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Palagonite is an alteration product from the interaction of water with
volcanic glass Volcanic glass is the amorphous solid, amorphous (uncrystallized) product of rapidly cooling magma. Like all types of glass, it is a state of matter intermediate between the closely packed, highly ordered array of a crystal and the highly disorde ...
of chemical composition similar to
basalt Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90 ...
. Palagonite can also result from the interaction between water and basalt melt. The water flashes to steam on contact with the hot
lava Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or un ...
and the small fragments of lava react with the steam to form the light-colored palagonite
tuff Tuff is a type of rock made of volcanic ash ejected from a vent during a volcanic eruption. Following ejection and deposition, the ash is lithified into a solid rock. Rock that contains greater than 75% ash is considered tuff, while rock ...
cones A cone is a three-dimensional geometric shape that tapers smoothly from a flat base (frequently, though not necessarily, circular) to a point called the apex or vertex. A cone is formed by a set of line segments, half-lines, or lines conn ...
common in areas of basaltic eruptions in contact with water. An example is found in the pyroclastic cones of the Galapagos Islands.
Charles Darwin Charles Robert Darwin ( ; 12 February 1809 – 19 April 1882) was an English naturalist, geologist, and biologist, widely known for his contributions to evolutionary biology. His proposition that all species of life have descended ...
recognized the origin of these cones during his visit to the islands. Palagonite can also be formed by a slower
weathering Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs ''in situ'' (on site, with little or no movement) ...
of lava into palagonite, resulting in a thin, yellow-orange rind on the surface of the rock. The process of conversion of lava to palagonite is called ''palagonitization.'' Palagonite soil is a light yellow-orange dust, comprising a mixture of particles ranging down to sub-micrometer sizes, usually found mixed with larger fragments of lava. The color is indicative of the presence of
iron Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...
in the +3
oxidation state In chemistry, the oxidation state, or oxidation number, is the hypothetical charge of an atom if all of its bonds to different atoms were fully ionic. It describes the degree of oxidation (loss of electrons) of an atom in a chemical compound. C ...
, embedded in an amorphous matrix. Palagonite tuff is a tuff composed of
sideromelane Sideromelane is a vitreous basaltic volcanic glass, usually occurring in palagonite tuff, for which it is characteristic. It is a less common form of tachylite, with which it usually occurs together; however it lacks the iron oxide crystals di ...
fragments and coarser pieces of basaltic rock, embedded in a palagonite matrix. A composite of sideromelane aggregate in palagonite matrix is called ''
hyaloclastite Hyaloclastite is a volcanoclastic accumulation or breccia consisting of glass (from the Greek ''hyalus'') fragments (clasts) formed by quench fragmentation of lava flow surfaces during submarine or subglacial extrusion. It occurs as thin margin ...
''.


Palagonite on Mars

Based on infrared spectroscopy, the fine-grained component of Mauna-Kea palagonite is the terrestrial material with the best match to the spectral properties of Martian dust, and is believed to be similar in composition and in origin to dusty component of the surface
regolith Regolith () is a blanket of unconsolidated, loose, heterogeneous superficial deposits covering solid rock. It includes dust, broken rocks, and other related materials and is present on Earth, the Moon, Mars, some asteroids, and other terrestr ...
of
Mars Mars is the fourth planet from the Sun and the second-smallest planet in the Solar System, only being larger than Mercury. In the English language, Mars is named for the Roman god of war. Mars is a terrestrial planet with a thin at ...
. The palagonitic
tephra Tephra is fragmental material produced by a volcanic eruption regardless of composition, fragment size, or emplacement mechanism. Volcanologists also refer to airborne fragments as pyroclasts. Once clasts have fallen to the ground, they re ...
from a cinder cone in Hawaii has been used to create
Martian regolith simulant Martian regolith simulant (or Martian soil simulant) is a terrestrial material that is used to simulate the chemical and mechanical properties of Martian regolith for research, experiments and prototype testing of activities related to Martian r ...
for researchers. The spectroscopic signature of palagonitic alteration on Mars is used as evidence for the existence of
water on Mars Almost all water on Mars today exists as ice, though it also exists in small quantities as vapor in the atmosphere. What was thought to be low-volume liquid brines in shallow Martian soil, also called recurrent slope lineae, may be grains of ...
.


References


Further reading


Volcan Darwin

J. R. Michalski*, M. D. Kraft, T. G. Sharp, and P. R. Christensen, ''Palagonite-like Alteration Products on the Earth and Mars I: Spectrocopy (0.4-25 microns) of Weathered Basalta and Silicate Alteration Products'' Lunar and Planetary Science XXXVI (2005) PDF
Igneous rocks Volcanology Glass in nature Weathering {{basalt