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Anorthosite () is a phaneritic, intrusive
igneous Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma or ...
rock characterized by its composition: mostly
plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more p ...
feldspar Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) felds ...
(90–100%), with a minimal
mafic A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks in ...
component (0–10%).
Pyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe I ...
,
ilmenite Ilmenite is a titanium-iron oxide mineral with the idealized formula . It is a weakly magnetic black or steel-gray solid. Ilmenite is the most important ore of titanium and the main source of titanium dioxide, which is used in paints, printing ...
,
magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With ...
, and
olivine The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers qui ...
are the mafic
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...
s most commonly present. Anorthosites are of enormous geologic interest, because it is still not fully understood how they form. Most models involve separating plagioclase crystals based on their density. Plagioclase crystals are usually less dense than magma; so, as plagioclase crystallizes in a magma chamber, the plagioclase crystals float to the top, concentrating there. Anorthosite on Earth can be divided into five types: #
Archean The Archean Eon ( , also spelled Archaean or Archæan) is the second of four geologic eons of Earth's history, representing the time from . The Archean was preceded by the Hadean Eon and followed by the Proterozoic. The Earth during the Arc ...
-age anorthosites #
Proterozoic The Proterozoic () is a geological eon spanning the time interval from 2500 to 538.8million years ago. It is the most recent part of the Precambrian "supereon". It is also the longest eon of the Earth's geologic time scale, and it is subdivided i ...
anorthosite (also known as massif or massif-type anorthosite) – the most abundant type of anorthosite on Earth # Layers within
Layered Intrusions Layer or layered may refer to: Arts, entertainment, and media * ''Layers'' (Kungs album) * ''Layers'' (Les McCann album) * ''Layers'' (Royce da 5'9" album) *"Layers", the title track of Royce da 5'9"'s sixth studio album * Layer, a female Maveri ...
(e.g.,
Bushveld The Bushveld (from af, bosveld, af, bos 'bush' and af, veld) is a sub-tropical woodland ecoregion of Southern Africa. It encompasses most of Limpopo Province and a small part of the North West Province of South Africa, the Central and Nort ...
and Stillwater intrusions) #
Mid-ocean ridge A mid-ocean ridge (MOR) is a seafloor mountain system formed by plate tectonics. It typically has a depth of about and rises about above the deepest portion of an ocean basin. This feature is where seafloor spreading takes place along a div ...
and
transform fault A transform fault or transform boundary, is a fault along a plate boundary where the motion is predominantly horizontal. It ends abruptly where it connects to another plate boundary, either another transform, a spreading ridge, or a subduct ...
anorthosites # Anorthosite
xenolith A xenolith ("foreign rock") is a rock fragment ( country rock) that becomes enveloped in a larger rock during the latter's development and solidification. In geology, the term ''xenolith'' is almost exclusively used to describe inclusions in ig ...
s in other rocks (often granites, kimberlites, or basalts) Of these, the first two are the most common. These two types have different modes of occurrence, appear to be restricted to different periods in Earth's history, and are thought to have had different origins.
Lunar Lunar most commonly means "of or relating to the Moon". Lunar may also refer to: Arts and entertainment * ''Lunar'' (series), a series of video games * "Lunar" (song), by David Guetta * "Lunar", a song by Priestess from the 2009 album ''Prior t ...
anorthosites constitute the light-coloured areas of the Moon's surface and have been the subject of much research.


Proterozoic anorthosite massifs


Age

Proterozoic anorthosites were emplaced during the Proterozoic Eon (ca. 2,500–542 Ma), though most were emplaced between 1,800 and 1,000 Ma.


Occurrence

Proterozoic anorthosites typically occur as extensive
stocks Stocks are feet restraining devices that were used as a form of corporal punishment and public humiliation. The use of stocks is seen as early as Ancient Greece, where they are described as being in use in Solon's law code. The law describing ...
or
batholith A batholith () is a large mass of intrusive igneous rock (also called plutonic rock), larger than in area, that forms from cooled magma deep in Earth's crust. Batholiths are almost always made mostly of felsic or intermediate rock types, s ...
s. The areal extent of anorthosite batholiths ranges from relatively small (dozens or hundreds of square kilometers) to nearly , in the instance of the Nain Plutonic Suite or Mistastin crater in northern Labrador, Canada. Major occurrences of Proterozoic anorthosite are found in the southwest U.S., the
Appalachian Mountains The Appalachian Mountains, often called the Appalachians, (french: Appalaches), are a system of mountains in eastern to northeastern North America. The Appalachians first formed roughly 480 million years ago during the Ordovician Period. The ...
(e.g., the Honeybrook Upland of eastern Pennsylvania), eastern
Canada Canada is a country in North America. Its ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, covering over , making it the world's second-largest country by to ...
(e.g., the Grenville Province), across southern
Scandinavia Scandinavia; Sámi languages: /. ( ) is a subregion in Northern Europe, with strong historical, cultural, and linguistic ties between its constituent peoples. In English usage, ''Scandinavia'' most commonly refers to Denmark, Norway, and S ...
and eastern
Europe Europe is a large peninsula conventionally considered a continent in its own right because of its great physical size and the weight of its history and traditions. Europe is also considered a Continent#Subcontinents, subcontinent of Eurasia ...
. Mapped onto the Pangaean continental configuration of that eon, these occurrences are all contained in a single straight belt, and must all have been emplaced intracratonally. The conditions and constraints of this pattern of origin and distribution are not clear. However, see the Origins section below.


Related rocks

Many Proterozoic anorthosites occur in spatial association with other highly distinctive, contemporaneous rock types: the so-called 'anorthosite suite' or 'anorthosite- mangerite- charnockite-granite (AMCG) complex'. These rock types can include: * Mangerite: a pyroxene-bearing monzonite intrusive igneous rock * Charnockite: an orthopyroxene-bearing quartz-feldspar rock, once thought to be intrusive igneous, now recognized as metamorphic * Iron-rich
felsic In geology, felsic is a modifier describing igneous rocks that are relatively rich in elements that form feldspar and quartz.Marshak, Stephen, 2009, ''Essentials of Geology,'' W. W. Norton & Company, 3rd ed. It is contrasted with mafic rocks, wh ...
rocks, including monzonite and rapakivi granite * Iron-rich
diorite Diorite ( ) is an intrusive igneous rock formed by the slow cooling underground of magma (molten rock) that has a moderate content of silica and a relatively low content of alkali metals. It is intermediate in composition between low-sil ...
,
gabbro Gabbro () is a phaneritic (coarse-grained), mafic intrusive igneous rock formed from the slow cooling of magnesium-rich and iron-rich magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is ...
, and
norite Norite is a mafic intrusive igneous rock composed largely of the calcium-rich plagioclase labradorite, orthopyroxene, and olivine. The name ''norite'' is derived from ''Norge'', the Norwegian name for Norway. Norite also known as orthopy ...
* Leucocratic mafic rocks such as leucotroctolite and leuconorite Though co-eval, these rocks likely represent chemically-independent magmas, likely produced by melting of
country rock Country rock is a genre of music which fuses rock and country. It was developed by rock musicians who began to record country-flavored records in the late 1960s and early 1970s. These musicians recorded rock records using country themes, vocal ...
into which the anorthosites intruded. Importantly, large volumes of
ultramafic Ultramafic rocks (also referred to as ultrabasic rocks, although the terms are not wholly equivalent) are igneous and meta-igneous rocks with a very low silica content (less than 45%), generally >18% MgO, high FeO, low potassium, and are composed ...
rocks are not found in association with Proterozoic anorthosites.


Physical characteristics

Since they are primarily composed of plagioclase feldspar, most of Proterozoic anorthosites appear, in
outcrop An outcrop or rocky outcrop is a visible exposure of bedrock or ancient superficial deposits on the surface of the Earth. Features Outcrops do not cover the majority of the Earth's land surface because in most places the bedrock or superficia ...
, to be grey or bluish. Individual plagioclase crystals may be black, white, blue, or grey, and may exhibit an
iridescence Iridescence (also known as goniochromism) is the phenomenon of certain surfaces that appear to gradually change color as the angle of view or the angle of illumination changes. Examples of iridescence include soap bubbles, feathers, butterfl ...
known as labradorescence on fresh surfaces. The feldspar variety labradorite is commonly present in anorthosites. Mineralogically, labradorite is a compositional term for any calcium-rich plagioclase feldspar containing 50–70 molecular percent anorthite (An 50–70), regardless of whether it shows labradorescence. The mafic mineral in Proterozoic anorthosite may be clinopyroxene,
orthopyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe I ...
,
olivine The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers qui ...
, or, more rarely,
amphibole Amphibole () is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is ...
.
Oxide An oxide () is a chemical compound that contains at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion of oxygen, an O2– (molecular) ion. with oxygen in the oxidation state of −2. Most of the E ...
s, such as
magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With ...
or
ilmenite Ilmenite is a titanium-iron oxide mineral with the idealized formula . It is a weakly magnetic black or steel-gray solid. Ilmenite is the most important ore of titanium and the main source of titanium dioxide, which is used in paints, printing ...
, are also common. Most anorthosite plutons are very coarse grained; that is, the individual plagioclase
crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macro ...
s and the accompanying mafic mineral are more than a few centimetres long. Less commonly, plagioclase crystals are megacrystic, or larger than one metre long. However, most Proterozoic anorthosites are deformed, and such large plagioclase crystals have recrystallized to form smaller crystals, leaving only the outline of the larger crystals behind. While many Proterozoic anorthosite plutons appear to have no large-scale relict igneous structures (having instead post-emplacement deformational structures), some do have igneous layering, which may be defined by crystal size, mafic content, or chemical characteristics. Such layering clearly has origins with a rheologically liquid-state
magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natura ...
.


Chemical and isotopic characteristics

Proterozoic anorthosites are typically >90% plagioclase, and the plagioclase composition is commonly between An40 and An60 (40–60%
anorthite Anorthite is the calcium endmember of the plagioclase feldspar mineral series. The chemical formula of pure anorthite is Ca Al2 Si2O8. Anorthite is found in mafic igneous rocks. Anorthite is rare on the Earth but abundant on the Moon. Minera ...
). This compositional range is intermediate, and is one of the characteristics which distinguish Proterozoic anorthosites from Archean anorthosites (which are typically >An80). Proterozoic anorthosites often have significant
mafic A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks in ...
components in addition to plagioclase. These phases can include olivine, pyroxene, Fe-Ti oxides, and/or apatite. Mafic minerals in Proterozoic anorthosites have a wide range of composition, but are not generally highly magnesian. The trace-element chemistry of Proterozoic anorthosites, and the associated rock types, has been examined in some detail by researchers with the aim of arriving at a plausible genetic theory. However, there is still little agreement on just what the results mean for anorthosite genesis; see the 'Origins' section below. A very short list of results, including results for rocks thought to be related to Proterozoic anorthosites, Some research has focused on
neodymium Neodymium is a chemical element with the symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth metals. It is a hard, slightly malleable, silvery metal that quickly tarn ...
(Nd) and
strontium Strontium is the chemical element with the symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is e ...
(Sr) isotopic determinations for anorthosites, particularly for anorthosites of the Nain Plutonic Suite (NPS). Such isotopic determinations are of use in gauging the viability of prospective sources for magmas that gave rise to anorthosites. Some results are detailed below in the 'Origins' section.


High-alumina orthopyroxene megacrysts (HAOMs)

Many Proterozoic-age anorthosites contain large crystals of orthopyroxene with distinctive compositions. These are the so-called high-alumina orthopyroxene megacrysts (HAOM). HAOM are distinctive because 1) they contain higher amounts of Al than typically seen in orthopyroxenes; 2) they are cut by numerous thin lathes of plagioclase, which may represent exsolution lamellae; and 3) they appear to be older than the anorthosites in which they are found. The origins of HAOMs are debated. One possible model suggests that, during anorthosite formation, a mantle-derived melt (or partially-crystalline mush) was injected into the lower crust and began crystallizing. HAOMs would have crystallized out during this time, perhaps as long as 80–120 million years. The HAOM-bearing melt could then have risen to the upper crust. This model is supported by the fact that aluminum is more soluble in orthopyroxene at high pressure. In this model, the HAOM represent lower-crustal cumulates that are related to the anorthosite source-magma. One problem with this model is that it requires the anorthosite source-magma to sit in the low crust for a considerable time. To solve this, some authors suggest that the HAOMs may have formed in the lower crust independent of the anorthosite source-magma. Later, the anorthosite source-magma may have entrained pieces of the HAOM-bearing lower crust on its way upward. Other researchers consider the chemical compositions of the HAOM to be the product of rapid crystallization at moderate or low pressures, eliminating the need for a lower-crustal origin altogether.


Origins of Proterozoic anorthosites

The origins of Proterozoic anorthosites have been a subject of theoretical debate for many decades. A brief synopsis of this problem is as follows: The problem begins with the generation of magma, the necessary precursor of any igneous rock. Magma generated by small amounts of partial melting of the
mantle A mantle is a piece of clothing, a type of cloak. Several other meanings are derived from that. Mantle may refer to: *Mantle (clothing), a cloak-like garment worn mainly by women as fashionable outerwear **Mantle (vesture), an Eastern Orthodox ve ...
is generally of
basaltic Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron ( mafic lava) exposed at or very near the surface of a rocky planet or moon. More than ...
composition. Under normal conditions, the composition of basaltic magma requires it to crystallize between 50 and 70% plagioclase, with the bulk of the remainder of the magma crystallizing as mafic minerals. However, anorthosites are defined by a high plagioclase content (90–100% plagioclase), and are not found in association with contemporaneous ultramafic rocks. This is now known as 'the anorthosite problem.' Proposed solutions to the anorthosite problem have been diverse, with many of the proposals drawing on different geological subdisciplines. It was suggested early in the history of anorthosite debate that a special type of magma, anorthositic magma, had been generated at depth, and emplaced into the crust. However, the solidus of an anorthositic magma is too high for it to exist as a liquid for very long at normal ambient crustal temperatures, so this appears to be unlikely. The presence of water vapor has been shown to lower the solidus temperature of anorthositic magma to more reasonable values, but most anorthosites are relatively dry. It may be postulated, then, that water vapor be driven off by subsequent metamorphism of the anorthosite, but some anorthosites are undeformed, thereby invalidating the suggestion. The discovery, in the late 1970s, of anorthositic dykes in the Nain Plutonic Suite, suggested that the possibility of anorthositic magmas existing at crustal temperatures needed to be reexamined. However, the dykes were later shown to be more complex than was originally thought. In summary, though liquid-state processes clearly operate in some anorthosite plutons, the plutons are probably not derived from anorthositic magmas. Many researchers have argued that anorthosites are the products of basaltic magma, and that mechanical removal of mafic minerals has occurred. Since the mafic minerals are not found with the anorthosites, these minerals must have been left at either a deeper level or the base of the crust. A typical theory is as follows: partial melting of the mantle generates a basaltic magma, which does not immediately ascend into the crust. Instead, the basaltic magma forms a large magma chamber at the base of the crust and fractionates large amounts of mafic minerals, which sink to the bottom of the chamber. The co-crystallizing plagioclase crystals float, and eventually are emplaced into the crust as anorthosite plutons. Most of the sinking mafic minerals form ultramafic cumulates which stay at the base of the crust. This theory has many appealing features, of which one is the capacity to explain the chemical composition of high-alumina orthopyroxene megacrysts (HAOM). This is detailed below in the section devoted to the HAOM. However, on its own, this hypothesis cannot coherently explain the origins of anorthosites, because it does not fit with, among other things, some important isotopic measurements made on anorthositic rocks in the Nain Plutonic Suite. The Nd and Sr isotopic data show the magma which produced the anorthosites cannot have been derived only from the mantle. Instead, the magma that gave rise to the Nain Plutonic Suite anorthosites must have had a significant crustal component. This discovery led to a slightly more complicated version of the previous hypothesis: Large amounts of basaltic magma form a magma chamber at the base of the crust, and, while crystallizing, assimilating large amounts of crust. This small addendum explains both the isotopic characteristics and certain other chemical niceties of Proterozoic anorthosite. However, at least one researcher has cogently argued, on the basis of geochemical data, that the mantle's role in production of anorthosites must actually be very limited: the mantle provides only the impetus (heat) for crustal melting, and a small amount of partial melt in the form of basaltic magma. Thus anorthosites are, in this view, derived almost entirely from lower crustal melts.


Archean anorthosites

Archean anorthosites represent the second largest anorthosite deposits on Earth. Most have been dated between 3,200 and 2,800 Ma, and commonly associated with basalts and/or greenstone belts. Archean anorthosites are distinct texturally and mineralogically from Proterozoic anorthosite bodies. Their most characteristic feature is the presence of equant, euhedral megacrysts (up to 30 cm) of plagioclase surrounded by a fine-grained mafic groundmass. The plagioclase in these anorthosites is commonly An80-90.


Economic value of anorthosite

The primary economic value of anorthosite bodies is the
titanium Titanium is a chemical element with the symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion i ...
-bearing oxide
ilmenite Ilmenite is a titanium-iron oxide mineral with the idealized formula . It is a weakly magnetic black or steel-gray solid. Ilmenite is the most important ore of titanium and the main source of titanium dioxide, which is used in paints, printing ...
. However, some
Proterozoic The Proterozoic () is a geological eon spanning the time interval from 2500 to 538.8million years ago. It is the most recent part of the Precambrian "supereon". It is also the longest eon of the Earth's geologic time scale, and it is subdivided i ...
anorthosite bodies have large amounts of labradorite, which is quarried for its value as both a
gemstone A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rocks (such as lapis lazuli, opal, ...
and a building material. Archean anorthosites, because they are
aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It ha ...
-rich, have large amounts of
aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It ha ...
substituting for
silicon Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic ...
; a few of these bodies are mined as ores of aluminium. Anorthosite was prominently represented in rock samples brought back from the
Moon The Moon is Earth's only natural satellite. It is the fifth largest satellite in the Solar System and the largest and most massive relative to its parent planet, with a diameter about one-quarter that of Earth (comparable to the width of ...
, and is important in investigations of
Mars Mars is the fourth planet from the Sun and the second-smallest planet in the Solar System, only being larger than Mercury. In the English language, Mars is named for the Roman god of war. Mars is a terrestrial planet with a thin at ...
,
Venus Venus is the second planet from the Sun. It is sometimes called Earth's "sister" or "twin" planet as it is almost as large and has a similar composition. As an interior planet to Earth, Venus (like Mercury) appears in Earth's sky never f ...
, and
meteorite A meteorite is a solid piece of debris from an object, such as a comet, asteroid, or meteoroid, that originates in outer space and survives its passage through the atmosphere to reach the surface of a planet or moon. When the original object ...
s.


Soil development on anorthosite

In the Adirondack Mountains, soils on anorthositic rock tend to be stony loamy sand with classic
podzol In soil science, podzols are the typical soils of coniferous or boreal forests and also the typical soils of eucalypt forests and heathlands in southern Australia. In Western Europe, podzols develop on heathland, which is often a construct of ...
profile development usually evident. In the
San Gabriel Mountains The San Gabriel Mountains ( es, Sierra de San Gabriel) are a mountain range located in northern Los Angeles County and western San Bernardino County, California, United States. The mountain range is part of the Transverse Ranges and lies betw ...
, soils on anorthosite have a dominance of 1:1 clay minerals (kaolinite and halloysite) in contrast to more mafic rock over which 2:1 clays develop. File:Anorthosit fin.jpg, Anorthosite from southern Finland Image:Labradoryt 1.JPG, Anorthosite from Poland File:Apollo_15_Genesis_Rock.jpg, Anorthosite from the Moon, Apollo 15 " Genesis Rock"


See also

*


References


Bibliography

* * * * * * * * *


External links


Anorthosite Complexes (web archive)
* ttps://web.archive.org/web/20031012172703/http://www.nasm.si.edu/galleries/attm/wl.an.2.html Anorthosite – Lunar Highland Rockbr>Lunar Anorthosite Specimen 60025 Photomicrographs
{{Authority control Plutonic rocks Archean Proterozoic