Oligoclase is a rock-forming
mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...
belonging to the
plagioclase feldspars.
[ In chemical composition and in its crystallographic and physical characters it is intermediate between albite ( Na Al Si3 O8) and anorthite ( CaAl2Si2O8).][ The albite:anorthite molar ratio of oligoclase ranges from 90:10 to 70:30.
Oligoclase is a high sodium feldspar crystallizing in the ]triclinic
180px, Triclinic (a ≠ b ≠ c and α ≠ β ≠ γ )
In crystallography, the triclinic (or anorthic) crystal system is one of the 7 crystal systems. A crystal system is described by three basis vectors. In the triclinic system, the crystal i ...
system. The Mohs hardness is 6 to 6.5 and the specific gravity is 2.64 to 2.66. The refractive indices
In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium.
The refractive index determines how much the path of light is bent, or ...
are: nα=1.533–1.543, nβ=1.537–1.548, and nγ=1.542–1.552. In color it is usually white, with shades of grey, green, or red.[
Oligoclase is a common mineral in the more ]silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is ...
-rich varieties of igneous rock
Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma o ...
and in many metamorphic rock
Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock ( protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, caus ...
s.
Name and discovery
The name oligoclase was given by August Breithaupt in 1826 from the grc, όλίγος, oligos, little, and grc, κλᾶν, klân, to break, because the mineral was thought to have a less perfect cleavage than albite.[ It had previously been recognized as a distinct species by J. J. Berzelius in 1824, and was named by him soda-spodumene (Natron-spodumen), because of its resemblance in appearance to spodumene.][
]
Occurrence
Perfectly colorless and transparent glassy material found at Bakersville, North Carolina has occasionally been faceted as a gemstone.[ Another variety more frequently used as a gemstone is the aventurine-feldspar or sun-stone found as reddish cleavage masses in gneiss at Tvedestrand in southern ]Norway
Norway, officially the Kingdom of Norway, is a Nordic country in Northern Europe, the mainland territory of which comprises the western and northernmost portion of the Scandinavian Peninsula. The remote Arctic island of Jan Mayen and the ...
; this presents a brilliant red to golden metallic glitter, due to the presence of numerous small scales of hematite oriented within the feldspar structure.[
Oligoclase occurs, often accompanying ]orthoclase
Orthoclase, or orthoclase feldspar ( endmember formula K Al Si3 O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture," because its two cleavage planes are at right angles ...
, as a constituent of plutonic igneous rock
Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma o ...
s such as granite
Granite () is a coarse-grained ( phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies under ...
, syenite, and diorite.[ It occurs in porphyry and diabase dikes and sills as well as in the ]volcanic
A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface.
On Earth, volcanoes are most often found where tectonic plates a ...
rocks andesite and trachyte
Trachyte () is an extrusive igneous rock composed mostly of alkali feldspar. It is usually light-colored and aphanitic (fine-grained), with minor amounts of mafic minerals, and is formed by the rapid cooling of lava enriched with silica and al ...
, and in mugearite where its presence is a defining feature. It also occurs in gneiss. The best developed and largest crystals are those found with orthoclase, quartz
Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...
, epidote, and calcite in veins in granite at Arendal in Norway.[ The distinctive texture of ]rapakivi granite
Rapakivi granite is a hornblende-biotite granite containing large round crystals of orthoclase each with a rim of oligoclase (a variety of plagioclase). The name has come to be used most frequently as a textural term where it implies plagioclase r ...
is due to oligoclase rims on orthoclase phenocryst
300px, feldspathic phenocrysts. This granite, from the Switzerland">Swiss side of the Mont Blanc massif, has large white plagioclase phenocrysts, triclinic minerals that give trapezoid shapes when cut through). 1 euro coins, 1 euro coin (diameter ...
s. Oligoclase is also found in metamorphic rocks
Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, caus ...
formed under transitional greenschist
Greenschists are metamorphic rocks that formed under the lowest temperatures and pressures usually produced by regional metamorphism, typically and 2–10 kilobars (). Greenschists commonly have an abundance of green minerals such as chlorite ...
to amphibolite facies conditions.
Schiller iridescence
Some examples are called moonstone and show Schiller iridescence due to the presence of exsolution
A solid solution, a term popularly used for metals, is a homogenous mixture of two different kinds of atoms in solid state and have a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The wor ...
lamellae on cooling in the peristerite miscibility gap A miscibility gap is a region in a phase diagram for a mixture of components where the mixture exists as two or more phases – any region of composition of mixtures where the constituents are not completely miscible.
The IUPAC Gold Book defines ...
, ~An5-An18.
References
* Hurlbut, Cornelius S.; Klein, Cornelis, 1985, ''Manual of Mineralogy'', 20th ed., Wiley,
Webmineral data
Gemstones
Tectosilicates
Sodium minerals
Calcium minerals
Feldspar
Triclinic minerals
{{silicate-mineral-stub