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Electrical breakdown or dielectric breakdown is a process that occurs when an electrical insulating material, subjected to a high enough
voltage Voltage, also known as electric pressure, electric tension, or (electric) potential difference, is the difference in electric potential between two points. In a static electric field, it corresponds to the work needed per unit of charge to mo ...
, suddenly becomes an
electrical conductor In physics and electrical engineering, a conductor is an object or type of material that allows the flow of charge (electric current) in one or more directions. Materials made of metal are common electrical conductors. Electric current is gener ...
and
electric current An electric current is a stream of charged particles, such as electrons or ions, moving through an electrical conductor or space. It is measured as the net rate of flow of electric charge through a surface or into a control volume. The moving pa ...
flows through it. All insulating materials undergo breakdown when the
electric field An electric field (sometimes E-field) is the physical field that surrounds electrically charged particles and exerts force on all other charged particles in the field, either attracting or repelling them. It also refers to the physical field f ...
caused by an applied voltage exceeds the material's
dielectric strength In physics, the term dielectric strength has the following meanings: *for a pure electrically insulating material, the maximum electric field that the material can withstand under ideal conditions without undergoing electrical breakdown and becom ...
. The
voltage Voltage, also known as electric pressure, electric tension, or (electric) potential difference, is the difference in electric potential between two points. In a static electric field, it corresponds to the work needed per unit of charge to mo ...
at which a given insulating object becomes conductive is called its
breakdown voltage The breakdown voltage of an insulator is the minimum voltage that causes a portion of an insulator to experience electrical breakdown and become electrically conductive. For diodes, the breakdown voltage is the minimum reverse voltage that make ...
and in addition to its dielectric strength depends on its size and shape, and the location on the object at which the voltage is applied. Under sufficient electrical potential, electrical breakdown can occur within solids, liquids, or gases (and theoretically even in a vacuum). However, the specific breakdown mechanisms are different for each kind of
dielectric In electromagnetism, a dielectric (or dielectric medium) is an electrical insulator that can be polarised by an applied electric field. When a dielectric material is placed in an electric field, electric charges do not flow through the mater ...
medium. Electrical breakdown may be a momentary event (as in an
electrostatic discharge Electrostatic discharge (ESD) is a sudden and momentary flow of electric current between two electrically charged objects caused by contact, an electrical short or dielectric breakdown. A buildup of static electricity can be caused by tribocha ...
), or may lead to a continuous
electric arc An electric arc, or arc discharge, is an electrical breakdown of a gas that produces a prolonged electrical discharge. The current through a normally nonconductive medium such as air produces a plasma; the plasma may produce visible light. An ...
if protective devices fail to interrupt the current in a power circuit. In this case electrical breakdown can cause catastrophic failure of electrical equipment, and fire hazards.


Explanation

Electric current An electric current is a stream of charged particles, such as electrons or ions, moving through an electrical conductor or space. It is measured as the net rate of flow of electric charge through a surface or into a control volume. The moving pa ...
is a flow of electrically
charged particle In physics, a charged particle is a particle with an electric charge. It may be an ion, such as a molecule or atom with a surplus or deficit of electrons relative to protons. It can also be an electron or a proton, or another elementary particle, ...
s in a material caused by an
electric field An electric field (sometimes E-field) is the physical field that surrounds electrically charged particles and exerts force on all other charged particles in the field, either attracting or repelling them. It also refers to the physical field f ...
, usually created by a
voltage Voltage, also known as electric pressure, electric tension, or (electric) potential difference, is the difference in electric potential between two points. In a static electric field, it corresponds to the work needed per unit of charge to mo ...
difference across the material. The mobile charged particles which make up an electric current are called
charge carrier In physics, a charge carrier is a particle or quasiparticle that is free to move, carrying an electric charge, especially the particles that carry electric charges in electrical conductors. Examples are electrons, ions and holes. The term is used ...
s. In different substances different particles serve as charge carriers: in metals and some other solids some of the outer
electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no kno ...
s of each atom ( conduction electrons) are able to move about in the material; in
electrolyte An electrolyte is a medium containing ions that is electrically conducting through the movement of those ions, but not conducting electrons. This includes most soluble salts, acids, and bases dissolved in a polar solvent, such as water. Upon dis ...
s and plasma it is
ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conv ...
s, electrically charged atoms or
molecule A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bioch ...
s, and electrons that are charge carriers. A material that has a high concentration of charge carriers available for conduction, such as a
metal A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typica ...
, will conduct a large current with a given electric field, and thus has a low
electrical resistivity Electrical resistivity (also called specific electrical resistance or volume resistivity) is a fundamental property of a material that measures how strongly it resists electric current. A low resistivity indicates a material that readily allows ...
; this is called an
electrical conductor In physics and electrical engineering, a conductor is an object or type of material that allows the flow of charge (electric current) in one or more directions. Materials made of metal are common electrical conductors. Electric current is gener ...
. A material that has few charge carriers, such as glass or ceramic, will conduct very little current with a given electric field and has a high resistivity; this is called an
electrical insulator An electrical insulator is a material in which electric current does not flow freely. The atoms of the insulator have tightly bound electrons which cannot readily move. Other materials—semiconductors and conductors—conduct electric current ...
or
dielectric In electromagnetism, a dielectric (or dielectric medium) is an electrical insulator that can be polarised by an applied electric field. When a dielectric material is placed in an electric field, electric charges do not flow through the mater ...
. All matter is composed of charged particles, but the common property of insulators is that the negative charges, the orbital electrons, are tightly bound to the positive charges, the
atomic nuclei The atomic nucleus is the small, dense region consisting of protons and neutrons at the center of an atom, discovered in 1911 by Ernest Rutherford based on the 1909 Geiger–Marsden gold foil experiment. After the discovery of the neutron i ...
, and cannot easily be freed to become mobile. However, when a large enough electric field is applied to any insulating substance, at a certain field strength the number of charge carriers in the material suddenly increases by many orders of magnitude, so its resistance drops and it becomes a conductor. This is called ''electrical breakdown''. The physical mechanism causing breakdown differs in different substances. In a solid, it usually occurs when the electric field becomes strong enough to pull outer
valence electron In chemistry and physics, a valence electron is an electron in the outer shell associated with an atom, and that can participate in the formation of a chemical bond if the outer shell is not closed. In a single covalent bond, a shared pair form ...
s away from their atoms, so they become mobile, and the heat created by their collisions with other atoms releases additional electrons. In a gas, the electric field accelerates the small number of free electrons naturally present (due to processes like
photoionization Photoionization is the physical process in which an ion is formed from the interaction of a photon with an atom or molecule. Cross section Not every interaction between a photon and an atom, or molecule, will result in photoionization. The pro ...
and
radioactive decay Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consi ...
) to a high enough speed that when they collide with gas molecules they knock additional electrons out of them, called
ionization Ionization, or Ionisation is the process by which an atom or a molecule acquires a negative or positive charge by gaining or losing electrons, often in conjunction with other chemical changes. The resulting electrically charged atom or molecule ...
, which go on to ionize more molecules creating more free electrons and ions in a chain reaction called a
Townsend discharge The Townsend discharge or Townsend avalanche is a gas ionisation process where free electrons are accelerated by an electric field, collide with gas molecules, and consequently free additional electrons. Those electrons are in turn accelerated and ...
. As these examples indicate, in most materials breakdown occurs by a rapid
chain reaction A chain reaction is a sequence of reactions where a reactive product or by-product causes additional reactions to take place. In a chain reaction, positive feedback leads to a self-amplifying chain of events. Chain reactions are one way that sys ...
in which mobile charged particles release additional charged particles.


Dielectric strength and breakdown voltage

The electric field strength (in
volt The volt (symbol: V) is the unit of electric potential, electric potential difference (voltage), and electromotive force in the International System of Units (SI). It is named after the Italian physicist Alessandro Volta (1745–1827). Defin ...
s per metre) at which breakdown occurs is an
intrinsic property In science and engineering, an intrinsic property is a property of a specified subject that exists itself or within the subject. An extrinsic property is not essential or inherent to the subject that is being characterized. For example, mass ...
of the insulating material called its ''
dielectric strength In physics, the term dielectric strength has the following meanings: *for a pure electrically insulating material, the maximum electric field that the material can withstand under ideal conditions without undergoing electrical breakdown and becom ...
''. The electric field is usually caused by a
voltage Voltage, also known as electric pressure, electric tension, or (electric) potential difference, is the difference in electric potential between two points. In a static electric field, it corresponds to the work needed per unit of charge to mo ...
difference applied across the material. The applied voltage required to cause breakdown in a given insulating object is called the object's ''
breakdown voltage The breakdown voltage of an insulator is the minimum voltage that causes a portion of an insulator to experience electrical breakdown and become electrically conductive. For diodes, the breakdown voltage is the minimum reverse voltage that make ...
''. The electric field created in a given insulating object by an applied voltage varies depending on the size and shape of the object and the location on the object where the voltage is applied, so in addition to the material's dielectric strength, the breakdown voltage depends on these factors. In a flat sheet of insulator between two flat metal electrodes, the electric field E is proportional to the voltage difference V divided by the thickness D of the insulator, so in general the breakdown voltage V_\text is proportional to the dielectric strength E_\text and the length of insulation between two conductors :V_\text = D E_\text However the shape of the conductors can influence the breakdown voltage.


Breakdown process

Breakdown is a local process, and in an insulating medium subjected to a high voltage difference begins at whatever point in the insulator the electric field first exceeds the local dielectric strength of the material. Since the electric field at the surface of a conductor is highest at protruding parts, sharp points and edges, for a conductor immersed in a homogeneous insulator like air or oil, breakdown usually starts at these points. If the breakdown is caused by a local defect in a solid insulator, such as a crack or bubble in a ceramic insulator, it may remain limited to a small region; this is called ''
partial discharge In electrical engineering, partial discharge (PD) is a localized dielectric breakdown (DB) (which does not completely bridge the space between the two conductors) of a small portion of a solid or fluid electrical insulation (EI) system under hi ...
''. In a gas adjacent to a sharp pointed conductor, local breakdown processes,
corona discharge A corona discharge is an electrical discharge caused by the ionization of a fluid such as air surrounding a conductor carrying a high voltage. It represents a local region where the air (or other fluid) has undergone electrical breakdown a ...
or
brush discharge A brush discharge is an electrical disruptive discharge similar to a corona discharge that takes place at an electrode with a high voltage applied to it, embedded in a nonconducting fluid, usually air. It is characterized by multiple luminous w ...
, can allow current to leak off the conductor into the gas as ions. However, usually in a homogeneous solid insulator after one region has broken down and become conductive there is no voltage drop across it, and the full voltage difference is applied to the remaining length of the insulator. Since the voltage drop is now across a shorter length, this creates a higher electric field in the remaining material, which causes more material to break down. So the breakdown region rapidly (within microseconds) spreads in the direction of the voltage gradient from one end of the insulator to the other, until a continuous conductive path is created through the material between the two contacts applying the voltage difference, allowing a current to flow between them. Electrical breakdown can also occur without an applied voltage, due to an electromagnetic wave. When a sufficiently intense
electromagnetic wave In physics, electromagnetic radiation (EMR) consists of waves of the electromagnetic (EM) field, which propagate through space and carry momentum and electromagnetic radiant energy. It includes radio waves, microwaves, infrared, (visible) ligh ...
passes through a material medium, the electric field of the wave can be strong enough to cause temporary electrical breakdown. For example a
laser A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word "laser" is an acronym for "light amplification by stimulated emission of radiation". The firs ...
beam focused to a small spot in air can cause electrical breakdown and
ionization Ionization, or Ionisation is the process by which an atom or a molecule acquires a negative or positive charge by gaining or losing electrons, often in conjunction with other chemical changes. The resulting electrically charged atom or molecule ...
of the air at the focal point.


Consequences

In practical
electric circuit An electrical network is an interconnection of electrical components (e.g., batteries, resistors, inductors, capacitors, switches, transistors) or a model of such an interconnection, consisting of electrical elements (e.g., voltage sources, c ...
s electrical breakdown is usually an unwanted occurrence, a failure of insulating material causing a
short circuit A short circuit (sometimes abbreviated to short or s/c) is an electrical circuit that allows a current to travel along an unintended path with no or very low electrical impedance. This results in an excessive current flowing through the circuit. ...
, possibly resulting in a catastrophic failure of the equipment. In power circuits, the sudden drop in resistance causes a high current to flow through the material, beginning an
electric arc An electric arc, or arc discharge, is an electrical breakdown of a gas that produces a prolonged electrical discharge. The current through a normally nonconductive medium such as air produces a plasma; the plasma may produce visible light. An ...
, and if safety devices do not interrupt the current quickly the sudden extreme
Joule heating Joule heating, also known as resistive, resistance, or Ohmic heating, is the process by which the passage of an electric current through a conductor produces heat. Joule's first law (also just Joule's law), also known in countries of former US ...
may cause the insulating material or other parts of the circuit to melt or vaporize explosively, damaging the equipment and creating a fire hazard. However, external protective devices in the circuit such as
circuit breaker A circuit breaker is an electrical safety device designed to protect an electrical circuit from damage caused by an overcurrent or short circuit. Its basic function is to interrupt current flow to protect equipment and to prevent the risk ...
s and
current limiting Current limiting is the practice of imposing a limit on the current that may be delivered to a load to protect the circuit generating or transmitting the current from harmful effects due to a short-circuit or overload. The term "current limiting" ...
can prevent the high current; and the breakdown process itself is not necessarily destructive and may be reversible. If the current supplied by the external circuit is removed sufficiently quickly, no damage is done to the material, and reducing the applied voltage causes a transition back to the material's insulating state.
Lightning Lightning is a naturally occurring electrostatic discharge during which two electrically charged regions, both in the atmosphere or with one on the ground, temporarily neutralize themselves, causing the instantaneous release of an average ...
and sparks due to
static electricity Static electricity is an imbalance of electric charges within or on the surface of a material or between materials. The charge remains until it is able to move away by means of an electric current or electrical discharge. Static electricity is na ...
are natural examples of the electrical breakdown of air. Electrical breakdown is part of the normal operating mode of a number of
electrical component An electronic component is any basic discrete device or physical entity in an electronic system used to affect electrons or their associated fields. Electronic components are mostly industrial products, available in a singular form and are not ...
s, such as
gas discharge lamp Gas-discharge lamps are a family of artificial light sources that generate light by sending an electric discharge through an ionized gas, a plasma. Typically, such lamps use a noble gas (argon, neon, krypton, and xenon) or a mixture of these ...
s like
fluorescent light A fluorescent lamp, or fluorescent tube, is a low-pressure mercury-vapor gas-discharge lamp that uses fluorescence to produce visible light. An electric current in the gas excites mercury vapor, which produces short-wave ultraviolet ligh ...
s, and
neon light Neon lighting consists of brightly glowing, electrified glass tubes or bulbs that contain rarefied neon or other gases. Neon lights are a type of cold cathode gas-discharge light. A neon tube is a sealed glass tube with a metal electrode a ...
s,
zener diode A Zener diode is a special type of diode designed to reliably allow current to flow "backwards" (inverted polarity) when a certain set reverse voltage, known as the ''Zener voltage'', is reached. Zener diodes are manufactured with a great var ...
s,
avalanche diode In electronics, an avalanche diode is a diode (made from silicon or other semiconductor) that is designed to experience avalanche breakdown at a specified reverse bias voltage. The junction of an avalanche diode is designed to prevent current con ...
s,
IMPATT diode An IMPATT diode (impact ionization avalanche transit-time diode) is a form of high-power semiconductor diode used in high-frequency microwave electronics devices. They have negative resistance and are used as oscillators and amplifiers at microwave ...
s, mercury-vapor rectifiers,
thyratron A thyratron is a type of gas-filled tube used as a high-power electrical switch and controlled rectifier. Thyratrons can handle much greater currents than similar hard-vacuum tubes. Electron multiplication occurs when the gas becomes ionized, pr ...
,
ignitron An ignitron is a type of gas-filled tube used as a controlled rectifier and dating from the 1930s. Invented by Joseph Slepian while employed by Westinghouse, Westinghouse was the original manufacturer and owned trademark rights to the name "Ignit ...
, and
krytron The krytron is a cold-cathode gas-filled tube intended for use as a very high-speed switch, somewhat similar to the thyratron. It consists of a sealed glass tube with four electrodes. A small triggering pulse on the grid electrode switches the tu ...
tubes, and
spark plug A spark plug (sometimes, in British English, a sparking plug, and, colloquially, a plug) is a device for delivering electric current from an ignition system to the combustion chamber of a spark-ignition engine to ignite the compressed fuel/air ...
s.


Failure of electrical insulation

Electrical breakdown is often associated with the failure of solid or liquid insulating materials used inside high voltage
transformer A transformer is a passive component that transfers electrical energy from one electrical circuit to another circuit, or multiple circuits. A varying current in any coil of the transformer produces a varying magnetic flux in the transformer's ...
s or
capacitors A capacitor is a device that stores electrical energy in an electric field by virtue of accumulating electric charges on two close surfaces insulated from each other. It is a passive electronic component with two terminals. The effect of a c ...
in the
electricity distribution Electric power distribution is the final stage in the delivery of electric power; it carries electricity from the transmission system to individual consumers. Distribution substations connect to the transmission system and lower the transmissio ...
grid, usually resulting in a
short circuit A short circuit (sometimes abbreviated to short or s/c) is an electrical circuit that allows a current to travel along an unintended path with no or very low electrical impedance. This results in an excessive current flowing through the circuit. ...
or a blown fuse. Electrical breakdown can also occur across the insulators that suspend overhead
power line An overhead power line is a structure used in electric power transmission and distribution to transmit electrical energy across large distances. It consists of one or more uninsulated electrical cables (commonly multiples of three for three-p ...
s, within underground power cables, or lines arcing to nearby branches of trees. Dielectric breakdown is also important in the design of
integrated circuit An integrated circuit or monolithic integrated circuit (also referred to as an IC, a chip, or a microchip) is a set of electronic circuits on one small flat piece (or "chip") of semiconductor material, usually silicon. Large numbers of tiny M ...
s and other solid state electronic devices. Insulating layers in such devices are designed to withstand normal operating voltages, but higher voltage such as from static electricity may destroy these layers, rendering a device useless. The dielectric strength of
capacitor A capacitor is a device that stores electrical energy in an electric field by virtue of accumulating electric charges on two close surfaces insulated from each other. It is a passivity (engineering), passive electronic component with two termi ...
s limits how much energy can be stored and the safe working voltage for the device.


Mechanism

Breakdown mechanisms differ in solids, liquids, and gases. Breakdown is influenced by electrode material, sharp curvature of conductor material (resulting in locally intensified electric fields), the size of the gap between the electrodes, and the density of the material in the gap.


Solids

In solid materials (such as in
power cable A power cable is an electrical cable, an assembly of one or more electrical conductors, usually held together with an overall sheath. The assembly is used for transmission of electrical power. Power cables may be installed as permanent wiring w ...
s) a long-time
partial discharge In electrical engineering, partial discharge (PD) is a localized dielectric breakdown (DB) (which does not completely bridge the space between the two conductors) of a small portion of a solid or fluid electrical insulation (EI) system under hi ...
typically precedes breakdown, degrading the insulators and metals nearest to the voltage gap. Ultimately the partial discharge chars through a channel of carbonized material that conducts current across the gap.


Liquids

Possible mechanisms for breakdown in liquids include bubbles, small impurities, and electrical super-heating. The process of breakdown in liquids is complicated by hydrodynamic effects, since additional pressure is exerted on the fluid by the non-linear electrical field strength in the gap between the electrodes. In liquefied gases used as
coolant A coolant is a substance, typically liquid, that is used to reduce or regulate the temperature of a system. An ideal coolant has high thermal capacity, low viscosity, is low-cost, non-toxic, chemically inert and neither causes nor promotes corrosio ...
s for
superconductivity Superconductivity is a set of physical properties observed in certain materials where electrical resistance vanishes and magnetic flux fields are expelled from the material. Any material exhibiting these properties is a superconductor. Unlike ...
– such as Helium at 4.2  K or Nitrogen at 77 K – bubbles can induce breakdown. In oil-cooled and oil-insulated transformers the field strength for breakdown is about 20 kV/mm (as compared to 3 kV/mm for dry air). Despite the purified oils used, small particle contaminants are blamed.


Gases

Electrical breakdown occurs within a gas when the
dielectric strength In physics, the term dielectric strength has the following meanings: *for a pure electrically insulating material, the maximum electric field that the material can withstand under ideal conditions without undergoing electrical breakdown and becom ...
of the gas is exceeded. Regions of intense voltage gradients can cause nearby gas to partially ionize and begin conducting. This is done deliberately in low pressure discharges such as in
fluorescent light A fluorescent lamp, or fluorescent tube, is a low-pressure mercury-vapor gas-discharge lamp that uses fluorescence to produce visible light. An electric current in the gas excites mercury vapor, which produces short-wave ultraviolet ligh ...
s. The voltage that leads to electrical breakdown of a gas is approximated by
Paschen's Law Paschen's law is an equation that gives the breakdown voltage, that is, the voltage necessary to start a discharge or electric arc, between two electrodes in a gas as a function of pressure and gap length. It is named after Friedrich Paschen who ...
. Partial discharge in air causes the "fresh air" smell of
ozone Ozone (), or trioxygen, is an inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , breaking down in the lowe ...
during thunderstorms or around high-voltage equipment. Although air is normally an excellent insulator, when stressed by a sufficiently high voltage (an
electric field An electric field (sometimes E-field) is the physical field that surrounds electrically charged particles and exerts force on all other charged particles in the field, either attracting or repelling them. It also refers to the physical field f ...
of about 3 x 106  V/m or 3 kV/mm), air can begin to break down, becoming partially conductive. Across relatively small gaps, breakdown voltage in air is a function of gap length times pressure. If the voltage is sufficiently high, complete electrical breakdown of the air will culminate in an
electrical spark An electric spark is an abrupt electrical discharge that occurs when a sufficiently high electric field creates an Ionization, ionized, Electric current, electrically conductive channel through a normally-insulating medium, often air or other ga ...
or an
electric arc An electric arc, or arc discharge, is an electrical breakdown of a gas that produces a prolonged electrical discharge. The current through a normally nonconductive medium such as air produces a plasma; the plasma may produce visible light. An ...
that bridges the entire gap. The color of the spark depends upon the gases that make up the gaseous media. While the small sparks generated by
static electricity Static electricity is an imbalance of electric charges within or on the surface of a material or between materials. The charge remains until it is able to move away by means of an electric current or electrical discharge. Static electricity is na ...
may barely be audible, larger sparks are often accompanied by a loud snap or bang.
Lightning Lightning is a naturally occurring electrostatic discharge during which two electrically charged regions, both in the atmosphere or with one on the ground, temporarily neutralize themselves, causing the instantaneous release of an average ...
is an example of an immense spark that can be many miles long.


Persistent arcs

If a fuse or
circuit breaker A circuit breaker is an electrical safety device designed to protect an electrical circuit from damage caused by an overcurrent or short circuit. Its basic function is to interrupt current flow to protect equipment and to prevent the risk ...
fails to interrupt the current through a spark in a power circuit, current may continue, forming a very hot
electric arc An electric arc, or arc discharge, is an electrical breakdown of a gas that produces a prolonged electrical discharge. The current through a normally nonconductive medium such as air produces a plasma; the plasma may produce visible light. An ...
(about 30 000 degrees  C). The color of an arc depends primarily upon the conducting gasses, some of which may have been solids before being vaporized and mixed into the hot plasma in the arc. The free ions in and around the arc recombine to create new chemical compounds, such as
ozone Ozone (), or trioxygen, is an inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , breaking down in the lowe ...
,
carbon monoxide Carbon monoxide (chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simpl ...
, and
nitrous oxide Nitrous oxide (dinitrogen oxide or dinitrogen monoxide), commonly known as laughing gas, nitrous, or nos, is a chemical compound, an oxide of nitrogen with the formula . At room temperature, it is a colourless non-flammable gas, and has a ...
. Ozone is most easily noticed due to its distinct odour. Although sparks and arcs are usually undesirable, they can be useful in applications such as spark plugs for gasoline engines, electrical
welding Welding is a fabrication process that joins materials, usually metals or thermoplastics, by using high heat to melt the parts together and allowing them to cool, causing fusion. Welding is distinct from lower temperature techniques such as bra ...
of metals, or for metal melting in an
electric arc furnace An electric arc furnace (EAF) is a furnace that heats material by means of an electric arc. Industrial arc furnaces range in size from small units of approximately one-tonne capacity (used in foundries for producing cast iron products) up to a ...
. Prior to gas discharge the gas glows with distinct colors that depend on the
energy levels A quantum mechanical system or particle that is bound—that is, confined spatially—can only take on certain discrete values of energy, called energy levels. This contrasts with classical particles, which can have any amount of energy. The t ...
of the atoms. Not all mechanisms are fully understood. The
vacuum A vacuum is a space devoid of matter. The word is derived from the Latin adjective ''vacuus'' for "vacant" or "void". An approximation to such vacuum is a region with a gaseous pressure much less than atmospheric pressure. Physicists often dis ...
itself is expected to undergo electrical breakdown at or near the
Schwinger limit In quantum electrodynamics (QED), the Schwinger limit is a scale above which the electromagnetic field is expected to become nonlinear. The limit was first derived in one of QED's earliest theoretical successes by Fritz Sauter in 1931 and discu ...
.


Voltage-current relation

Before gas breakdown, there is a non-linear relation between voltage and current as shown in the figure. In region 1, there are free ions that can be accelerated by the field and induce a current. These will be saturated after a certain voltage and give a constant current, region 2. Region 3 and 4 are caused by ion avalanche as explained by the
Townsend discharge The Townsend discharge or Townsend avalanche is a gas ionisation process where free electrons are accelerated by an electric field, collide with gas molecules, and consequently free additional electrons. Those electrons are in turn accelerated and ...
mechanism.
Friedrich Paschen Louis Carl Heinrich Friedrich Paschen (22 January 1865 - 25 February 1947), was a German physicist, known for his work on electrical discharges. He is also known for the Paschen series, a series of hydrogen spectral lines in the infrared region ...
established the relation between the breakdown condition to breakdown voltage. He derived a formula that defines the breakdown voltage (V_\text) for uniform field gaps as a function of gap length (d) and gap pressure (p). : V_\text = Paschen also derived a relation between the minimum value of pressure gap for which breakdown occurs with a minimum voltage. : \begin (pd)_\min &= \ln\left(1 + \frac\right) \\ V_ &= 2.718 \ln\left(1 + \frac\right) \end A and B are constants depending on the gas used.


Corona breakdown

Partial breakdown of the air occurs as a
corona discharge A corona discharge is an electrical discharge caused by the ionization of a fluid such as air surrounding a conductor carrying a high voltage. It represents a local region where the air (or other fluid) has undergone electrical breakdown a ...
on high voltage conductors at points with the highest electrical stress. Conductors that have sharp points, or balls with small
radii In classical geometry, a radius ( : radii) of a circle or sphere is any of the line segments from its center to its perimeter, and in more modern usage, it is also their length. The name comes from the latin ''radius'', meaning ray but also the ...
, are prone to causing dielectric breakdown, because the field strength around points is higher than that around a flat surface. High-voltage apparatus is designed with rounded curves and grading rings to avoid concentrated fields that precipitate breakdown.


Appearance

Corona is sometimes seen as a bluish glow around high voltage wires and heard as a sizzling sound along high voltage power lines. Corona also generates radio frequency noise that can also be heard as ‘static’ or buzzing on radio receivers. Corona can also occur naturally as "
St. Elmo's Fire St. Elmo's fire — also called Witchfire or Witch's Fire — is a weather phenomenon in which luminous plasma is created by a corona discharge from a rod-like object such as a mast, spire, chimney, or animal hornHeidorn, K., Weather Elemen ...
" at high points such as church spires, treetops, or ship masts during thunderstorms.


Ozone generation

Corona discharge ozone generators have been used for more than 30 years in the
water purification Water purification is the process of removing undesirable chemicals, biological contaminants, suspended solids, and gases from water. The goal is to produce water that is fit for specific purposes. Most water is purified and disinfected for hu ...
process. Ozone is a toxic gas, even more potent than chlorine. In a typical drinking water treatment plant, the ozone gas is dissolved into the filtered water to kill bacteria and destroy
virus A virus is a submicroscopic infectious agent that replicates only inside the living cells of an organism. Viruses infect all life forms, from animals and plants to microorganisms, including bacteria and archaea. Since Dmitri Ivanovsky's ...
es. Ozone also removes the bad odours and taste from the water. The main advantage of ozone is that any residual overdose decomposes to gaseous oxygen well before the water reaches the consumer. This is in contrast with
chlorine Chlorine is a chemical element with the symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is ...
gas or chlorine salts, which stay in the water longer and can be tasted by the consumer.


Other uses

Although corona discharge is usually undesirable, until recently it was essential in the operation of photocopiers (
xerography Xerography is a dry photocopying technique. Originally called electrophotography, it was renamed xerography—from the roots el, ξηρός, label=none ''xeros'', meaning "dry" and -γραφία ''-graphia'', meaning "writing"—to emphasiz ...
) and
laser printers Laser printing is an electrostatic digital printing process. It produces high-quality text and graphics (and moderate-quality photographs) by repeatedly passing a laser beam back and forth over a negatively-charged cylinder called a "drum" to ...
. Many modern copiers and laser printers now charge the photoconductor drum with an electrically conductive roller, reducing undesirable indoor
ozone Ozone (), or trioxygen, is an inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , breaking down in the lowe ...
pollution.
Lightning rod A lightning rod or lightning conductor (British English) is a metal rod mounted on a structure and intended to protect the structure from a lightning strike. If lightning hits the structure, it will preferentially strike the rod and be conducte ...
s use corona discharge to create conductive paths in the air that point towards the rod, deflecting potentially-damaging
lightning Lightning is a naturally occurring electrostatic discharge during which two electrically charged regions, both in the atmosphere or with one on the ground, temporarily neutralize themselves, causing the instantaneous release of an average ...
away from buildings and other structures. Corona discharges are also used to modify the surface properties of many
polymers A polymer (; Greek '' poly-'', "many" + '' -mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic and ...
. An example is the corona treatment of plastic materials which allows paint or ink to adhere properly.


Disruptive devices

A disruptive device is designed to electrically overstress a
dielectric In electromagnetism, a dielectric (or dielectric medium) is an electrical insulator that can be polarised by an applied electric field. When a dielectric material is placed in an electric field, electric charges do not flow through the mater ...
beyond its
dielectric strength In physics, the term dielectric strength has the following meanings: *for a pure electrically insulating material, the maximum electric field that the material can withstand under ideal conditions without undergoing electrical breakdown and becom ...
so as to intentionally cause electrical breakdown of the device. The disruption causes a sudden transition of a portion of the dielectric, from an insulating state to a highly
conductive In physics and electrical engineering, a conductor is an object or type of material that allows the flow of charge (electric current) in one or more directions. Materials made of metal are common electrical conductors. Electric current is gener ...
state. This transition is characterized by the formation of an
electric spark An electric spark is an abrupt electrical discharge that occurs when a sufficiently high electric field creates an ionized, electrically conductive channel through a normally-insulating medium, often air or other gases or gas mixtures. Michael ...
or plasma channel, possibly followed by an
electric arc An electric arc, or arc discharge, is an electrical breakdown of a gas that produces a prolonged electrical discharge. The current through a normally nonconductive medium such as air produces a plasma; the plasma may produce visible light. An ...
through part of the dielectric material. If the dielectric happens to be a solid, permanent physical and chemical changes along the path of the discharge will significantly reduce the material's dielectric strength, and the device can only be used one time. However, if the dielectric material is a liquid or gas, the dielectric can fully recover its insulating properties once current through the plasma channel has been externally interrupted. Commercial
spark gap A spark gap consists of an arrangement of two conducting electrodes separated by a gap usually filled with a gas such as air, designed to allow an electric spark to pass between the conductors. When the potential difference between the conductor ...
s use this property to abruptly switch high voltages in
pulsed power Pulsed power is the science and technology of accumulating energy over a relatively long period of time and releasing it instantly, thus increasing the instantaneous power. They can be used in some applications such as food processing, water treatme ...
systems, to provide
surge Surge means a sudden transient rush or flood, and may refer to: Science * Storm surge, the onshore gush of water associated with a low-pressure weather system * Surge (glacier), a short-lived event where a glacier can move up to velocities 100 ...
protection for
telecommunication Telecommunication is the transmission of information by various types of technologies over wire, radio, optical, or other electromagnetic systems. It has its origin in the desire of humans for communication over a distance greater than that fe ...
and
electrical power Electric power is the rate at which electrical energy is transferred by an electric circuit. The SI unit of power is the watt, one joule per second. Standard prefixes apply to watts as with other SI units: thousands, millions and billions of ...
systems, and ignite fuel via
spark plug A spark plug (sometimes, in British English, a sparking plug, and, colloquially, a plug) is a device for delivering electric current from an ignition system to the combustion chamber of a spark-ignition engine to ignite the compressed fuel/air ...
s in
internal combustion engine An internal combustion engine (ICE or IC engine) is a heat engine in which the combustion of a fuel occurs with an oxidizer (usually air) in a combustion chamber that is an integral part of the working fluid flow circuit. In an internal combust ...
s.
Spark-gap transmitter A spark-gap transmitter is an obsolete type of radio transmitter which generates radio waves by means of an electric spark."Radio Transmitters, Early" in Spark-gap transmitters were the first type of radio transmitter, and were the main type used ...
s were used in early radio telegraph systems.


See also

*
Comparative Tracking Index The Comparative Tracking Index (CTI) is used to measure the electrical breakdown (tracking) properties of an insulating material. Tracking is an electrical breakdown on the ''surface'' of an insulating material wherein an initial exposure to elect ...


References

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