cone-in-cone structures
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Cone-in-cone structures are secondary
sedimentary structures Sedimentary structures include all kinds of features in sediments and sedimentary rocks, formed at the time of deposition. Sediments and sedimentary rocks are characterized by bedding, which occurs when layers of sediment, with different particl ...
that form in association with deeper burial and
diagenesis Diagenesis () is the process that describes physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a ...
. They consist of concentric inter-bedded cones of calcite or more rarely
gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywal ...
,
siderite Siderite is a mineral composed of iron(II) carbonate (FeCO3). It takes its name from the Greek word σίδηρος ''sideros,'' "iron". It is a valuable iron mineral, since it is 48% iron and contains no sulfur or phosphorus. Zinc, magnesium and ...
or
pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue giv ...
. Although several mechanisms may be responsible for the formation of cone-in-cone structures, displacive crystal mechanism is preferred. It accounts for the most uniform and consistent explanation of growth and why cone-in-cone can occur with such variable composition.


Description

Cone-in-cone structures are identifiable by their distinctive conical appearance. They are composed of concentric cones nested inside each other. The actual composition of the cones is variable and dependent on the environment in which they were formed, with the majority of the cone-in-cone structures being composed of calcite with thin layers of clay between cones. There are also, more rarely, structures composed of
siderite Siderite is a mineral composed of iron(II) carbonate (FeCO3). It takes its name from the Greek word σίδηρος ''sideros,'' "iron". It is a valuable iron mineral, since it is 48% iron and contains no sulfur or phosphorus. Zinc, magnesium and ...
,
gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywal ...
,
pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue giv ...
. Often the cone-in-cone will be found as features of calcite layers within a shale,Carstens, H. 1985. Early diagenetic cone-in-cone-structures in pyrite concretions. Journal of Sedimentary Petrology. Volume 55. Pg 105-108. and rarely within a dedolomite (calcitized
dolomite Dolomite may refer to: *Dolomite (mineral), a carbonate mineral *Dolomite (rock), also known as dolostone, a sedimentary carbonate rock *Dolomite, Alabama, United States, an unincorporated community *Dolomite, California, United States, an unincor ...
). Cone-in-cone structures should not be confused with either
shatter cone Shatter cones are rare geological features that are only known to form in the bedrock beneath meteorite impact craters or underground nuclear explosions. They are evidence that the rock has been subjected to a shock with pressures in the rang ...
s such as are produced by meteorite impacts, or with shear cones like those developed in coals. Both these structures differ from cone-in-cone structures in that they are the product of very high instantaneous stresses. Thus they have a spatial dependence on impact areas for the former and fault zones for the latter, whereas cone-in-cone structures do not.Selles-Martinez, J. (1994) New insights in the origin of cone-in-cone structures. Carbonates Evaporites 9, 172–186


Formation

The formation of cone-in-cone structures has been attributed to: #Volume increase inversion from
aragonite Aragonite is a carbonate mineral, one of the three most common naturally occurring crystal forms of calcium carbonate, (the other forms being the minerals calcite and vaterite). It is formed by biological and physical processes, including pre ...
to calcite in which expansion of conical aragonite pushed cones apart and allowed for clay to intrude # Burial-induced pressure solution and clay layers remaining as insoluble residues # Fracturing of crystalline mineral composites that form in over-pressured chambers, with fractures forming from a decrease in pore pressure # Formation during early diagenesis by expansive mineral growth (force of crystal growth), in which the cones are produced by the growth of cone-shaped aggregates of fibrous calcite, the clay layers originate as the crystals displace and disturb the original clay-rich sediment. # Gillman and MetzgerGillman, R.A., Metzger, W.J.. 1967. Cone-in-cone concretions from western New York. Journal of Sedimentary Petrology. Volume 37. Pg 87-95 proposed that their cone-in-cone structures were formed as a result that as fibrous aragonite grew, it displaced the still plastic clay materials. This is very similar to the displacive crystal growth mechanism proposed above in point number four. The displacive crystal growth mechanism tends to be the more popular and widely used explanation for cone-in-cone formation. In all cases the common trend is for crystal formation to begin within partially consolidated sediment. As cone-in-cone formation happens it begins to take up more and more space within the sediment bed which begins to cause pressure. The pressure results in the cone shape, as parts of the structure are under greater or lesser pressures and grow differentially based on these varying pressures. The nature of displacement from crystal growth has led many to believe that most of the actual precipitation occurs very early during shallow burial. Some have concluded that, based upon 18O depleted values from some of the cone-in-cone material that they can form later, perhaps at hundreds of meters of burial depth.


History

Cone-in-cone structures have been known since the late 1700s, and people have attempted to explain the reasons for their formations. One of the earlier explanations was actually on par with the currently accepted methods for formation as discussed above. Some of the other methods offered for their formation were given by Shaub (1937). It was suggested that the formation of cone-in-cone resulted from volume shrinkage and slow dewatering of highly saturated and loosely packed materials. He suggests that partially developed conical surfaces are also possible as a result of pressure developed from overlying sediments under conditions where a unilateral release of horizontal pressure may become effective. He goes on to suggest that the current explanations of his time are inadequate to cover the structure and its formation. He even suggested that formation due to crystallization was not consistent.Shaub, B.M. (1937) Origin of Cone-In-Cone and its Bearing on the Origin of Concretions and Septaria. American Journal of Science. Pg 331-344. This growth due to crystallization is a significant portion of the currently accepted mode of formation.


References

{{reflist, 30em Sedimentary structures