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A germicidal lamp (also known as disinfection lamp or sterilizer lamp) is an
electric light An electric light, lamp, or light bulb is an electrical component that produces light. It is the most common form of artificial lighting. Lamps usually have a base made of ceramic, metal, glass, or plastic, which secures the lamp in the soc ...
that produces
ultraviolet C Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nm (with a corresponding frequency around 30  PHz) to 400 nm (750  THz), shorter than that of visible light, but longer than X-rays. UV radiatio ...
(UVC) light. This short-wave ultraviolet light disrupts DNA
base pair A base pair (bp) is a fundamental unit of double-stranded nucleic acids consisting of two nucleobases bound to each other by hydrogen bonds. They form the building blocks of the DNA double helix and contribute to the folded structure of both D ...
ing, causing formation of
pyrimidine dimer Pyrimidine dimers are molecular lesions formed from thymine or cytosine bases in DNA via photochemical reactions, commonly associated with direct DNA damage. Ultraviolet light (UV; particularly UVB) induces the formation of covalent linkages betw ...
s, and leads to the inactivation of
bacteria Bacteria (; singular: bacterium) are ubiquitous, mostly free-living organisms often consisting of one biological cell. They constitute a large domain of prokaryotic microorganisms. Typically a few micrometres in length, bacteria were am ...
,
virus A virus is a submicroscopic infectious agent that replicates only inside the living cells of an organism. Viruses infect all life forms, from animals and plants to microorganisms, including bacteria and archaea. Since Dmitri Ivanovsk ...
es, and
protozoa Protozoa (singular: protozoan or protozoon; alternative plural: protozoans) are a group of single-celled eukaryotes, either free-living or parasitic, that feed on organic matter such as other microorganisms or organic tissues and debris. Histo ...
ns. It can also be used to produce
ozone Ozone (), or trioxygen, is an inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , breaking down in the l ...
for
water disinfection Water purification is the process of removing undesirable chemicals, biological contaminants, suspended solids, and gases from water. The goal is to produce water that is fit for specific purposes. Most water is purified and disinfected for hu ...
. They are used in
ultraviolet germicidal irradiation Ultraviolet germicidal irradiation (UVGI) is a disinfection method that uses short-wavelength ultraviolet ( ultraviolet C or UV-C) light to kill or inactivate microorganisms by destroying nucleic acids and disrupting their DNA, leaving them unab ...
(UVGI). There are four common types available: * Low-pressure mercury lamps * High-pressure mercury lamps * Excimer lamps * LEDs


Low-pressure mercury lamps

Low-pressure mercury lamps are very similar to a
fluorescent lamp A fluorescent lamp, or fluorescent tube, is a low-pressure mercury-vapor gas-discharge lamp that uses fluorescence to produce visible light. An electric current in the gas excites mercury vapor, which produces short-wave ultraviolet, ult ...
, with a
wavelength In physics, the wavelength is the spatial period of a periodic wave—the distance over which the wave's shape repeats. It is the distance between consecutive corresponding points of the same phase on the wave, such as two adjacent crests, tr ...
of 253.7 nm (1182.5 THz). The most common form of germicidal lamp looks similar to an ordinary fluorescent lamp but the tube contains no fluorescent
phosphor A phosphor is a substance that exhibits the phenomenon of luminescence; it emits light when exposed to some type of radiant energy. The term is used both for fluorescent or phosphorescent substances which glow on exposure to ultraviolet or v ...
. In addition, rather than being made of ordinary
borosilicate glass Borosilicate glass is a type of glass with silica and boron trioxide as the main glass-forming constituents. Borosilicate glasses are known for having very low coefficients of thermal expansion (≈3 × 10−6 K−1 at 20 °C), m ...
, the tube is made of
fused quartz Fused quartz, fused silica or quartz glass is a glass consisting of almost pure silica (silicon dioxide, SiO2) in amorphous (non-crystalline) form. This differs from all other commercial glasses in which other ingredients are added which change ...
or vycor 7913 glass. These two changes combine to allow the 253.7 nm ultraviolet light produced by the mercury arc to pass out of the lamp unmodified (whereas, in common fluorescent lamps, it causes the phosphor to
fluoresce Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore a lower photon energy, tha ...
, producing
visible light Light or visible light is electromagnetic radiation that can be perceived by the human eye. Visible light is usually defined as having wavelengths in the range of 400–700 nanometres (nm), corresponding to frequencies of 750–420 t ...
). Germicidal lamps still produce a small amount of visible light due to other mercury radiation bands. An older design looks like an
incandescent lamp An incandescent light bulb, incandescent lamp or incandescent light globe is an electric light with a wire filament heated until it glows. The filament is enclosed in a glass bulb with a vacuum or inert gas to protect the filament from oxida ...
but with the envelope containing a few droplets of mercury. In this design, the incandescent filament heats the mercury, producing a vapor which eventually allows an arc to be struck,
short circuit A short circuit (sometimes abbreviated to short or s/c) is an electrical circuit that allows a current to travel along an unintended path with no or very low electrical impedance. This results in an excessive current flowing through the circu ...
ing the incandescent filament. As with all
gas-discharge lamp Gas-discharge lamps are a family of artificial light sources that generate light by sending an electric discharge through an ionized gas, a plasma. Typically, such lamps use a noble gas (argon, neon, krypton, and xenon) or a mixture of t ...
s, low- and high-pressure mercury lamps exhibit
negative resistance In electronics, negative resistance (NR) is a property of some electrical circuits and devices in which an increase in voltage across the device's terminals results in a decrease in electric current through it. This is in contrast to an ordina ...
and require the use of an external
ballast Ballast is material that is used to provide stability to a vehicle or structure. Ballast, other than cargo, may be placed in a vehicle, often a ship or the gondola of a balloon or airship, to provide stability. A compartment within a boat, ship ...
to regulate the current flow. The older lamps that resembled an incandescent lamp were often operated in series with an ordinary 40 W incandescent "appliance" lamp; the incandescent lamp acted as the ballast for the germicidal lamp.


High-pressure mercury lamps

High-pressure lamps are much more similar to HID lamps than fluorescent lamps. These lamps radiate a broad-band UVC radiation, rather than a single line. They are widely used in industrial water treatment, because they are very intense radiation sources. High-pressure lamps produce very bright bluish white light.


Excimer lamps

Excimer lamps emit narrow-band UVC and vacuum-ultraviolet radiation at a variety of wavelengths depending on the medium. They are mercury-free and reach full output quicker than a mercury lamp, and generate less heat. Excimer emission at 207 and 222 nm appears to be safer than traditional 254 nm germicidal radiation, due to greatly reduced penetration of these wavelengths in human skin.


Light emitting diodes (LEDs)

Recent developments in
light-emitting diode A light-emitting diode (LED) is a semiconductor device that emits light when current flows through it. Electrons in the semiconductor recombine with electron holes, releasing energy in the form of photons. The color of the light (co ...
(LED) technology have led to the commercial availability of UVC LED sources. UVC LEDs use semiconductor materials to produce light in a solid-state device. The wavelength of emission is tuneable by adjusting the chemistry of the semiconductor material, giving a selectivity to the emission profile of the LED across, and beyond, the germicidal wavelength band. Advances in understanding and synthesis of the AlGaN materials system led to significant increases in the output power, device lifetime, and efficiency of UVC LEDs in the early 2010s. The reduced size of LEDs opens up options for small reactor systems allowing for point-of-use applications and integration into medical devices. Low power consumption of semiconductors introduce UV disinfection systems that utilized small solar cells in remote or Third World applications. By 2019 LEDs made up 41.4% of UV Light Sales, up from 19.2% in 2014 The UV-C LED global market is expected to rise from $223m in 2017 to US$991m in 2023.


Uses

Germicidal lamps are used to sterilize workspaces and tools used in biology laboratories and medical facilities. If the quartz envelope transmits shorter wavelengths, such as the 185 nm mercury emission line, they can also be used wherever
ozone Ozone (), or trioxygen, is an inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , breaking down in the l ...
is desired, for example, in the sanitizing systems of hot tubs and aquariums. They are also used by
geologist A geologist is a scientist who studies the solid, liquid, and gaseous matter that constitutes Earth and other terrestrial planets, as well as the processes that shape them. Geologists usually study geology, earth science, or geophysics, althoug ...
s to provoke fluorescence in
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...
samples, aiding in their identification. In this application, the light produced by the lamp is usually
filtered Filtration is a physical separation process that separates solid matter and fluid from a mixture using a ''filter medium'' that has a complex structure through which only the fluid can pass. Solid particles that cannot pass through the filter m ...
to remove as much visible light as possible, leaving just the UV light. Germicidal lamps are also used in waste water treatment in order to kill microorganisms. The light produced by germicidal lamps is also used to erase
EPROM An EPROM (rarely EROM), or erasable programmable read-only memory, is a type of programmable read-only memory (PROM) chip that retains its data when its power supply is switched off. Computer memory that can retrieve stored data after a power s ...
s; the ultraviolet photons are sufficiently energetic to allow the electrons trapped on the transistors' floating gates to tunnel through the gate insulation, eventually removing the stored charge that represents binary ones and zeroes.


Ozone production

For most purposes, ozone production would be a detrimental side effect of lamp operation. To prevent this, most germicidal lamps are treated to absorb the 185 nm mercury emission line (which is the longest wavelength of mercury light which will ionize oxygen). In some cases (such as water sanitization), ozone production is precisely the point. This requires specialized lamps which do not have the surface treatment.


Safety concerns

Short-wave UV light is harmful to humans. In addition to causing
sunburn Sunburn is a form of radiation burn that affects living tissue, such as skin, that results from an overexposure to ultraviolet (UV) radiation, usually from the Sun. Common symptoms in humans and animals include: red or reddish skin that is h ...
and (over time)
skin cancer Skin cancers are cancers that arise from the skin. They are due to the development of abnormal cells that have the ability to invade or spread to other parts of the body. There are three main types of skin cancers: basal-cell skin cancer (BCC) ...
, this light can produce extremely painful inflammation of the
cornea The cornea is the transparent front part of the eye that covers the iris, pupil, and anterior chamber. Along with the anterior chamber and lens, the cornea refracts light, accounting for approximately two-thirds of the eye's total optical ...
of the eye, which may lead to temporary or permanent
vision impairment Visual impairment, also known as vision impairment, is a medical definition primarily measured based on an individual's better eye visual acuity; in the absence of treatment such as correctable eyewear, assistive devices, and medical treatment� ...
. For this reason, the light produced by a germicidal lamp must be carefully shielded against direct viewing, with consideration of reflections and dispersed light. A February 2017 risk analysis of UVC lights concluded that ultraviolet light from these lamps can cause skin and eye problems.


References


External links

* {{Artificial light sources Gas discharge lamps Disinfectants Ultraviolet radiation