tectosilicate
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust.
In mineralogy, silica (silicon dioxide, ) is usually consi ...
mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
species belonging to the
zeolite
Zeolites are microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ･y where is either a metal ion or H+. These po ...
group. It is a hydrated
sodium
Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable is ...
and
aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It has ...
Hohentwiel
Hohentwiel is an extinct volcano in the Hegau region of Baden-Württemberg in southern Germany The mountain is west of the city of Singen and 20 miles (30 km) from Lake Constance.
Hohentwiel began forming, along with the chain of v ...
Martin Heinrich Klaproth
Martin Heinrich Klaproth (1 December 1743 – 1 January 1817) was a German chemist. He trained and worked for much of his life as an apothecary, moving in later life to the university. His shop became the second-largest apothecary in Berlin, and ...
in 1803. The name is derived from ''natron'' (), the Greek word for soda, in reference to the sodium content, and ''lithos'' (), meaning stone. Needle stone or needle-zeolite are other informal names, alluding to the common acicular habit of the crystals, which are often very slender and are aggregated in divergent tufts. The crystals are frequently epitaxial overgrowths of natrolite,
mesolite
Mesolite is a tectosilicate mineral with formula Na2 Ca2( Al2 Si3 O10)3·8 H2O. It is a member of the zeolite group and is closely related to natrolite which it also resembles in appearance.
Mesolite crystallizes in the orthorhombic system and t ...
, and
gonnardite
Gonnardite is a comparatively rare, fibrous zeolite, natrolite subgroup. Older papers claim that a complete solid solution exists between tetranatrolite and gonnardite, but tetranatrolite was discredited as a separate species in 1999.American M ...
in various orders.
Properties
Larger crystals most commonly have the form of a square prism terminated by a low pyramid, the prism angle being nearly a right angle. The crystals are tetragonal in appearance, though actually orthorhombic. There are perfect cleavages parallel to the faces of the prism. The mineral also often occurs in compact fibrous aggregates, the fibers having a divergent or radial arrangement. Natrolite is readily distinguished from other fibrous zeolites by its optical characteristics.
Between crossed
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s the fibers extinguish parallel to their length, and they do not show an optic figure in convergent polarized light. Natrolite is usually white or colorless, but sometimes reddish or yellowish. The luster is vitreous, or, in finely fibrous specimens, silky.
The
specific gravity
Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water at its densest ...
is 2.2, and the
hardness
In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion. In general, different materials differ in their hardness; for example hard ...
is 5.5. The mineral is readily fusible, melting in a candle-flame to which it imparts a yellow color owing to the presence of sodium. It is decomposed by
hydrochloric acid
Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride. It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid. It is a component of the gastric acid in the digestiv ...
with separation of gelatinous
silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
.
Environment
Natrolite occurs with other zeolites in the amygdaloidal cavities of
basalt
Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90% of a ...
ic
igneous rock
Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma or ...
s. It is also common in nepheline syenites.
Notable localities
Excellent specimens of diverging groups of white prismatic crystals are found in compact
basalt
Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90% of a ...
at the Puy-deMarman,
Puy-de-Dôme
Puy-de-Dôme (; oc, label=Auvergnat, lo Puèi de Doma or ''lo Puèi Domat'') is a department in the Auvergne-Rhône-Alpes region in the centre of France. In 2019, it had a population of 662,152.France. Huge crystals have been found on the Kola Peninsula, Russia (30 cm by 13 cm). The walls of cavities in the basalt of the Giants Causeway, in
County Antrim
County Antrim (named after the town of Antrim, ) is one of six counties of Northern Ireland and one of the thirty-two counties of Ireland. Adjoined to the north-east shore of Lough Neagh, the county covers an area of and has a population of ...
, are frequently encrusted with slender needles of natrolite, and similar material is found abundantly in the volcanic rocks (basalt and
phonolite
Phonolite is an uncommon extrusive rock, of intermediate chemical composition between felsic and mafic, with texture ranging from aphanitic (fine-grained) to porphyritic (mixed fine- and coarse-grained). Phonolite is a variation of the igneous ...
) of Salesel, Aussig and several other places in the north of
Bohemia
Bohemia ( ; cs, Čechy ; ; hsb, Čěska; szl, Czechy) is the westernmost and largest historical region of the Czech Republic. Bohemia can also refer to a wider area consisting of the historical Lands of the Bohemian Crown ruled by the Bohe ...
. Mont St. Hilaire,
Quebec
Quebec ( ; )According to the Canadian government, ''Québec'' (with the acute accent) is the official name in Canadian French and ''Quebec'' (without the accent) is the province's official name in Canadian English is one of the thirteen ...
has produced large crystals associated with many rare minerals. The
Bay of Fundy
The Bay of Fundy (french: Baie de Fundy) is a bay between the Canadian provinces of New Brunswick and Nova Scotia, with a small portion touching the U.S. state of Maine. It is an arm of the Gulf of Maine. Its extremely high tidal range is the h ...
in
Nova Scotia
Nova Scotia ( ; ; ) is one of the thirteen provinces and territories of Canada. It is one of the three Maritime provinces and one of the four Atlantic provinces. Nova Scotia is Latin for "New Scotland".
Most of the population are native Engl ...
,
New Jersey
New Jersey is a state in the Mid-Atlantic and Northeastern regions of the United States. It is bordered on the north and east by the state of New York; on the east, southeast, and south by the Atlantic Ocean; on the west by the Delaware ...
,
Oregon
Oregon () is a state in the Pacific Northwest region of the Western United States. The Columbia River delineates much of Oregon's northern boundary with Washington, while the Snake River delineates much of its eastern boundary with Idaho. ...
, and British Columbia have also produced excellent specimens.
Several varieties of natrolite have been distinguished by special Nips. Fargite is a red natrolite from Glenfarg in Perthshire. Bergmannite, or Spreustein, is an impure variety which has resulted by the alteration of other minerals, chiefly
sodalite
Sodalite ( ) is a tectosilicate mineral with the formula , with royal blue varieties widely used as an ornamental gemstone. Although massive sodalite samples are opaque, crystals are usually transparent to translucent. Sodalite is a member of the ...
, in the
augite
Augite is a common rock-forming pyroxene mineral with formula . The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees.
Characteristics
Augite is a solid solution in the pyroxene grou ...
syenite
Syenite is a coarse-grained intrusive igneous rock with a general composition similar to that of granite, but deficient in quartz, which, if present at all, occurs in relatively small concentrations (< 5%). Some syenites contain larger proport ...
of southern Norway.
Natrolite is one of the closely associated minerals with Benitoite, a rare mineral with the type locality in San Benito County, California.
Images
File:Zeolite-greenland hg.jpg, Natrolite from the plateau basalts in east Greenland
File:Natrolite-61051.jpg, Colorless, radiating natrolite in zeolite pod
File:Catapleiite, Natrolite-168971.jpg, Catapleiite and natrolite from Poudrette quarry, Québec, Canada
File:Natrolite-Inesite-21148.jpg, Slender needles of natrolite are accented by deep pink inesites
File:Natrolite-223955.jpg, Natrolite in spherical clusters inside protective pocket of volcanic rock
File:Natrolite-Inesite-37029.jpg, Natrolite sprays of stark white crystals are shooting out from a
vug
A vug, vugh, or vugg (
) is a small- to medium-sized cavity inside rock. It may be formed through a variety of processes. Most commonly, cracks and fissures opened by tectonic activity ( folding and faulting) are partially filled by quartz, c ...