HOME

TheInfoList



OR:

Enstatite is a mineral; the magnesium endmember of the
pyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe I ...
silicate mineral series enstatite (MgSiO3) – ferrosilite (FeSiO3). The magnesium rich members of the solid solution series are common rock-forming
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...
s found in
igneous Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma or ...
and metamorphic rocks. The intermediate composition, , has historically been known as hypersthene, although this name has been formally abandoned and replaced by orthopyroxene. When determined petrographically or chemically the composition is given as relative proportions of enstatite (En) and ferrosilite (Fs) (e.g., En80Fs20).


Polymorphs and varieties

Most natural
crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macro ...
s are orthorhombic ( space group P''bca'') although three polymorphs are known. The high temperature, low pressure polymorphs are protoenstatite and protoferrosilite (also orthorhombic, space group P''bcn'') while the low temperature forms, clinoenstatite and clinoferrosilite, are
monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic ...
(space group P2''1/c'').
Weathered ''Weathered'' is the third studio album by American rock band Creed, released on November 20, 2001. It was the last Creed album to be released until '' Full Circle'' came out in October 2009, with Creed disbanding in June 2004. It is the only Cr ...
enstatite with a small amount of iron takes on a submetallic luster and a bronze-like color. This material is termed
bronzite Bronzite is a member of the pyroxene group of minerals, belonging with enstatite and hypersthene to the orthorhombic series of the group. Rather than a distinct species, it is really a ferriferous variety of enstatite, which owing to partial ...
, although it is more correctly called altered enstatite. Bronzite and hypersthene were known long before enstatite, which was first described by G. A. Kenngott in 1855. An emerald-green variety of enstatite is called chrome-enstatite and is cut as a
gemstone A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rocks (such as lapis lazuli, opal, ...
. The green color is caused by traces of
chromium Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal. Chromium metal is valued for its high corrosion resistance and hard ...
, hence the varietal name. In addition, bronzite is also sometimes used as a gemstone.


Identification

Enstatite and the other orthorhombic pyroxenes are distinguished from those of the monoclinic series by their optical characteristics, such as straight extinction, much weaker double refraction and stronger pleochroism. They also have a prismatic cleavage that is perfect in two directions at 90 degrees. Enstatite is white, gray, greenish, or brown in color; its
hardness In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion. In general, different materials differ in their hardness; for example hard ...
is 5–6 on the
Mohs scale The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. The scale was introduced in 1812 by ...
, and its
specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water at its dens ...
is 3.2–3.3. This prismatic form is used in gemstones, and for academic purposes.


Occurrence

Isolated crystals are rare, but orthopyroxene is an essential constituent of various types of
igneous rock Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma o ...
s and
metamorphic rock Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, caus ...
s. Magnesian orthopyroxene occurs in plutonic rocks such as
gabbro Gabbro () is a phaneritic (coarse-grained), mafic intrusive igneous rock formed from the slow cooling of magnesium-rich and iron-rich magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is ...
(norite) and
diorite Diorite ( ) is an intrusive igneous rock formed by the slow cooling underground of magma (molten rock) that has a moderate content of silica and a relatively low content of alkali metals. It is intermediate in composition between low-sil ...
. It may form small idiomorphic phenocrysts and also groundmass grains in volcanic rocks such as
basalt Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90 ...
,
andesite Andesite () is a volcanic rock of intermediate composition. In a general sense, it is the intermediate type between silica-poor basalt and silica-rich rhyolite. It is fine-grained (aphanitic) to porphyritic in texture, and is composed predo ...
, and
dacite Dacite () is a volcanic rock formed by rapid solidification of lava that is high in silica and low in alkali metal oxides. It has a fine-grained ( aphanitic) to porphyritic texture and is intermediate in composition between andesite and rhyo ...
. Enstatite, close to En90Fs10 in composition, is an essential mineral in typical
peridotite Peridotite ( ) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high pr ...
and
pyroxenite Pyroxenite is an ultramafic igneous rock consisting essentially of minerals of the pyroxene group, such as augite, diopside, hypersthene, bronzite or enstatite. Pyroxenites are classified into clinopyroxenites, orthopyroxenites, and the we ...
of the Earth's mantle.
Xenolith A xenolith ("foreign rock") is a rock fragment ( country rock) that becomes enveloped in a larger rock during the latter's development and solidification. In geology, the term ''xenolith'' is almost exclusively used to describe inclusions in ig ...
s of peridotite are common in kimberlite and in some basalt. Measurements of the
calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar ...
,
aluminum Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It ha ...
, and
chromium Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal. Chromium metal is valued for its high corrosion resistance and hard ...
contents of enstatite in these xenoliths have been crucial in reconstructing the depths from which the xenoliths were plucked by the ascending magmas. Orthopyroxene is an important constituent of some metamorphic rocks such as granulite. Orthopyroxene near pure enstatite in composition occurs in some metamorphosed serpentines. Large crystals, a foot in length and mostly altered to steatite, were found in 1874 in the
apatite Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of OH−, F− and Cl− ions, respectively, in the crystal. The formula of the admixture of the three most common ...
veins traversing
mica Micas ( ) are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into extremely thin elastic plates. This characteristic is described as perfect basal cleavage. Mica is ...
-
schist Schist ( ) is a medium-grained metamorphic rock showing pronounced schistosity. This means that the rock is composed of mineral grains easily seen with a low-power hand lens, oriented in such a way that the rock is easily split into thin flakes ...
and hornblende-schist at the apatite mine of Kjørstad, near Brevik in southern
Norway Norway, officially the Kingdom of Norway, is a Nordic countries, Nordic country in Northern Europe, the mainland territory of which comprises the western and northernmost portion of the Scandinavian Peninsula. The remote Arctic island of ...
. Enstatite is a common mineral in meteorites.
Crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macro ...
s have been found in stony and iron
meteorite A meteorite is a solid piece of debris from an object, such as a comet, asteroid, or meteoroid, that originates in outer space and survives its passage through the atmosphere to reach the surface of a planet or moon. When the original object ...
s, including one that fell at Breitenbach in the Ore Mountains, Bohemia. In some meteorites, together with
olivine The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers qui ...
it forms the bulk of the material; it can occur in small spherical masses, or
chondrule A chondrule (from Ancient Greek χόνδρος ''chondros'', grain) is a round grain found in a chondrite. Chondrules form as molten or partially molten droplets in space before being accreted to their parent asteroids. Because chondrites repr ...
s, with an internal radiated structure.


Enstatite in space

Enstatite is one of the few silicate minerals that have been observed in crystalline form outside the
Solar System The Solar System Capitalization of the name varies. The International Astronomical Union, the authoritative body regarding astronomical nomenclature, specifies capitalizing the names of all individual astronomical objects but uses mixed "Solar ...
, particularly around evolved stars and planetary nebulae such as NGC 6302. Enstatite is thought to be one of the early stages for the formation of crystalline silicates in space. Many correlations have been noted between the occurrence of the mineral and the structure of the object around which it has been observed. Enstatite is thought to be a main component of the E-type asteroids.H. U. Keller, et all - E-Type Asteroid (2867) Steins as Imaged by OSIRIS on Board Rosetta - Science 8 January 2010: Vol. 327. no. 5962, pp. 190 - 193
The
Hungaria asteroid The Hungaria asteroids, also known as the Hungaria group, are a dynamical group of asteroids in the asteroid belt which orbit the Sun with a semi-major axis (longest radius of an ellipse) between 1.78 and 2.00 astronomical units (AU). They are the ...
s are the main examples in the Solar System.


See also

* *


References

*Deer, W. A., Howie, R. A., and Zussman, J. (1992). '' An introduction to the rock-forming minerals (2nd ed.)''. Harlow: Longman {{Commons category Inosilicates Magnesium minerals Iron(II) minerals Pyroxene group Orthorhombic minerals Minerals in space group 61