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Beryllium-8 (8Be, Be-8) is a
radionuclide A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess nuclear energy, making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transferr ...
with 4
neutron The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons behav ...
s and 4
proton A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive electric charge of +1 ''e'' elementary charge. Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton–electron mass ...
s. It is an unbound
resonance Resonance describes the phenomenon of increased amplitude that occurs when the frequency of an applied periodic force (or a Fourier component of it) is equal or close to a natural frequency of the system on which it acts. When an oscillati ...
and nominally an isotope of beryllium. It decays into two alpha particles with a half-life on the order of 8.19 seconds. This has important ramifications in
stellar nucleosynthesis Stellar nucleosynthesis is the creation (nucleosynthesis) of chemical elements by nuclear fusion reactions within stars. Stellar nucleosynthesis has occurred since the original creation of hydrogen, helium and lithium during the Big Bang. As a ...
as it creates a bottleneck in the creation of heavier
chemical element A chemical element is a species of atoms that have a given number of protons in their nuclei, including the pure substance consisting only of that species. Unlike chemical compounds, chemical elements cannot be broken down into simpler sub ...
s. The properties of 8Be have also led to speculation on the
fine tuning In theoretical physics, fine-tuning is the process in which parameters of a model must be adjusted very precisely in order to fit with certain observations. This had led to the discovery that the fundamental constants and quantities fall into su ...
of the
Universe The universe is all of space and time and their contents, including planets, stars, galaxies, and all other forms of matter and energy. The Big Bang theory is the prevailing cosmological description of the development of the universe. A ...
, and theoretical investigations on cosmological evolution had 8Be been stable.


Discovery

The discovery of beryllium-8 occurred shortly after the construction of the first
particle accelerator A particle accelerator is a machine that uses electromagnetic fields to propel charged particles to very high speeds and energies, and to contain them in well-defined beams. Large accelerators are used for fundamental research in particle ...
in 1932. British physicists John Douglas Cockcroft and
Ernest Walton Ernest Thomas Sinton Walton (6 October 1903 – 25 June 1995) was an Irish physicist and Nobel laureate. He is best known for his work with John Cockcroft to construct one of the earliest types of particle accelerator, the Cockcroft–Walton g ...
performed their first experiment with their accelerator at the
Cavendish Laboratory The Cavendish Laboratory is the Department of Physics at the University of Cambridge, and is part of the School of Physical Sciences. The laboratory was opened in 1874 on the New Museums Site as a laboratory for experimental physics and is named ...
in
Cambridge Cambridge ( ) is a university city and the county town in Cambridgeshire, England. It is located on the River Cam approximately north of London. As of the 2021 United Kingdom census, the population of Cambridge was 145,700. Cambridge becam ...
, in which they irradiated
lithium-7 Naturally occurring lithium (3Li) is composed of two stable isotopes, lithium-6 and lithium-7, with the latter being far more abundant on Earth. Both of the natural isotopes have an unexpectedly low nuclear binding energy per nucleon ( for lith ...
with
proton A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive electric charge of +1 ''e'' elementary charge. Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton–electron mass ...
s. They reported that this populated a nucleus with ''A'' = 8 that near-instantaneously decays into two alpha particles. This activity was observed again several months later, and was inferred to originate from 8Be.


Properties

Beryllium-8 is unbound with respect to alpha emission by 92 keV; it is a resonance having a width of 6 eV. The nucleus of helium-4 is particularly stable, having a doubly magic configuration and larger binding energy per nucleon than 8Be. As the total energy of 8Be is greater than that of two
alpha particle Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay, but may also be produce ...
s, the decay into two alpha particles is energetically favorable, and the synthesis of 8Be from two 4He nuclei is endothermic. The decay of 8Be is facilitated by the structure of the 8Be nucleus; it is highly deformed, and is believed to be a molecule-like cluster of two alpha particles that are very easily separated. Furthermore, while other
alpha nuclide An alpha nuclide is a nuclide that consists of an integer number of alpha particles. Alpha nuclides have equal, even numbers of protons and neutrons; they are important in stellar nucleosynthesis since the energetic environment within stars is ame ...
s have similar short-lived resonances, 8Be is exceptionally already in the
ground state The ground state of a quantum-mechanical system is its stationary state of lowest energy; the energy of the ground state is known as the zero-point energy of the system. An excited state is any state with energy greater than the ground state. ...
. The unbound system of two α-particles has a low energy of the
Coulomb barrier The Coulomb barrier, named after Coulomb's law, which is in turn named after physicist Charles-Augustin de Coulomb, is the energy barrier due to electrostatic interaction that two nuclei need to overcome so they can get close enough to undergo a ...
, which enables its existence for any significant length of time. Namely, 8Be decays with a half-life of 8.19 seconds. 8Be also has several excited states. These are also short-lived resonances, having widths up to several MeV and varying isospins, that quickly decay to the ground state or into two alpha particles.


Decay anomaly and possible fifth force

A 2015 experiment by Attila Krasznahorkay ''et al.'' at the Hungarian Academy of Sciences's Institute for Nuclear Research found anomalous decays in the 17.64 and 18.15 MeV excited states of 8Be, populated by proton irradiation of 7Li. An excess of decays creating
electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no kno ...
-
positron The positron or antielectron is the antiparticle or the antimatter counterpart of the electron. It has an electric charge of +1 '' e'', a spin of 1/2 (the same as the electron), and the same mass as an electron. When a positron collides ...
pairs at a 140° angle with a combined energy of 17 MeV was observed. Jonathan Feng ''et al.'' attribute this 6.8- σ anomaly to a 17 MeV protophobic X-
boson In particle physics, a boson ( ) is a subatomic particle whose spin quantum number has an integer value (0,1,2 ...). Bosons form one of the two fundamental classes of subatomic particle, the other being fermions, which have odd half-integer s ...
dubbed the
X17 particle The X17 particle is a hypothetical subatomic particle proposed by Attila Krasznahorkay and his colleagues to explain certain anomalous measurement results. The particle has been proposed to explain wide angles observed in the trajectory paths of ...
. This boson would mediate a fifth fundamental force acting over a short range (12  fm) and perhaps explain the decay of these 8Be excited states. A 2018 rerun of this experiment found the same anomalous particle scattering, and set a narrower mass range of the proposed fifth boson, MeV/c2. While further experiments are needed to corroborate these observations, the influence of a fifth boson has been proposed as "the most straightforward possibility".


Role in stellar nucleosynthesis

In
stellar nucleosynthesis Stellar nucleosynthesis is the creation (nucleosynthesis) of chemical elements by nuclear fusion reactions within stars. Stellar nucleosynthesis has occurred since the original creation of hydrogen, helium and lithium during the Big Bang. As a ...
, two
helium-4 Helium-4 () is a stable isotope of the element helium. It is by far the more abundant of the two naturally occurring isotopes of helium, making up about 99.99986% of the helium on Earth. Its nucleus is identical to an alpha particle, and consis ...
nuclei may collide and fuse into a single beryllium-8 nucleus. Beryllium-8 has an extremely short half-life (8.19 seconds), and decays back into two helium-4 nuclei. This, along with the unbound nature of 5He and 5Li, creates a bottleneck in
Big Bang nucleosynthesis In physical cosmology, Big Bang nucleosynthesis (abbreviated BBN, also known as primordial nucleosynthesis) is the production of nuclei other than those of the lightest isotope of hydrogen (hydrogen-1, 1H, having a single proton as a nucleus) du ...
and
stellar nucleosynthesis Stellar nucleosynthesis is the creation (nucleosynthesis) of chemical elements by nuclear fusion reactions within stars. Stellar nucleosynthesis has occurred since the original creation of hydrogen, helium and lithium during the Big Bang. As a ...
, for it necessitates a very fast reaction rate. This impedes formation of heavier elements in the former, and limits the yield in the latter process. If the beryllium-8 collides with a helium-4 nucleus before decaying, they can fuse into a
carbon-12 Carbon-12 (12C) is the most abundant of the two stable isotopes of carbon (carbon-13 being the other), amounting to 98.93% of element carbon on Earth; its abundance is due to the triple-alpha process by which it is created in stars. Carbon-12 i ...
nucleus. This reaction was first theorized independently by Öpik and Salpeter in the early 1950s. Owing to the instability of 8Be, the
triple-alpha process The triple-alpha process is a set of nuclear fusion reactions by which three helium-4 nuclei (alpha particles) are transformed into carbon. Triple-alpha process in stars Helium accumulates in the cores of stars as a result of the proton–p ...
is the only reaction in which 12C and heavier elements may be produced in observed quantities. The triple-alpha process, despite being a three-body reaction, is facilitated when 8Be production increases such that its concentration is approximately 10−8 relative to 4He; this occurs when 8Be is produced faster than it decays. However, this alone is insufficient, as the collision between 8Be and 4He is more likely to break apart the system rather than enable fusion; the reaction rate would still not be fast enough to explain the observed abundance of 12C. In 1954,
Fred Hoyle Sir Fred Hoyle FRS (24 June 1915 – 20 August 2001) was an English astronomer who formulated the theory of stellar nucleosynthesis and was one of the authors of the influential B2FH paper. He also held controversial stances on other sci ...
thus postulated the existence of a
resonance Resonance describes the phenomenon of increased amplitude that occurs when the frequency of an applied periodic force (or a Fourier component of it) is equal or close to a natural frequency of the system on which it acts. When an oscillati ...
in carbon-12 within the stellar energy region of the triple-alpha process, enhancing the creation of carbon-12 despite the extremely short half-life of beryllium-8. The existence of this resonance (the
Hoyle state Carbon-12 (12C) is the most abundant of the two stable isotopes of carbon (carbon-13 being the other), amounting to 98.93% of element carbon on Earth; its abundance is due to the triple-alpha process by which it is created in stars. Carbon-12 is ...
) was confirmed experimentally shortly thereafter; its discovery has been cited in formulations of the
anthropic principle The anthropic principle, also known as the "observation selection effect", is the hypothesis, first proposed in 1957 by Robert Dicke, that there is a restrictive lower bound on how statistically probable our observations of the universe are, beca ...
and the fine-tuned Universe hypothesis.


Hypothetical universes with stable 8Be

As beryllium-8 is unbound by only 92 keV, it is theorized that very small changes in nuclear potential and the fine tuning of certain constants (such as α, the fine structure constant), could sufficiently increase the binding energy of 8Be to prevent its alpha decay, thus making it
stable A stable is a building in which livestock, especially horses, are kept. It most commonly means a building that is divided into separate stalls for individual animals and livestock. There are many different types of stables in use today; the ...
. This has led to investigations of hypothetical scenarios in which 8Be is stable and speculation about other universes with different fundamental constants. These studies suggest that the disappearance of the bottleneck created by 8Be would result in a very different reaction mechanism in
Big Bang nucleosynthesis In physical cosmology, Big Bang nucleosynthesis (abbreviated BBN, also known as primordial nucleosynthesis) is the production of nuclei other than those of the lightest isotope of hydrogen (hydrogen-1, 1H, having a single proton as a nucleus) du ...
and the triple-alpha process, as well as alter the abundances of heavier chemical elements. As Big Bang nucleosynthesis only occurred within a short period having the necessary conditions, it is thought that there would be no significant difference in carbon production even if 8Be were stable. However, stable 8Be would enable alternative reaction pathways in helium burning (such as 8Be + 4He and 8Be + 8Be; constituting a "beryllium burning" phase) and possibly affect the abundance of the resultant 12C, 16O, and heavier nuclei, though 1H and 4He would remain the most abundant nuclides. This would also affect
stellar evolution Stellar evolution is the process by which a star changes over the course of time. Depending on the mass of the star, its lifetime can range from a few million years for the most massive to trillions of years for the least massive, which is cons ...
through an earlier onset and faster rate of helium burning (and beryllium burning), and result in a different
main sequence In astronomy, the main sequence is a continuous and distinctive band of stars that appears on plots of stellar color versus brightness. These color-magnitude plots are known as Hertzsprung–Russell diagrams after their co-developers, Ejnar H ...
than our Universe.


Notes


References

{{Authority control Isotopes of beryllium Nucleosynthesis