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Hornfels is the group name for a set of
contact metamorphic Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of chem ...
rocks that have been baked and hardened by the heat of intrusive igneous masses and have been rendered massive, hard, splintery, and in some cases exceedingly tough and durable. These properties are due to fine grained non-aligned crystals with platy or prismatic habits, characteristic of metamorphism at high temperature but without accompanying deformation. The term is derived from the German word ''Hornfels'', meaning "hornstone", because of its exceptional toughness and texture both reminiscent of animal horns. These rocks were referred to by miners in northern
England England is a country that is part of the United Kingdom. It shares land borders with Wales to its west and Scotland to its north. The Irish Sea lies northwest and the Celtic Sea to the southwest. It is separated from continental Europe ...
as whetstones. Most hornfels are fine-grained, and while the original rocks (such as
sandstone Sandstone is a clastic sedimentary rock composed mainly of sand-sized (0.0625 to 2 mm) silicate grains. Sandstones comprise about 20–25% of all sedimentary rocks. Most sandstone is composed of quartz or feldspar (both silicat ...
,
shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especiall ...
,
slate Slate is a fine-grained, foliated, homogeneous metamorphic rock derived from an original shale-type sedimentary rock composed of clay or volcanic ash through low-grade regional metamorphism. It is the finest grained foliated metamorphic rock. ...
and
limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms w ...
) may have been more or less fissile owing to the presence of bedding or cleavage planes, this structure is effaced or rendered inoperative in the hornfels. Though many hornfels show vestiges of the original bedding, they break across this as readily as along it; in fact, they tend to separate into cubical fragments rather than into thin plates. Sheet minerals may be abundant but are aligned at random. Hornfels most commonly form in the aureole of granitic intrusions in the upper or middle crust. Hornfels formed from contact metamorphism by volcanic activity very close to the surface can produce unusual and distinctive minerals. Changes in composition caused by fluids give off by the magmatic body ( metasomatism) sometimes takes place. The ''hornfels facies'' is the
metamorphic facies A metamorphic facies is a set of mineral assemblages in metamorphic rocks formed under similar pressures and temperatures.Essentials of Geology, 3rd Edition, Stephen Marshak The assemblage is typical of what is formed in conditions corresponding ...
which occupies the lowest pressure portion of the metamorphic pressure-temperature space.Blatt and Tracy, p.378-380, 512 The most common hornfels (the
biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron- endmember annite, and the magnesium-endmember phlogopite; more ...
hornfels) are dark-brown to black with a somewhat velvety luster owing to the abundance of small
crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macro ...
s of shining black
mica Micas ( ) are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into extremely thin elastic plates. This characteristic is described as perfect basal cleavage. Mica is ...
. The lime hornfels are often white, yellow, pale-green, brown and other colors. Green and dark-green are the prevalent tints of the hornfels produced by the alteration of
igneous rock Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma o ...
s. Although for the most part the constituent grains are too small to be determined by the unaided eye, there are often larger crystals ( porphyroblasts) of cordierite,
garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. All species of garnets possess similar physical properties and crystal forms, but differ in chemical composition. The different ...
or andalusite scattered through the fine matrix, and these may become very prominent on the
weathered ''Weathered'' is the third studio album by American rock band Creed, released on November 20, 2001. It was the last Creed album to be released until '' Full Circle'' came out in October 2009, with Creed disbanding in June 2004. It is the only Cr ...
faces of the rock.Yardley 1989, p.161


Structure

The structure of the hornfels is very characteristic. Very rarely do any of the minerals show crystalline form, but the small grains fit closely together like the fragments of a mosaic; they are usually of nearly equal dimensions. This has been called pflaster or pavement structure from the resemblance to rough pavement work. Each
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...
may also enclose particles of the others; in the
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical f ...
, for example, small crystals of
graphite Graphite () is a crystalline form of the element carbon. It consists of stacked layers of graphene. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on la ...
, biotite,
iron oxide Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of wh ...
s, sillimanite or feldspar may appear in great numbers. Often the whole of the grains are rendered semi-opaque in this way. The minutest crystals may show traces of crystalline outlines; undoubtedly they are of new formation and have originated ''in situ''. This leads us to believe that the whole rock has been recrystallized at a high temperature and in the solid state so that there was little freedom for the mineral
molecule A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and b ...
s to build up well-individualized crystals. The regeneration of the rock has been sufficient to efface most of the original structures and to replace the former minerals more-or-less completely by new ones. But crystallization has been hampered by the solid condition of the mass and the new minerals are formless and have been unable to reject impurities, but have grown around them.


Compositions of hornfels


Pelitic

Clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay pa ...
s, sedimentary slates and shales yield biotite hornfels in which the most conspicuous mineral is biotite mica, the small scales of which are transparent under the microscope and have a dark reddish-brown color and strong
dichroism In optics, a dichroic material is either one which causes visible light to be split up into distinct beams of different wavelengths (colours) (not to be confused with dispersion), or one in which light rays having different polarizations are abs ...
. There is also quartz, and often a considerable amount of feldspar, while graphite,
tourmaline Tourmaline ( ) is a crystalline Silicate mineral, silicate mineral group in which boron is compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. Tourmaline is a gemstone and can be found in a wide variety o ...
and iron oxides frequently occur in lesser quantity. In these biotite hornfels the minerals, which consist of aluminium silicates, are commonly found; they are usually andalusite and sillimanite, but kyanite appears also in hornfels, especially in those that have a
schist Schist ( ) is a medium-grained metamorphic rock showing pronounced schistosity. This means that the rock is composed of mineral grains easily seen with a low-power hand lens, oriented in such a way that the rock is easily split into thin flakes ...
ose character. The andalusite may be pink and is then often pleochroic in thin sections, or it may be white with the cross-shaped dark enclosures of the matrix that are characteristic of chiastolite. Sillimanite usually forms exceedingly minute needles embedded in quartz. In the rocks of this group cordierite also occurs, not rarely, and may have the outlines of imperfect hexagonal prisms that are divided up into six sectors when seen in polarized light. In biotite hornfels, a faint striping may indicate the original bedding of the unaltered rock and corresponds to small changes in the nature of the
sediment Sediment is a naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of wind, water, or ice or by the force of gravity acting on the particles. For example, sand ...
deposited. More commonly there is a distinct spotting, visible on the surfaces of the hand specimens. The spots are round or elliptical, and may be paler or darker than the rest of the rock. In some cases they are rich in graphite or carbonaceous matter; in others they are full of brown mica; some spots consist of rather coarser grains of quartz than occur in the matrix. The frequency with which this feature reappears in the less altered slates and hornfels is rather remarkable, especially as it seems certain that the spots are not always of the same nature or origin. Tourmaline hornfels are found sometimes near the margins of tourmaline granites; they are black with small needles of schorl that under the microscope are dark brown and richly pleochroic. As the tourmaline contains
boron Boron is a chemical element with the symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the '' boron group'' it has t ...
, there must have been some permeation of vapors from the granite into the sediments. Rocks of this group are often seen in the Cornish tin-mining districts, especially near the lodes.


Carbonate

A second great group of hornfels are the calc–silicate hornfels that arise from the thermal alteration of impure
limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms w ...
. The purer beds recrystallize as
marble Marble is a metamorphic rock composed of recrystallized carbonate minerals, most commonly calcite or dolomite. Marble is typically not foliated (layered), although there are exceptions. In geology, the term ''marble'' refers to metamorphose ...
s, but where there has been originally an admixture of
sand Sand is a granular material composed of finely divided mineral particles. Sand has various compositions but is defined by its grain size. Sand grains are smaller than gravel and coarser than silt. Sand can also refer to a textural class ...
or clay lime-bearing silicates are formed, such as diopside,
epidote Epidote is a calcium aluminium iron sorosilicate mineral. Description Well developed crystals of epidote, Ca2Al2(Fe3+;Al)(SiO4)(Si2O7)O(OH), crystallizing in the monoclinic system, are of frequent occurrence: they are commonly prismatic in ...
,
garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. All species of garnets possess similar physical properties and crystal forms, but differ in chemical composition. The different ...
, sphene, vesuvianite and scapolite; with these phlogopite, various feldspars,
pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic Luster (mineralogy), lust ...
s, quartz and actinolite often occur. These rocks are fine-grained, and though often banded, are tough and much harder than the original limestones. They are excessively variable in their mineralogical composition, and very often alternate in thin seams with biotite hornfels and indurated
quartzite Quartzite is a hard, non- foliated metamorphic rock which was originally pure quartz sandstone.Essentials of Geology, 3rd Edition, Stephen Marshak, p 182 Sandstone is converted into quartzite through heating and pressure usually related to tec ...
s. When perfused with boric and fluoric vapors from the granite they may contain much axinite, fluorite and datolite, but the altiminous silicates are absent from these rocks.


Mafic

From
diabase Diabase (), also called dolerite () or microgabbro, is a mafic, holocrystalline, subvolcanic rock equivalent to volcanic basalt or plutonic gabbro. Diabase dikes and sills are typically shallow intrusive bodies and often exhibit fine-grain ...
s,
basalt Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90 ...
s,
andesite Andesite () is a volcanic rock of intermediate composition. In a general sense, it is the intermediate type between silica-poor basalt and silica-rich rhyolite. It is fine-grained (aphanitic) to porphyritic in texture, and is composed predo ...
s and other igneous rocks a third type of hornfels is produced. They consist essentially of feldspar with hornblende (generally of brown color) and pale pyroxene. Sphene, biotite and iron oxides are the other common constituents, but these rocks show much variety of composition and structure. Where the original mass was decomposed and contained calcite,
zeolite Zeolites are microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ・y where is either a metal ion or H+. These p ...
s,
chlorite The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chlorou ...
and other secondary minerals either in veins or in cavities, there are usually rounded areas or irregular streaks containing a suite of new minerals, which may resemble those of the calcium-silicate hornfelses above described. The original
porphyritic Porphyritic is an adjective used in geology to describe igneous rocks with a distinct difference in the size of mineral crystals, with the larger crystals known as phenocrysts. Both extrusive and intrusive rocks can be porphyritic, meaning a ...
, fluidal, vesicular or fragmental structures of the igneous rock are clearly visible in the less advanced stages of hornfelsing, but become less evident as the alteration progresses. In some districts hornfelsed rocks occur that have acquired a schistose structure through shearing, and these form transitions to schists and
gneiss Gneiss ( ) is a common and widely distributed type of metamorphic rock. It is formed by high-temperature and high-pressure metamorphic processes acting on formations composed of igneous or sedimentary rocks. Gneiss forms at higher temperatures a ...
es that contain the same minerals as the hornfels, but have a schistose instead of a hornfels structure. Among these may be mentioned cordierite and sillimanite gneisses, andalusite and kyanite mica-schists, and those schistose calcite-silicate rocks that are known as cipolins. That these are sediments that have undergone thermal alteration is generally admitted, but the exact conditions under which they were formed are not always clear. The essential features of hornfelsing are ascribed to the action of heat,
pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country a ...
and permeating vapors, regenerating a rock mass without the production of fusion (at least on a large scale). It has been argued, however, that often there is extensive chemical change owing to the introduction of matter from the granite into the rocks surrounding it. The formation of new feldspar in the hornfelses is pointed out as evidence of this. While this felspathization may have occurred in a few localities, it seems conspicuously absent from others. Most authorities at the present time regard the changes as being purely of a physical and not of a chemical nature.


Hornfels metamorphic facies

The hornfels facies occupies the portion of the metamorphic pressure-temperature space of lowest pressure and low to high temperature. It is subdivided into a low-temperature regime of
albite Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicate ...
-
epidote Epidote is a calcium aluminium iron sorosilicate mineral. Description Well developed crystals of epidote, Ca2Al2(Fe3+;Al)(SiO4)(Si2O7)O(OH), crystallizing in the monoclinic system, are of frequent occurrence: they are commonly prismatic in ...
hornfels, a medium-temperature regime of
hornblende Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rock ...
hornfels, a high-temperature regime of
pyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe I ...
hornfels, and an ultra-high-temperature sanidinite regime. The latter is sometimes regarded as a separate facies. Maximum pressures are around 2 kbar and temperatures are around 300-500 C for the albite-epidote hornfels facies, 500-650 C for the hornblende hornfels facies, 650-800 C for the pyroxene hornfels facies, and above 800 C for the sanidinite facies. The actual minerals present in each facies depends on the composition of the
protolith A protolith () is the original, unmetamorphosed rock from which a given metamorphic rock is formed. For example, the protolith of a slate is a shale or mudstone. Metamorphic rocks can be derived from any other kind of non-metamorphic rock an ...
. For a mafic protolith, the albite-epidote hornfels facies is characterized by albite and epidote or
zoisite Zoisite, first known as saualpite, after its type locality, is a calcium aluminium hydroxy sorosilicate belonging to the epidote group of minerals. Its chemical formula is Ca2 Al3( Si O4)(Si2O7)O(O H). Zoisite occurs as prismatic, orthorho ...
with minor actinolite and
chlorite The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chlorou ...
. This gives way to hornblende,
plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more p ...
, pyroxene, and
garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. All species of garnets possess similar physical properties and crystal forms, but differ in chemical composition. The different ...
in the hornblende hornfels facies, which in turn gives way to
orthopyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe I ...
,
augite Augite is a common rock-forming pyroxene mineral with formula . The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees. Characteristics Augite is a solid solution in the pyroxene group ...
, plagioclase, and characteristic trace garnet in the pyroxene hornfels facies and sanidinite facies, the latter two being indistinguishable for this composition of protolith. For an ultramafic protolith, the albite-epidote facies is characterized by serpentine, talc,
tremolite Tremolite is a member of the amphibole group of silicate minerals with composition: Ca2(Mg5.0-4.5Fe2+0.0-0.5)Si8O22(OH)2. Tremolite forms by metamorphism of sediments rich in dolomite and quartz. Tremolite forms a series with actinolite and fe ...
, and chlorite, giving way to forsterite, orthopyroxene, hornblende, chlorite, and characteristic minor aluminum
spinel Spinel () is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula in the cubic crystal system. Its name comes from the Latin word , which means ''spine'' in reference to its pointed crystals. Properties S ...
and
magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With ...
in the hornblende facies, which in turn gives way to forsterite, orthopyroxene, augite, plagioclase, and aluminum spinel in the pyroxene hornfels facies. The sanidinite facies for this composition differs from the pyroxene hornfels facies only in the disappearance of aluminum spinel. For a pelitic protolith, the sequence is
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical f ...
, plagioclase, muscovite, chlorite, and cordierite in the albite-epidote facies; quartz, plagioclase, muscovite, biotite, cordierite, and andalusite in the hornblende hornfels facies; and quartz, plagioclase, orthoclase, andalusite, sillimanite, cordierite, and orthopyroxene in the pyroxene hornfels facies. The sanidinite facies features quartz, plagioclase, sillimanite, cordierite, orthopyroxene, sapphirine, and aluminum spinel. For a calcareous protolith, the sequence is
calcite Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on scratc ...
,
dolomite Dolomite may refer to: *Dolomite (mineral), a carbonate mineral *Dolomite (rock), also known as dolostone, a sedimentary carbonate rock *Dolomite, Alabama, United States, an unincorporated community *Dolomite, California, United States, an unincor ...
, quartz, tremolite, talc, and forsterite for the albite-epidote hornfels facies; calcite, dolomite, quartz, tremolite, diopside, and forsterite for the hornblende hornfels facies; calcite, quartz, diposide, forsterite, and
wollastonite Wollastonite is a calcium inosilicate mineral ( Ca Si O3) that may contain small amounts of iron, magnesium, and manganese substituting for calcium. It is usually white. It forms when impure limestone or dolomite is subjected to high temperature ...
for the pyroxene hornfels facies; and calcite, quartz, diopside, forsterite, wollastonite, monticellite, and akermanite for the sanidinite facies.


Acoustic properties

Hornfels have the ability to resonate when struck. Michael Tellinger had described these stones in
South Africa South Africa, officially the Republic of South Africa (RSA), is the southernmost country in Africa. It is bounded to the south by of coastline that stretch along the South Atlantic and Indian Oceans; to the north by the neighbouring coun ...
also known as "ring-stones" due to their ability to ring like a bell. The Musical Stones of Skiddaw are an example of a
lithophone A lithophone is a musical instrument consisting of a rock or pieces of rock which are struck to produce musical notes. Notes may be sounded in combination (producing harmony) or in succession (melody). It is an idiophone comparable to instrumen ...
made from hornfels.


See also

*


References


External links

{{commons category inline, Hornfels Metamorphic rocks