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physics Physics is the natural science that studies matter, its fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge which ...
, a state of matter is one of the distinct forms in which
matter In classical physics and general chemistry, matter is any substance that has mass and takes up space by having volume. All everyday objects that can be touched are ultimately composed of atoms, which are made up of interacting subatomic part ...
can exist. Four states of matter are observable in everyday life:
solid Solid is one of the four fundamental states of matter (the others being liquid, gas, and plasma). The molecules in a solid are closely packed together and contain the least amount of kinetic energy. A solid is characterized by structur ...
,
liquid A liquid is a nearly incompressible fluid that conforms to the shape of its container but retains a (nearly) constant volume independent of pressure. As such, it is one of the four fundamental states of matter (the others being solid, gas, ...
, gas, and plasma. Many intermediate states are known to exist, such as
liquid crystal Liquid crystal (LC) is a state of matter whose properties are between those of conventional liquids and those of solid crystals. For example, a liquid crystal may flow like a liquid, but its molecules may be oriented in a crystal-like way. Th ...
, and some states only exist under extreme conditions, such as
Bose–Einstein condensate In condensed matter physics, a Bose–Einstein condensate (BEC) is a state of matter that is typically formed when a gas of bosons at very low densities is cooled to temperatures very close to absolute zero (−273.15 °C or −459.6 ...
s (in extreme cold), neutron-degenerate matter (in extreme density), and
quark–gluon plasma Quark–gluon plasma (QGP) or quark soup is an interacting localized assembly of quarks and gluons at thermal (local kinetic) and (close to) chemical (abundance) equilibrium. The word ''plasma'' signals that free color charges are allowed. In a ...
(at extremely high energy). For a complete list of all exotic states of matter, see the
list of states of matter States of matter are distinguished by changes in the properties of matter associated with external factors like pressure and temperature. States are usually distinguished by a discontinuity in one of those properties—for example, raising the te ...
. Historically, the distinction is made based on qualitative differences in properties. Matter in the solid state maintains a fixed
volume Volume is a measure of occupied three-dimensional space. It is often quantified numerically using SI derived units (such as the cubic metre and litre) or by various imperial or US customary units (such as the gallon, quart, cubic inch). ...
(assuming no change in temperature or air pressure) and shape, with component particles (
atoms Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas ...
,
molecules A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bio ...
or
ions An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...
) close together and fixed into place. Matter in the liquid state maintains a fixed volume (assuming no change in temperature or air pressure), but has a variable shape that adapts to fit its container. Its particles are still close together but move freely. Matter in the gaseous state has both variable volume and shape, adapting both to fit its container. Its particles are neither close together nor fixed in place. Matter in the plasma state has variable volume and shape, and contains neutral atoms as well as a significant number of ions and
electrons The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have n ...
, both of which can move around freely. The term " phase" is sometimes used as a
synonym A synonym is a word, morpheme, or phrase that means exactly or nearly the same as another word, morpheme, or phrase in a given language. For example, in the English language, the words ''begin'', ''start'', ''commence'', and ''initiate'' are al ...
for state of matter, but it is possible for a single compound to form different phases that are in the same state of matter. For example, ice is the solid state of water, but there are multiple phases of ice with different
crystal structure In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric pattern ...
s, which are formed at different pressures and temperatures.


Four fundamental states


Solid

In a solid, constituent particles (ions, atoms, or molecules) are closely packed together. The forces between particles are so strong that the particles cannot move freely but can only vibrate. As a result, a solid has a stable, definite shape, and a definite volume. Solids can only change their shape by an outside force, as when broken or cut. In
crystalline solids A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...
, the particles (atoms, molecules, or ions) are packed in a regularly ordered, repeating pattern. There are various different
crystal structure In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric pattern ...
s, and the same substance can have more than one structure (or solid phase). For example,
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in ...
has a body-centred cubic structure at temperatures below , and a face-centred cubic structure between 912 and . Ice has fifteen known crystal structures, or fifteen solid phases, which exist at various temperatures and pressures.
Glass Glass is a non- crystalline, often transparent, amorphous solid that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most often formed by rapid cooling (quenchin ...
es and other non-crystalline,
amorphous solid In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid, glassy solid) is a solid that lacks the long-range order that is characteristic of a crystal. Etymology The term comes from the Greek ''a'' (" ...
s without long-range order are not
thermal equilibrium Two physical systems are in thermal equilibrium if there is no net flow of thermal energy between them when they are connected by a path permeable to heat. Thermal equilibrium obeys the zeroth law of thermodynamics. A system is said to be in ...
ground states; therefore they are described below as nonclassical states of matter. Solids can be transformed into liquids by melting, and liquids can be transformed into solids by freezing. Solids can also change directly into gases through the process of sublimation, and gases can likewise change directly into solids through
deposition Deposition may refer to: * Deposition (law), taking testimony outside of court * Deposition (politics), the removal of a person of authority from political power * Deposition (university), a widespread initiation ritual for new students practiced f ...
.


Liquid

A liquid is a nearly incompressible
fluid In physics, a fluid is a liquid, gas, or other material that continuously deforms (''flows'') under an applied shear stress, or external force. They have zero shear modulus, or, in simpler terms, are substances which cannot resist any shear ...
that conforms to the shape of its container but retains a (nearly) constant volume independent of pressure. The volume is definite if the
temperature Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied o ...
and
pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country a ...
are constant. When a solid is heated above its
melting point The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depen ...
, it becomes liquid, given that the pressure is higher than the
triple point In thermodynamics, the triple point of a substance is the temperature and pressure at which the three phases (gas, liquid, and solid) of that substance coexist in thermodynamic equilibrium.. It is that temperature and pressure at which the ...
of the substance. Intermolecular (or interatomic or interionic) forces are still important, but the molecules have enough energy to move relative to each other and the structure is mobile. This means that the shape of a liquid is not definite but is determined by its container. The volume is usually greater than that of the corresponding solid, the best known exception being
water Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as ...
, HO. The highest temperature at which a given liquid can exist is its
critical temperature Critical or Critically may refer to: *Critical, or critical but stable, medical states **Critical, or intensive care medicine * Critical juncture, a discontinuous change studied in the social sciences. * Critical Software, a company specializing ...
.


Gas

A gas is a compressible fluid. Not only will a gas conform to the shape of its container but it will also expand to fill the container. In a gas, the molecules have enough
kinetic energy In physics, the kinetic energy of an object is the energy that it possesses due to its motion. It is defined as the work needed to accelerate a body of a given mass from rest to its stated velocity. Having gained this energy during its acce ...
so that the effect of intermolecular forces is small (or zero for an
ideal gas An ideal gas is a theoretical gas composed of many randomly moving point particles that are not subject to interparticle interactions. The ideal gas concept is useful because it obeys the ideal gas law, a simplified equation of state, and is a ...
), and the typical distance between neighboring molecules is much greater than the molecular size. A gas has no definite shape or volume, but occupies the entire container in which it is confined. A liquid may be converted to a gas by heating at constant pressure to the
boiling point The boiling point of a substance is the temperature at which the vapor pressure of a liquid equals the pressure surrounding the liquid and the liquid changes into a vapor. The boiling point of a liquid varies depending upon the surrounding env ...
, or else by reducing the pressure at constant temperature. At temperatures below its
critical temperature Critical or Critically may refer to: *Critical, or critical but stable, medical states **Critical, or intensive care medicine * Critical juncture, a discontinuous change studied in the social sciences. * Critical Software, a company specializing ...
, a gas is also called a
vapor In physics, a vapor (American English) or vapour (British English and Canadian English; see spelling differences) is a substance in the gas phase at a temperature lower than its critical temperature,R. H. Petrucci, W. S. Harwood, and F. G. Her ...
, and can be liquefied by compression alone without cooling. A vapor can exist in equilibrium with a liquid (or solid), in which case the gas pressure equals the
vapor pressure Vapor pressure (or vapour pressure in English-speaking countries other than the US; see spelling differences) or equilibrium vapor pressure is defined as the pressure exerted by a vapor in thermodynamic equilibrium with its condensed pha ...
of the liquid (or solid). A
supercritical fluid A supercritical fluid (SCF) is any substance at a temperature and pressure above its critical point (chemistry), critical point, where distinct liquid and gas phases do not exist, but below the pressure required to compress it into a solid. It ca ...
(SCF) is a gas whose temperature and pressure are above the critical temperature and critical pressure respectively. In this state, the distinction between liquid and gas disappears. A supercritical fluid has the physical properties of a gas, but its high density confers solvent properties in some cases, which leads to useful applications. For example,
supercritical carbon dioxide Supercritical carbon dioxide (s) is a fluid state of carbon dioxide where it is held at or above its critical temperature and critical pressure. Carbon dioxide usually behaves as a gas in air at standard temperature and pressure (STP), or as ...
is used to
extract An extract is a substance made by extracting a part of a raw material, often by using a solvent such as ethanol, oil or water. Extracts may be sold as tinctures, absolutes or in powder form. The aromatic principles of many spices, nuts ...
caffeine Caffeine is a central nervous system (CNS) stimulant of the methylxanthine chemical classification, class. It is mainly recreational drug use, used recreationally as a Nootropic, cognitive enhancer, increasing alertness and attentional perfor ...
in the manufacture of
decaffeinated Decaffeination is the removal of caffeine from coffee beans, cocoa, tea leaves, and other caffeine-containing materials. Decaffeinated drinks contain typically 1–2% of the original caffeine content, and sometimes as much as 20%. Decaffeinate ...
coffee.


Plasma

Like a gas, plasma does not have definite shape or volume. Unlike gases, plasmas are electrically conductive, produce magnetic fields and electric currents, and respond strongly to electromagnetic forces. Positively charged nuclei swim in a "sea" of freely-moving disassociated electrons, similar to the way such charges exist in conductive metal, where this electron "sea" allows matter in the plasma state to conduct electricity. A gas is usually converted to a plasma in one of two ways, either from a huge voltage difference between two points, or by exposing it to extremely high temperatures. Heating matter to high temperatures causes electrons to leave the atoms, resulting in the presence of free electrons. This creates a so-called partially ionised plasma. At very high temperatures, such as those present in stars, it is assumed that essentially all electrons are "free", and that a very high-energy plasma is essentially bare nuclei swimming in a sea of electrons. This forms the so-called fully ionised plasma. The plasma state is often misunderstood, and although not freely existing under normal conditions on Earth, it is quite commonly generated by either
lightning Lightning is a naturally occurring electrostatic discharge during which two electrically charged regions, both in the atmosphere or with one on the ground, temporarily neutralize themselves, causing the instantaneous release of an average ...
,
electric spark An electric spark is an abrupt electrical discharge that occurs when a sufficiently high electric field creates an ionized, electrically conductive channel through a normally-insulating medium, often air or other gases or gas mixtures. Michael F ...
s, fluorescent lights, neon lights or in plasma televisions. The Sun's corona, some types of
flame A flame (from Latin '' flamma'') is the visible, gaseous part of a fire. It is caused by a highly exothermic chemical reaction taking place in a thin zone. When flames are hot enough to have ionized gaseous components of sufficient density the ...
, and stars are all examples of illuminated matter in the plasma state.


Phase transitions

A state of matter is also characterized by
phase transitions In chemistry, thermodynamics, and other related fields, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states of ...
. A phase transition indicates a change in structure and can be recognized by an abrupt change in properties. A distinct state of matter can be defined as any set of states distinguished from any other set of states by a
phase transition In chemistry, thermodynamics, and other related fields, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states ...
. Water can be said to have several distinct solid states. The appearance of superconductivity is associated with a phase transition, so there are superconductive states. Likewise,
ferromagnetic Ferromagnetism is a property of certain materials (such as iron) which results in a large observed magnetic permeability, and in many cases a large magnetic coercivity allowing the material to form a permanent magnet. Ferromagnetic materials ...
states are demarcated by phase transitions and have distinctive properties. When the change of state occurs in stages the intermediate steps are called mesophases. Such phases have been exploited by the introduction of
liquid crystal Liquid crystal (LC) is a state of matter whose properties are between those of conventional liquids and those of solid crystals. For example, a liquid crystal may flow like a liquid, but its molecules may be oriented in a crystal-like way. Th ...
technology. The state or ''phase'' of a given set of matter can change depending on
pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country a ...
and
temperature Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied o ...
conditions, transitioning to other phases as these conditions change to favor their existence; for example, solid transitions to liquid with an increase in temperature. Near
absolute zero Absolute zero is the lowest limit of the thermodynamic temperature scale, a state at which the enthalpy and entropy of a cooled ideal gas reach their minimum value, taken as zero kelvin. The fundamental particles of nature have minimum vibra ...
, a substance exists as a
solid Solid is one of the four fundamental states of matter (the others being liquid, gas, and plasma). The molecules in a solid are closely packed together and contain the least amount of kinetic energy. A solid is characterized by structur ...
. As heat is added to this substance it melts into a liquid at its
melting point The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depen ...
, boils into a gas at its
boiling point The boiling point of a substance is the temperature at which the vapor pressure of a liquid equals the pressure surrounding the liquid and the liquid changes into a vapor. The boiling point of a liquid varies depending upon the surrounding env ...
, and if heated high enough would enter a plasma state in which the
electrons The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have n ...
are so energized that they leave their parent atoms. Forms of matter that are not composed of molecules and are organized by different forces can also be considered different states of matter. Superfluids (like
Fermionic condensate A fermionic condensate or Fermi–Dirac condensate is a superfluid phase formed by fermionic particles at low temperatures. It is closely related to the Bose–Einstein condensate, a superfluid phase formed by bosonic atoms under similar cond ...
) and the
quark–gluon plasma Quark–gluon plasma (QGP) or quark soup is an interacting localized assembly of quarks and gluons at thermal (local kinetic) and (close to) chemical (abundance) equilibrium. The word ''plasma'' signals that free color charges are allowed. In a ...
are examples. In a chemical equation, the state of matter of the chemicals may be shown as (s) for solid, (l) for liquid, and (g) for gas. An
aqueous solution An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, or sodium chloride (NaCl), in water would be r ...
is denoted (aq). Matter in the plasma state is seldom used (if at all) in chemical equations, so there is no standard symbol to denote it. In the rare equations that plasma is used it is symbolized as (p).


Non-classical states


Glass

Glass Glass is a non- crystalline, often transparent, amorphous solid that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most often formed by rapid cooling (quenchin ...
is a non-crystalline or
amorphous solid In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid, glassy solid) is a solid that lacks the long-range order that is characteristic of a crystal. Etymology The term comes from the Greek ''a'' (" ...
material that exhibits a
glass transition The glass–liquid transition, or glass transition, is the gradual and reversible transition in amorphous materials (or in amorphous regions within semicrystalline materials) from a hard and relatively brittle "glassy" state into a viscous or ru ...
when heated towards the liquid state. Glasses can be made of quite different classes of materials: inorganic networks (such as window glass, made of
silicate In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is a ...
plus additives), metallic alloys, ionic melts,
aqueous solution An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, or sodium chloride (NaCl), in water would be r ...
s, molecular liquids, and
polymers A polymer (; Greek '' poly-'', "many" + '' -mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...
. Thermodynamically, a glass is in a
metastable state In chemistry and physics, metastability denotes an intermediate energetic state within a dynamical system other than the system's state of least energy. A ball resting in a hollow on a slope is a simple example of metastability. If the ball ...
with respect to its crystalline counterpart. The conversion rate, however, is practically zero.


Crystals with some degree of disorder

A plastic crystal is a molecular solid with long-range positional order but with constituent molecules retaining rotational freedom; in an
orientational glass In solid-state physics, an orientational glass is a molecular solid in which crystalline long-range order coexists with quenched disorder in some rotational degree of freedom. An orientational glass is either obtained by quenching a plastic cryst ...
this degree of freedom is frozen in a quenched disordered state. Similarly, in a spin glass magnetic disorder is frozen.


Liquid crystal states

Liquid crystal states have properties intermediate between mobile liquids and ordered solids. Generally, they are able to flow like a liquid, but exhibiting long-range order. For example, the
nematic phase Liquid crystal (LC) is a state of matter whose properties are between those of conventional liquids and those of solid crystals. For example, a liquid crystal may flow like a liquid, but its molecules may be oriented in a crystal-like way. The ...
consists of long rod-like molecules such as para-azoxyanisole, which is nematic in the temperature range . In this state the molecules flow as in a liquid, but they all point in the same direction (within each domain) and cannot rotate freely. Like a crystalline solid, but unlike a liquid, liquid crystals react to polarized light. Other types of liquid crystals are described in the main article on these states. Several types have technological importance, for example, in
liquid crystal display A liquid-crystal display (LCD) is a flat-panel display or other electronically modulated optical device that uses the light-modulating properties of liquid crystals combined with polarizers. Liquid crystals do not emit light directly but ...
s.


Magnetically ordered

Transition metal In chemistry, a transition metal (or transition element) is a chemical element in the d-block of the periodic table (groups 3 to 12), though the elements of group 12 (and less often group 3) are sometimes excluded. They are the elements that can ...
atoms often have
magnetic moment In electromagnetism, the magnetic moment is the magnetic strength and orientation of a magnet or other object that produces a magnetic field. Examples of objects that have magnetic moments include loops of electric current (such as electroma ...
s due to the net
spin Spin or spinning most often refers to: * Spinning (textiles), the creation of yarn or thread by twisting fibers together, traditionally by hand spinning * Spin, the rotation of an object around a central axis * Spin (propaganda), an intentionally ...
of electrons that remain unpaired and do not form chemical bonds. In some solids the magnetic moments on different atoms are ordered and can form a ferromagnet, an antiferromagnet or a ferrimagnet. In a
ferromagnet Ferromagnetism is a property of certain materials (such as iron) which results in a large observed magnetic permeability, and in many cases a large magnetic coercivity allowing the material to form a permanent magnet. Ferromagnetic materials ...
—for instance, solid
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in ...
—the magnetic moment on each atom is aligned in the same direction (within a magnetic domain). If the domains are also aligned, the solid is a permanent
magnet A magnet is a material or object that produces a magnetic field. This magnetic field is invisible but is responsible for the most notable property of a magnet: a force that pulls on other ferromagnetic materials, such as iron, steel, nicke ...
, which is magnetic even in the absence of an external
magnetic field A magnetic field is a vector field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to ...
. The
magnetization In classical electromagnetism, magnetization is the vector field that expresses the density of permanent or induced magnetic dipole moments in a magnetic material. Movement within this field is described by direction and is either Axial or D ...
disappears when the magnet is heated to the Curie point, which for iron is . An
antiferromagnet In materials that exhibit antiferromagnetism, the magnetic moments of atoms or molecules, usually related to the spins of electrons, align in a regular pattern with neighboring spins (on different sublattices) pointing in opposite directions. ...
has two networks of equal and opposite magnetic moments, which cancel each other out so that the net magnetization is zero. For example, in nickel(II) oxide (NiO), half the nickel atoms have moments aligned in one direction and half in the opposite direction. In a ferrimagnet, the two networks of magnetic moments are opposite but unequal, so that cancellation is incomplete and there is a non-zero net magnetization. An example is
magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With ...
(FeO), which contains Fe and Fe ions with different magnetic moments. A quantum spin liquid (QSL) is a disordered state in a system of interacting quantum spins which preserves its disorder to very low temperatures, unlike other disordered states. It is not a liquid in physical sense, but a solid whose magnetic order is inherently disordered. The name "liquid" is due to an analogy with the molecular disorder in a conventional liquid. A QSL is neither a
ferromagnet Ferromagnetism is a property of certain materials (such as iron) which results in a large observed magnetic permeability, and in many cases a large magnetic coercivity allowing the material to form a permanent magnet. Ferromagnetic materials ...
, where magnetic domains are parallel, nor an
antiferromagnet In materials that exhibit antiferromagnetism, the magnetic moments of atoms or molecules, usually related to the spins of electrons, align in a regular pattern with neighboring spins (on different sublattices) pointing in opposite directions. ...
, where the magnetic domains are antiparallel; instead, the magnetic domains are randomly oriented. This can be realized e.g. by geometrically frustrated magnetic moments that cannot point uniformly parallel or antiparallel. When cooling down and settling to a state, the domain must "choose" an orientation, but if the possible states are similar in energy, one will be chosen randomly. Consequently, despite strong short-range order, there is no long-range magnetic order.


Microphase-separated

Copolymers In polymer chemistry, a copolymer is a polymer derived from more than one species of monomer. The polymerization of monomers into copolymers is called copolymerization. Copolymers obtained from the copolymerization of two monomer species are some ...
can undergo microphase separation to form a diverse array of periodic nanostructures, as shown in the example of the styrene-butadiene-styrene block copolymer shown at right. Microphase separation can be understood by analogy to the phase separation between oil and water. Due to chemical incompatibility between the blocks, block copolymers undergo a similar phase separation. However, because the blocks are covalently bonded to each other, they cannot demix macroscopically as water and oil can, and so instead the blocks form nanometre-sized structures. Depending on the relative lengths of each block and the overall block topology of the polymer, many morphologies can be obtained, each its own phase of matter.
Ionic liquid An ionic liquid (IL) is a salt in the liquid state. In some contexts, the term has been restricted to salts whose melting point is below a specific temperature, such as . While ordinary liquids such as water and gasoline are predominantly made of ...
s also display microphase separation. The anion and cation are not necessarily compatible and would demix otherwise, but electric charge attraction prevents them from separating. Their anions and cations appear to diffuse within compartmentalized layers or micelles instead of freely as in a uniform liquid.


Low-temperature states


Superconductor

Superconductors are materials which have zero electrical resistivity, and therefore perfect conductivity. This is a distinct physical state which exists at low temperature, and the resistivity increases discontinuously to a finite value at a sharply-defined transition temperature for each superconductor. A superconductor also excludes all magnetic fields from its interior, a phenomenon known as the Meissner effect or perfect
diamagnetism Diamagnetic materials are repelled by a magnetic field; an applied magnetic field creates an induced magnetic field in them in the opposite direction, causing a repulsive force. In contrast, paramagnetic and ferromagnetic materials are attracte ...
.
Superconducting magnet A superconducting magnet is an electromagnet made from coils of superconducting wire. They must be cooled to cryogenic temperatures during operation. In its superconducting state the wire has no electrical resistance and therefore can conduct much ...
s are used as electromagnets in
magnetic resonance imaging Magnetic resonance imaging (MRI) is a medical imaging technique used in radiology to form pictures of the anatomy and the physiological processes of the body. MRI scanners use strong magnetic fields, magnetic field gradients, and radio wave ...
machines. The phenomenon of superconductivity was discovered in 1911, and for 75 years was only known in some metals and metallic alloys at temperatures below 30 K. In 1986 so-called
high-temperature superconductivity High-temperature superconductors (abbreviated high-c or HTS) are defined as materials that behave as superconductors at temperatures above , the boiling point of liquid nitrogen. The adjective "high temperature" is only in respect to previou ...
was discovered in certain
ceramic A ceramic is any of the various hard, brittle, heat-resistant and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcelain, ...
oxides, and has now been observed in temperatures as high as 164 K.


Superfluid

Close to absolute zero, some liquids form a second liquid state described as superfluid because it has zero
viscosity The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the int ...
(or infinite fluidity; i.e., flowing without friction). This was discovered in 1937 for
helium Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic ta ...
, which forms a superfluid below the lambda temperature of . In this state it will attempt to "climb" out of its container. It also has infinite
thermal conductivity The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by k, \lambda, or \kappa. Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal ...
so that no
temperature gradient A temperature gradient is a physical quantity that describes in which direction and at what rate the temperature changes the most rapidly around a particular location. The temperature gradient is a dimensional quantity expressed in units of degre ...
can form in a superfluid. Placing a superfluid in a spinning container will result in
quantized vortices In physics, a quantum vortex represents a quantized flux circulation of some physical quantity. In most cases, quantum vortices are a type of topological defect exhibited in superfluids and superconductors. The existence of quantum vortices was fi ...
. These properties are explained by the theory that the common isotope
helium-4 Helium-4 () is a stable isotope of the element helium. It is by far the more abundant of the two naturally occurring isotopes of helium, making up about 99.99986% of the helium on Earth. Its nucleus is identical to an alpha particle, and cons ...
forms a
Bose–Einstein condensate In condensed matter physics, a Bose–Einstein condensate (BEC) is a state of matter that is typically formed when a gas of bosons at very low densities is cooled to temperatures very close to absolute zero (−273.15 °C or −459.6 ...
(see next section) in the superfluid state. More recently,
Fermionic condensate A fermionic condensate or Fermi–Dirac condensate is a superfluid phase formed by fermionic particles at low temperatures. It is closely related to the Bose–Einstein condensate, a superfluid phase formed by bosonic atoms under similar cond ...
superfluids have been formed at even lower temperatures by the rare isotope
helium-3 Helium-3 (3He see also helion) is a light, stable isotope of helium with two protons and one neutron (the most common isotope, helium-4, having two protons and two neutrons in contrast). Other than protium (ordinary hydrogen), helium-3 is the ...
and by
lithium-6 Naturally occurring lithium (3Li) is composed of two stable isotopes, lithium-6 and lithium-7, with the latter being far more abundant on Earth. Both of the natural isotopes have an unexpectedly low nuclear binding energy per nucleon ( for l ...
.


Bose–Einstein condensate

In 1924,
Albert Einstein Albert Einstein ( ; ; 14 March 1879 – 18 April 1955) was a German-born theoretical physicist, widely acknowledged to be one of the greatest and most influential physicists of all time. Einstein is best known for developing the theor ...
and Satyendra Nath Bose predicted the "Bose–Einstein condensate" (BEC), sometimes referred to as the fifth state of matter. In a BEC, matter stops behaving as independent particles, and collapses into a single quantum state that can be described with a single, uniform wavefunction. In the gas phase, the Bose–Einstein condensate remained an unverified theoretical prediction for many years. In 1995, the research groups of Eric Cornell and
Carl Wieman Carl Edwin Wieman (born March 26, 1951) is an American physicist and educationist at Stanford University, and currently the A.D White Professor at Large at Cornell University. In 1995, while at the University of Colorado Boulder, he and Eric All ...
, of JILA at the
University of Colorado at Boulder The University of Colorado Boulder (CU Boulder, CU, or Colorado) is a public research university in Boulder, Colorado. Founded in 1876, five months before Colorado became a state, it is the flagship university of the University of Colorado sy ...
, produced the first such condensate experimentally. A Bose–Einstein condensate is "colder" than a solid. It may occur when atoms have very similar (or the same) quantum levels, at temperatures very close to
absolute zero Absolute zero is the lowest limit of the thermodynamic temperature scale, a state at which the enthalpy and entropy of a cooled ideal gas reach their minimum value, taken as zero kelvin. The fundamental particles of nature have minimum vibra ...
, .


Fermionic condensate

A ''fermionic condensate'' is similar to the Bose–Einstein condensate but composed of
fermion In particle physics, a fermion is a particle that follows Fermi–Dirac statistics. Generally, it has a half-odd-integer spin: spin , spin , etc. In addition, these particles obey the Pauli exclusion principle. Fermions include all quarks and ...
s. The
Pauli exclusion principle In quantum mechanics, the Pauli exclusion principle states that two or more identical particles with half-integer spins (i.e. fermions) cannot occupy the same quantum state within a quantum system simultaneously. This principle was formula ...
prevents fermions from entering the same quantum state, but a pair of fermions can behave as a boson, and multiple such pairs can then enter the same quantum state without restriction.


Rydberg molecule

One of the
metastable state In chemistry and physics, metastability denotes an intermediate energetic state within a dynamical system other than the system's state of least energy. A ball resting in a hollow on a slope is a simple example of metastability. If the ball ...
s of strongly non-ideal plasma are condensates of excited atoms, called Rydberg matter. These atoms can also turn into ions and
electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have n ...
s if they reach a certain temperature. In April 2009, ''
Nature Nature, in the broadest sense, is the physical world or universe. "Nature" can refer to the phenomena of the physical world, and also to life in general. The study of nature is a large, if not the only, part of science. Although humans are ...
'' reported the creation of Rydberg molecules from a Rydberg atom and a
ground state The ground state of a quantum-mechanical system is its stationary state of lowest energy; the energy of the ground state is known as the zero-point energy of the system. An excited state is any state with energy greater than the ground state. ...
atom, confirming that such a state of matter could exist. The experiment was performed using ultracold
rubidium Rubidium is the chemical element with the symbol Rb and atomic number 37. It is a very soft, whitish-grey solid in the alkali metal group, similar to potassium and caesium. Rubidium is the first alkali metal in the group to have a density higher ...
atoms.


Quantum Hall state

A ''quantum Hall state'' gives rise to quantized Hall voltage measured in the direction perpendicular to the current flow. A '' quantum spin Hall state'' is a theoretical phase that may pave the way for the development of electronic devices that dissipate less energy and generate less heat. This is a derivation of the Quantum Hall state of matter.


Photonic matter

Photonic matter is a phenomenon where
photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they alwa ...
s interacting with a gas develop apparent mass, and can interact with each other, even forming photonic "molecules". The source of mass is the gas, which is massive. This is in contrast to photons moving in empty space, which have no
rest mass The invariant mass, rest mass, intrinsic mass, proper mass, or in the case of bound systems simply mass, is the portion of the total mass of an object or system of objects that is independent of the overall motion of the system. More precisely, i ...
, and cannot interact.


Dropleton

A "quantum fog" of electrons and holes that flow around each other and even ripple like a liquid, rather than existing as discrete pairs.


High-energy states


Degenerate matter

Under extremely high pressure, as in the cores of dead stars, ordinary matter undergoes a transition to a series of exotic states of matter collectively known as
degenerate matter Degenerate matter is a highly dense state of fermionic matter in which the Pauli exclusion principle exerts significant pressure in addition to, or in lieu of, thermal pressure. The description applies to matter composed of electrons, protons, n ...
, which are supported mainly by quantum mechanical effects. In physics, "degenerate" refers to two states that have the same energy and are thus interchangeable. Degenerate matter is supported by the
Pauli exclusion principle In quantum mechanics, the Pauli exclusion principle states that two or more identical particles with half-integer spins (i.e. fermions) cannot occupy the same quantum state within a quantum system simultaneously. This principle was formula ...
, which prevents two
fermion In particle physics, a fermion is a particle that follows Fermi–Dirac statistics. Generally, it has a half-odd-integer spin: spin , spin , etc. In addition, these particles obey the Pauli exclusion principle. Fermions include all quarks and ...
ic particles from occupying the same quantum state. Unlike regular plasma, degenerate plasma expands little when heated, because there are simply no momentum states left. Consequently, degenerate stars collapse into very high densities. More massive degenerate stars are smaller, because the gravitational force increases, but pressure does not increase proportionally. Electron-degenerate matter is found inside
white dwarf A white dwarf is a stellar core remnant composed mostly of electron-degenerate matter. A white dwarf is very dense: its mass is comparable to the Sun's, while its volume is comparable to the Earth's. A white dwarf's faint luminosity comes ...
stars. Electrons remain bound to atoms but are able to transfer to adjacent atoms. Neutron-degenerate matter is found in
neutron star A neutron star is the collapsed core of a massive supergiant star, which had a total mass of between 10 and 25 solar masses, possibly more if the star was especially metal-rich. Except for black holes and some hypothetical objects (e.g. w ...
s. Vast gravitational pressure compresses atoms so strongly that the electrons are forced to combine with protons via inverse beta-decay, resulting in a superdense conglomeration of neutrons. Normally free
neutron The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the atomic nucleus, nuclei of atoms. Since protons and ...
s outside an atomic nucleus will decay with a half life of approximately 10 minutes, but in a neutron star, the decay is overtaken by inverse decay. Cold degenerate matter is also present in planets such as
Jupiter Jupiter is the fifth planet from the Sun and the largest in the Solar System. It is a gas giant with a mass more than two and a half times that of all the other planets in the Solar System combined, but slightly less than one-thousand ...
and in the even more massive
brown dwarf Brown dwarfs (also called failed stars) are substellar objects that are not massive enough to sustain nuclear fusion of ordinary hydrogen ( 1H) into helium in their cores, unlike a main-sequence star. Instead, they have a mass between the most ...
s, which are expected to have a core with
metallic hydrogen Metallic hydrogen is a phase of hydrogen in which it behaves like an electrical conductor. This phase was predicted in 1935 on theoretical grounds by Eugene Wigner and Hillard Bell Huntington. At high pressure and temperatures, metallic hydroge ...
. Because of the degeneracy, more massive brown dwarfs are not significantly larger. In metals, the electrons can be modeled as a degenerate gas moving in a lattice of non-degenerate positive ions.


Quark matter

In regular cold matter,
quark A quark () is a type of elementary particle and a fundamental constituent of matter. Quarks combine to form composite particles called hadrons, the most stable of which are protons and neutrons, the components of atomic nuclei. All commonly ...
s, fundamental particles of nuclear matter, are confined by the strong force into
hadron In particle physics, a hadron (; grc, ἁδρός, hadrós; "stout, thick") is a composite subatomic particle made of two or more quarks held together by the strong interaction. They are analogous to molecules that are held together by the ...
s that consist of 2–4 quarks, such as protons and neutrons. Quark matter or quantum chromodynamical (QCD) matter is a group of phases where the strong force is overcome and quarks are deconfined and free to move. Quark matter phases occur at extremely high densities or temperatures, and there are no known ways to produce them in equilibrium in the laboratory; in ordinary conditions, any quark matter formed immediately undergoes radioactive decay. Strange matter is a type of quark matter that is suspected to exist inside some neutron stars close to the Tolman–Oppenheimer–Volkoff limit (approximately 2–3
solar mass The solar mass () is a standard unit of mass in astronomy, equal to approximately . It is often used to indicate the masses of other stars, as well as stellar clusters, nebulae, galaxies and black holes. It is approximately equal to the mass ...
es), although there is no direct evidence of its existence. In strange matter, part of the energy available manifests as
strange quark The strange quark or s quark (from its symbol, s) is the third lightest of all quarks, a type of elementary particle. Strange quarks are found in subatomic particles called hadrons. Examples of hadrons containing strange quarks include kaons ( ...
s, a heavier analogue of the common
down quark The down quark or d quark (symbol: d) is the second-lightest of all quarks, a type of elementary particle, and a major constituent of matter. Together with the up quark, it forms the neutrons (one up quark, two down quarks) and protons (two up ...
. It may be stable at lower energy states once formed, although this is not known.
Quark–gluon plasma Quark–gluon plasma (QGP) or quark soup is an interacting localized assembly of quarks and gluons at thermal (local kinetic) and (close to) chemical (abundance) equilibrium. The word ''plasma'' signals that free color charges are allowed. In a ...
is a very high-temperature phase in which
quark A quark () is a type of elementary particle and a fundamental constituent of matter. Quarks combine to form composite particles called hadrons, the most stable of which are protons and neutrons, the components of atomic nuclei. All commonly ...
s become free and able to move independently, rather than being perpetually bound into particles, in a sea of
gluon A gluon ( ) is an elementary particle that acts as the exchange particle (or gauge boson) for the strong force between quarks. It is analogous to the exchange of photons in the electromagnetic force between two charged particles. Gluons bind ...
s, subatomic particles that transmit the strong force that binds quarks together. This is analogous to the liberation of electrons from atoms in a plasma. This state is briefly attainable in extremely high-energy heavy ion collisions in
particle accelerator A particle accelerator is a machine that uses electromagnetic fields to propel charged particles to very high speeds and energies, and to contain them in well-defined beams. Large accelerators are used for fundamental research in particle ...
s, and allows scientists to observe the properties of individual quarks, and not just theorize. Quark–gluon plasma was discovered at
CERN The European Organization for Nuclear Research, known as CERN (; ; ), is an intergovernmental organization that operates the largest particle physics laboratory in the world. Established in 1954, it is based in a northwestern suburb of Gen ...
in 2000. Unlike plasma, which flows like a gas, interactions within QGP are strong and it flows like a liquid. At high densities but relatively low temperatures, quarks are theorized to form a quark liquid whose nature is presently unknown. It forms a distinct color-flavor locked (CFL) phase at even higher densities. This phase is superconductive for color charge. These phases may occur in
neutron star A neutron star is the collapsed core of a massive supergiant star, which had a total mass of between 10 and 25 solar masses, possibly more if the star was especially metal-rich. Except for black holes and some hypothetical objects (e.g. w ...
s but they are presently theoretical.


Color-glass condensate

Color-glass condensate is a type of matter theorized to exist in atomic nuclei traveling near the speed of light. According to Einstein's theory of relativity, a high-energy nucleus appears length contracted, or compressed, along its direction of motion. As a result, the gluons inside the nucleus appear to a stationary observer as a "gluonic wall" traveling near the speed of light. At very high energies, the density of the gluons in this wall is seen to increase greatly. Unlike the quark–gluon plasma produced in the collision of such walls, the color-glass condensate describes the walls themselves, and is an intrinsic property of the particles that can only be observed under high-energy conditions such as those at RHIC and possibly at the Large Hadron Collider as well.


Very high energy states

Various theories predict new states of matter at very high energies. An unknown state has created the baryon asymmetry in the universe, but little is known about it. In
string theory In physics, string theory is a theoretical framework in which the point-like particles of particle physics are replaced by one-dimensional objects called strings. String theory describes how these strings propagate through space and intera ...
, a Hagedorn temperature is predicted for superstrings at about 1030 K, where superstrings are copiously produced. At Planck temperature (1032 K), gravity becomes a significant force between individual particles. No current theory can describe these states and they cannot be produced with any foreseeable experiment. However, these states are important in
cosmology Cosmology () is a branch of physics and metaphysics dealing with the nature of the universe. The term ''cosmology'' was first used in English in 1656 in Thomas Blount's ''Glossographia'', and in 1731 taken up in Latin by German philosopher ...
because the universe may have passed through these states in the
Big Bang The Big Bang event is a physical theory that describes how the universe expanded from an initial state of high density and temperature. Various cosmological models of the Big Bang explain the evolution of the observable universe from the ...
. The gravitational singularity predicted by
general relativity General relativity, also known as the general theory of relativity and Einstein's theory of gravity, is the geometric theory of gravitation published by Albert Einstein in 1915 and is the current description of gravitation in modern physics ...
to exist at the center of a
black hole A black hole is a region of spacetime where gravity is so strong that nothing, including light or other electromagnetic waves, has enough energy to escape it. The theory of general relativity predicts that a sufficiently compact mass can def ...
is ''not'' a phase of matter; it is not a material object at all (although the mass-energy of matter contributed to its creation) but rather a property of
spacetime In physics, spacetime is a mathematical model that combines the three dimensions of space and one dimension of time into a single four-dimensional manifold. Spacetime diagrams can be used to visualize relativistic effects, such as why differ ...
. Because spacetime breaks down there, the singularity should not be thought of as a localized structure, but as a global, topological feature of spacetime. It has been argued that elementary particles are fundamentally not material, either, but are localized properties of spacetime. In quantum gravity, singularities may in fact mark transitions to a new phase of matter.


Other proposed states


Supersolid

A supersolid is a spatially ordered material (that is, a solid or crystal) with superfluid properties. Similar to a superfluid, a supersolid is able to move without friction but retains a rigid shape. Although a supersolid is a solid, it exhibits so many characteristic properties different from other solids that many argue it is another state of matter.


String-net liquid

In a string-net liquid, atoms have apparently unstable arrangement, like a liquid, but are still consistent in overall pattern, like a solid. When in a normal solid state, the atoms of matter align themselves in a grid pattern, so that the spin of any electron is the opposite of the spin of all electrons touching it. But in a string-net liquid, atoms are arranged in some pattern that requires some electrons to have neighbors with the same spin. This gives rise to curious properties, as well as supporting some unusual proposals about the fundamental conditions of the universe itself.


Superglass

A superglass is a phase of matter characterized, at the same time, by superfluidity and a frozen amorphous structure.


Arbitrary definition

Although multiple attempts have been made to create a unified account, ultimately the definitions of what states of matter exist and the point at which states change are arbitrary. Some authors have suggested that states of matter are better thought of as a
spectrum A spectrum (plural ''spectra'' or ''spectrums'') is a condition that is not limited to a specific set of values but can vary, without gaps, across a continuum. The word was first used scientifically in optics to describe the rainbow of colors ...
between a solid and plasma instead of being rigidly defined.


See also

* Hidden states of matter *
Classical element Classical elements typically refer to earth, water, air, fire, and (later) aether which were proposed to explain the nature and complexity of all matter in terms of simpler substances. Ancient cultures in Greece, Tibet, and India had simi ...
*
Condensed matter physics Condensed matter physics is the field of physics that deals with the macroscopic and microscopic physical properties of matter, especially the solid and liquid phases which arise from electromagnetic forces between atoms. More generally, the su ...
* Cooling curve *
Phase (matter) In the physical sciences, a phase is a region of space (a thermodynamic system), throughout which all physical properties of a material are essentially uniform. Examples of physical properties include density, index of refraction, magnet ...
*
Supercooling Supercooling, also known as undercooling, is the process of lowering the temperature of a liquid or a gas below its melting point without it becoming a solid. It achieves this in the absence of a seed crystal or nucleus around which a crystal ...
*
Superheating In thermodynamics, superheating (sometimes referred to as boiling retardation, or boiling delay) is the phenomenon in which a liquid is heated to a temperature higher than its boiling point, without boiling. This is a so-called '' metastable sta ...


Notes and references


External links


2005-06-22, MIT News: MIT physicists create new form of matter
Citat: "... They have become the first to create a new type of matter, a gas of atoms that shows high-temperature superfluidity."

* ttps://www.sciencedaily.com/releases/2004/01/040115074553.htm 2004-01-15, ScienceDaily: Probable Discovery Of A New, Supersolid, Phase Of MatterCitat: "...We apparently have observed, for the first time, a solid material with the characteristics of a superfluid...but because all its particles are in the identical quantum state, it remains a solid even though its component particles are continually flowing..."
2004-01-29, ScienceDaily: NIST/University Of Colorado Scientists Create New Form Of Matter: A Fermionic Condensate

Short videos demonstrating of States of Matter, solids, liquids and gases by Prof. J M Murrell, University of Sussex
{{DEFAULTSORT:State Of Matter Condensed matter physics Engineering thermodynamics