.png, Phyllosilicate, mica group,
muscovite Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula K Al2(Al Si3 O10)( F,O H)2, or ( KF)2( Al2O3)3( SiO2)6( H2O). It has a highly perfect basal cleavag ...
(red: Si, blue: O) File:Apophyllite.sheet.png, Phyllosilicate, single net of tetrahedra with 4-membered rings, apophyllite-(KF)-apophyllite-(KOH) series File:Pyrosmalite.sheet.png, Phyllosilicate, single tetrahedral nets of 6-membered rings, pyrosmalite-(Fe)-pyrosmalite-(Mn) series File:Zeophyllite.sheet.png, Phyllosilicate, single tetrahedral nets of 6-membered rings, zeophyllite File:Carletonite.sheet.png, Phyllosilicate, double nets with 4- and 6-membered rings,
carletonite Carletonite is a rare silicate mineral with formula KNa4Ca4(CO3)4Si8O18(F,OH)·(H2O). It is a phyllosilicate and a member of the apophyllite group. Its tetragonal crystals are a translucent blue, white, colorless or pink with a vitreous to dull l ...


Tectosilicates

Tectosilicates, or "framework silicates," have a three-dimensional framework of silicate
tetrahedra In geometry, a tetrahedron (plural: tetrahedra or tetrahedrons), also known as a triangular pyramid, is a polyhedron composed of four triangular faces, six straight edges, and four vertex corners. The tetrahedron is the simplest of all th ...
with in a 1:2 ratio. This group comprises nearly 75% of the crust of the
Earth Earth is the third planet from the Sun and the only astronomical object known to harbor life. While large volumes of water can be found throughout the Solar System, only Earth sustains liquid surface water. About 71% of Earth's sur ...
. Tectosilicates, with the exception of the quartz group, are aluminosilicates. The Nickel–Strunz classifications are 09.F and 09.G, 04.DA (Quartz/ silica family). Examples include: *3D-Silicates, quartz family **
Quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical f ...
– **
Tridymite Tridymite is a high-temperature polymorph of silica and usually occurs as minute tabular white or colorless pseudo-hexagonal crystals, or scales, in cavities in felsic volcanic rocks. Its chemical formula is Si O2. Tridymite was first describe ...
– **
Cristobalite Cristobalite is a mineral polymorph of silica that is formed at very high temperatures. It has the same chemical formula as quartz, SiO2, but a distinct crystal structure. Both quartz and cristobalite are polymorphs with all the members of the ...
– ** Coesite – **
Stishovite Stishovite is an extremely hard, dense tetragonal form ( polymorph) of silicon dioxide. It is very rare on the Earth's surface; however, it may be a predominant form of silicon dioxide in the Earth, especially in the lower mantle. Stishovite ...
– **
Moganite Moganite is an oxide mineral with the chemical formula Si O2 ( silicon dioxide) that was discovered in 1976. It was initially described as a new form of silica from specimens found in the Barranco de Medio Almud, in the municipality of Mogán ...
– **
Chalcedony Chalcedony ( , or ) is a cryptocrystalline form of silica, composed of very fine intergrowths of quartz and moganite. These are both silica minerals, but they differ in that quartz has a trigonal crystal structure, while moganite is monocli ...
– *Tectosilicates,
feldspar Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) felds ...
group **Alkali feldspars (potassium feldspars) ***
Microcline Microcline (KAlSi3O8) is an important igneous rock-forming tectosilicate mineral. It is a potassium-rich alkali feldspar. Microcline typically contains minor amounts of sodium. It is common in granite and pegmatites. Microcline forms durin ...
– ***
Orthoclase Orthoclase, or orthoclase feldspar ( endmember formula K Al Si3 O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture," because its two cleavage planes are at right angles ...
– ***
Anorthoclase The mineral anorthoclase ((Na,K)AlSi3O8) is a crystalline solid solution in the alkali feldspar series, in which the sodium-aluminium silicate member exists in larger proportion. It typically consists of between 10 and 36 percent of KAlSi3O8 and ...
– ***
Sanidine Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal s ...
– **
Plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more p ...
feldspars ***
Albite Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicate ...
– ***
Oligoclase Oligoclase is a rock-forming mineral belonging to the plagioclase feldspars. In chemical composition and in its crystallographic and physical characters it is intermediate between albite ( Na Al Si3 O8) and anorthite ( CaAl2Si2O8). The albite: ...
–      (Na:Ca 4:1) *** Andesine –      (Na:Ca 3:2) *** Labradorite –      (Na:Ca 2:3) ***
Bytownite Bytownite is a calcium rich member of the plagioclase solid solution series of feldspar minerals with composition between anorthite and labradorite. It is usually defined as having between 70 and 90% An (formula: (Ca0.7-0.9,Na0.3-0.1) l(Al,Si)Si2 ...
–      (Na:Ca 1:4) ***
Anorthite Anorthite is the calcium endmember of the plagioclase feldspar mineral series. The chemical formula of pure anorthite is Ca Al2 Si2O8. Anorthite is found in mafic igneous rocks. Anorthite is rare on the Earth but abundant on the Moon. Minera ...
– *Tectosilicates,
feldspathoid The feldspathoids are a group of tectosilicate minerals which resemble feldspars but have a different structure and much lower silica content. They occur in rare and unusual types of igneous rocks, and are usually not found in rocks containing ...
family ** Nosean – ** Cancrinite – **
Leucite Leucite is a rock-forming mineral of the feldspathoid group, silica-undersaturated and composed of potassium and aluminium tectosilicate KAlSi2O6. Crystals have the form of cubic icositetrahedra but, as first observed by Sir David Brewster in ...
– **
Nepheline Nepheline, also called nephelite (), is a rock-forming mineral in the feldspathoid groupa silica-undersaturated aluminosilicate, Na3 K Al4 Si4 O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmati ...
– ** Sodalite – ** Hauyne – ***
Lazurite Lazurite is a tectosilicate mineral with sulfate, sulfur and chloride with formula . It is a feldspathoid and a member of the sodalite group. Lazurite crystallizes in the isometric system although well‐formed crystals are rare. It is usual ...
– *Tectosilicates, scapolite group **
Marialite Marialite is a silicate mineral with a chemical formula of if a pure endmember or with increasing meionite content. Marialite is a member of the scapolite group and a solid solution exists between marialite and meionite, the calcium endmember ...
– ** Meionite – *Tectosilicates,
zeolite Zeolites are microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ・y where is either a metal ion or H+. These p ...
family ** Natrolite – ** Erionite – ** Chabazite – **
Heulandite Heulandite is the name of a series of tecto-silicate minerals of the zeolite group. Prior to 1997, heulandite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a ser ...
– ** Stilbite – ** Scolecite – **
Mordenite Mordenite is a zeolite mineral with the chemical formula, ( Ca, Na2, K2) Al2 Si10 O24·7 H2O. and it is one of the six most abundant zeolites and is used commercially. It was first described in 1864 by Henry How. He named it after the small ...
– ** Analcime


See also

* * *


References


External links


Mindat.org, Dana classification

Webmineral : Dana's New Silicate Classification
{{Authority control ja:ケイ酸塩鉱物 pl:Krzemiany