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A monoisotopic element is an element which has only a single
stable isotope The term stable isotope has a meaning similar to stable nuclide, but is preferably used when speaking of nuclides of a specific element. Hence, the plural form stable isotopes usually refers to isotopes of the same element. The relative abundanc ...
(nuclide). There are only 26 elements that have this property. A list is given in a following section. Stability is experimentally defined for chemical elements, as there are a number of stable nuclides with atomic numbers over ~40 which are theoretically unstable, but apparently have half-lives so long that they have not been observed directly or indirectly (from measurement of products) to decay. Monoisotopic elements are characterized, except in a single case, by odd numbers of protons (odd ''Z''), and even numbers of neutrons. Because of the energy gain from nuclear pairing effects, the odd number of protons imparts instability to isotopes of an odd ''Z'', which in heavier elements requires a completely paired set of neutrons to offset this tendency into stability. (The five stable nuclides with odd ''Z'' and odd neutron numbers are hydrogen-2, lithium-6, boron-10, nitrogen-14, and tantalum-180m1.) The single mononuclidic exception to the odd ''Z'' rule is beryllium; its single stable, primordial isotope, beryllium-9, has 4 protons and 5 neutrons. This element is prevented from having a stable isotope with equal numbers of neutrons and protons (
beryllium-8 Beryllium-8 (8Be, Be-8) is a radionuclide with 4 neutrons and 4 protons. It is an unbound resonance and nominally an isotope of beryllium. It decays into two alpha particles with a half-life on the order of 8.19 seconds. This has important r ...
, with 4 of each) by its instability toward
alpha decay Alpha decay or α-decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle (helium nucleus) and thereby transforms or 'decays' into a different atomic nucleus, with a mass number that is reduced by four and an at ...
, which is favored due to the extremely tight binding of
helium-4 Helium-4 () is a stable isotope of the element helium. It is by far the more abundant of the two naturally occurring isotopes of helium, making up about 99.99986% of the helium on Earth. Its nucleus is identical to an alpha particle, and cons ...
nuclei. It is prevented from having a stable isotope with 4 protons and 6 neutrons by the very large mismatch in proton/neutron ratio for such a light element. (Nevertheless,
beryllium-10 Beryllium-10 (10Be) is a radioactive isotope of beryllium. It is formed in the Earth's atmosphere mainly by cosmic ray spallation of nitrogen and oxygen. Beryllium-10 has a half-life of 1.39 × 106 years, and decays by beta decay to stable boron- ...
has a half-life of 1.36 million years, which is too short to be
primordial Primordial may refer to: * Primordial era, an era after the Big Bang. See Chronology of the universe * Primordial sea (a.k.a. primordial ocean, ooze or soup). See Abiogenesis * Primordial nuclide, nuclides, a few radioactive, that formed before t ...
, but still indicates unusual stability for a light isotope with such an imbalance.)


Differentiation from mononuclidic elements

The set of monoisotopic elements overlap but are not the same as the set of 21
mononuclidic element A mononuclidic element or monotopic element is one of the 21 chemical elements that is found naturally on Earth essentially as a single nuclide (which may, or may not, be a stable nuclide). This single nuclide will have a characteristic atomic m ...
s, which are characterized as having essentially only one isotope (nuclide) found in nature. The reason for this is the occurrence of certain long-lived radioactive
primordial nuclide In geochemistry, geophysics and nuclear physics, primordial nuclides, also known as primordial isotopes, are nuclides found on Earth that have existed in their current form since before Earth was formed. Primordial nuclides were present in the ...
s in nature, which may form admixtures with the monoisotopics, and thus prevent them from being naturally mononuclidic. This happens in the cases of 7 () of the monoisotopic elements. These isotopes are monoisotopic, but due to the presence of the long-lived radioactive primordial nuclide, are not mononuclidic. These elements are
vanadium Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer ( pass ...
,
rubidium Rubidium is the chemical element with the symbol Rb and atomic number 37. It is a very soft, whitish-grey solid in the alkali metal group, similar to potassium and caesium. Rubidium is the first alkali metal in the group to have a density higher ...
,
indium Indium is a chemical element with the symbol In and atomic number 49. Indium is the softest metal that is not an alkali metal. It is a silvery-white metal that resembles tin in appearance. It is a post-transition metal that makes up 0.21 parts ...
,
lanthanum Lanthanum is a chemical element with the symbol La and atomic number 57. It is a soft, ductile, silvery-white metal that tarnishes slowly when exposed to air. It is the eponym of the lanthanide series, a group of 15 similar elements between l ...
,
europium Europium is a chemical element with the symbol Eu and atomic number 63. Europium is the most reactive lanthanide by far, having to be stored under an inert fluid to protect it from atmospheric oxygen or moisture. Europium is also the softest lan ...
,
lutetium Lutetium is a chemical element with the symbol Lu and atomic number 71. It is a silvery white metal, which resists corrosion in dry air, but not in moist air. Lutetium is the last element in the lanthanide series, and it is traditionally counted am ...
and
rhenium Rhenium is a chemical element with the symbol Re and atomic number 75. It is a silvery-gray, heavy, third-row transition metal in group 7 of the periodic table. With an estimated average concentration of 1 part per billion (ppb), rhenium is one ...
. See the list below; in two noted cases (indium and rhenium), the long-lived radionuclide is actually the most abundant isotope in nature, and the stable isotope is less abundant. In 2 additional cases (
bismuth Bismuth is a chemical element with the symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs ...
Until 2003, 209Bi was thought to be in the first category. It was then found to have a
half-life Half-life (symbol ) is the time required for a quantity (of substance) to reduce to half of its initial value. The term is commonly used in nuclear physics to describe how quickly unstable atoms undergo radioactive decay or how long stable ...
of 1019 years, about a billion times the age of the universe. See
Bismuth Bismuth is a chemical element with the symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs ...
and
protactinium Protactinium (formerly protoactinium) is a chemical element with the symbol Pa and atomic number 91. It is a dense, silvery-gray actinide metal which readily reacts with oxygen, water vapor and inorganic acids. It forms various chemical compounds ...
), mononuclidic elements occur primordially which are not monoisotopic because the naturally occurring nuclide is radioactive, and thus the element has no stable isotopes at all. For an element to be monoisotopic, it must have one stable nuclide.


List of (observationally-stable) monoisotopic elements, ordered by atomic number and weight

Non-
mononuclidic element A mononuclidic element or monotopic element is one of the 21 chemical elements that is found naturally on Earth essentially as a single nuclide (which may, or may not, be a stable nuclide). This single nuclide will have a characteristic atomic m ...
s are marked with an asterisk, and the long-lived primordial radioisotope given. In two notable cases (indium and rhenium), the highest abundance naturally occurring isotope is the mildly radioactive one, and in the case of europium, nearly half of it is. #
Beryllium-9 Beryllium (4Be) has 11 known isotopes and 3 known isomers, but only one of these isotopes () is stable and a primordial nuclide. As such, beryllium is considered a monoisotopic element. It is also a mononuclidic element, because its other isot ...
# Fluorine-19 # Sodium-23 # Aluminium-27 # Phosphorus-31 # Scandium-45 # Vanadium-51* naturally occurs with 0.25% of radioactive vanadium-50 # Manganese-55 #
Cobalt-59 Naturally occurring cobalt (Co) consists of a single stable isotope, Co. Twenty-eight radioisotopes have been characterized; the most stable are Co with a half-life of 5.2714 years, Co (271.8 days), Co (77.27 days), and Co (70.86 days). All other ...
# Arsenic-75 #
Rubidium-85 Rubidium (37Rb) has 36 isotopes, with naturally occurring rubidium being composed of just two isotopes; 85Rb (72.2%) and the radioactive 87Rb (27.8%). Normal mixes of rubidium are radioactive enough to fog photographic film in approximately 30 t ...
* naturally occurs with 27.835% of radioactive
rubidium-87 Rubidium (37Rb) has 36 isotopes, with naturally occurring rubidium being composed of just two isotopes; 85Rb (72.2%) and the radioactive 87Rb (27.8%). Normal mixes of rubidium are radioactive enough to fog photographic film in approximately 30 to ...
#
Yttrium-89 Natural yttrium (39Y) is composed of a single isotope yttrium-89. The most stable radioisotopes are 88Y, which has a half-life of 106.6 days and 91Y with a half-life of 58.51 days. All the other isotopes have half-lives of less than a day, except ...
# Niobium-93 #
Rhodium-103 Naturally occurring rhodium (45Rh) is composed of only one stable isotope, 103Rh. The most stable radioisotopes are 101Rh with a half-life of 3.3 years, 102Rh with a half-life of 207 days, and 99Rh with a half-life of 16.1 days. Thirty other radio ...
# Indium-113* naturally occurs with majority (95.7%) radioactive isotope indium-115 # Iodine-127 #
Caesium-133 Caesium (55Cs) has 40 known isotopes, making it, along with barium and mercury, one of the elements with the most isotopes. The atomic masses of these isotopes range from 112 to 151. Only one isotope, 133Cs, is stable. The longest-lived radioiso ...
# Lanthanum-139* naturally occurs with 0.09% radioactive lanthanum-138 # Praseodymium-141 # Europium-153* naturally occurs with 47.8% radioactive europium-151 #
Terbium-159 Naturally occurring terbium (65Tb) is composed of one stable isotope, 159Tb. Thirty-seven radioisotopes have been characterized, with the most stable being 158Tb with a half-life of 180 years, 157Tb with a half-life of 71 years, and 160Tb with a h ...
# Holmium-165 #
Thulium-169 Naturally occurring thulium (69Tm) is composed of one stable isotope, 169Tm (100% natural abundance). Thirty-four radioisotopes have been characterized, with the most stable being 171Tm with a half-life of 1.92 years, 170Tm with a half-life of 128 ...
# Lutetium-175* naturally occurs with 2.59% radioactive lutetium-176 #
Rhenium-185 Naturally occurring rhenium (75Re) is 37.4% 185Re, which is stable (although it is predicted to decay), and 62.6% 187Re, which is unstable but has a very long half-life (4.12×1010 years). Among elements with a known stable isotope, only indium ...
* naturally occurs with majority (62.6%) radioactive isotope rhenium-187 #
Gold-197 Gold (79Au) has one stable isotope, 197Au, and 36 radioisotopes, with 195Au being the most stable with a half-life of 186 days. Gold is currently considered the heaviest monoisotopic element. Bismuth formerly held that distinction until alpha-dec ...


See also

*
Primordial nuclide In geochemistry, geophysics and nuclear physics, primordial nuclides, also known as primordial isotopes, are nuclides found on Earth that have existed in their current form since before Earth was formed. Primordial nuclides were present in the ...
*
List of nuclides This list of nuclides shows observed nuclides that either are stable or, if radioactive, have half-lives longer than one hour. This represents isotopes of the first 105 elements, except for elements 87 (francium) and 102 (nobelium). At least 3,300 ...
(sorted by half-life) *
Table of nuclides A table or chart of nuclides is a two-dimensional Cartesian coordinate system, graph of isotopes of the elements, in which one axis represents the number of neutrons (symbol ''N'') and the other represents the number of protons (atomic number, sy ...
*
Isotope geochemistry Isotope geochemistry is an aspect of geology based upon the study of natural variations in the relative abundances of isotopes of various elements. Variations in isotopic abundance are measured by isotope ratio mass spectrometry, and can reveal ...
*
Radionuclide A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess nuclear energy, making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transfer ...
*
Mononuclidic element A mononuclidic element or monotopic element is one of the 21 chemical elements that is found naturally on Earth essentially as a single nuclide (which may, or may not, be a stable nuclide). This single nuclide will have a characteristic atomic m ...
*
Stable isotope The term stable isotope has a meaning similar to stable nuclide, but is preferably used when speaking of nuclides of a specific element. Hence, the plural form stable isotopes usually refers to isotopes of the same element. The relative abundanc ...
*
List of elements by stability of isotopes Atomic nuclei consist of protons and neutrons, which attract each other through the nuclear force, while protons repel each other via the electric force due to their positive charge. These two forces compete, leading to some combinations of neut ...


References


External links


Atomic Weights of the Elements as of year 2000, with a section on monoisotopics starting page 708
{{DEFAULTSORT:Monoisotopic Element Isotopes Sets of chemical elements Metrology