An aragonite sea contains

aragonite Aragonite is a carbonate mineral, one of the three most common naturally occurring crystal forms of calcium carbonate, (the other forms being the minerals calcite and vaterite). It is formed by biological and physical processes, including pre ...

and high-magnesium

calcite Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on scratc ...

as the primary inorganic calcium carbonate precipitates. The chemical conditions of the seawater must be notably high in

magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ...

content relative to calcium (high Mg/Ca ratio) for an aragonite sea to form. This is in contrast to a

calcite sea A calcite sea is a sea in which low-magnesium calcite is the primary inorganic marine calcium carbonate precipitate. An aragonite sea is the alternate seawater chemistry in which aragonite and high-magnesium calcite are the primary inorganic ca ...

in which seawater low in magnesium content relative to calcium (low Mg/Ca ratio) favors the formation of low-magnesium calcite as the primary inorganic marine calcium carbonate precipitate. The Early

Paleozoic The Paleozoic (or Palaeozoic) Era is the earliest of three geologic eras of the Phanerozoic Eon. The name ''Paleozoic'' ( ;) was coined by the British geologist Adam Sedgwick in 1838 by combining the Greek words ''palaiós'' (, "old") and ...

and the Middle to Late

Mesozoic The Mesozoic Era ( ), also called the Age of Reptiles, the Age of Conifers, and colloquially as the Age of the Dinosaurs is the second-to-last era of Earth's geological history, lasting from about , comprising the Triassic, Jurassic and Cretace ...

oceans were predominantly calcite seas, whereas the Middle Paleozoic through the Early Mesozoic and the

Cenozoic The Cenozoic ( ; ) is Earth's current geological era, representing the last 66million years of Earth's history. It is characterised by the dominance of mammals, birds and flowering plants, a cooling and drying climate, and the current configu ...

(including today) are characterized by aragonite seas. Aragonite seas occur due to several factors, the most obvious of these is a high seawater Mg/Ca ratio (Mg/Ca > 2), which occurs during intervals of slow

seafloor spreading Seafloor spreading or Seafloor spread is a process that occurs at mid-ocean ridges, where new oceanic crust is formed through volcanic activity and then gradually moves away from the ridge. History of study Earlier theories by Alfred Wegener a ...

. However, the

sea level Mean sea level (MSL, often shortened to sea level) is an average surface level of one or more among Earth's coastal bodies of water from which heights such as elevation may be measured. The global MSL is a type of vertical datuma standardis ...

, temperature, and calcium carbonate saturation state of the surrounding system also determine which polymorph of calcium carbonate (aragonite, low-magnesium calcite, high-magnesium calcite) will form. Likewise, the occurrence of calcite seas is controlled by the same suite of factors controlling aragonite seas, with the most obvious being a low seawater Mg/Ca ratio (Mg/Ca < 2), which occurs during intervals of rapid seafloor spreading. This trend has been observed by looking at the chemistry of both biogenic and abiogenic carbonates, dating them, and analyzing the conditions under which they were formed. Various studies have examined these relationships and concluded that the mineralogy of both biogenic (major carbonate sediment and rock-forming organisms) and abiogenic marine carbonates (

limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms w ...

s and

marl Marl is an earthy material rich in carbonate minerals, clays, and silt. When hardened into rock, this becomes marlstone. It is formed in marine or freshwater environments, often through the activities of algae. Marl makes up the lower part ...

s) throughout

Phanerozoic The Phanerozoic Eon is the current geologic eon in the geologic time scale, and the one during which abundant animal and plant life has existed. It covers 538.8 million years to the present, and it began with the Cambrian Period, when anim ...

time has generally been synchronized with calcium carbonate mineralogies expected from seawater magnesium/calcium ratios reconstructed from derivatives of ancient seawater trapped in

halite Halite (), commonly known as rock salt, is a type of salt, the mineral (natural) form of sodium chloride ( Na Cl). Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, p ...

crystals in the geologic record (

fluid inclusion image:Inclumed.gif, 250px, Trapped in a time capsule the same size as the diameter of a human hair, the ore-forming liquid in this inclusion was so hot and contained so much dissolved solids that when it cooled, crystals of halite, sylvite, gypsum, ...

s).

Citations

References

* * * * * * * * * * * * * * * * * * * * {{cite journal , author = Wilson, M.A. , author2=Palmer, T.J. , year = 1992 , title = Hardgrounds and hardground faunas , journal = University of Wales, Aberystwyth, Institute of Earth Studies Publications , volume = 9 , pages = 1–131 Limestone Marine geology Historical geology