image:Inclumed.gif, 250px, Trapped in a time capsule the same size as the diameter of a human hair, the ore-forming liquid in this inclusion was so hot and contained so much dissolved solids that when it cooled, crystals of halite, sylvite, gypsum, and hematite formed. As the samples cooled, the fluid shrank more than the surrounding mineral, and created a vapor bubble. Source: USGS A fluid inclusion is a microscopic bubble of liquid and/or gas that is trapped within a crystal. As minerals often form from a liquid or aqueous medium, tiny bubbles of that liquid can become trapped within the crystal, or along healed crystal fractures. These small inclusions range in size from 0.01 mm to 1 mm and are usually only visible in detail by microscopic study. These inclusions occur in a wide variety of environments. For example, they are found within cementing minerals of sedimentary rocks, in

gangue In mining, gangue () is the commercially worthless material that surrounds, or is closely mixed with, a wanted mineral in an ore deposit. It is thus distinct from overburden, which is the waste rock or materials overlying an ore or mineral body ...

minerals such as

quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...

or calcite in

hydrothermal circulation Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...

deposits, in fossil

amber Amber is fossilized tree resin that has been appreciated for its color and natural beauty since Neolithic times. Much valued from antiquity to the present as a gemstone, amber is made into a variety of decorative objects."Amber" (2004). In ...

, and in deep

ice cores An ice core is a core sample that is typically removed from an ice sheet or a high mountain glacier. Since the ice forms from the incremental buildup of annual layers of snow, lower layers are older than upper ones, and an ice core contains ic ...

from the

Greenland Greenland ( kl, Kalaallit Nunaat, ; da, Grønland, ) is an island country in North America that is part of the Kingdom of Denmark. It is located between the Arctic and Atlantic oceans, east of the Canadian Arctic Archipelago. Greenland i ...

and Antarctic ice caps. The inclusions can provide information about the conditions existing during the formation of the enclosing mineral. Fourier transform infrared spectroscopy and Raman spectroscopy can be used to determine the composition of fluid inclusions.

Formation

Hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...

ore Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 Apr ...

minerals, which typically form from high temperature aqueous solutions, trap tiny bubbles of liquids or gases when cooling and forming solid rock. The trapped fluid in an inclusion preserves a record of the composition, temperature and pressure of the mineralizing environment. An inclusion often contains two or more phases. If a vapor bubble is present in the inclusion along with a liquid phase, simple heating of the inclusion to the point of resorption of the vapor bubble gives a likely temperature of the original fluid. If minute crystals, such as

halite Halite (), commonly known as rock salt, is a type of salt, the mineral (natural) form of sodium chloride ( Na Cl). Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, p ...

, sylvite, hematite or sulfides, are present in the inclusion, they provide direct clues as to the composition of the original fluid.

Fluid inclusions and mineral exploration

Fluid inclusions can provide useful data in mineral exploration, as their characteristics depend on the mineralization process. The methods of using fluid inclusions to identify mineral deposits include assessing the abundance of a specific inclusion type, looking into variations in the inclusions' temperatures of phase changes during heating and cooling, and variations in other properties such as

decrepitation Decrepitation is the noise produced when certain chemical compounds are heated, or it refers to the cracking, or breaking-up of lumps of limestone during heating.Oates, J.A.H. (1998) 'Lime and Limestone' Wiley-VCH pp 406. Such compounds include l ...

behavior, and inclusions chemistry. Observation and point-counting of thin-sections of samples is used to identify the occurrence of specific inclusion types. If an abundance of similar fluid inclusions are found in close geographic proximity, one can conclude that the surrounding rock types are similar if not the same. Microthermometric properties (changes in temperature during phase changes) are used to characterize and categorize areas that witnessed thermal activity during mineral formation. Fluid inclusions have been used to identify deposits of oil and gas. Drilling cuts, cores, and/or outcrop materials are preserved for their pore-fluids, and the chemistry of the fluid is analyzed with Fluid Inclusion Stratigraphy (FIS). FIS analysis takes the spectrometric reading of a fluid inclusion's volatile species; these are indicative of a natural gas or oil deposit nearby. The abundance of similar fluid inclusions could, however, be attributed to hydrocarbon migration and accumulation, so other techniques are used to confirm the presence of the oil deposit after initial detection of fluid inclusions.

Metamorphic signatures

In the recent years, fluid inclusion research has been extensively applied to understand the role of fluids in the deep crust and crust-mantle interface. Fluid inclusions trapped within

granulite Granulites are a class of high-grade metamorphic rocks of the granulite facies that have experienced high-temperature and moderate-pressure metamorphism. They are medium to coarse–grained and mainly composed of feldspars sometimes associated ...

facies rocks have provided important clues on the

petrogenesis Petrogenesis, also known as petrogeny, is a branch of petrology dealing with the origin and formation of rocks. While the word petrogenesis is most commonly used to refer to the processes that form igneous rocks, it can also include metamorphic an ...

of dry granulite facies rocks through the influx of CO₂-rich fluids from sub-lithospheric sources. CO₂-rich fluid inclusions were also recorded from a number of ultra high temperature granulite facies

terrane In geology, a terrane (; in full, a tectonostratigraphic terrane) is a crust (geology), crust fragment formed on a tectonic plate (or broken off from it) and Accretion (geology), accreted or "Suture (geology), sutured" to crust lying on another pla ...

s, suggesting the involvement of CO₂ in extreme crustal metamorphism. Some recent studies speculate that CO₂ derived by sub-solidus decarbonation reactions during extreme metamorphism has contributed to the deglaciation of the snowball Earth.

Orogenic application

Fluid inclusions trapped in veins and minerals have been used as a proxy to explore the deformation history in orogenic belts. As fluid activities are considerably more in shear zones in an orogenic belt, the fluid inclusions in a shear zone have been also used to explore the seismic activities during the evolution of the shear zone. In orogenic belts the earthquakes sometimes attributed to be linked with fluid activity at depth. Indirect geophysical evidence points out the role of fluid in earthquakes in many shear zones, however a few studies provide geological evidence for the role of fluid in earthquakes. Treesmed

Paleoclimate applications

Trapped bubbles of air and water within fossil amber can be analyzed to provide direct evidence of the climate conditions existing when the resin or tree sap formed. The analysis of these trapped air bubbles provides a record of atmosphere composition going back 140 million years. The data indicate that the oxygen content of the atmosphere reached a high of nearly 35% during the

Cretaceous The Cretaceous ( ) is a geological period that lasted from about 145 to 66 million years ago (Mya). It is the third and final period of the Mesozoic Era, as well as the longest. At around 79 million years, it is the longest geological period of ...

Period Period may refer to: Common uses * Era, a length or span of time * Full stop (or period), a punctuation mark Arts, entertainment, and media * Period (music), a concept in musical composition * Periodic sentence (or rhetorical period), a concept ...

and then plummeted to near present levels during the early

Tertiary Tertiary ( ) is a widely used but obsolete term for the geologic period from 66 million to 2.6 million years ago. The period began with the demise of the non-avian dinosaurs in the Cretaceous–Paleogene extinction event, at the start ...

. The abrupt decline corresponds to or closely follows the

Cretaceous–Paleogene extinction event The Cretaceous–Paleogene (K–Pg) extinction event (also known as the Cretaceous–Tertiary extinction) was a sudden mass extinction of three-quarters of the plant and animal species on Earth, approximately 66 million years ago. With the ...

and may be the result of a major meteorite impact that created the

Chicxulub Crater The Chicxulub crater () is an impact crater buried underneath the Yucatán Peninsula in Mexico. Its center is offshore near the community of Chicxulub, after which it is named. It was formed slightly over 66 million years ago when a large a ...

. In paleoceanography studies, fluid inclusions can inform about the chemical composition of seawater. The trapped seawater in sediments evaporates and leaves behind the salt content. The depth at which these evaporites are found relative to the composition of the trapped salt allows oceanographers to reconstruct seawater evolution.{{Citation, last1=Bąbel, first1=M., title=Geochemistry of Evaporites and Evolution of Seawater, date=2014, url=http://dx.doi.org/10.1016/b978-0-08-095975-7.00718-x, work=Treatise on Geochemistry, pages=483–560, publisher=Elsevier, access-date=, last2=Schreiber, first2=B.C., doi=10.1016/b978-0-08-095975-7.00718-x , isbn=9780080983004 Air bubbles trapped within the deep ice caps can also be analyzed for clues to ancient climate conditions.

References

External links

Fluid inclusions - USGS

Geochemistry Mineralogy Petrology