Phillipsite is a mineral series of the

zeolite Zeolites are microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ･y where is either a metal ion or H+. These p ...

group; a hydrated

potassium Potassium is the chemical element with the symbol K (from Neo-Latin '' kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmos ...

calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar ...

and

aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It ha ...

silicate, approximating to . The members of the series are phillipsite-K, phillipsite-Na and phillipsite-Ca. The crystals are

monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic ...

, but only complex cruciform

twins Twins are two offspring produced by the same pregnancy.MedicineNet > Definition of TwinLast Editorial Review: 19 June 2000 Twins can be either ''monozygotic'' ('identical'), meaning that they develop from one zygote, which splits and forms two em ...

are known, these being exactly like twins of

harmotome Harmotome is a mineral, one of the rarer zeolites; a hydrated barium silicate with formula: ( Ba0.5, Ca0.5, Na, K)5 Al5, Si11 O32·12( H2O). It forms vitreous white well defined monoclinic crystals, often associated with calcite and other zeolit ...

which also forms a series with phillipsite-Ca. Crystals of phillipsite are, however, usually smaller and more transparent and glassy than those of harmotome. Spherical groups with a radially fibrous structure and bristled with crystals on the surface are not uncommon. The

Mohs hardness The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. The scale was introduced in 1812 by ...

is 4.5, and the

specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water at its dens ...

is 2.2. The species was established by Armand Lévy in 1825 and named after

William Phillips William Phillips may refer to: Entertainment * William Phillips (editor) (1907–2002), American editor and co-founder of ''Partisan Review'' * William T. Phillips (1863–1937), American author * William Phillips (director), Canadian film-make ...

. French authors use the name Christianite (after

Christian VIII Christian VIII (18 September 1786 – 20 January 1848) was King of Denmark from 1839 to 1848 and, as Christian Frederick, King of Norway in 1814. Christian Frederick was the eldest son of Hereditary Prince Frederick of Denmark and Norway, Hereditar ...

Denmark ) , song = ( en, "King Christian stood by the lofty mast") , song_type = National and royal anthem , image_map = EU-Denmark.svg , map_caption = , subdivision_type = Sovereign state , subdivision_name = Kingdom of Denmark , establish ...

), given by A. Des Cloizeaux in 1847. Phillipsite is a mineral of secondary origin, and occurs with other zeolites in the amygdaloidal cavities of

mafic A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks in ...

volcanic rock Volcanic rock (often shortened to volcanics in scientific contexts) is a rock formed from lava erupted from a volcano. In other words, it differs from other igneous rock by being of volcanic origin. Like all rock types, the concept of volcanic ...

s: for example in the

basalt Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90 ...

of the

Giants Causeway The Giant's Causeway is an area of about 40,000 interlocking basalt columns, the result of an ancient volcanic fissure eruption. It is located in County Antrim on the north coast of Northern Ireland, about three miles (5 km) northeast of ...

in County Antrim, and near

Melbourne Melbourne ( ; Boonwurrung/ Woiwurrung: ''Narrm'' or ''Naarm'') is the capital and most populous city of the Australian state of Victoria, and the second-most populous city in both Australia and Oceania. Its name generally refers to a metro ...

Victoria Victoria most commonly refers to: * Victoria (Australia), a state of the Commonwealth of Australia * Victoria, British Columbia, provincial capital of British Columbia, Canada * Victoria (mythology), Roman goddess of Victory * Victoria, Seychelle ...

; and in Lencitite near

Rome , established_title = Founded , established_date = 753 BC , founder = King Romulus ( legendary) , image_map = Map of comune of Rome (metropolitan city of Capital Rome, region Lazio, Italy).svg , map_caption ...

. Small crystals of recent formation have been observed in the masonry of the hot baths at Plombires and Bourbonne-les-Bains, in

France France (), officially the French Republic ( ), is a country primarily located in Western Europe. It also comprises of Overseas France, overseas regions and territories in the Americas and the Atlantic Ocean, Atlantic, Pacific Ocean, Pac ...

. Minute spherical aggregates embedded in

pelagic red clay Pelagic red clay, also known as simply red clay, brown clay or pelagic clay, is a type of pelagic sediment.Rothwell, R.G., (2005) ''Deep Ocean Pelagic Oozes'', Vol. 5. of Selley, Richard C., L. Robin McCocks, and Ian R. Plimer, Encyclopedia of Ge ...

were dredged by the

Challenger Challenger, Challengers, or The Challengers may refer to: Entertainment Comics and manga * Challenger (character), comic book character * ''Challengers'' (manga), manga by Hinako Takanaga Film and TV * ''The Challengers'' (TV series), a 1979 ...

from deep sea sedimentary deposits in the

Pacific Ocean The Pacific Ocean is the largest and deepest of Earth's five oceanic divisions. It extends from the Arctic Ocean in the north to the Southern Ocean (or, depending on definition, to Antarctica) in the south, and is bounded by the conti ...

. It has been discovered that the volcanic ash that Romans employed in the mix for construction of harbor piers and sea walls contained phillipsite, and that an interaction with sea water actually causes crystalline aluminous tobermorite structures in the mortar to expand and strengthen, making the material substantially more durable than modern concrete.''Ancient lessons: Roman concrete durable, green'', Jim Destefani, ed., Ceramic Tech Today, The American Ceramic Society, June 7, 2013
/ref>

References

External links

Structure type PHI
Calcium minerals Sodium minerals Potassium minerals Aluminium minerals Zeolites Monoclinic minerals Minerals in space group 11 {{silicate-mineral-stub

See also

References

External links