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Acrylic paint is a fast-drying paint made of
pigment A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compou ...
suspended in acrylic
polymer A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...
emulsion An emulsion is a mixture of two or more liquids that are normally immiscible (unmixable or unblendable) owing to liquid-liquid phase separation. Emulsions are part of a more general class of two-phase systems of matter called colloids. Altho ...
and plasticizers, silicone oils, defoamers, stabilizers, or metal soaps. Most acrylic paints are water-based, but become
water-resistant Waterproofing is the process of making an object or structure waterproof or water-resistant so that it remains relatively unaffected by water or resisting the ingress of water under specified conditions. Such items may be used in wet environme ...
when dry. Depending on how much the paint is diluted with water, or modified with acrylic gels, mediums, or pastes, the finished acrylic painting can resemble a
watercolor Watercolor (American English) or watercolour (British English; see spelling differences), also ''aquarelle'' (; from Italian diminutive of Latin ''aqua'' "water"), is a painting method”Watercolor may be as old as art itself, going back to ...
, a gouache, or an
oil painting Oil painting is the process of painting with pigments with a medium of drying oil as the binder. It has been the most common technique for artistic painting on wood panel or canvas for several centuries, spreading from Europe to the rest of ...
, or have its own unique characteristics not attainable with other media. Water-based acrylic paints are used as
latex Latex is an emulsion (stable dispersion) of polymer microparticles in water. Latexes are found in nature, but synthetic latexes are common as well. In nature, latex is found as a milky fluid found in 10% of all flowering plants (angiosperms ...
house paints, as latex is the technical term for a suspension of polymer microparticles in water. Interior latex house paints tend to be a combination of binder (sometimes acrylic,
vinyl Vinyl may refer to: Chemistry * Polyvinyl chloride (PVC), a particular vinyl polymer * Vinyl cation, a type of carbocation * Vinyl group, a broad class of organic molecules in chemistry * Vinyl polymer, a group of polymers derived from vinyl ...
, pva, and others), filler,
pigment A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compou ...
, and
water Water (chemical formula ) is an Inorganic compound, inorganic, transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living ...
. Exterior latex house paints may also be a co-polymer blend, but the best exterior water-based paints are 100% acrylic, because of its elasticity and other factors. Vinyl, however, costs half of what 100% acrylic resins cost, and polyvinyl acetate (PVA) is even cheaper, so paint companies make many different combinations of them to match the market.


History

Otto Röhm invented
acrylic resin 186 px, Polyhydroxyethylmethacrylate is a typical acrylate resin. An acrylic resin is a thermoplastic or thermosetting plastic substance typically derived from acrylic acid, methacrylic acid and acrylate monomers such as butyl acrylate and or ...
, which was quickly transformed into acrylic paint. As early as 1934, the first usable acrylic resin dispersion was developed by German chemical company
BASF BASF SE () is a German multinational chemical company and the largest chemical producer in the world. Its headquarters is located in Ludwigshafen, Germany. The BASF Group comprises subsidiaries and joint ventures in more than 80 countries ...
, which was patented by
Rohm and Haas Rohm and Haas Company is a manufacturer of specialty chemicals for end use markets such as building and construction, electronic devices, packaging, household and personal care products. Headquartered in Philadelphia, the company is organized i ...
. The synthetic paint was first used in the 1940s, combining some of the properties of oil and watercolor. Between 1946 and 1949,
Leonard Bocour Leonard Bocour (March 18, 1910 – September 6, 1993) was an American artist. Bocour was born in New York City. Around 1933, he formed the New York City based company Bocour Artists Colors. He was the co-developer along with Sam Golden of Ma ...
and
Sam Golden Sam Golden (May 20, 1915 – March 11, 1997) started his paintmaking career in 1936 at Bocour Artist Colors with his uncle Leonard Bocour. In 1947, he developed Magna paint, the world's first artist acrylic paint. He returned from retirement in 1 ...
invented a solution acrylic paint under the brand
Magna paint Magna is the brand name of an acrylic resin paint, developed by Leonard Bocour and sold by Bocour Artist Colors, Inc. in 1947. It is somewhat different from modern acrylic paint, as it is composed of pigments ground in an acrylic resin brought int ...
. These were mineral spirit-based paints. Water-based acrylic paints were subsequently sold as
latex Latex is an emulsion (stable dispersion) of polymer microparticles in water. Latexes are found in nature, but synthetic latexes are common as well. In nature, latex is found as a milky fluid found in 10% of all flowering plants (angiosperms ...
house paints. Soon after the water-based acrylic binders were introduced as house paints, artists and companies alike began to explore the potential of the new binders.
Diego Rivera Diego María de la Concepción Juan Nepomuceno Estanislao de la Rivera y Barrientos Acosta y Rodríguez, known as Diego Rivera (; December 8, 1886 – November 24, 1957), was a prominent Mexican painter. His large frescoes helped establish the ...
, David Alfaro Siqueiros, and José Clemente Orozco were the first ones who experimented with acrylic paint. This is because they were very impressed with the durability of the acrylic paint. Because of this, artists and companies alike began to produce Politic Acrylic Artists' Colors in Mexico in 1953. According to ''The Times'' newspaper, Lancelot Ribeiro pioneered the use of acrylic paints in the UK because of his "increasing impatience" by the 1960s over the time it took for oil paints to dry, as also its "lack of brilliance in its colour potential." He took to the new synthetic plastic bases that commercial paints were beginning to use, and soon got help from manufacturers like ICI, Courtaulds and
Geigy Novartis AG is a Swiss-American multinational pharmaceutical corporation based in Basel, Switzerland and Cambridge, Massachusetts, United States (global research).name="novartis.com">https://www.novartis.com/research-development/research-loca ...
. The companies supplied him samples of their latest paints in quantities that he was using three decades later, according to the paper. Initially, the firms thought the PVA compounds would not be needed in commercially viable quantities. But they quickly recognised the potential demand and "so Ribeiro became the godfather of generations of artists using acrylics as an alternative to oils." In 1956, José L. Gutiérrez produced ''Politec Acrylic Artists' Colors'' in Mexico,Sandra Zetina et al. (2020)
Painting with Acrylics: José Gutiérrez, Gunther Gerzso and the Material Innovation in Mexican Contemporary Painting
in: ''Science and Art: The Contemporary Painted Surface'', Antonio Sgamellotti et al. (eds.), Royal Society of Chemistry. Retrieved 8 June 2021.

, Politec. Retrieved 8 June 2021.
and Henry Levison of Cincinnati-based Permanent Pigments Co. produced
Liquitex Liquitex is a US company that supplies art materials, focusing exclusively on the development, manufacture and distribution of acrylic paints. Founded by Henry Levison as "Permanent Pigments" in 1955, the company created the first water-based acr ...
colors. These two product lines were the first acrylic emulsion artists' paints, with modern high-viscosity paints becoming available in the early 1960s. Following that development, Golden came up with a waterborne acrylic paint called "Aquatec". In 1963, George Rowney (part of
Daler-Rowney Daler-Rowney Ltd is an England, English list of art media, art materials manufacturer based in Bracknell. The company, a subsidiary of conglomerate F.I.L.A. (company), F.I.L.A. Group, manufactures and commercialises a wide range of artist product ...
since 1983) was the first manufacturer to introduce artists' acrylic paints in Europe, under the brand name "Cryla".


Painting with acrylics

Acrylic painters can modify the appearance, hardness, flexibility, texture, and other characteristics of the paint surface by using acrylic mediums or simply by adding water. Watercolor and oil painters also use various mediums, but the range of acrylic mediums is much greater. Acrylics have the ability to bond to many different surfaces, and mediums can be used to modify their binding characteristics. Acrylics can be used on paper, canvas, and a range of other materials; however, their use on engineered woods such as
medium-density fiberboard Medium-density fibreboard (MDF) is an engineered wood product made by breaking down hardwood or softwood residuals into wood fibres, often in a defibrator, combining it with wax and a resin binder, and forming it into panels by applying high te ...
can be problematic because of the porous nature of those surfaces. In these cases, it is recommended that the surface first be sealed with an appropriate sealer. Acrylics can be applied in thin layers or washes to create effects that resemble watercolors and other water-based mediums. They can also be used to build thick layers of paint — gel and molding paste are sometimes used to create paintings with relief features. Acrylic paints are also used in hobbies such as trains, cars, houses, DIY projects, and human models. People who make such models use acrylic paint to build facial features on dolls or raised details on other types of models. Wet acrylic paint is easily removed from paintbrushes and skin with water, whereas oil paints require the use of a hydrocarbon. Acrylics are the most common paints used in grattage, a surrealist technique that began to be used with the advent of this type of paint. Acrylics are used for this purpose because they easily scrape or peel from a surface.


Painting techniques

Acrylic artists' paints may be thinned with water or acrylic medium and used as washes in the manner of watercolor paints, but unlike watercolor the washes are not rehydratable once dry. For this reason, acrylics do not lend themselves to the color lifting techniques of
gum arabic Gum arabic, also known as gum sudani, acacia gum, Arabic gum, gum acacia, acacia, Senegal gum, Indian gum, and by other names, is a natural gum originally consisting of the hardened sap of two species of the ''Acacia'' tree, '' Senegalia se ...
-based watercolor paints. Instead, the paint is applied in layers, sometimes diluting with water or acrylic medium to allow layers underneath to partially show through. Using an acrylic medium gives the paint more of a rich and glossy appearance, whereas using water makes the paint look more like watercolor and have a matte finish. Acrylic paints with gloss or matte finishes are common, although a satin (semi-matte) sheen is most common. Some brands exhibit a range of finishes (e.g. heavy-body paints from Golden,
Liquitex Liquitex is a US company that supplies art materials, focusing exclusively on the development, manufacture and distribution of acrylic paints. Founded by Henry Levison as "Permanent Pigments" in 1955, the company created the first water-based acr ...
, Winsor & Newton and
Daler-Rowney Daler-Rowney Ltd is an England, English list of art media, art materials manufacturer based in Bracknell. The company, a subsidiary of conglomerate F.I.L.A. (company), F.I.L.A. Group, manufactures and commercialises a wide range of artist product ...
); Politec acrylics are fully matte. As with oils, pigment amounts and particle size or shape can affect the paint sheen. Matting agents can also be added during manufacture to dull the finish. If desired, the artist can mix different media with their paints and use topcoats or varnishes to alter or unify sheen. When dry, acrylic paint is generally non-removable from a solid surface if it adheres to the surface. Water or mild solvents do not re-solubilize it, although
isopropyl alcohol Isopropyl alcohol (IUPAC name propan-2-ol and also called isopropanol or 2-propanol) is a colorless, flammable organic compound with a pungent alcoholic odor. As an isopropyl group linked to a hydroxyl group ( chemical formula ) it is the s ...
can lift some fresh paint films off.
Toluene Toluene (), also known as toluol (), is a substituted aromatic hydrocarbon. It is a colorless, water-insoluble liquid with the smell associated with paint thinners. It is a mono-substituted benzene derivative, consisting of a methyl group (CH3) a ...
and
acetone Acetone (2-propanone or dimethyl ketone), is an organic compound with the formula . It is the simplest and smallest ketone (). It is a colorless, highly volatile and flammable liquid with a characteristic pungent odour. Acetone is miscib ...
can remove paint films, but they do not lift paint stains very well and are not selective. The use of a solvent to remove paint may result in removal of all of the paint layers (acrylic
gesso Gesso (; "chalk", from the la, gypsum, from el, γύψος) is a white paint mixture consisting of a binder mixed with chalk, gypsum, pigment, or any combination of these. It is used in painting as a preparation for any number of substrates suc ...
, et cetera). Oils and warm, soapy water can remove acrylic paint from skin. Acrylic paint can be removed from non-porous plastic surfaces, such as miniatures or models using certain cleaning products such as Dettol (containing chloroxylenol 4.8% v/w). An acrylic sizing should be used to prime canvas in preparation for painting with acrylic paints, to prevent Support Induced Discoloration (SID). Acrylic paint contains surfactants that can pull up discoloration from a raw canvas, especially in transparent glazed or translucent gelled areas. Gesso alone will not stop SID; a sizing must be applied before using a gesso. The viscosity of acrylic can be successfully reduced by using suitable extenders that maintain the integrity of the paint film. There are retarders to slow drying and extend ''workability'' time, and ''flow releases'' to increase color-blending ability.


Properties


Grades

Commercial acrylic paints come in two grades by manufacturers: * Artist acrylics (professional acrylics) are created and designed to resist chemical reactions from exposure to water, ultraviolet light, and oxygen. Professional-grade acrylics have the most pigment, which allows for more medium manipulation and limits the color shift when mixed with other colors or after drying. * Student acrylics have working characteristics similar to artist acrylics, but with lower pigment concentrations, less-expensive formulas, and fewer available colors. More expensive pigments are generally replicated by hues. Colors are designed to be mixed even though color strength is lower. Hues may not have exactly the same mixing characteristics as full-strength colors.


Varieties

*Heavy body acrylics are typically found in the Artist and Student Grade paints. "Heavy Body" refers to the viscosity or thickness of the paint. They are the best choice for impasto or heavier paint applications and will hold a brush or knife stroke and even a medium stiff peak. Gel Mediums ("pigment-less paints") are also available in various viscosities and used to thicken or thin paints, as well as extend paints and add transparency. **Examples of Heavy Body Acrylics are Matisse Structure Acrylic Colors, Lukas Pastos Acrylics, Liquitex Heavy Body Acrylics and Golden Heavy Body Acrylics. *Medium viscosity acrylics – Fluid acrylics, Soft body acrylics, or High Flow acrylics – have a lower viscosity but generally the same pigmentation as the Heavy Body acrylics. Available in either Artist quality or Craft quality, the cost and quality vary accordingly. These paints are good for watercolor techniques, airbrush application, or when smooth coverage is desired. Fluid acrylics can be mixed with any medium to thicken them for impasto work, or to thin them for glazing applications. **Examples of fluid acrylics include Lukascryl Liquid, Lukascryl Studio, Liquitex Soft Body and Golden Fluid acrylics. *Open acrylics were created to address the one major difference between oil and acrylic paints: the shortened time it takes acrylic paints to dry. Designed by Golden Artist Colors, Inc. with a hydrophilic acrylic resin, these paints can take anywhere from a few hours to a few days, or even weeks, to dry completely, depending on paint thickness, support characteristics, temperature, and humidity. *Iridescent, pearl and interference acrylic colors combine conventional pigments with powdered mica ( aluminium silicate) or powdered bronze to achieve complex visual effects. Colors have shimmering or reflective characteristics, depending on the coarseness or fineness of the powder. Iridescent colors are used in fine arts and crafts. *Acrylic gouache is like traditional gouache because it dries to a matte, opaque finish. However, unlike traditional gouache, the acrylic binder makes it water-resistant once it dries. Like craft paint, it will adhere to a variety of surfaces, not only canvas and paper. This paint is typically used by water-colorists, cartoonists, or illustrators, and for decorative or
folk art Folk art covers all forms of visual art made in the context of folk culture. Definitions vary, but generally the objects have practical utility of some kind, rather than being exclusively decorative. The makers of folk art are typically tr ...
applications. **Examples of acrylic gouache are Lascaux Gouache and Turner Acryl Gouache. *Craft acrylics can be used on surfaces besides canvas, such as wood, metal, fabrics, and ceramics. They are used in decorative painting techniques and faux finishes to decorate objects of ordinary life. Although colors can be mixed, pigments are often not specified. Each color line is formulated instead to achieve a wide range of premixed colors. Craft paints usually employ vinyl or PVA resins to increase adhesion and lower cost. *Interactive acrylics are all-purpose acrylic artists' colors which have the characteristic fast-drying nature of artists' acrylics, but are formulated to allow artists to delay drying when they need more working time, or re-wet their work when they want to do more wet blending. *Exterior acrylics are paints that can withstand outdoor conditions. Like craft acrylics, they adhere to many surfaces. They are more resistant to both water and ultraviolet light. This makes them the acrylic of choice for architectural murals, outdoor signs, and many faux-finishing techniques. *Acrylic glass paint is water-based and semi-permanent, making it a suitable paint for temporary displays on glass windows. *Acrylic enamel paint creates a smooth, hard shell. It can be oven-baked or air dried. It can be permanent if kept away from harsh conditions such as dishwashing.


Differences between acrylic and oil paint

The vehicle and binder of
oil paint Oil paint is a type of slow-drying paint that consists of particles of pigment suspended in a drying oil, commonly linseed oil. The viscosity of the paint may be modified by the addition of a solvent such as turpentine or white spirit, and va ...
s is linseed oil (or another
drying oil A drying oil is an oil that hardens to a tough, solid film after a period of exposure to air, at room temperature. The oil hardens through a chemical reaction in which the components crosslink (and hence, polymerize) by the action of oxygen (no ...
), whereas acrylic paint has water as the vehicle for an
emulsion An emulsion is a mixture of two or more liquids that are normally immiscible (unmixable or unblendable) owing to liquid-liquid phase separation. Emulsions are part of a more general class of two-phase systems of matter called colloids. Altho ...
(suspension) of acrylic polymer, which serves as the binder. Thus, oil paint is said to be "oil-based", whereas acrylic paint is "water-based" (or sometimes "water-borne"). The main practical difference between most acrylics and oil paints is the inherent drying time. Oils allow for more time to blend colors and apply even glazes over
underpainting In art, an underpainting is an initial layer of paint applied to a ground, which serves as a base for subsequent layers of paint. Underpaintings are often monochromatic and help to define color values for later painting. Underpainting gets its name ...
s. This slow-drying aspect of oil can be seen as an advantage for certain techniques, but it impedes an artist trying to work quickly. The fast evaporation of water from regular acrylic paint films can be slowed with the use of
acrylic retarder In painting, a retarder is a substance, usually a glycol and usually added to water, that is used to slow the drying time of acrylic paints, giving more time for Mixing (process engineering), blending or layering Specular highlight, highlights. Us ...
s. Retarders are generally glycol or glycerin-based additives. The addition of a retarder slows the evaporation rate of the water. Oil paints may require the use of solvents such as mineral spirits or
turpentine Turpentine (which is also called spirit of turpentine, oil of turpentine, terebenthene, terebinthine and (colloquially) turps) is a fluid obtained by the distillation of resin harvested from living trees, mainly pines. Mainly used as a spec ...
to thin the paint and clean up. These solvents generally have some level of toxicity and can be found objectionable. Relatively recently, water-miscible oil paints have been developed for artists' use. Oil paint films can gradually yellow and lose their flexibility over time creating cracks in the paint film; the " fat over lean" rule must be observed to ensure its durability. Oil paint has a higher pigment load than acrylic paint. As linseed oil contains a smaller molecule than acrylic paint, oil paint is able to absorb substantially more pigment. Oil provides a
refractive index In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium. The refractive index determines how much the path of light is bent, or ...
that is less clear than acrylic dispersions, which imparts a unique "look and feel" to the resultant paint film. Not all the pigments of oil paints are available in acrylics and vice versa, as each medium has different chemical sensitivities. Some historical pigments are alkali sensitive, and therefore cannot be made in an acrylic emulsion; others are just too difficult to formulate. Approximate "hue" color formulations, that do not contain the historical pigments, are typically offered as substitutes. Because of acrylic paint's more flexible nature and more consistent drying time between layers, an artist does not have to follow the same rules of oil painting, where more medium must be applied to each layer to avoid cracking. It usually takes 10–20 minutes for one to two layers of acrylic paint to dry, depending on the brand, quality, and humidity levels of the surrounding environment. Some professional grades of acrylic paint can take 20-30 minutes or even more than an hour. Although canvas needs to be properly primed before painting with oils to prevent the paint medium from eventually rotting the canvas, acrylic can be safely applied straight to the canvas. The rapid drying of acrylic paint tends to discourage blending of color and use of wet-in-wet technique as in oil painting. Even though acrylic retarders can slow drying time to several hours, it remains a relatively fast-drying medium and adding too much acrylic retarder can prevent the paint from ever drying properly. Meanwhile, acrylic paint is very elastic, which prevents cracking from occurring. Acrylic paint's binder is acrylic polymer emulsion – as this binder dries, the paint remains flexible. Another difference between oil and acrylic paints is the versatility offered by acrylic paints. Acrylics are very useful in mixed media, allowing the use of pastel (oil and chalk), charcoal and pen (among others) on top of the dried acrylic painted surface. Mixing other bodies into the acrylic is possible—sand, rice, and even pasta may be incorporated in the artwork. Mixing artist or student grade acrylic paint with household acrylic emulsions is possible, allowing the use of premixed tints straight from the tube or tin, and thereby presenting the painter with a vast color range at their disposal. This versatility is also illustrated by the variety of additional artistic uses for acrylics. Specialized acrylics have been manufactured and used for linoblock printing (acrylic
block printing Woodblock printing or block printing is a technique for printing text, images or patterns used widely throughout East Asia and originating in China in antiquity as a method of printing on textiles and later paper. Each page or image is create ...
ink has been produced by Derivan since the early 1980s), face painting,
airbrushing An airbrush is a small, Pneumatics, air-operated tool that Atomizer nozzle, atomizes and sprays various media, most often paint but also ink and dye, and Foundation (cosmetics), foundation. Spray painting developed from the airbrush and is c ...
,
watercolor Watercolor (American English) or watercolour (British English; see spelling differences), also ''aquarelle'' (; from Italian diminutive of Latin ''aqua'' "water"), is a painting method”Watercolor may be as old as art itself, going back to ...
-like techniques, and fabric screen printing. Another difference between oil and acrylic paint is the cleanup. Acrylic paint can be cleaned out of a brush with any soap, while oil paint needs a specific type to be sure to get all the oil out of the brushes. Also, it is easier to let a palette with oil paint dry and then scrape the paint off, whereas one can easily clean wet acrylic paint with water.


Difference between acrylic and watercolor paint

The biggest difference is that acrylic paint is opaque, whereas
watercolor Watercolor (American English) or watercolour (British English; see spelling differences), also ''aquarelle'' (; from Italian diminutive of Latin ''aqua'' "water"), is a painting method”Watercolor may be as old as art itself, going back to ...
paint is translucent in nature. Watercolors take about 5 to 15 minutes to dry while acrylics take about 10 to 20 minutes. In order to change the tone or shade of a watercolor pigment, you change the percentage of water mixed in to the color. For brighter colors, add more water. For darker colors, add less water. In order to create lighter or darker colors with acrylic paints, you add white or black. Another difference is that watercolors must be painted onto a porous surface, primarily watercolor paper. Acrylic paints can be used on many different surfaces. Both acrylic and watercolor are easy to clean up with water. Acrylic paint should be cleaned with soap and water immediately following use. Watercolor paint can be cleaned with just water.Why WaterColo

accessed August 21, 2020


See also

*


Notes and references


External links


National Acrylic Painter's Association

Handling and Care Tips for paintings
{{DEFAULTSORT:Acrylic Paint American inventions Visual arts materials Paints Watermedia