In
statistical mechanics
In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. It does not assume or postulate any natural laws, but explains the macroscopic be ...
, an Ursell function or connected correlation function, is a
cumulant
In probability theory and statistics, the cumulants of a probability distribution are a set of quantities that provide an alternative to the '' moments'' of the distribution. Any two probability distributions whose moments are identical will ha ...
of a
random variable
A random variable (also called random quantity, aleatory variable, or stochastic variable) is a mathematical formalization of a quantity or object which depends on random events. It is a mapping or a function from possible outcomes (e.g., the po ...
. It can often be obtained by summing over connected
Feynman diagram
In theoretical physics, a Feynman diagram is a pictorial representation of the mathematical expressions describing the behavior and interaction of subatomic particles. The scheme is named after American physicist Richard Feynman, who introduc ...
s (the sum over all Feynman diagrams gives the
correlation function
A correlation function is a function that gives the statistical correlation between random variables, contingent on the spatial or temporal distance between those variables. If one considers the correlation function between random variables rep ...
s).
The Ursell function was named after
Harold Ursell, who introduced it in 1927.
Definition
If ''X'' is a random variable, the
moment
Moment or Moments may refer to:
* Present time
Music
* The Moments, American R&B vocal group Albums
* ''Moment'' (Dark Tranquillity album), 2020
* ''Moment'' (Speed album), 1998
* ''Moments'' (Darude album)
* ''Moments'' (Christine Guldbrand ...
s ''s''
''n'' and cumulants (same as the Ursell functions) ''u''
''n'' are functions of ''X'' related by the
exponential formula In combinatorial mathematics, the exponential formula (called the polymer expansion in physics) states that the exponential generating function for structures on finite sets is the exponential of the exponential generating function for connected str ...
:
:
(where
is the
expectation
Expectation or Expectations may refer to:
Science
* Expectation (epistemic)
* Expected value, in mathematical probability theory
* Expectation value (quantum mechanics)
* Expectation–maximization algorithm, in statistics
Music
* ''Expectation' ...
).
The Ursell functions for multivariate random variables are defined analogously to the above, and in the same way as multivariate cumulants.
:
The Ursell functions of a single random variable ''X'' are obtained from these by setting .
The first few are given by
:
Characterization
showed that the Ursell functions, considered as multilinear functions of several random variables, are uniquely determined up to a constant by the fact that they vanish whenever the variables ''X''
''i'' can be divided into two nonempty independent sets.
See also
*
Cumulant
In probability theory and statistics, the cumulants of a probability distribution are a set of quantities that provide an alternative to the '' moments'' of the distribution. Any two probability distributions whose moments are identical will ha ...
References
*
*
*{{citation, first=H. D. , last=Ursell, title=The evaluation of Gibbs phase-integral for imperfect gases, journal=Proc. Cambridge Philos. Soc., volume=23 , year=1927, issue=6, pages=685–697, doi=10.1017/S0305004100011191, bibcode=1927PCPS...23..685U, s2cid=123023251
Statistical mechanics
Theory of probability distributions