Allophane is an

amorphous In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid, glassy solid) is a solid that lacks the long-range order that is characteristic of a crystal. Etymology The term comes from the Greek ''a'' ("wi ...

to poorly crystalline hydrous

aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It ...

silicate

clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay parti ...

mineraloid A mineraloid is a naturally occurring mineral-like substance that does not demonstrate crystallinity. Mineraloids possess chemical compositions that vary beyond the generally accepted ranges for specific minerals. For example, obsidian is an amo ...

. Its chemical formula is Al₂O₃·(SiO₂)_1.3-2·(2.5-3)H₂O. Since it has short-range atomic order, it is a mineraloid, rather than a mineral, and can be identified by its distinctive infrared spectrum and its

X-ray diffraction X-ray crystallography is the experimental science determining the atomic and molecular structure of a crystal, in which the crystalline structure causes a beam of incident X-rays to diffract into many specific directions. By measuring the angles ...

pattern. It was first described in 1816 in Gräfenthal,

Thuringia Thuringia (; german: Thüringen ), officially the Free State of Thuringia ( ), is a state of central Germany, covering , the sixth smallest of the sixteen German states. It has a population of about 2.1 million. Erfurt is the capital and la ...

, Germany. Allophane is a

weathering Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs ''in situ'' (on site, with little or no movement), ...

hydrothermal alteration Metasomatism (from the Greek μετά ''metá'' "change" and σῶμα ''sôma'' "body") is the chemical alteration of a rock by hydrothermal and other fluids. It is the replacement of one rock by another of different mineralogical and chemical co ...

product of

volcanic glass Volcanic glass is the amorphous (uncrystallized) product of rapidly cooling magma. Like all types of glass, it is a state of matter intermediate between the closely packed, highly ordered array of a crystal and the highly disordered array of liq ...

and

feldspar Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feld ...

s and sometimes has a composition similar to

kaolinite Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral s ...

but generally has a molar ratio of Al:Si = 2. It typically forms under mildly acidic to neutral pH (5–7). Its structure has been debated, but it is similar to

clay mineral Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay minerals ...

s and is composed of curved alumina octahedral and silica tetrahedral layers.Smalley, I.J. 1979. A spherical structure for allophane. Nature 281, 339 only Transmission electron micrographs show that it is generally made up of aggregates of hollow spherules ~3–5 nm in diameter. Allophane can alter to form

halloysite Halloysite is an aluminosilicate clay mineral with the empirical formula Al2Si2O5(OH)4. Its main constituents are oxygen (55.78%), silicon (21.76%), aluminium (20.90%), and hydrogen (1.56%). Halloysite typically forms by hydrothermal alteration o ...

under resilicating aqueous conditions and can alter to form

gibbsite Gibbsite, Al(OH)3, is one of the mineral forms of aluminium hydroxide. It is often designated as γ-Al(OH)3 (but sometimes as α-Al(OH)3.). It is also sometimes called hydrargillite (or hydrargyllite). Gibbsite is an important ore of aluminiu ...

under desilicating conditions. A

copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish- ...

-containing variety ''cupro-allophane'' has been reported. It forms waxy botryoidal to crusty masses with color varying from white through green, blue, yellow, to brown. It has a

Mohs hardness The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. The scale was introduced in 1812 by t ...

of 3 and a

specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water at its densest ...

of 1.0. It was named from the

Greek Greek may refer to: Greece Anything of, from, or related to Greece, a country in Southern Europe: *Greeks, an ethnic group. *Greek language, a branch of the Indo-European language family. **Proto-Greek language, the assumed last common ancestor ...

''allos'' – "other" and ''phanos'' – "to appear", as it gave a deceptive reaction in the blowpipe flame in old mineralogical testing.

References

Webmineral dataHandbook of Mineralogy
*Wada, K. (1989), Allophane and Imogolite in Minerals in Soil Environments, Soil Science Society of America, no.1, pp. 1051–1087. *Parfitt, R.L. (1990), Allophane in New Zealand. A Review. Australian Journal of Soil Research 28, pp. 343–360. Aluminium minerals Phyllosilicates Volcanic soils {{silicate-mineral-stub