capillary attraction

Capillary action (sometimes called capillarity, capillary motion, capillary rise, capillary effect, or wicking) is the process of a liquid flowing in a narrow space without the assistance of, or even in opposition to, any external forces like gravity. The effect can be seen in the drawing up of liquids between the hairs of a paint-brush, in a thin tube, in porous materials such as paper and plaster, in some non-porous materials such as sand and liquefied carbon fiber, or in a biological cell. It occurs because of intermolecular forces between the liquid and surrounding solid surfaces. If the diameter of the tube is sufficiently small, then the combination of surface tension (which is caused by cohesion within the liquid) and adhesive forces between the liquid and container wall act to propel the liquid.

Etymology

Capillary comes from the Latin word capillaris, meaning "of or resembling hair." The meaning stems from the tiny, hairlike diameter of a capillary. While capillary is usually used as a noun, the word also is used as an adjective, as in "capillary action," in which a liquid is moved along — even upward, against gravity — as the liquid is attracted to the internal surface of the capillaries.

History

The first recorded observation of capillary action was by Leonardo da Vinci. A former student of Galileo, Niccolò Aggiunti, was said to have investigated capillary action. In 1660, capillary action was still a novelty to the Irish chemist Robert Boyle, when he reported that "some inquisitive French Men" had observed that when a capillary tube was dipped into water, the water would ascend to "some height in the Pipe". Boyle then reported an experiment in which he dipped a capillary tube into red wine and then subjected the tube to a partial vacuum. He found that the vacuum had no observable influence on the height of the liquid in the capillary, so the behavior of liquids in capillary tubes was due to some phenomenon different from that which governed mercury barometers.

Others soon followed Boyle's lead. Some (e.g., Honoré Fabri) thought that liquids rose in capillaries because air could not enter capillaries as easily as liquids, so the air pressure was lower inside capillaries. Others (e.g., Isaac Vossius, Giovanni Alfonso Borelli, Louis Carré, Francis Hauksbee, Josia Weitbrecht) thought that the particles of liquid were attracted to each other and to the walls of the capillary.

Although experimental studies continued during the 18th century, a successful quantitative treatment of capillary action was not attained until 1805 by two investigators: Thomas Young of the United Kingdom and Pierre-Simon Laplace of France. They derived the Young–Laplace equation of capillary action. By 1830, the German mathematician Carl Friedrich Gauss had determined the boundary conditions governing capillary action (i.e., the conditions at the liquid-solid interface). In 1871, the British physicist Sir William Thomson (later Lord Kelvin) determined the effect of the meniscus on a liquid's vapor pressure—a relation known as the Kelvin equation. German physicist Franz Ernst Neumann (1798–1895) subsequently determined the interaction between two immiscible liquids.

Albert Einstein's first paper, which was submitted to ''Annalen der Physik'' in 1900, was on capillarity.

Phenomena and physics

Capillary penetration in porous media shares its dynamic mechanism with flow in hollow tubes, as both processes are resisted by viscous forces. Consequently, a common apparatus used to demonstrate the phenomenon is the ''capillary tube''. When the lower end of a glass tube is placed in a liquid, such as water, a concave meniscus forms. Adhesion occurs between the fluid and the solid inner wall pulling the liquid column along until there is a sufficient mass of liquid for gravitational forces to overcome these intermolecular forces. The contact length (around the edge) between the top of the liquid column and the tube is proportional to the radius of the tube, while the weight of the liquid column is proportional to the square of the tube's radius. So, a narrow tube will draw a liquid column along further than a wider tube will, given that the inner water molecules cohere sufficiently to the outer ones.

Examples

In the built environment, evaporation limited capillary penetration is responsible for the phenomenon of rising damp in concrete and masonry, while in industry and diagnostic medicine this phenomenon is increasingly being harnessed in the field of paper-based microfluidics.

In physiology, capillary action is essential for the drainage of continuously produced tear fluid from the eye. Two canaliculi of tiny diameter are present in the inner corner of the eyelid, also called the lacrimal ducts; their openings can be seen with the naked eye within the lacrymal sacs when the eyelids are everted.

Wicking is the absorption of a liquid by a material in the manner of a candle wick.
Paper towels absorb liquid through capillary action, allowing a fluid to be transferred from a surface to the towel. The small pores of a sponge act as small capillaries, causing it to absorb a large amount of fluid. Some textile fabrics are said to use capillary action to "wick" sweat away from the skin. These are often referred to as wicking fabrics, after the capillary properties of candle and lamp wicks.

Capillary action is observed in thin layer chromatography, in which a solvent moves vertically up a plate via capillary action. In this case the pores are gaps between very small particles.

Capillary action draws ink to the tips of fountain pen nibs from a reservoir or cartridge inside the pen.

With some pairs of materials, such as mercury and glass, the intermolecular forces within the liquid exceed those between the solid and the liquid, so a convex meniscus forms and capillary action works in reverse.

In hydrology, capillary action describes the attraction of water molecules to soil particles. Capillary action is responsible for moving groundwater from wet areas of the soil to dry areas. Differences in soil potential ($\Psi_m$) drive capillary action in soil.

A practical application of capillary action is the capillary action siphon. Instead of utilizing a hollow tube (as in most siphons), this device consists of a length of cord made of a fibrous material (cotton cord or string works well). After saturating the cord with water, one (weighted) end is placed in a reservoir full of water, and the other end placed in a receiving vessel. The reservoir must be higher than the receiving vessel. A related but simplified capillary siphon only consists of two hook-shaped stainless-steel rods, whose surface is hydrophilic, allowing water to wet the narrow grooves between them. Due to capillary action and gravity, water will slowly transfer from the reservoir to the receiving vessel. This simple device can be used to water houseplants when nobody is home. This property is also made use of in the lubrication of steam locomotives: wicks of worsted wool are used to draw oil from reservoirs into delivery pipes leading to the bearings.

In plants and animals

Capillary action is seen in many plants, and plays a part in transpiration. Water is brought high up in trees by branching; evaporation at the leaves creating depressurization; probably by osmotic pressure added at the roots; and possibly at other locations inside the plant, especially when gathering humidity with air roots.

Capillary action for uptake of water has been described in some small animals, such as '' Ligia exotica'' and ''Moloch horridus''.

Height of a meniscus

Capillary rise of liquid in a capillary

The height ''h'' of a liquid column is given by Jurin's law G.K. Batchelor, 'An Introduction To Fluid Dynamics', Cambridge University Press (1967) ,
:$h=,$
where $\scriptstyle \gamma$ is the liquid-air surface tension (force/unit length), ''θ'' is the contact angle, ''ρ'' is the density of liquid (mass/volume), ''g'' is the local acceleration due to gravity (length/square of time), and ''r'' is the radius of tube.

As ''r'' is in the denominator, the thinner the space in which the liquid can travel, the further up it goes. Likewise, lighter liquid and lower gravity increase the height of the column.

For a water-filled glass tube in air at standard laboratory conditions, at 20°C, , and . Because water spreads on clean glass, the effective equilibrium contact angle is approximately zero. For these values, the height of the water column is
:$h\approx .$

Thus for a radius glass tube in lab conditions given above, the water would rise an unnoticeable . However, for a radius tube, the water would rise , and for a radius tube, the water would rise .

Capillary rise of liquid between two glass plates

The product of layer thickness (''d'') and elevation height (''h'') is constant (''d''·''h'' = constant), the two quantities are inversely proportional. The surface of the liquid between the planes is hyperbola.

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Liquid transport in porous media

When a dry porous medium is brought into contact with a liquid, it will absorb the liquid at a rate which decreases over time. When considering evaporation, liquid penetration will reach a limit dependent on parameters of temperature, humidity and permeability. This process is known as evaporation limited capillary penetration and is widely observed in common situations including fluid absorption into paper and rising damp in concrete or masonry walls. For a bar shaped section of material with cross-sectional area ''A'' that is wetted on one end, the cumulative volume ''V'' of absorbed liquid after a time ''t'' is
:$V = AS\sqrt,$
where ''S'' is the sorptivity of the medium, in units of m·s^−1/2 or mm·min^−1/2. This time dependence relation is similar to Washburn's equation for the wicking in capillaries and porous media. The quantity
:$i = \frac$
is called the cumulative liquid intake, with the dimension of length. The wetted length of the bar, that is the distance between the wetted end of the bar and the so-called ''wet front'', is dependent on the fraction ''f'' of the volume occupied by voids. This number ''f'' is the porosity of the medium; the wetted length is then
:$x = \frac = \frac\sqrt.$
Some authors use the quantity ''S/f'' as the sorptivity.C. Hall, W.D. Hoff, Water transport in brick, stone, and concrete. (2002
page 131 on Google books

The above description is for the case where gravity and evaporation do not play a role.

Sorptivity is a relevant property of building materials, because it affects the amount of rising dampness. Some values for the sorptivity of building materials are in the table below.

See also

* Bond number
* Bound water
* Capillary fringe
* Capillary pressure
* Capillary wave
* Capillary bridges
* Damp-proof course
* Darcy's law
* Frost flowers
* Frost heaving
* Hindu milk miracle
* Krogh model
* Mercury intrusion porosimetry
* Needle ice
* Surface tension
* Washburn's equation
* Young–Laplace equation

References

Further reading

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Fluid dynamics
Hydrology
Surface science
Porous media