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Kainite ( or ) (KMg(SO4)Cl·3H2O) is an
evaporite An evaporite () is a water-soluble sedimentary mineral deposit that results from concentration and crystallization by evaporation from an aqueous solution. There are two types of evaporite deposits: marine, which can also be described as ocean ...
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
in the class of "Sulfates (selenates, etc.) with additional anions, with H2O" according to the
Nickel–Strunz classification Nickel–Strunz classification is a scheme for categorizing minerals based upon their chemical composition, introduced by German mineralogist Karl Hugo Strunz (24 February 1910 – 19 April 2006) in his ''Mineralogische Tabellen'' (1941). The 4th ...
. It is a hydrated potassium-magnesium sulfate-chloride, naturally occurring in irregular granular masses or as crystalline coatings in cavities or fissures. This mineral is dull and soft, and is colored white, yellowish, grey, reddish, or blue to violet. Its name is derived from Greek καινος ainos("(hitherto) unknown"), as it was the first mineral discovered that contained both
sulfate The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ...
and
chloride The chloride ion is the anion (negatively charged ion) Cl−. It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents. Chloride salts ...
as
anion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...
s. Kainite forms
monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic s ...
crystals.


Properties

Kainite is of bitter taste and soluble in water. On recrystallization
picromerite Picromerite (synonyms: schoenite, schönite) is a mineral from the class of hydrous sulfates lacking additional anions, and containing medium to large cations according to the Nickel–Strunz classification. Etymology The name comes from the Gr ...
is deposited from the solution.


Genesis and occurrence

Kainite was discovered in the Stassfurt salt mines in today's
Saxony-Anhalt Saxony-Anhalt (german: Sachsen-Anhalt ; nds, Sassen-Anholt) is a state of Germany, bordering the states of Brandenburg, Saxony, Thuringia and Lower Saxony. It covers an area of and has a population of 2.18 million inhabitants, making it th ...
, Germany in 1865 by the mine official Schöne and was first described by Carl Friedrich Jacob Zincken. Kainite is a typical secondary mineral that forms through metamorphosis in marine deposits of
potassium carbonate Potassium carbonate is the inorganic compound with the formula K2 CO3. It is a white salt, which is soluble in water. It is deliquescent, often appearing as a damp or wet solid. Potassium carbonate is mainly used in the production of soap and ...
, and is also occasionally formed through resublimation from volcanic vapours. It is often accompanied by
anhydrite Anhydrite, or anhydrous calcium sulfate, is a mineral with the chemical formula CaSO4. It is in the orthorhombic crystal system, with three directions of perfect cleavage parallel to the three planes of symmetry. It is not isomorphous with the ...
,
carnallite Carnallite (also carnalite) is an evaporite mineral, a hydrated potassium magnesium chloride with formula KMgCl3·6(H2O). It is variably colored yellow to white, reddish, and sometimes colorless or blue. It is usually massive to fibrous with rare ...
,
halite Halite (), commonly known as rock salt, is a type of salt, the mineral (natural) form of sodium chloride ( Na Cl). Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, p ...
, and
kieserite Kieserite, or magnesium sulfate monohydrate, is a hydrous magnesium sulfate mineral with formula (MgSO4·H2O). It has a vitreous luster and it is colorless, grayish-white or yellowish. Its hardness is 3.5 and crystallizes in the monoclinic crysta ...
. Kainite is only found in comparatively few places, among them in salt mines in central and northern Germany,
Bad Ischl Bad Ischl (Austrian German ) is a spa town in Austria. It lies in the southern part of Upper Austria, at the Traun River in the centre of the Salzkammergut region. The town consists of the Katastralgemeinden ''Ahorn'', ''Bad Ischl'', ''Haiden ...
(Austria), on Pasquasia in
Sicily Sicily ( it, Sicilia , ) is the list of islands in the Mediterranean, largest island in the Mediterranean Sea and one of the 20 regions of Italy, regions of Italy. The Strait of Messina divides it from the region of Calabria in Southern Italy. I ...
, in
Whitby Whitby is a seaside town, port and civil parish in the Scarborough borough of North Yorkshire, England. Situated on the east coast of Yorkshire at the mouth of the River Esk, Whitby has a maritime, mineral and tourist heritage. Its East Cli ...
(UK), and in the Carlsbad Potash District in
New Mexico ) , population_demonym = New Mexican ( es, Neomexicano, Neomejicano, Nuevo Mexicano) , seat = Santa Fe, New Mexico, Santa Fe , LargestCity = Albuquerque, New Mexico, Albuquerque , LargestMetro = Albuquerque metropolitan area, Tiguex , Offi ...
, in volcanic deposits in
Kamchatka The Kamchatka Peninsula (russian: полуостров Камчатка, Poluostrov Kamchatka, ) is a peninsula in the Russian Far East, with an area of about . The Pacific Ocean and the Sea of Okhotsk make up the peninsula's eastern and west ...
and in
Iceland Iceland ( is, Ísland; ) is a Nordic island country in the North Atlantic Ocean and in the Arctic Ocean. Iceland is the most sparsely populated country in Europe. Iceland's capital and largest city is Reykjavík, which (along with its s ...
, and in salt lakes in western China. It has also been identified in
Gusev Crater Gusev is a crater on the planet Mars and is located at and is in the Aeolis quadrangle. The crater is about 166 kilometers in diameter and formed approximately three to four billion years ago. It was named after Russian astronomer Matvey Gusev ...
on
Mars Mars is the fourth planet from the Sun and the second-smallest planet in the Solar System, only being larger than Mercury. In the English language, Mars is named for the Roman god of war. Mars is a terrestrial planet with a thin atmosp ...
.Rice, M. S., et al. "Silica-rich deposits and hydrated minerals at Gusev Crater, Mars: Vis-NIR spectral characterization and regional mapping." Icarus 205.2 (2010): 375-395.


Uses

Kainite is used as a source of
potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosp ...
and
magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ...
compounds, as a
fertilizer A fertilizer (American English) or fertiliser (British English; see spelling differences) is any material of natural or synthetic origin that is applied to soil or to plant tissues to supply plant nutrients. Fertilizers may be distinct from ...
, and as gritting salt.


References

Magnesium minerals Potassium minerals Halide minerals Sulfate minerals Monoclinic minerals Minerals in space group 12 Evaporite Potash {{sulfate-mineral-stub