Cryolite ( Na₃ Al F₆,

sodium hexafluoroaluminate Sodium aluminium hexafluoride is an inorganic compound with formula Na3 Al F6. This white solid, discovered in 1799 by Peder Christian Abildgaard (1740–1801), occurs naturally as the mineral cryolite and is used extensively in the industrial pr ...

) is an uncommon

mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...

identified with the once-large deposit at Ivittuut on the west coast of

Greenland Greenland ( kl, Kalaallit Nunaat, ; da, Grønland, ) is an island country in North America that is part of the Kingdom of Denmark. It is located between the Arctic and Atlantic oceans, east of the Canadian Arctic Archipelago. Greenland ...

, mined commercially until 1987.

History

Cryolite was first described in 1798 by Danish veterinarian and physician Peder Christian Abildgaard (1740–1801); it was obtained from a deposit of it in Ivigtut (old spelling) and nearby Arsuk Fjord, Southwest Greenland. The name is derived from the

Greek language Greek ( el, label= Modern Greek, Ελληνικά, Elliniká, ; grc, Ἑλληνική, Hellēnikḗ) is an independent branch of the Indo-European family of languages, native to Greece, Cyprus, southern Italy ( Calabria and Salento), souther ...

words ''κρύος'' (cryos) = frost, and ''λίθος'' (lithos) = stone. The

Pennsylvania Salt Manufacturing Company Arkema S.A. is a publicly listed, multi-national manufacturer of specialty materials, headquartered in Colombes, near Paris, France. It has three specialty materials segments (or divisions); adhesives, advanced materials and coatings. A further ...

used large amounts of cryolite to make

caustic soda Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations and hydroxide anions . Sodium hydroxide is a highly caustic base and alkali ...

and

fluorine Fluorine is a chemical element with the symbol F and atomic number 9. It is the lightest halogen and exists at standard conditions as a highly toxic, pale yellow diatomic gas. As the most electronegative reactive element, it is extremely reactiv ...

compounds, including

hydrofluoric acid Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colourless, acidic and highly corrosive. It is used to make most fluorine-containing compounds; examples include the commonly used pharmaceutical antidepres ...

at its

Natrona, Pennsylvania Natrona is an unincorporated community in Harrison Township, Allegheny County in the U.S. state of Pennsylvania. It is located in western Pennsylvania within the Pittsburgh Metropolitan Statistical Area, approximately northeast of Downtown Pit ...

works, and at its integrated chemical plant in

Cornwells Heights, Pennsylvania Cornwells Heights is a census-designated place located in Bensalem Township in Bucks County, Pennsylvania, United States. The community was formerly part of Cornwells Heights-Eddington, but was split into two separate CDPs. As of the 2010 cen ...

, during the 19th and 20th centuries. It was historically used as an ore of aluminium and later in the electrolytic processing of the

aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It ha ...

-rich oxide ore

bauxite Bauxite is a sedimentary rock with a relatively high aluminium content. It is the world's main source of aluminium and gallium. Bauxite consists mostly of the aluminium minerals gibbsite (Al(OH)3), boehmite (γ-AlO(OH)) and diaspore (α-AlO ...

(itself a combination of aluminium oxide minerals such as

gibbsite Gibbsite, Al(OH)3, is one of the mineral forms of aluminium hydroxide. It is often designated as γ-Al(OH)3 (but sometimes as α-Al(OH)3.). It is also sometimes called hydrargillite (or hydrargyllite). Gibbsite is an important ore of aluminiu ...

boehmite Boehmite or böhmite is an aluminium oxide hydroxide (γ-AlO(OH)) mineral, a component of the aluminium ore bauxite. It is dimorphous with diaspore. It crystallizes in the orthorhombic dipyramidal system and is typically massive in habit. It is ...

and

diaspore Diaspore , also known as diasporite, empholite, kayserite, or tanatarite, is an aluminium oxide hydroxide mineral, α-AlO(OH), crystallizing in the orthorhombic system and isomorphous with goethite. It occurs sometimes as flattened crystals, but ...

). The difficulty of separating aluminium from oxygen in the oxide ores was overcome by the use of cryolite as a

flux Flux describes any effect that appears to pass or travel (whether it actually moves or not) through a surface or substance. Flux is a concept in applied mathematics and vector calculus which has many applications to physics. For transport ...

to dissolve the oxide mineral(s). Pure cryolite itself melts at 1012 °C (1285 K), and it can dissolve the aluminium oxides sufficiently well to allow easy extraction of the aluminium by

electrolysis In chemistry and manufacturing, electrolysis is a technique that uses direct electric current (DC) to drive an otherwise non-spontaneous chemical reaction. Electrolysis is commercially important as a stage in the separation of elements from n ...

. Substantial energy is still needed for both heating the materials and the electrolysis, but it is much more energy-efficient than melting the oxides themselves. As natural cryolite is now too rare to be used for this purpose, synthetic sodium aluminium fluoride is produced from the common mineral

fluorite Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs sca ...

Source locations

Besides Ivittuut, on the west coast of

where cryolite was once found in commercial quantities, small deposits of cryolite have also been reported in some areas of

Spain , image_flag = Bandera de España.svg , image_coat = Escudo de España (mazonado).svg , national_motto = '' Plus ultra'' (Latin)(English: "Further Beyond") , national_anthem = (English: "Royal March") , ...

, at the foot of

Pikes Peak Pikes Peak is the highest summit of the southern Front Range of the Rocky Mountains, in North America. The ultra-prominent fourteener is located in Pike National Forest, west of downtown Colorado Springs, Colorado. The town of Manitou S ...

Colorado Colorado (, other variants) is a state in the Mountain West subregion of the Western United States. It encompasses most of the Southern Rocky Mountains, as well as the northeastern portion of the Colorado Plateau and the western edge of the ...

, Francon Quarry near

Montreal Montreal ( ; officially Montréal, ) is the second-most populous city in Canada and most populous city in the Canadian province of Quebec. Founded in 1642 as '' Ville-Marie'', or "City of Mary", it is named after Mount Royal, the triple- ...

Quebec Quebec ( ; )According to the Canadian government, ''Québec'' (with the acute accent) is the official name in Canadian French and ''Quebec'' (without the accent) is the province's official name in Canadian English is one of the thirte ...

Canada Canada is a country in North America. Its ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, covering over , making it the world's second-largest country by to ...

and also in Miask,

Russia Russia (, , ), or the Russian Federation, is a transcontinental country spanning Eastern Europe and Northern Asia. It is the largest country in the world, with its internationally recognised territory covering , and encompassing one-ei ...

Uses

Molten cryolite is used as a solvent for aluminium oxide (Al₂O₃) in the

Hall–Héroult process The Hall–Héroult process is the major industrial process for smelting aluminium. It involves dissolving aluminium oxide (alumina) (obtained most often from bauxite, aluminium's chief ore, through the Bayer process) in molten cryolite, and el ...

, used in the refining of

. It decreases the melting point of aluminium oxide from 2000 to 2500 °C to 900–1000 °C, and increases its conductivity thus making the extraction of aluminium more economical. Cryolite is used as an

insecticide Insecticides are substances used to kill insects. They include ovicides and larvicides used against insect eggs and larvae, respectively. Insecticides are used in agriculture, medicine, industry and by consumers. Insecticides are claimed t ...

and a

pesticide Pesticides are substances that are meant to control pests. This includes herbicide, insecticide, nematicide, molluscicide, piscicide, avicide, rodenticide, bactericide, insect repellent, animal repellent, microbicide, fungicide, and ...

. It is also used to give

firework Fireworks are a class of low explosive pyrotechnic devices used for aesthetic and entertainment purposes. They are most commonly used in fireworks displays (also called a fireworks show or pyrotechnics), combining a large number of devices in ...

s a yellow color.

Physical properties

Cryolite occurs as glassy, colorless, white-reddish to gray-black prismatic

monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic ...

crystals. It has a

Mohs hardness The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. The scale was introduced in 1812 by ...

of 2.5 to 3 and a

specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water at its dens ...

of about 2.95 to 3.0. It is translucent to transparent with a very low

refractive index In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium. The refractive index determines how much the path of light is bent, ...

of about 1.34, which is very close to that of

water Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as ...

; thus if immersed in water, cryolite becomes essentially invisible.

References

''Phase transitions and volumetric properties of cryolite, Na₃AlF₆: Differential thermal analysis to 100 MPa;'' American Mineralogist; January 2006; v. 91; no. 1; p. 97-103
{{Authority control Aluminium minerals History of Greenland Natural history of Greenland Pyrotechnic colorants Sodium minerals Monoclinic minerals Minerals in space group 14 Fluorine minerals Inorganic insecticides Pesticides