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A gamma-ray spectrometer (GRS) is an instrument for measuring the distribution (or
spectrum A spectrum (plural ''spectra'' or ''spectrums'') is a condition that is not limited to a specific set of values but can vary, without gaps, across a continuum. The word was first used scientifically in optics to describe the rainbow of colors ...
—see figure) of the intensity of gamma radiation versus the energy of each
photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they alwa ...
. The study and analysis of gamma-ray spectra for scientific and technical use is called
gamma spectroscopy Gamma-ray spectroscopy is the quantitative study of the energy spectra of gamma-ray sources, such as in the nuclear industry, geochemical investigation, and astrophysics. Most radioactive sources produce gamma rays, which are of various energie ...
, and gamma-ray spectrometers are the instruments which observe and collect such data. Because the energy of each photon of EM radiation is proportional to its frequency, gamma rays have sufficient energy that they are typically observed by counting individual photons.


Gamma-ray spectroscopy

Atomic nuclei have an energy-level structure somewhat analogous to the energy levels of atoms, so that they may emit (or absorb) photons of particular energies, much as atoms do, but at energies that are thousands to millions of times higher than those typically studied in optical spectroscopy. (Note that the short-wavelength high-energy end, of the atomic spectroscopy energy range (few eV to few hundred keV), generally termed
X-ray An X-ray, or, much less commonly, X-radiation, is a penetrating form of high-energy electromagnetic radiation. Most X-rays have a wavelength ranging from 10 picometers to 10  nanometers, corresponding to frequencies in the range 30&nb ...
s, overlaps somewhat with the low end of the nuclear gamma-ray range (~10 MeV to ~10 keV) so that the terminology used to distinguish X-rays from gamma rays can be arbitrary or ambiguous in the overlap region.) As with atoms, the particular energy levels of nuclei are characteristic of each species, so that the photon energies of the gamma rays emitted, which correspond to the energy differences of the nuclei, can be used to identify particular elements and isotopes. Distinguishing between gamma-rays of slightly different energy is an important consideration in the analysis of complex spectra, and the ability of a GRS to do so is characterized by the instrument's
spectral resolution The spectral resolution of a spectrograph, or, more generally, of a frequency spectrum, is a measure of its ability to resolve features in the electromagnetic spectrum. It is usually denoted by \Delta\lambda, and is closely related to the resolvi ...
, or the accuracy with which the energy of each photon is measured. Semi-conductor detectors, based on cooled
germanium Germanium is a chemical element with the symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid in the carbon group that is chemically similar to its group neighbors ...
or
silicon Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic ...
detecting elements, have been invaluable for such applications. Because the energy level spectrum of nuclei typically dies out above about 10 MeV, gamma-ray instruments looking to still higher energies generally observe only continuum spectra, so that the moderate spectral resolution of scintillation (often sodium iodide (NaI) or caesium iodide, (CsI) spectrometers), often suffices for such applications.


Astronomical spectrometers

A number of investigations have been performed to observe the gamma-ray spectra of the
Sun The Sun is the star at the center of the Solar System. It is a nearly perfect ball of hot plasma, heated to incandescence by nuclear fusion reactions in its core. The Sun radiates this energy mainly as light, ultraviolet, and infrared radi ...
and other
astronomical source Astronomy () is a natural science that studies astronomical object, celestial objects and phenomena. It uses mathematics, physics, and chemistry in order to explain their origin and chronology of the Universe, evolution. Objects of interest ...
s, both galactic and extra-galactic. The
Gamma-Ray Imaging Spectrometer The Gamma-Ray Imaging Spectrometer (GRIS) was a gamma-ray spectrometer instrument on a balloon-borne airborne observatory. It used germanium detectors to achieve high resolution spectroscopy. GRIS was operated from 1988 to 1995 by NASA's Goddar ...
, the Hard X-ray/Low-Energy Gamma-ray experiment (A-4) on HEAO 1, the Burst and Transient Spectrometry Experiment (BATSE) and the OSSI (Oriented Scintillation Spectrometer Experiment) on CGRO, the C1
germanium Germanium is a chemical element with the symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid in the carbon group that is chemically similar to its group neighbors ...
(Ge) gamma-ray instrument on HEAO 3, and the Ge gamma-ray spectrometer (SPI) on the ESA
INTEGRAL In mathematics, an integral assigns numbers to functions in a way that describes displacement, area, volume, and other concepts that arise by combining infinitesimal data. The process of finding integrals is called integration. Along with ...
mission are examples of cosmic spectrometers, while the GRS on the SMM and the imaging Ge spectrometer on the RHESSI satellite have been devoted to solar observations.


Planetary gamma-ray spectrometers

Gamma-ray spectrometers have been widely used for the elemental and isotopic analysis of bodies in the
Solar System The Solar System Capitalization of the name varies. The International Astronomical Union, the authoritative body regarding astronomical nomenclature, specifies capitalizing the names of all individual astronomical objects but uses mixed "Solar ...
, especially the
Moon The Moon is Earth's only natural satellite. It is the fifth largest satellite in the Solar System and the largest and most massive relative to its parent planet, with a diameter about one-quarter that of Earth (comparable to the width of ...
and
Mars Mars is the fourth planet from the Sun and the second-smallest planet in the Solar System, only being larger than Mercury. In the English language, Mars is named for the Roman god of war. Mars is a terrestrial planet with a thin at ...
. These surfaces are subjected to a continual bombardment of high-energy
cosmic rays Cosmic rays are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar System in our ...
, which excite nuclei in them to emit characteristic gamma-rays which can be detected from orbit. Thus an orbiting instrument can in principle map the surface distribution of the elements for an entire planet. Examples include the mapping of 20 elements observed in the exploration of Mars,
Eros In Greek mythology, Eros (, ; grc, Ἔρως, Érōs, Love, Desire) is the Greek god of love and sex. His Roman counterpart was Cupid ("desire").''Larousse Desk Reference Encyclopedia'', The Book People, Haydock, 1995, p. 215. In the ear ...
and the
Moon The Moon is Earth's only natural satellite. It is the fifth largest satellite in the Solar System and the largest and most massive relative to its parent planet, with a diameter about one-quarter that of Earth (comparable to the width of ...
. They are usually associated with neutron detectors that can look for water and ice in the soil by measuring
neutron The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the atomic nucleus, nuclei of atoms. Since protons and ...
s. They are able to measure the abundance and distribution of about 20 primary elements of the periodic table, including
silicon Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic ...
,
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements ...
,
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in ...
,
magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ...
,
potassium Potassium is the chemical element with the symbol K (from Neo-Latin '' kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmos ...
,
aluminum Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It ha ...
,
calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar ...
,
sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formul ...
, and
carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon ma ...
. Knowing what elements are at or near the surface will give detailed information about how planetary bodies have changed over time. To determine the elemental makeup of the Martian surface, the
Mars Odyssey ''2001 Mars Odyssey'' is a robotic spacecraft orbiting the planet Mars. The project was developed by NASA, and contracted out to Lockheed Martin, with an expected cost for the entire mission of US$297 million. Its mission is to use spectro ...
used a gamma-ray
spectrometer A spectrometer () is a scientific instrument used to separate and measure spectral components of a physical phenomenon. Spectrometer is a broad term often used to describe instruments that measure a continuous variable of a phenomenon where the ...
and two neutron detectors. GRS instruments supply data on the distribution and abundance of chemical elements, much as the
Lunar Prospector ''Lunar Prospector'' was the third mission selected by NASA for full development and construction as part of the Discovery Program. At a cost of $62.8 million, the 19-month mission was designed for a low polar orbit investigation of the Moon ...
mission did on the Moon. In this case, the chemical element
thorium Thorium is a weakly radioactive metallic chemical element with the symbol Th and atomic number 90. Thorium is silvery and tarnishes black when it is exposed to air, forming thorium dioxide; it is moderately soft and malleable and has a high ...
was mapped, with higher concentrations shown in yellow/orange/red in the left-hand side image shown on the right.


How a GRS works

Some constructions of
scintillation counter A scintillation counter is an instrument for detecting and measuring ionizing radiation by using the excitation effect of incident radiation on a scintillating material, and detecting the resultant light pulses. It consists of a scintillator wh ...
s can be used as gamma-ray spectrometers. The gamma photon energy is discerned from the intensity of the flash of the
scintillator A scintillator is a material that exhibits scintillation, the property of luminescence, when excited by ionizing radiation. Luminescent materials, when struck by an incoming particle, absorb its energy and scintillate (i.e. re-emit the absorbe ...
, a number of low-energy photons produced by the single high-energy one. Another approach relies on using Germanium detectors - a crystal of hyperpure
germanium Germanium is a chemical element with the symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid in the carbon group that is chemically similar to its group neighbors ...
that produces pulses proportional to the captured photon energy; while more sensitive, it has to be cooled to a low temperature, requiring a bulky
cryogenic In physics, cryogenics is the production and behaviour of materials at very low temperatures. The 13th IIR International Congress of Refrigeration (held in Washington DC in 1971) endorsed a universal definition of “cryogenics” and “cr ...
apparatus. Handheld and many laboratory gamma spectrometers are therefore the scintillator kind, mostly with
thallium Thallium is a chemical element with the symbol Tl and atomic number 81. It is a gray post-transition metal that is not found free in nature. When isolated, thallium resembles tin, but discolors when exposed to air. Chemists William Crookes an ...
- doped
sodium iodide Sodium iodide (chemical formula NaI) is an ionic compound formed from the chemical reaction of sodium metal and iodine. Under standard conditions, it is a white, water-soluble solid comprising a 1:1 mix of sodium cations (Na+) and iodide anions (I ...
, thallium-doped caesium iodide, or, more recently,
cerium Cerium is a chemical element with the symbol Ce and atomic number 58. Cerium is a soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it often shows the +3 ...
doped lanthanum bromide. Spectrometers for space missions conversely tend to be of the germanium kind. When exposed to
cosmic rays Cosmic rays are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar System in our ...
(charged particles from space thought to possibly originate in
supernova A supernova is a powerful and luminous explosion of a star. It has the plural form supernovae or supernovas, and is abbreviated SN or SNe. This transient astronomical event occurs during the last evolutionary stages of a massive star or whe ...
and
active galactic nuclei An active galactic nucleus (AGN) is a compact region at the center of a galaxy that has a much-higher-than-normal luminosity over at least some portion of the electromagnetic spectrum with characteristics indicating that the luminosity is not prod ...
), chemical elements in soils and rocks emit uniquely identifiable signatures of energy in the form of gamma rays. The gamma-ray spectrometer looks at these signatures, or energies, coming from the elements present in the target soil. By measuring gamma rays coming from the target body, it is possible to calculate the abundance of various elements and how they are distributed around the planet's surface. Gamma rays, emitted from the nuclei of
atoms Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas ...
, show up as sharp
emission lines A spectral line is a dark or bright line in an otherwise uniform and continuous spectrum, resulting from emission or absorption of light in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to ident ...
on the instrument's spectrum output. While the energy represented in these emissions determines which elements are present, the intensity of the spectrum reveals the elements concentrations. Spectrometers are expected to add significantly to the growing understanding of the origin and evolution of planets like Mars and the processes shaping them today and in the past. How are gamma rays and neutrons produced by cosmic rays? Incoming
cosmic rays Cosmic rays are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar System in our ...
—some of the highest-energy particles—collide with the
nucleus Nucleus ( : nuclei) is a Latin word for the seed inside a fruit. It most often refers to: * Atomic nucleus, the very dense central region of an atom *Cell nucleus, a central organelle of a eukaryotic cell, containing most of the cell's DNA Nucl ...
of atoms in the soil. When nuclei are hit with such energy, neutrons are released, which scatter and collide with other nuclei. The nuclei get "excited" in the process, and emit gamma rays to release the extra energy so they can return to their normal rest state. Some elements like potassium,
uranium Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...
, and
thorium Thorium is a weakly radioactive metallic chemical element with the symbol Th and atomic number 90. Thorium is silvery and tarnishes black when it is exposed to air, forming thorium dioxide; it is moderately soft and malleable and has a high ...
are naturally radioactive and give off gamma rays as they decay, but all elements can be excited by collisions with cosmic rays to produce gamma rays. The HEND and Neutron Spectrometers on GRS directly detect scattered neutrons, and the gamma sensor detects the gamma rays.


Water detection

By measuring neutrons, it is possible to calculate the abundance of hydrogen, thus inferring the presence of water. The neutron detectors are sensitive to concentrations of hydrogen in the upper meter of the surface. When cosmic rays hit the surface of Mars, neutrons and gamma-rays come out of the soil. The GRS measured their energies. Certain energies are produced by hydrogen. Since hydrogen is most likely present in the form of water ice, the spectrometer will be able to measure directly the amount of permanent ground ice and how it changes with the seasons. Like a virtual shovel "digging into" the surface, the spectrometer will allow scientists to peer into this shallow subsurface of Mars and measure the existence of hydrogen. GRS will supply data similar to that of the successful Lunar Prospector mission, which told us how much hydrogen, and thus water, is likely on the Moon. The gamma-ray spectrometer used on the Odyssey spacecraft consists of four main components: the gamma sensor head, the neutron spectrometer, the high energy neutron detector, and the central electronics assembly. The sensor head is separated from the rest of the spacecraft by a 6.2 meter (20 ft) boom, which was extended after Odyssey entered the mapping orbit at Mars. This maneuver is done to minimize interference from any gamma rays coming from the spacecraft itself. The initial spectrometer activity, lasting between 15 and 40 days, performed an instrument calibration before the boom was deployed. After about 100 days of the mapping mission, the boom was deployed and remained in this position for the duration of the mission. The two neutron detectors-the neutron spectrometer and the high-energy neutron detector-are mounted on the main spacecraft structure and operated continuously throughout the mapping mission.


GRS specifications for the Odyssey mission

The Gamma-Ray Spectrometer weighs 30.5 kilograms (67.2 lb) and uses 32 watts of power. Along with its cooler, it measures 468 by 534 by 604 mm (18.4 by 21.0 by 23.8 in). The detector is a photodiode made of a 1.2 kg germanium crystal, reverse biased to about 3 kilovolts, mounted at the end of a six-meter boom to minimize interferences from the gamma radiation produced by the spacecraft itself. Its spatial resolution is about 300 km.NASA Space Science Data Coordinated Archive
/ref> The neutron spectrometer is 173 by 144 by 314 mm (6.8 by 5.7 by 12.4 in). The high-energy neutron detector measures 303 by 248 by 242 mm (11.9 by 9.8 by 9.5 in). The instrument's central electronics box is 281 by 243 by 234 mm (11.1 by 9.6 by 9.2 in).


See also

*
Total absorption spectroscopy Total absorption spectroscopy is a measurement technique that allows the measurement of the gamma radiation emitted in the different nuclear gamma transitions that may take place in the daughter nucleus after its unstable parent has decayed by mean ...
*
Pandemonium effect The pandemonium effect is a problem that may appear when high resolution detectors (usually germanium detectors) are used in beta decay studies. It can affect the correct determination of the feeding to the different levels of the daughter nucl ...


References


External links


NASA Jet Propulsion Laboratory Gamma Ray Spectrometer page

Mars Odyssey GRS instrument site
at the
University of Arizona The University of Arizona (Arizona, U of A, UArizona, or UA) is a Public university, public Land-grant university, land-grant research university in Tucson, Arizona. Founded in 1885 by the 13th Arizona Territorial Legislature, it was the first ...

Apollo 16 Gamma Ray Spectrometer

NEAR Science instruments
(including GRS)

at NASA
Ames Research Center The Ames Research Center (ARC), also known as NASA Ames, is a major NASA research center at Moffett Federal Airfield in California's Silicon Valley. It was founded in 1939 as the second National Advisory Committee for Aeronautics (NACA) labo ...

Lunar Prospector's GRS
at National Space Science Data Center (NSSDC) {{DEFAULTSORT:Gamma Ray Spectrometer Spectrometers