Neutron radiation is a form of
ionizing radiation
Ionizing radiation (or ionising radiation), including nuclear radiation, consists of subatomic particles or electromagnetic waves that have sufficient energy to ionize atoms or molecules by detaching electrons from them. Some particles can travel ...
that presents as
free neutrons. Typical phenomena are
nuclear fission
Nuclear fission is a reaction in which the nucleus of an atom splits into two or more smaller nuclei. The fission process often produces gamma photons, and releases a very large amount of energy even by the energetic standards of radio ...
or
nuclear fusion causing the release of free neutrons, which then
react REACT or React may refer to:
Science and technology
* REACT (telescope), a telescope at Fenton Hill Observatory, New Mexico, US
Computing
* React (JavaScript library) , a JavaScript library for building user interfaces, from Facebook
** React Nat ...
with
nuclei of other
atom
Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons.
Every solid, liquid, gas, a ...
s to form new
isotope
Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers ( mass num ...
s—which, in turn, may trigger further neutron radiation. Free neutrons are unstable,
decaying into a
proton
A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive electric charge of +1 ''e'' elementary charge. Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton–electron mass ...
, an
electron
The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family,
and are generally thought to be elementary particles because they have n ...
, plus an
electron antineutrino. Free neutrons have a mean lifetime of 887 seconds (14 minutes, 47 seconds).
Neutron radiation is distinct from
alpha
Alpha (uppercase , lowercase ; grc, ἄλφα, ''álpha'', or ell, άλφα, álfa) is the first letter of the Greek alphabet. In the system of Greek numerals, it has a value of one. Alpha is derived from the Phoenician letter aleph , whi ...
,
beta
Beta (, ; uppercase , lowercase , or cursive ; grc, βῆτα, bē̂ta or ell, βήτα, víta) is the second letter of the Greek alphabet. In the system of Greek numerals, it has a value of 2. In Modern Greek, it represents the voiced labiod ...
and
gamma
Gamma (uppercase , lowercase ; ''gámma'') is the third letter of the Greek alphabet. In the system of Greek numerals it has a value of 3. In Ancient Greek, the letter gamma represented a voiced velar stop . In Modern Greek, this letter r ...
radiation.
Sources
Neutron
The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the atomic nucleus, nuclei of atoms. Since protons and ...
s may be emitted from
nuclear fusion or
nuclear fission
Nuclear fission is a reaction in which the nucleus of an atom splits into two or more smaller nuclei. The fission process often produces gamma photons, and releases a very large amount of energy even by the energetic standards of radio ...
, or from other
nuclear reaction
In nuclear physics and nuclear chemistry, a nuclear reaction is a process in which two nuclei, or a nucleus and an external subatomic particle, collide to produce one or more new nuclides. Thus, a nuclear reaction must cause a transformatio ...
s such as
radioactive decay
Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consid ...
or particle interactions with
cosmic ray
Cosmic rays are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar System in our own ...
s or within
particle accelerators. Large neutron sources are rare, and usually limited to large-sized devices such as
nuclear reactor
A nuclear reactor is a device used to initiate and control a fission nuclear chain reaction or nuclear fusion reactions. Nuclear reactors are used at nuclear power plants for electricity generation and in nuclear marine propulsion. Heat fr ...
s or
particle accelerators, including the
Spallation Neutron Source
The Spallation Neutron Source (SNS) is an accelerator-based neutron source facility in the U.S. that provides the most intense pulsed neutron beams in the world for scientific research and industrial development.In 2007, SNS was entered into th ...
.
Neutron radiation was discovered from observing an
alpha particle
Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay, but may also be prod ...
colliding with a
beryllium
Beryllium is a chemical element with the symbol Be and atomic number 4. It is a steel-gray, strong, lightweight and brittle alkaline earth metal. It is a divalent element that occurs naturally only in combination with other elements to for ...
nucleus
Nucleus ( : nuclei) is a Latin word for the seed inside a fruit. It most often refers to:
* Atomic nucleus, the very dense central region of an atom
*Cell nucleus, a central organelle of a eukaryotic cell, containing most of the cell's DNA
Nucl ...
, which was transformed into a
carbon
Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon ma ...
nucleus
Nucleus ( : nuclei) is a Latin word for the seed inside a fruit. It most often refers to:
* Atomic nucleus, the very dense central region of an atom
*Cell nucleus, a central organelle of a eukaryotic cell, containing most of the cell's DNA
Nucl ...
while emitting a
neutron
The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the atomic nucleus, nuclei of atoms. Since protons and ...
,
Be(
α,
n)
C. The combination of an alpha particle emitter and an isotope with a large (
α,
n)
nuclear reaction probability is still a common neutron source.
Neutron radiation from fission
The neutrons in nuclear reactors are generally categorized as
slow (thermal) neutrons or
fast neutrons depending on their energy. Thermal neutrons are similar in energy distribution (the
Maxwell–Boltzmann distribution
In physics (in particular in statistical mechanics), the Maxwell–Boltzmann distribution, or Maxwell(ian) distribution, is a particular probability distribution named after James Clerk Maxwell and Ludwig Boltzmann.
It was first defined and use ...
) to a gas in
thermodynamic equilibrium
Thermodynamic equilibrium is an axiomatic concept of thermodynamics. It is an internal state of a single thermodynamic system, or a relation between several thermodynamic systems connected by more or less permeable or impermeable walls. In the ...
; but are easily captured by atomic nuclei and are the primary means by which elements undergo
nuclear transmutation
Nuclear transmutation is the conversion of one chemical element or an isotope into another chemical element. Nuclear transmutation occurs in any process where the number of protons or neutrons in the nucleus of an atom is changed.
A transmutatio ...
.
To achieve an effective fission chain reaction, neutrons produced during fission must be captured by fissionable nuclei, which then split, releasing more neutrons. In most fission reactor designs, the
nuclear fuel
Nuclear fuel is material used in nuclear power stations to produce heat to power turbines. Heat is created when nuclear fuel undergoes nuclear fission.
Most nuclear fuels contain heavy fissile actinide elements that are capable of undergo ...
is not sufficiently refined to absorb enough fast neutrons to carry on the chain reaction, due to the lower
cross section for higher-energy neutrons, so a
neutron moderator
In nuclear engineering, a neutron moderator is a medium that reduces the speed of fast neutrons, ideally without capturing any, leaving them as thermal neutrons with only minimal (thermal) kinetic energy. These thermal neutrons are immensely m ...
must be introduced to slow the fast neutrons down to thermal velocities to permit sufficient absorption. Common neutron moderators include
graphite
Graphite () is a crystalline form of the element carbon. It consists of stacked layers of graphene. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on la ...
, ordinary (light)
water
Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as ...
and
heavy water. A few reactors (
fast neutron reactors) and all
nuclear weapon
A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either fission (fission bomb) or a combination of fission and fusion reactions ( thermonuclear bomb), producing a nuclear explosion. Both bomb ...
s rely on fast neutrons.
Cosmogenic neutrons
Cosmogenic neutrons, neutrons produced from
cosmic radiation
Cosmic rays are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar System in our ow ...
in the Earth's atmosphere or surface, and those produced in particle accelerators can be significantly higher energy than those encountered in reactors. Most of them activate a nucleus before reaching the ground; a few react with nuclei in the air . The reactions with
nitrogen-14
Natural nitrogen (7N) consists of two stable isotopes: the vast majority (99.6%) of naturally occurring nitrogen is nitrogen-14, with the remainder being nitrogen-15. Fourteen radioisotopes are also known, with atomic masses ranging from 10 to 2 ...
lead to the formation of
carbon-14
Carbon-14, C-14, or radiocarbon, is a radioactive isotope of carbon with an atomic nucleus containing 6 protons and 8 neutrons. Its presence in organic materials is the basis of the radiocarbon dating method pioneered by Willard Libby and co ...
(
14C), widely used in
radiocarbon dating
Radiocarbon dating (also referred to as carbon dating or carbon-14 dating) is a method for determining the age of an object containing organic material by using the properties of radiocarbon, a radioactive isotope of carbon.
The method was de ...
.
Uses
''Cold'', ''thermal'' and ''hot'' neutron radiation is most commonly used in
scattering
Scattering is a term used in physics to describe a wide range of physical processes where moving particles or radiation of some form, such as light or sound, are forced to deviate from a straight trajectory by localized non-uniformities (including ...
and
diffraction
Diffraction is defined as the interference or bending of waves around the corners of an obstacle or through an aperture into the region of geometrical shadow of the obstacle/aperture. The diffracting object or aperture effectively becomes a s ...
experiments, to assess the properties and the structure of materials in
crystallography
Crystallography is the experimental science of determining the arrangement of atoms in crystalline solids. Crystallography is a fundamental subject in the fields of materials science and solid-state physics ( condensed matter physics). The wor ...
,
condensed matter physics
Condensed matter physics is the field of physics that deals with the macroscopic and microscopic physical properties of matter, especially the solid and liquid phases which arise from electromagnetic forces between atoms. More generally, the su ...
,
biology
Biology is the scientific study of life. It is a natural science with a broad scope but has several unifying themes that tie it together as a single, coherent field. For instance, all organisms are made up of cells that process hereditary ...
,
solid state chemistry,
materials science,
geology
Geology () is a branch of natural science concerned with Earth and other Astronomical object, astronomical objects, the features or rock (geology), rocks of which it is composed, and the processes by which they change over time. Modern geology ...
,
mineralogy
Mineralogy is a subject of geology specializing in the scientific study of the chemistry, crystal structure, and physical (including optical) properties of minerals and mineralized artifacts. Specific studies within mineralogy include the proce ...
, and related sciences. Neutron radiation is also used in
Boron Neutron Capture Therapy
Neutron capture therapy (NCT) is a type of radiotherapy for treating locally invasive malignant tumors such as primary brain tumors, recurrent cancers of the head and neck region, and cutaneous and extracutaneous melanomas. It is a two-step pro ...
to treat cancerous tumors due to its highly penetrating and damaging nature to cellular structure. Neutrons can also be used for imaging of industrial parts termed
neutron radiography when using film, neutron radioscopy when taking a digital image, such as through image plates, and
neutron tomography for three-dimensional images.
Neutron imaging is commonly used in the nuclear industry, the space and aerospace industry, as well as the high reliability explosives industry.
Ionization mechanisms and properties
Neutron radiation is often called ''indirectly
ionizing radiation
Ionizing radiation (or ionising radiation), including nuclear radiation, consists of subatomic particles or electromagnetic waves that have sufficient energy to ionize atoms or molecules by detaching electrons from them. Some particles can travel ...
''. It does not ionize atoms in the same way that charged particles such as
proton
A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive electric charge of +1 ''e'' elementary charge. Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton–electron mass ...
s and
electron
The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family,
and are generally thought to be elementary particles because they have n ...
s do (exciting an electron), because neutrons have no charge. However, neutron interactions are largely ionizing, for example when neutron absorption results in gamma emission and the
gamma ray
A gamma ray, also known as gamma radiation (symbol γ or \gamma), is a penetrating form of electromagnetic radiation arising from the radioactive decay of atomic nuclei. It consists of the shortest wavelength electromagnetic waves, typically ...
(photon) subsequently removes an electron from an atom, or a nucleus recoiling from a neutron interaction is ionized and causes more traditional subsequent ionization in other atoms. Because neutrons are uncharged, they are more penetrating than
alpha radiation or
beta radiation. In some cases they are more penetrating than gamma radiation, which is impeded in materials of high
atomic number
The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of an atomic nucleus. For ordinary nuclei, this is equal to the proton number (''n''p) or the number of protons found in the nucleus of ever ...
. In materials of low atomic number such as
hydrogen
Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-to ...
, a low energy gamma ray may be more penetrating than a high energy neutron.
Health hazards and protection
In
health physics, neutron radiation is a type of radiation hazard. Another, more severe hazard of neutron radiation, is
neutron activation
Neutron activation is the process in which neutron radiation induces radioactivity in materials, and occurs when atomic nuclei capture free neutrons, becoming heavier and entering excited states. The excited nucleus decays immediately by emit ...
, the ability of neutron radiation to induce
radioactivity in most substances it encounters, including bodily tissues. This occurs through the capture of neutrons by atomic nuclei, which are transformed to another
nuclide
A nuclide (or nucleide, from atomic nucleus, nucleus, also known as nuclear species) is a class of atoms characterized by their number of protons, ''Z'', their number of neutrons, ''N'', and their nuclear energy state.
The word ''nuclide'' was co ...
, frequently a
radionuclide
A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess nuclear energy, making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transfer ...
. This process accounts for much of the radioactive material released by the detonation of a
nuclear weapon
A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either fission (fission bomb) or a combination of fission and fusion reactions ( thermonuclear bomb), producing a nuclear explosion. Both bomb ...
. It is also a problem in nuclear fission and nuclear fusion installations as it gradually renders the equipment radioactive such that eventually it must be replaced and disposed of as low-level
radioactive waste
Radioactive waste is a type of hazardous waste that contains radioactive material. Radioactive waste is a result of many activities, including nuclear medicine, nuclear research, nuclear power generation, rare-earth mining, and nuclear weapon ...
.
Neutron
radiation protection
Radiation protection, also known as radiological protection, is defined by the International Atomic Energy Agency (IAEA) as "The protection of people from harmful effects of exposure to ionizing radiation, and the means for achieving this". Expos ...
relies on
radiation shielding. Due to the high kinetic energy of neutrons, this radiation is considered the most severe and dangerous radiation to the whole body when it is exposed to external radiation sources. In comparison to conventional ionizing radiation based on photons or charged particles, neutrons are repeatedly bounced and slowed (absorbed) by light nuclei so hydrogen-rich material is more effective at shielding than
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in ...
nuclei. The light atoms serve to slow down the neutrons by
elastic scattering so they can then be absorbed by
nuclear reaction
In nuclear physics and nuclear chemistry, a nuclear reaction is a process in which two nuclei, or a nucleus and an external subatomic particle, collide to produce one or more new nuclides. Thus, a nuclear reaction must cause a transformatio ...
s. However, gamma radiation is often produced in such reactions, so additional shielding must be provided to absorb it. Care must be taken to avoid using materials whose nuclei undergo fission or
neutron capture
Neutron capture is a nuclear reaction in which an atomic nucleus and one or more neutrons collide and merge to form a heavier nucleus. Since neutrons have no electric charge, they can enter a nucleus more easily than positively charged protons ...
that causes
radioactive decay
Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consid ...
of nuclei, producing gamma rays.
Neutrons readily pass through most material, and hence the absorbed dose (measured in
Gray
Grey (more common in British English) or gray (more common in American English) is an intermediate color between black and white. It is a neutral or achromatic color, meaning literally that it is "without color", because it can be compose ...
s) from a given amount of radiation is low, but interact enough to cause biological damage. The most effective shielding materials are
water
Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as ...
, or
hydrocarbon
In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ...
s like
polyethylene
Polyethylene or polythene (abbreviated PE; IUPAC name polyethene or poly(methylene)) is the most commonly produced plastic. It is a polymer, primarily used for packaging ( plastic bags, plastic films, geomembranes and containers including b ...
or
paraffin wax
Paraffin wax (or petroleum wax) is a soft colorless solid derived from petroleum, coal, or oil shale that consists of a mixture of hydrocarbon molecules containing between 20 and 40 carbon atoms. It is solid at room temperature and begins t ...
. Water-extended polyester (WEP) is effective as a shielding wall in harsh environments due to its high hydrogen content and resistance to fire, allowing it to be used in a range of nuclear, health physics, and defense industries. Hydrogen-based materials are suitable for shielding as they are proper barriers against radiation.
Concrete
Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most wid ...
(where a considerable number of water molecules chemically bind to the cement) and
gravel
Gravel is a loose aggregation of rock fragments. Gravel occurs naturally throughout the world as a result of sedimentary and erosive geologic processes; it is also produced in large quantities commercially as crushed stone.
Gravel is classifi ...
provide a cheap solution due to their combined shielding of both gamma rays and neutrons.
Boron
Boron is a chemical element with the symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the '' boron group'' it has t ...
is also an excellent neutron absorber (and also undergoes some neutron scattering). Boron decays into carbon or helium and produces virtually no gamma radiation with
boron carbide
Boron carbide (chemical formula approximately B4C) is an extremely hard boron– carbon ceramic, a covalent material used in tank armor, bulletproof vests, engine sabotage powders,
as well as numerous industrial applications. With a Vickers ...
, a shield commonly used where concrete would be cost prohibitive. Commercially, tanks of water or fuel oil, concrete, gravel, and B
4C are common shields that surround areas of large amounts of
neutron flux
The neutron flux, φ, is a scalar quantity used in nuclear physics and nuclear reactor physics. It is the total length travelled by all free neutrons per unit time and volume. Equivalently, it can be defined as the number of neutrons travellin ...
, e.g., nuclear reactors. Boron-impregnated silica glass, standard
borosilicate glass, high-
boron steel, paraffin, and
Plexiglas have niche uses.
Because neutrons that strike the hydrogen nucleus (
proton
A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive electric charge of +1 ''e'' elementary charge. Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton–electron mass ...
, or
deuteron) impart energy to that nucleus, they in turn break from their chemical bonds and travel a short distance before stopping. Such hydrogen nuclei are high
linear energy transfer
In dosimetry, linear energy transfer (LET) is the amount of energy that an ionizing particle transfers to the material traversed per unit distance. It describes the action of radiation into matter.
It is identical to the retarding force acting o ...
particles, and are in turn stopped by ionization of the material they travel through. Consequently, in living tissue, neutrons have a relatively high
relative biological effectiveness
In radiobiology, the relative biological effectiveness (often abbreviated as RBE) is the ratio of biological effectiveness of one type of ionizing radiation relative to another, given the same amount of absorbed energy. The RBE is an empiric ...
, and are roughly ten times more effective at causing biological damage compared to gamma or beta radiation of equivalent energy exposure. These neutrons can either cause cells to change in their functionality or to completely stop replicating, causing damage to the body over time.
Neutrons are particularly damaging to soft tissues like the
cornea
The cornea is the transparent front part of the eye that covers the iris, pupil, and anterior chamber. Along with the anterior chamber and lens, the cornea refracts light, accounting for approximately two-thirds of the eye's total optical ...
of the eye.
Effects on materials
High-energy neutrons damage and degrade materials over time; bombardment of materials with neutrons creates
collision cascades that can produce
point defects and
dislocation
In materials science, a dislocation or Taylor's dislocation is a linear crystallographic defect or irregularity within a crystal structure that contains an abrupt change in the arrangement of atoms. The movement of dislocations allow atoms to s ...
s in the material, the creation of which is the primary driver behind microstructural changes occurring over time in materials exposed to radiation. At high neutron
fluences this can lead to
embrittlement of metals and other materials, and to
neutron-induced swelling in some of them. This poses a problem for nuclear reactor vessels and significantly limits their lifetime (which can be somewhat prolonged by controlled
annealing of the vessel, reducing the number of the built-up dislocations). Graphite
neutron moderator
In nuclear engineering, a neutron moderator is a medium that reduces the speed of fast neutrons, ideally without capturing any, leaving them as thermal neutrons with only minimal (thermal) kinetic energy. These thermal neutrons are immensely m ...
blocks are especially susceptible to this effect, known as
Wigner effect
The Wigner effect (named for its discoverer, Eugene Wigner), also known as the discomposition effect or Wigner's disease, is the displacement of atoms in a solid caused by neutron radiation.
Any solid can display the Wigner effect. The effect ...
, and must be annealed periodically. The
Windscale fire was caused by a mishap during such an annealing operation.
Radiation damage to materials occurs as a result of the interaction of an energetic incident particle (a neutron, or otherwise) with a lattice atom in the material. The collision causes a massive transfer of kinetic energy to the lattice atom, which is displaced from its lattice site, becoming what is known as the
primary knock-on atom
In condensed-matter physics, a primary knock-on atom (PKA) is an atom that is displaced from its lattice site by irradiation; it is, by definition, the first atom that an incident particle encounters in the target. After it is displaced from its ...
(PKA). Because the PKA is surrounded by other lattice atoms, its displacement and passage through the lattice results in many subsequent collisions and the creations of additional knock-on atoms, producing what is known as the collision cascade or displacement cascade. The knock-on atoms lose energy with each collision, and terminate as
interstitials, effectively creating a series of
Frenkel defect
In crystallography, a Frenkel defect is a type of point defect in crystalline solids, named after its discoverer Yakov Frenkel. The defect forms when an atom or smaller ion (usually cation) leaves its place in the lattice, creating a vacanc ...
s in the lattice. Heat is also created as a result of the collisions (from electronic energy loss), as are possibly
transmuted atoms. The magnitude of the damage is such that a single 1
MeV neutron creating a PKA in an iron lattice produces approximately 1,100 Frenkel pairs.
[ unand, David. "Materials in Nuclear Power Generation." Materials Science & Engineering 381: Materials for Energy Efficient Technology. Northwestern University, Evanston. 3 Feb. 2015. Lecture/ref> The entire cascade event occurs over a timescale of 1 × 10−13 seconds, and therefore, can only be "observed" in computer simulations of the event.][A. Struchbery, E. Bezakova "Thermal-Spike Lifetime from Picosecond-Duration Preequilibrium Effects in Hyperfine Magnetic Fields Following Ion Implantation". 3 May. 1999.]
The knock-on atoms terminate in non-equilibrium interstitial lattice positions, many of which annihilate themselves by diffusing back into neighboring vacant lattice sites and restore the ordered lattice. Those that do not or cannot leave vacancies, which causes a local rise in the vacancy concentration far above that of the equilibrium concentration. These vacancies tend to migrate as a result of thermal diffusion towards vacancy sinks (i.e., grain boundaries
In materials science, a grain boundary is the interface between two grains, or crystallites, in a polycrystalline material. Grain boundaries are two-dimensional defects in the crystal structure, and tend to decrease the electrical and therma ...
, dislocations) but exist for significant amounts of time, during which additional high-energy particles bombard the lattice, creating collision cascades and additional vacancies, which migrate towards sinks. The main effect of irradiation in a lattice is the significant and persistent flux of defects to sinks in what is known as the defect wind. Vacancies can also annihilate by combining with one another to form dislocation loops and later, lattice voids.
The collision cascade creates many more vacancies and interstitials in the material than equilibrium for a given temperature, and diffusivity
Diffusivity is a rate of diffusion, a measure of the rate at which particles or heat or fluids can spread.
It is measured differently for different mediums.
Diffusivity may refer to:
* Thermal diffusivity, diffusivity of heat
*Diffusivity of mas ...
in the material is dramatically increased as a result. This leads to an effect called radiation-enhanced diffusion, which leads to microstructural evolution of the material over time. The mechanisms leading to the evolution of the microstructure are many, may vary with temperature, flux, and fluence, and are a subject of extensive study.
* Radiation-induced segregation results from the aforementioned flux of vacancies to sinks, implying a flux of lattice atoms away from sinks; but not necessarily in the same proportion to alloy composition in the case of an alloyed material. These fluxes may therefore lead to depletion of alloying elements in the vicinity of sinks. For the flux of interstitials introduced by the cascade, the effect is reversed: the interstitials diffuse toward sinks resulting in alloy enrichment near the sink.
* Dislocation loops are formed if vacancies form clusters on a lattice plane. If these vacancy concentration expand in three dimensions, a void forms. By definition, voids are under vacuum, but may became gas-filled in the case of alpha-particle radiation (helium) or if the gas is produced as a result of transmutation reactions. The void is then called a bubble, and leads to dimensional instability (neutron-induced swelling) of parts subject to radiation. Swelling presents a major long-term design problem, especially in reactor components made out of stainless steel. Alloys with crystallographic isotropy
Isotropy is uniformity in all orientations; it is derived . Precise definitions depend on the subject area. Exceptions, or inequalities, are frequently indicated by the prefix ' or ', hence '' anisotropy''. ''Anisotropy'' is also used to describ ...
, such as Zircaloy
Zirconium alloys are solid solutions of zirconium or other metals, a common subgroup having the trade mark Zircaloy. Zirconium has very low absorption cross-section of thermal neutrons, high hardness, ductility and corrosion resistance. One of the ...
s are subject to the creation of dislocation loops, but do not exhibit void formation. Instead, the loops form on particular lattice planes, and can lead to irradiation-induced growth, a phenomenon distinct from swelling, but that can also produce significant dimensional changes in an alloy.[Adamson, R. "Effects of Neutron Radiation on Microstructure and the Properties of Zircaloy" 1977. 08 Feb. 2015.]
*Irradiation of materials can also induce phase transformations in the material: in the case of a solid solution, the solute enrichment or depletion at sinks radiation-induced segregation can lead to the precipitation of new phases in the material.[Hyun Ju Jin, Tae Kyu Kim. "Neutron irradiation performance of Zircaloy-4 under research reactor operating conditions." Annals of Nuclear Energy. 13 Sept. 2014 Web. 08 Feb. 2015.]
The mechanical effects of these mechanisms include irradiation hardening, embrittlement, creep
Creep, Creeps or CREEP may refer to:
People
* Creep, a creepy person
Politics
* Committee for the Re-Election of the President (CRP), mockingly abbreviated as CREEP, an fundraising organization for Richard Nixon's 1972 re-election campaign
Art ...
, and environmentally-assisted cracking. The defect clusters, dislocation loops, voids, bubbles, and precipitates produced as a result of radiation in a material all contribute to the strengthening and embrittlement (loss of ductility
Ductility is a mechanical property commonly described as a material's amenability to drawing (e.g. into wire). In materials science, ductility is defined by the degree to which a material can sustain plastic deformation under tensile str ...
) in the material. Embrittlement is of particular concern for the material comprising the reactor pressure vessel, where as a result the energy required to fracture the vessel decreases significantly. It is possible to restore ductility by annealing the defects out, and much of the life-extension of nuclear reactors depends on the ability to safely do so. Creep
Creep, Creeps or CREEP may refer to:
People
* Creep, a creepy person
Politics
* Committee for the Re-Election of the President (CRP), mockingly abbreviated as CREEP, an fundraising organization for Richard Nixon's 1972 re-election campaign
Art ...
is also greatly accelerated in irradiated materials, though not as a result of the enhanced diffusivities, but rather as a result of the interaction between lattice stress and the developing microstructure. Environmentally-assisted cracking or, more specifically, irradiation-assisted stress corrosion cracking (IASCC) is observed especially in alloys subject to neutron radiation and in contact with water, caused by hydrogen absorption at crack tips resulting from radiolysis
Radiolysis is the dissociation of molecules by ionizing radiation. It is the cleavage of one or several chemical bonds resulting from exposure to high-energy flux. The radiation in this context is associated with ionizing radiation; radiolysis is ...
of the water, leading to a reduction in the required energy to propagate the crack.
See also
* Neutron emission
* Neutron flux
The neutron flux, φ, is a scalar quantity used in nuclear physics and nuclear reactor physics. It is the total length travelled by all free neutrons per unit time and volume. Equivalently, it can be defined as the number of neutrons travellin ...
* Neutron radiography
References
https://journals.aps.org/prl/abstract/10.1103/PhysRevLett.111.222501
External links
neutronradiation EPA definitions of various terms]
Neutron techniques A unique tool for research and development
{{Authority control
IARC Group 1 carcinogens
Ionizing radiation
Radiation
In physics, radiation is the emission or transmission of energy in the form of waves or particles through space or through a material medium. This includes:
* ''electromagnetic radiation'', such as radio waves, microwaves, infrared, visi ...
Neutron-related techniques