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Lamproite is an ultrapotassic
mantle A mantle is a piece of clothing, a type of cloak. Several other meanings are derived from that. Mantle may refer to: *Mantle (clothing), a cloak-like garment worn mainly by women as fashionable outerwear **Mantle (vesture), an Eastern Orthodox ve ...
-derived
volcanic A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. On Earth, volcanoes are most often found where tectonic plat ...
or subvolcanic rock. It has low CaO, Al2O3, Na2O, high K2O/Al2O3, a relatively high
MgO Magnesium oxide ( Mg O), or magnesia, is a white hygroscopic solid mineral that occurs naturally as periclase and is a source of magnesium (see also oxide). It has an empirical formula of MgO and consists of a lattice of Mg2+ ions and O2− ion ...
content and extreme enrichment in incompatible elements. Lamproites are geographically widespread yet are volumetrically insignificant. Unlike kimberlites, which are found exclusively in Archaean
craton A craton (, , or ; from grc-gre, κράτος "strength") is an old and stable part of the continental lithosphere, which consists of Earth's two topmost layers, the crust and the uppermost mantle. Having often survived cycles of merging and ...
s, lamproites are found in terrains of varying age, ranging from Archaean in Western Australia, to Palaeozoic and Mesozoic in southern Spain. They also vary widely in age, from
Proterozoic The Proterozoic () is a geological eon spanning the time interval from 2500 to 538.8million years ago. It is the most recent part of the Precambrian "supereon". It is also the longest eon of the Earth's geologic time scale, and it is subdivided i ...
to
Pleistocene The Pleistocene ( , often referred to as the ''Ice age'') is the geological Epoch (geology), epoch that lasted from about 2,580,000 to 11,700 years ago, spanning the Earth's most recent period of repeated glaciations. Before a change was fina ...
, the youngest known example from Gaussberg in Antarctica being 56,000 ± 5,000 years old. Lamproite volcanology is varied, with both
diatreme A diatreme, sometimes known as a maar-diatreme volcano, is a volcanic pipe formed by a gaseous explosion. When magma rises up through a crack in Earth's crust and makes contact with a shallow body of groundwater, rapid expansion of heated wate ...
styles and
cinder cone A cinder cone (or scoria cone) is a steep conical hill of loose pyroclastic fragments, such as volcanic clinkers, volcanic ash, or scoria that has been built around a volcanic vent. The pyroclastic fragments are formed by explosive eruption ...
or cone edifices known.


Petrology

Lamproites form from partially melted
mantle A mantle is a piece of clothing, a type of cloak. Several other meanings are derived from that. Mantle may refer to: *Mantle (clothing), a cloak-like garment worn mainly by women as fashionable outerwear **Mantle (vesture), an Eastern Orthodox ve ...
at depths exceeding 150 km. The molten material is forced to the surface in volcanic pipes, bringing with it
xenolith A xenolith ("foreign rock") is a rock fragment ( country rock) that becomes enveloped in a larger rock during the latter's development and solidification. In geology, the term ''xenolith'' is almost exclusively used to describe inclusions in ig ...
s and diamonds from the harzburgitic
peridotite Peridotite ( ) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high pr ...
or eclogite mantle regions where diamond formation is stabilized. Recent research, for example on the lamproites at Gaussberg in Antarctica, and lead-lead isotope geochemistry have revealed that the source of lamproites may be transition zone melts of subducted
lithosphere A lithosphere () is the rigid, outermost rocky shell of a terrestrial planet or natural satellite. On Earth, it is composed of the crust and the portion of the upper mantle that behaves elastically on time scales of up to thousands of years ...
which has become trapped at the base of the lithospheric mantle. This observation also reconciles the depth of melting with the peculiar geochemistry, which is most easily explained by melting of already felsic material under deep mantle conditions.


Mineralogy

The mineralogy of lamproites is controlled by their peculiar
geochemistry Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing th ...
, with a predominance of rare silica-deficient mineral species and rare, mantle-derived minerals predominating. Minerals typical of lamproites include: forsteritic olivine; high
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in ...
leucite;
titanium Titanium is a chemical element with the symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion i ...
-rich
aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It ha ...
-poor phlogopite;
potassium Potassium is the chemical element with the symbol K (from Neo-Latin '' kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmos ...
- and titanium-rich richterite; low aluminium
diopside Diopside is a monoclinic pyroxene mineral with composition . It forms complete solid solution series with hedenbergite () and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull ...
; and iron-rich
sanidine Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal s ...
. A variety of rare trace minerals occur. The rocks are high in potassium with 6 to 8%
potassium oxide Potassium oxide ( K O) is an ionic compound of potassium and oxygen. It is a base. This pale yellow solid is the simplest oxide of potassium. It is a highly reactive compound that is rarely encountered. Some industrial materials, such as fertili ...
. High
chromium Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal. Chromium metal is valued for its high corrosion resistance and hard ...
and
nickel Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow t ...
content is typical. The rocks commonly are altered to talc with
carbonate A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate ...
or serpentine,
chlorite The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chlorou ...
, and
magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With ...
.
Zeolite Zeolites are microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ・y where is either a metal ion or H+. These p ...
s and
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical f ...
may also occur. Lamproites are characterized by the presence of widely varying amounts (5-90 vol.%) of the following primary phases (Mitchell & Bergman, 1991): * titanian (2-10 wt% TiO2), aluminium-poor (5-12 wt% Al2O3) phenocrystic phlogopite * titanian (5-10 wt% TiO2) groundmass poikilitic "tetraferriphlogopite" * titanian (3-5 wt% TiO2) potassium (4-6 wt% K2O) richterite * forsteritic olivine * aluminium-poor (<1 wt% Al2O3), sodium-poor (<1 wt% Na2O) diopside * nonstoichiometric iron-rich (1-4 wt% Fe2O3) leucite, and * iron-rich sanidine (typically 1-5 wt% Fe2O3)). The presence of all the above phases is not required in order to classify a rock as a lamproite. Any one mineral may be dominant, and this, together with the two or three other major minerals present, suffices to determine the petrographic name. The presence of the following minerals precludes a rock from being classified as a lamproite: primary
plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more p ...
, melilite, monticellite, kalsilite,
nepheline Nepheline, also called nephelite (), is a rock-forming mineral in the feldspathoid groupa silica-undersaturated aluminosilicate, Na3 K Al4 Si4 O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmati ...
, Na-rich
alkali feldspar Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feldspa ...
, sodalite, nosean, hauyne, melanite, schorlomite or kimzeyite.


Geochemistry

Lamproites conform to the following chemical characteristics: * molar K2O/Na2O > 3, i.e., ultrapotassic * molar K2O/Al2O3> 0.8 and commonly > 1 * molar K2O + Na2O/ Al2O3 typically > 1 i.e., peralkaline * typically <10 wt% each of FeO and CaO, TiO2 1-7 wt%, >2000 and commonly >5000 ppm Ba, >500 ppm Zr, >1000 ppm Sr and >200 ppm La.


Economic importance

The economic significance of lamproite became known with the discovery of Ellendale E4 and E9 lamproite pipes and better known 1979 discovery of the Argyle diamond pipe in
Western Australia Western Australia (commonly abbreviated as WA) is a state of Australia occupying the western percent of the land area of Australia excluding external territories. It is bounded by the Indian Ocean to the north and west, the Southern Ocean to t ...
. This discovery led to the intense study and re-evaluation of other known lamproite occurrences worldwide; previously only kimberlite pipes were considered economically viable sources of
diamond Diamond is a solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Another solid form of carbon known as graphite is the chemically stable form of carbon at room temperature and pressure, b ...
s. The Argyle diamond mine remains the only economically viable source of lamproite diamonds. This deposit differs markedly by having a high content of diamonds but low quality of most stones. Research at Argyle diamond have shown that most stones are of E-type; they originate from eclogite source rocks and were formed under high temperature ~. The Argyle diamond mine is the main source of rare pink diamonds.
Olivine The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers qui ...
lamproite
pyroclastic Pyroclastic rocks (derived from the el, πῦρ, links=no, meaning fire; and , meaning broken) are clastic rocks composed of rock fragments produced and ejected by explosive volcanic eruptions. The individual rock fragments are known as pyroc ...
rocks and
dikes Dyke (UK) or dike (US) may refer to: General uses * Dyke (slang), a slang word meaning "lesbian" * Dike (geology), a subvertical sheet-like intrusion of magma or sediment * Dike (mythology), ''Dikē'', the Greek goddess of moral justice * Dikes ...
are sometimes hosts for
diamond Diamond is a solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Another solid form of carbon known as graphite is the chemically stable form of carbon at room temperature and pressure, b ...
s. The diamonds occur as
xenocryst A xenolith ("foreign rock") is a rock fragment (country rock) that becomes enveloped in a larger rock during the latter's development and solidification. In geology, the term ''xenolith'' is almost exclusively used to describe inclusions in ig ...
s that have been carried to the surface or to shallow depths by the lamproite
diapir A diapir (; , ) is a type of igneous intrusion in which a more mobile and ductily deformable material is forced into brittle overlying rocks. Depending on the tectonic environment, diapirs can range from idealized mushroom-shaped Rayleigh–T ...
ic
intrusion In geology, an igneous intrusion (or intrusive body or simply intrusion) is a body of intrusive igneous rock that forms by crystallization of magma slowly cooling below the surface of the Earth. Intrusions have a wide variety of forms and com ...
s. The diamonds of Crater of Diamonds State Park near Murfreesboro, Arkansas are found in a lamproite host.


Nomenclature

Lamproites, as a group, were known by a variety of localised names due to the fact their mineralogy is quite variable and because of their rarity often few examples of the following lamproite variants were known. Modern terminology classes all as lamproites but modifies this term with the mineral abundances as per the standard IUGS rules.


Related rock types

* * *


References


Further reading

* Bergman, S. C.; 1987: Lamproites and other potassium-rich igneous rocks: a review of their occurrences, mineralogy and geochemistry. In: Alkaline Igneous rocks, Fitton, J.G. and Upton, B.G.J (Eds.), Geological Society of London special publication No. 30. pp. 103–19. * * * Woolley, A.R., Bergman, S.C., Edgar, A.D, Le Bas, M.J., Mitchell, R.H., Rock, N.M.S. & Scott Smith, B.H., 1996. Classification of lamprophyres, lamproites, kimberlites, and the kalsilitic, melilitic, and leucitic rocks. The Canadian Mineralogist, Vol 34, Part 2. pp. 175–186. * Müller, Daniel, Groves, David I., (2019): Potassic igneous rocks and associated gold-copper mineralization (5th ed.). Mineral Resource Reviews. Springer Verlag, Cham; 398pp.


External links


LAMPROITE-HOSTED DIAMONDS
retrieved June 7, 2005

retrieved June 7, 2005

retrieved June 7, 2005

{{Authority control Ultrapotassic rocks Economic geology Igneous petrology Volcanic rocks Subvolcanic rocks