Uranopilite
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Uranopilite is a minor
ore Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 Apr ...
of
uranium Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...
with the chemistry ( U O2)6 SO4(O H)6O2·14 H2O or, hydrated uranyl sulfate hydroxide. As with many uranyl minerals, it is
fluorescent Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore a lower photon energy, ...
and
radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consi ...
. It is straw yellow in normal light. Uranopilite fluoresces a bright green under
ultraviolet light Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nanometer, nm (with a corresponding frequency around 30 Hertz, PHz) to 400 nm (750 Hertz, THz), shorter than that of visible light, but longer than ...
. Uranopilite contains clusters of six uranyl pentagonal bipyramids that share equatorial edges and vertices, with the clusters cross-linked to form chains by sharing vertices with sulfate tetrahedra. In uranopilite, the chains are linked directly by hydrogen bonds, as well as to interstitial H2O groups. Uranopilite is associated with other uranyl minerals such as zippeite and johannite and, like them, is usually found as an
efflorescent In chemistry, efflorescence (which means "to flower out" in French) is the migration of a salt to the surface of a porous material, where it forms a coating. The essential process involves the dissolving of an internally held salt in water, o ...
crust in uranium mines. Notable occurrences include: *
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* San Juan County,
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See also

*
Uranyl sulfate Uranyl sulfate describes a family of inorganic compounds with the formula UO2SO4(H2O)n. These salts consist of sulfate, the uranyl ion, and water. They are lemon-yellow solids. Uranyl sulfates are intermediates in some extraction methods used for ...
*
List of minerals This is a list of minerals for which there are articles on Wikipedia. Minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various ''species''. Within a m ...


References


Progress in Solid State Chemistry

ATHENA MINERAL: Mineral Data
Uranium(VI) minerals Sulfate minerals Triclinic minerals Minerals in space group 2 {{Sulfate-mineral-stub