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In the study of past climates (" paleoclimatology"), climate proxies are preserved physical characteristics of the past that stand in for direct meteorological measurements and enable scientists to reconstruct the climatic conditions over a longer fraction of the Earth's history. Reliable global records of climate only began in the 1880s, and proxies provide the only means for scientists to determine climatic patterns before record-keeping began. A large number of climate proxies have been studied from a variety of geologic contexts. Examples of proxies include stable isotope measurements from
ice core An ice core is a core sample that is typically removed from an ice sheet or a high mountain glacier. Since the ice forms from the incremental buildup of annual layers of snow, lower layers are older than upper ones, and an ice core contains i ...
s, growth rates in
tree rings Dendrochronology (or tree-ring dating) is the scientific method of dating tree rings (also called growth rings) to the exact year they were formed. As well as dating them, this can give data for dendroclimatology, the study of climate and atmo ...
, species composition of sub-fossil pollen in lake sediment or
foraminifera Foraminifera (; Latin for "hole bearers"; informally called "forams") are single-celled organisms, members of a phylum or class of amoeboid protists characterized by streaming granular ectoplasm for catching food and other uses; and commonly a ...
in ocean sediments, temperature profiles of
borehole A borehole is a narrow shaft bored in the ground, either vertically or horizontally. A borehole may be constructed for many different purposes, including the extraction of water ( drilled water well and tube well), other liquids (such as pet ...
s, and stable isotopes and mineralogy of
coral Corals are marine invertebrates within the class Anthozoa of the phylum Cnidaria. They typically form compact colonies of many identical individual polyps. Coral species include the important reef builders that inhabit tropical oceans and ...
s and carbonate
speleothems A speleothem (; ) is a geological formation by mineral deposits that accumulate over time in natural caves. Speleothems most commonly form in calcareous caves due to carbonate dissolution reactions. They can take a variety of forms, depending o ...
. In each case, the proxy indicator has been influenced by a particular seasonal climate parameter (e.g., summer temperature or monsoon intensity) at the time in which they were laid down or grew. Interpretation of climate proxies requires a range of ancillary studies, including calibration of the sensitivity of the proxy to climate and cross-verification among proxy indicators. Proxies can be combined to produce temperature reconstructions longer than the
instrumental temperature record The instrumental temperature record is a record of temperatures within Earth's climate based on direct, instrument-based measurements of air temperature and ocean temperature. Instrumental temperature records are distinguished from indirect re ...
and can inform discussions of
global warming In common usage, climate change describes global warming—the ongoing increase in global average temperature—and its effects on Earth's climate system. Climate change in a broader sense also includes previous long-term changes to E ...
and climate history. The geographic distribution of proxy records, just like the instrumental record, is not at all uniform, with more records in the northern hemisphere."Borehole Temperatures Confirm Global Warming Pattern."
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Proxies

In science, it is sometimes necessary to study a variable which cannot be measured directly. This can be done by "proxy methods," in which a variable which correlates with the variable of interest is measured, and then used to infer the value of the variable of interest. Proxy methods are of particular use in the study of the past climate, beyond times when direct measurements of temperatures are available. Most proxy records have to be calibrated against independent temperature measurements, or against a more directly calibrated proxy, during their period of overlap to estimate the relationship between temperature and the proxy. The longer history of the proxy is then used to reconstruct temperature from earlier periods.


Ice cores


Drilling

Ice cores An ice core is a core sample that is typically removed from an ice sheet or a high mountain glacier. Since the ice forms from the incremental buildup of annual layers of snow, lower layers are older than upper ones, and an ice core contains ic ...
are cylindrical samples from within
ice sheets In glaciology, an ice sheet, also known as a continental glacier, is a mass of glacial ice that covers surrounding terrain and is greater than . The only current ice sheets are in Antarctica and Greenland; during the Last Glacial Period at Las ...
in the
Greenland Greenland ( kl, Kalaallit Nunaat, ; da, Grønland, ) is an island country in North America that is part of the Kingdom of Denmark. It is located between the Arctic and Atlantic oceans, east of the Canadian Arctic Archipelago. Greenland is ...
,
Antarctic The Antarctic ( or , American English also or ; commonly ) is a polar region around Earth's South Pole, opposite the Arctic region around the North Pole. The Antarctic comprises the continent of Antarctica, the Kerguelen Plateau and other ...
, and
North American North America is a continent in the Northern Hemisphere and almost entirely within the Western Hemisphere. It is bordered to the north by the Arctic Ocean, to the east by the Atlantic Ocean, to the southeast by South America and the Car ...
regions.Strom, Robert. ''Hot House.'' p. 255"Core Location Maps."
First attempts of extraction occurred in 1956 as part of the
International Geophysical Year The International Geophysical Year (IGY; french: Année géophysique internationale) was an international scientific project that lasted from 1 July 1957 to 31 December 1958. It marked the end of a long period during the Cold War when scientific i ...
. As original means of extraction, the U.S. Army's Cold Regions Research and Engineering Laboratory used an -long modified electrodrill in 1968 at
Camp Century Camp Century was an Arctic United States military scientific research base in Greenland. situated 240 km (150 miles) east of Thule Air Base. When built, Camp Century was publicized as a demonstration for affordable ice-cap military outpost ...
,
Greenland Greenland ( kl, Kalaallit Nunaat, ; da, Grønland, ) is an island country in North America that is part of the Kingdom of Denmark. It is located between the Arctic and Atlantic oceans, east of the Canadian Arctic Archipelago. Greenland is ...
, and
Byrd Station The Byrd Station is a former research station established by the United States during the International Geophysical Year by U.S. Navy Seabees during Operation Deep Freeze II in West Antarctica. History A joint Army, Navy, Air Force, and Mari ...
,
Antarctica Antarctica () is Earth's southernmost and least-populated continent. Situated almost entirely south of the Antarctic Circle and surrounded by the Southern Ocean, it contains the geographic South Pole. Antarctica is the fifth-largest cont ...
. Their machinery could drill through of
ice Ice is water frozen into a solid state, typically forming at or below temperatures of 0 degrees Celsius or Depending on the presence of impurities such as particles of soil or bubbles of air, it can appear transparent or a more or less opaq ...
in 40–50 minutes. From 1300 to in depth,
core sample A core sample is a cylindrical section of (usually) a naturally-occurring substance. Most core samples are obtained by drilling with special drills into the substance, such as sediment or rock, with a hollow steel tube, called a core drill. The h ...
s were in
diameter In geometry, a diameter of a circle is any straight line segment that passes through the center of the circle and whose endpoints lie on the circle. It can also be defined as the longest chord of the circle. Both definitions are also valid ...
and 10 to long. Deeper samples of 15 to long were not uncommon. Every subsequent
drilling Drilling is a cutting process where a drill bit is spun to cut a hole of circular cross-section in solid materials. The drill bit is usually a rotary cutting tool, often multi-point. The bit is pressed against the work-piece and rotated at ...
team improves their method with each new effort.


Proxy

The ratio between the 16O and 18O water molecule isotopologues in an
ice core An ice core is a core sample that is typically removed from an ice sheet or a high mountain glacier. Since the ice forms from the incremental buildup of annual layers of snow, lower layers are older than upper ones, and an ice core contains i ...
helps determine past temperatures and snow accumulations. The heavier
isotope Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numbers ...
(18O) condenses more readily as
temperatures Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied on ...
decrease and falls more easily as
precipitation In meteorology, precipitation is any product of the condensation of atmospheric water vapor that falls under gravitational pull from clouds. The main forms of precipitation include drizzle, rain, sleet, snow, ice pellets, graupel and hail. ...
, while the lighter isotope (16O) needs colder conditions to precipitate. The farther
north North is one of the four compass points or cardinal directions. It is the opposite of south and is perpendicular to east and west. ''North'' is a noun, adjective, or adverb indicating direction or geography. Etymology The word ''north'' is ...
one needs to go to find elevated levels of the 18O isotopologue, the warmer the period. In addition to oxygen isotopes, water contains hydrogen isotopes – 1H and 2H, usually referred to as H and D (for
deuterium Deuterium (or hydrogen-2, symbol or deuterium, also known as heavy hydrogen) is one of two stable isotopes of hydrogen (the other being protium, or hydrogen-1). The nucleus of a deuterium atom, called a deuteron, contains one proton and one ...
) – that are also used for temperature proxies. Normally, ice cores from Greenland are analyzed for δ18O and those from Antarctica for δ-deuterium. Those cores that analyze for both show a lack of agreement. (In the figure, δ18O is for the trapped air, not the ice. δD is for the ice.)
Air bubble A bubble is a globule of one substance in another, usually gas in a liquid. Due to the Marangoni effect, bubbles may remain intact when they reach the surface of the immersive substance. Common examples Bubbles are seen in many places in eve ...
s in the ice, which contain trapped
greenhouse gases A greenhouse gas (GHG or GhG) is a gas that absorbs and emits radiant energy within the thermal infrared range, causing the greenhouse effect. The primary greenhouse gases in Earth's atmosphere are water vapor (), carbon dioxide (), meth ...
such as
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is tr ...
and
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on ...
, are also helpful in determining past climate changes. From 1989 to 1992, the European Greenland Ice Core Drilling Project drilled in central
Greenland Greenland ( kl, Kalaallit Nunaat, ; da, Grønland, ) is an island country in North America that is part of the Kingdom of Denmark. It is located between the Arctic and Atlantic oceans, east of the Canadian Arctic Archipelago. Greenland is ...
at coordinates 72° 35' N, 37° 38' W. The ices in that core were 3840 years old at a depth of 770 m, 40,000 years old at 2521 m, and 200,000 years old or more at 3029 m
bedrock In geology, bedrock is solid rock that lies under loose material ( regolith) within the crust of Earth or another terrestrial planet. Definition Bedrock is the solid rock that underlies looser surface material. An exposed portion of be ...
.
Ice cores An ice core is a core sample that is typically removed from an ice sheet or a high mountain glacier. Since the ice forms from the incremental buildup of annual layers of snow, lower layers are older than upper ones, and an ice core contains ic ...
in Antarctica can reveal the climate records for the past 650,000 years. Location
map A map is a symbolic depiction emphasizing relationships between elements of some space, such as objects, regions, or themes. Many maps are static, fixed to paper or some other durable medium, while others are dynamic or interactive. Althou ...
s and a complete list of U.S.
ice core An ice core is a core sample that is typically removed from an ice sheet or a high mountain glacier. Since the ice forms from the incremental buildup of annual layers of snow, lower layers are older than upper ones, and an ice core contains i ...
drilling sites can be found on the website for the National Ice Core Laboratory.


Tree rings

Dendroclimatology is the science of determining past climates from trees, primarily from properties of the annual
tree rings Dendrochronology (or tree-ring dating) is the scientific method of dating tree rings (also called growth rings) to the exact year they were formed. As well as dating them, this can give data for dendroclimatology, the study of climate and atmo ...
. Tree rings are wider when conditions favor growth, narrower when times are difficult. Other properties of the annual rings, such as maximum latewood density (MXD) have been shown to be better proxies than simple ring width. Using tree rings, scientists have estimated many local climates for hundreds to thousands of years previous. By combining multiple tree-ring studies (sometimes with other climate proxy records), scientists have estimated past regional and global climates (see
Temperature record of the past 1000 years The temperature record of the last 2,000 years is reconstructed using data from climate proxy records in conjunction with the modern instrumental temperature record which only covers the last 170 years at a global scale. Large-scale reconstruct ...
).


Fossil leaves

Paleoclimatologists often use leaf teeth to reconstruct mean annual temperature in past climates, and they use leaf size as a proxy for mean annual precipitation. In the case of mean annual precipitation reconstructions, some researchers believe taphonomic processes cause smaller leaves to be overrepresented in the fossil record, which can bias reconstructions. However, recent research suggests that the leaf fossil record may not be significantly biased toward small leaves. New approaches retrieve data such as content of past atmospheres from fossil leaf
stoma In botany, a stoma (from Greek ''στόμα'', "mouth", plural "stomata"), also called a stomate (plural "stomates"), is a pore found in the epidermis of leaves, stems, and other organs, that controls the rate of gas exchange. The pore is bor ...
ta and isotope composition, measuring cellular CO2 concentrations. A 2014 study was able to use the
carbon-13 Carbon-13 (13C) is a natural, stable isotope of carbon with a nucleus containing six protons and seven neutrons. As one of the environmental isotopes, it makes up about 1.1% of all natural carbon on Earth. Detection by mass spectrometry A ma ...
isotope ratio The term stable isotope has a meaning similar to stable nuclide, but is preferably used when speaking of nuclides of a specific element. Hence, the plural form stable isotopes usually refers to isotopes of the same element. The relative abundanc ...
s to estimate the CO2 amounts of the past 400 million years, the findings hint at a higher
climate sensitivity Climate sensitivity is a measure of how much Earth's surface will cool or warm after a specified factor causes a change in its climate system, such as how much it will warm for a doubling in the atmospheric carbon dioxide () concentration. In te ...
to CO2 concentrations.


Boreholes

Borehole A borehole is a narrow shaft bored in the ground, either vertically or horizontally. A borehole may be constructed for many different purposes, including the extraction of water ( drilled water well and tube well), other liquids (such as pet ...
temperatures are used as temperature proxies. Since heat transfer through the ground is slow, temperature measurements at a series of different depths down the borehole, adjusted for the effect of rising heat from inside the Earth, can be " inverted" (a mathematical formula to solve matrix equations) to produce a non-unique series of surface temperature values. The solution is "non-unique" because there are multiple possible surface temperature reconstructions that can produce the same borehole temperature profile. In addition, due to physical limitations, the reconstructions are inevitably "smeared", and become more smeared further back in time. When reconstructing temperatures around 1500 AD, boreholes have a temporal resolution of a few centuries. At the start of the 20th century, their resolution is a few decades; hence they do not provide a useful check on the
instrumental temperature record The instrumental temperature record is a record of temperatures within Earth's climate based on direct, instrument-based measurements of air temperature and ocean temperature. Instrumental temperature records are distinguished from indirect re ...
. However, they are broadly comparable. These confirmations have given paleoclimatologists the confidence that they can measure the temperature of 500 years ago. This is concluded by a depth scale of about 492 feet (150 meters) to measure the temperatures from 100 years ago and 1,640 feet (500 meters) to measure the temperatures from 1,000 years ago.Environmental News Network staff. "Borehole temperatures confirm global warming."
Boreholes have a great advantage over many other proxies in that no calibration is required: they are actual temperatures. However, they record surface temperature not the near-surface temperature (1.5 meter) used for most "surface" weather observations. These can differ substantially under extreme conditions or when there is surface snow. In practice the effect on borehole temperature is believed to be generally small. A second source of error is contamination of the well by groundwater may affect the temperatures, since the water "carries" more modern temperatures with it. This effect is believed to be generally small, and more applicable at very humid sites. It does not apply in ice cores where the site remains frozen all year. More than 600 boreholes, on all continents, have been used as proxies for reconstructing surface temperatures. The highest concentration of boreholes exist in
North America North America is a continent in the Northern Hemisphere and almost entirely within the Western Hemisphere. It is bordered to the north by the Arctic Ocean, to the east by the Atlantic Ocean, to the southeast by South America and the C ...
and Europe. Their depths of drilling typically range from 200 to greater than 1,000 meters into the crust of the Earth or ice sheet. A small number of boreholes have been drilled in the ice sheets; the purity of the ice there permits longer reconstructions. Central Greenland borehole temperatures show "a warming over the last 150 years of approximately 1°C ± 0.2°C preceded by a few centuries of cool conditions. Preceding this was a warm period centered around A.D. 1000, which was warmer than the late 20th century by approximately 1°C." A borehole in the Antarctica icecap shows that the "temperature at A.D. 1 asapproximately 1°C warmer than the late 20th century".BOREHOLES IN GLACIAL ICE
Surface Temperature Reconstructions for the Last 2,000 Years (2006), pp 81,82 Board on Atmospheric Sciences and Climate (BASC), National Academy of Science,
Borehole temperatures in Greenland were responsible for an important revision to the isotopic temperature reconstruction, revealing that the former assumption that "spatial slope equals temporal slope" was incorrect.


Corals

Ocean The ocean (also the sea or the world ocean) is the body of salt water that covers approximately 70.8% of the surface of Earth and contains 97% of Earth's water. An ocean can also refer to any of the large bodies of water into which the wo ...
coral Corals are marine invertebrates within the class Anthozoa of the phylum Cnidaria. They typically form compact colonies of many identical individual polyps. Coral species include the important reef builders that inhabit tropical oceans and ...
skeletal A skeleton is the structural frame that supports the body of an animal. There are several types of skeletons, including the exoskeleton, which is the stable outer shell of an organism, the endoskeleton, which forms the support structure insi ...
rings, or bands, also share paleoclimatological information, similarly to tree rings. In 2002, a report was published on the findings of Drs. Lisa Greer and Peter Swart, associates of
University of Miami The University of Miami (UM, UMiami, Miami, U of M, and The U) is a private research university in Coral Gables, Florida. , the university enrolled 19,096 students in 12 colleges and schools across nearly 350 academic majors and programs, incl ...
at the time, in regard to stable oxygen isotopes in the calcium carbonate of coral. Cooler temperatures tend to cause coral to use heavier isotopes in its structure, while warmer temperatures result in more normal
oxygen isotopes There are three known stable isotopes of oxygen (8O): , , and . Radioactive isotopes ranging from to have also been characterized, all short-lived. The longest-lived radioisotope is with a half-life of , while the shortest-lived isotope i ...
being built into the coral structure. Denser water
salinity Salinity () is the saltiness or amount of salt dissolved in a body of water, called saline water (see also soil salinity). It is usually measured in g/L or g/kg (grams of salt per liter/kilogram of water; the latter is dimensionless and equal t ...
also tends to contain the heavier isotope. Greer's coral sample from the
Atlantic Ocean The Atlantic Ocean is the second-largest of the world's five oceans, with an area of about . It covers approximately 20% of Earth's surface and about 29% of its water surface area. It is known to separate the "Old World" of Africa, Europe ...
was taken in 1994 and dated back to 1935. Greer recalls her conclusions, "When we look at the averaged annual data from 1935 to about 1994, we see it has the shape of a
sine wave A sine wave, sinusoidal wave, or just sinusoid is a mathematical curve defined in terms of the '' sine'' trigonometric function, of which it is the graph. It is a type of continuous wave and also a smooth periodic function. It occurs often i ...
. It is periodic and has a significant pattern of
oxygen isotope There are three known stable isotopes of oxygen (8O): , , and . Radioactive isotopes ranging from to have also been characterized, all short-lived. The longest-lived radioisotope is with a half-life of , while the shortest-lived isotope ...
composition that has a peak at about every twelve to fifteen years." Surface water temperatures have coincided by also peaking every twelve and a half years. However, since recording this temperature has only been practiced for the last fifty years, correlation between recorded water temperature and coral structure can only be drawn so far back.


Pollen grains

Pollen can be found in sediments. Plants produce
pollen Pollen is a powdery substance produced by seed plants. It consists of pollen grains (highly reduced microgametophytes), which produce male gametes (sperm cells). Pollen grains have a hard coat made of sporopollenin that protects the gametoph ...
in large quantities and it is extremely resistant to decay. It is possible to identify a plant species from its pollen grain. The identified plant community of the area at the relative time from that sediment layer, will provide information about the climatic condition. The abundance of pollen of a given
vegetation Vegetation is an assemblage of plant species and the ground cover they provide. It is a general term, without specific reference to particular taxa, life forms, structure, spatial extent, or any other specific botanical or geographic characte ...
period or year depends partly on the weather conditions of the previous months, hence pollen density provides information on short-term climatic conditions. The study of prehistoric pollen is
palynology Palynology is the "study of dust" (from grc-gre, παλύνω, palynō, "strew, sprinkle" and ''-logy'') or of "particles that are strewn". A classic palynologist analyses particulate samples collected from the air, from water, or from deposits ...
.


Dinoflagellate cysts

Dinoflagellates occur in most aquatic environments and during their life cycle, some species produce highly resistant organic-walled
cysts A cyst is a closed sac, having a distinct envelope and division compared with the nearby tissue. Hence, it is a cluster of cells that have grouped together to form a sac (like the manner in which water molecules group together to form a bubble); ...
for a dormancy period when environmental conditions are not appropriate for growth. Their living depth is relatively shallow (dependent upon light penetration), and closely coupled to diatoms on which they feed. Their distribution patterns in surface waters are closely related to physical characteristics of the water bodies, and nearshore assemblages can also be distinguished from oceanic assemblages. The distribution of dinocysts in sediments has been relatively well documented and has contributed to understanding the average sea-surface conditions that determine the distribution pattern and abundances of the taxa (). Several studies, including and have compiled box and gravity cores in the North Pacific analyzing them for palynological content to determine the distribution of dinocysts and their relationships with sea surface temperature, salinity, productivity and upwelling. Similarly, and use a box core at 576.5 m of water depth from 1992 in the central Santa Barbara Basin to determine oceanographic and climatic changes during the past 40 kyr in the area.


Lake and ocean sediments

Similar to their study on other proxies, paleoclimatologists examine
oxygen isotopes There are three known stable isotopes of oxygen (8O): , , and . Radioactive isotopes ranging from to have also been characterized, all short-lived. The longest-lived radioisotope is with a half-life of , while the shortest-lived isotope i ...
in the contents of ocean
sediments Sediment is a naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of wind, water, or ice or by the force of gravity acting on the particles. For example, sand a ...
. Likewise, they measure the layers of
varve A varve is an annual layer of sediment or sedimentary rock. The word 'varve' derives from the Swedish word ''varv'' whose meanings and connotations include 'revolution', 'in layers', and 'circle'. The term first appeared as ''Hvarfig lera'' (va ...
(deposited fine and coarse silt or clay) laminating lake sediments. Lake varves are primarily influenced by: * Summer temperature, which shows the energy available to melt seasonal snow and ice * Winter snowfall, which determines the level of disturbance to sediments when melting occurs * Rainfall
Diatom A diatom ( Neo-Latin ''diatoma''), "a cutting through, a severance", from el, διάτομος, diátomos, "cut in half, divided equally" from el, διατέμνω, diatémno, "to cut in twain". is any member of a large group comprising se ...
s,
foraminifera Foraminifera (; Latin for "hole bearers"; informally called "forams") are single-celled organisms, members of a phylum or class of amoeboid protists characterized by streaming granular ectoplasm for catching food and other uses; and commonly a ...
,
radiolaria The Radiolaria, also called Radiozoa, are protozoa of diameter 0.1–0.2 mm that produce intricate mineral skeletons, typically with a central capsule dividing the cell into the inner and outer portions of endoplasm and ectoplasm. The ela ...
ns,
ostracod Ostracods, or ostracodes, are a class of the Crustacea (class Ostracoda), sometimes known as seed shrimp. Some 70,000 species (only 13,000 of which are extant) have been identified, grouped into several orders. They are small crustaceans, typica ...
s, and
coccolithophore Coccolithophores, or coccolithophorids, are single celled organisms which are part of the phytoplankton, the autotrophic (self-feeding) component of the plankton community. They form a group of about 200 species, and belong either to the kingdo ...
s are examples of biotic proxies for lake and ocean conditions that are commonly used to reconstruct past climates. The distribution of the species of these and other aquatic creatures preserved in the sediments are useful proxies. The optimal conditions for species preserved in the sediment act as clues. Researchers use these clues to reveal what the climate and environment was like when the creatures died. The oxygen isotope ratios in their shells can also be used as proxies for temperature.


Water isotopes and temperature reconstruction

Ocean water is mostly H216O, with small amounts of HD16O and H218O, where D denotes
deuterium Deuterium (or hydrogen-2, symbol or deuterium, also known as heavy hydrogen) is one of two stable isotopes of hydrogen (the other being protium, or hydrogen-1). The nucleus of a deuterium atom, called a deuteron, contains one proton and one ...
, i.e. hydrogen with an extra neutron. In
Vienna Standard Mean Ocean Water Vienna Standard Mean Ocean Water (VSMOW) is an isotopic standard for water. Despite the name, VSMOW is pure water with no salt or other chemicals found in the oceans. The VSMOW standard was promulgated by the International Atomic Energy Agency ( ...
(VSMOW) the ratio of D to H is 155.76x10−6 and O-18 to O-16 is 2005.2x10−6.
Isotope fractionation Isotope fractionation describes fractionation processes that affect the relative abundance of isotopes, phenomena which are taken advantage of in isotope geochemistry and other fields. Normally, the focus is on stable isotopes of the same element ...
occurs during changes between condensed and vapour phases: the vapour pressure of heavier isotopes is lower, so vapour contains relatively more of the lighter isotopes and when the vapour condenses the precipitation preferentially contains heavier isotopes. The difference from VSMOW is expressed as δ18O = 1000‰ \times \left( \frac - 1\right); and a similar formula for δD. δ values for precipitation are always negative. The major influence on δ is the difference between ocean temperatures where the moisture evaporated and the place where the final precipitation occurred; since ocean temperatures are relatively stable the δ value mostly reflects the temperature where precipitation occurs. Taking into account that the precipitation forms above the
inversion Inversion or inversions may refer to: Arts * , a French gay magazine (1924/1925) * ''Inversion'' (artwork), a 2005 temporary sculpture in Houston, Texas * Inversion (music), a term with various meanings in music theory and musical set theory * ...
layer, we are left with a linear relation: δ 18O = aT + b This is empirically calibrated from measurements of temperature and δ as a = 0.67
Per mille (from Latin , "in each thousand") is an expression that means parts per thousand. Other recognised spellings include per mil, per mill, permil, permill, or permille. The associated sign is written , which looks like a percent sig ...
/°C for
Greenland Greenland ( kl, Kalaallit Nunaat, ; da, Grønland, ) is an island country in North America that is part of the Kingdom of Denmark. It is located between the Arctic and Atlantic oceans, east of the Canadian Arctic Archipelago. Greenland is ...
and 0.76 ‰/°C for East
Antarctica Antarctica () is Earth's southernmost and least-populated continent. Situated almost entirely south of the Antarctic Circle and surrounded by the Southern Ocean, it contains the geographic South Pole. Antarctica is the fifth-largest cont ...
. The calibration was initially done on the basis of ''spatial'' variations in temperature and it was assumed that this corresponded to ''temporal'' variations. More recently, borehole thermometry has shown that for glacial-interglacial variations, a = 0.33 ‰/°C, implying that glacial-interglacial temperature changes were twice as large as previously believed. A study published in 2017 called the previous methodology to reconstruct paleo ocean temperatures 100 million years ago into question, suggesting it has been relatively stable during that time, much colder.


Membrane lipids

A novel climate proxy obtained from
peat Peat (), also known as turf (), is an accumulation of partially decayed vegetation or organic matter. It is unique to natural areas called peatlands, bogs, mires, moors, or muskegs. The peatland ecosystem covers and is the most efficie ...
( lignites, ancient peat) and soils,
membrane lipids Membrane lipids are a group of compounds (structurally similar to fats and oils) which form the double-layered surface of all cells (lipid bilayer). The three major classes of membrane lipids are phospholipids, glycolipids, and cholesterol. Lipid ...
known as
glycerol dialkyl glycerol tetraether Glycerol dialkyl glycerol tetraether lipids (GDGTs) are a class of membrane lipids synthesized by archaea and some bacteria, making them useful biomarkers for these organisms in the geological record. Their presence, structure, and relative abundan ...
(GDGT) is helping to study paleo environmental factors, which control relative distribution of differently branched GDGT
isomers In chemistry, isomers are molecules or polyatomic ions with identical molecular formulae – that is, same number of atoms of each element – but distinct arrangements of atoms in space. Isomerism is existence or possibility of isomers. Iso ...
. The study authors note, "These branched membrane lipids are produced by an as yet unknown group of anaerobic soil bacteria." , there is a decade of research demonstrating that in mineral soils the degree of
methylation In the chemical sciences, methylation denotes the addition of a methyl group on a substrate, or the substitution of an atom (or group) by a methyl group. Methylation is a form of alkylation, with a methyl group replacing a hydrogen atom. These t ...
of bacteria (brGDGTs), helps to calculate mean annual air temperatures. This proxy method was used to study the climate of the early Palaeogene, at the Cretaceous–Paleogene boundary, and researchers found that annual air temperatures, over land and at mid-latitude, averaged about 23–29 °C (± 4.7 °C), which is 5–10 °C higher than most previous findings.


Pseudoproxies

The skill of algorithms used to combine proxy records into an overall hemispheric temperature reconstruction may be tested using a technique known as " pseudoproxies". In this method, output from a
climate model Numerical climate models use quantitative methods to simulate the interactions of the important drivers of climate, including atmosphere, oceans, land surface and ice. They are used for a variety of purposes from study of the dynamics of the c ...
is sampled at locations corresponding to the known proxy network, and the temperature record produced is compared to the (known) overall temperature of the model.


See also

*
Dendrochronology Dendrochronology (or tree-ring dating) is the scientific method of dating tree rings (also called growth rings) to the exact year they were formed. As well as dating them, this can give data for dendroclimatology, the study of climate and atmos ...
*
Historical climatology Historical climatology is the study of historical changes in climate and their effect on civilization from the emergence of homininis to the present day. This differs from paleoclimatology which encompasses climate change over the entire history ...
, the study of climate over human history (as opposed to the
Earth Earth is the third planet from the Sun and the only astronomical object known to harbor life. While large volumes of water can be found throughout the Solar System, only Earth sustains liquid surface water. About 71% of Earth's surfa ...
's) *
Ice core An ice core is a core sample that is typically removed from an ice sheet or a high mountain glacier. Since the ice forms from the incremental buildup of annual layers of snow, lower layers are older than upper ones, and an ice core contains i ...
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Paleotempestology Paleotempestology is the study of past tropical cyclone activity by means of geological proxies as well as historical documentary records. The term was coined by American meteorologist Kerry Emanuel. The usual approach in paleotempestology is ...
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Paleothermometer A paleothermometer is a methodology that provides an estimate of the ambient temperature at the time of formation of a natural material. Most paleothermometers are based on empirically-calibrated proxy relationships, such as the tree ring or TEX ...
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Palynology Palynology is the "study of dust" (from grc-gre, παλύνω, palynō, "strew, sprinkle" and ''-logy'') or of "particles that are strewn". A classic palynologist analyses particulate samples collected from the air, from water, or from deposits ...
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Speleothem A speleothem (; ) is a geological formation by mineral deposits that accumulate over time in natural caves. Speleothems most commonly form in calcareous caves due to carbonate dissolution reactions. They can take a variety of forms, depending o ...


References


Further reading

* "Borehole Temperatures Confirm Global Warming Pattern." UniSci. 27 Feb. 2001. 7 Oct. 2009

* Bruckner, Monica. "Paleoclimatology: How Can We Infer Past Climates?" Microbial Life. 29 Sept. 2008. 23 Nov. 2009

* "Climate Change 2001: 2.3.2.1 Palaeoclimate proxy indicators." IPCC. 2003. Sept. 23, 2009.

* "Coral Layers Good Proxy for Atlantic Climate Cycles." Earth Observatory. Webmaster: Paul Przyborski. 7 Dec. 2002. 2 Nov. 2009

* "Core Location Maps." National Ice Core Laboratory. 9 Apr. 2009. 23 Nov. 2009

* "Dendrochronology." Merriam-Webster Online Dictionary. Merriam-Webster Online. 2009. 2 Oct. 2009

* Environmental News Network staff. "Borehole temperatures confirm global warming." CNN.com. 17 Feb. 2000. 7 Oct. 2009

* "The GRIP Coring Effort." NCDC. 26 Sept. 2009

* "Growth ring." Encyclopædia Britannica. Encyclopædia Britannica Online. 2009. 23 Oct. 2009

* Huang, Shaopeng, et al. "Temperature trends over the past five centuries reconstructed from borehole temperatures." Nature. 2009. 6 Oct. 2009

* "Objectives – Kola Superdeep Borehole (KSDB) – IGCP 408: 'Rocks and Minerals at Great Depths and on the Surface.'"
International Continental Scientific Drilling Program The International Continental Scientific Drilling Program is a multinational program to further and fund geosciences in the field of Continental Scientific Drilling. Scientific drilling is a critical tool in understanding of Earth processes and ...
. 18 July 2006. 6 Oct. 2009

* "Paleoclimatology: the Oxygen Balance." Earth Observatory. Webmaster: Paul Przyborski. 24 Nov. 2009. 24 Nov. 2009

* Schweingruber, Fritz Hans. ''Tree Rings: Basics and Application of Dendrochronology.'' Dordrecht: 1988. 2, 47–8, 54, 256–7. * Strom, Robert. ''Hot House.'' New York: Praxis, 2007. 255. * "Varve." Merriam-Webster Online Dictionary. Merriam-Webster Online. 2009. 2 Nov. 2009

* Wolff, E. W. (2000) ''History of the atmosphere from ice cores''; ERCA vol 4 pp 147–177


External links


Chemical climate proxies
at
Royal Society of Chemistry The Royal Society of Chemistry (RSC) is a learned society (professional association) in the United Kingdom with the goal of "advancing the chemical sciences". It was formed in 1980 from the amalgamation of the Chemical Society, the Royal Inst ...
, January 23, 2013 *Quintana, Favia et al., 2018 ″Multiproxy response to climate- and human-driven changes in a remote lake of southern Patagonia (Laguna Las Vizcachas, Argentina) during the last 1.6 kyr″, Boletín de la Sociedad Geológica Mexicana, Mexico, VOL. 70 NO. 1 P. 173 ‒ 18

{{DEFAULTSORT:Proxy (Climate) Paleoclimatology Paleoceanography