HOME

TheInfoList



OR:

Tholins (after the Greek (') "hazy" or "muddy"; from the
ancient Greek Ancient Greek includes the forms of the Greek language used in ancient Greece and the ancient world from around 1500 BC to 300 BC. It is often roughly divided into the following periods: Mycenaean Greek (), Dark Ages (), the Archaic pe ...
word meaning "sepia ink") are a wide variety of
organic compounds In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The s ...
formed by solar
ultraviolet Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nm (with a corresponding frequency around 30  PHz) to 400 nm (750  THz), shorter than that of visible light, but longer than X-rays. UV radiation ...
or
cosmic ray Cosmic rays are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar System in our own ...
irradiation of simple carbon-containing compounds such as
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is t ...
(),
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane ...
() or
ethane Ethane ( , ) is an organic chemical compound with chemical formula . At standard temperature and pressure, ethane is a colorless, odorless gas. Like many hydrocarbons, ethane is isolated on an industrial scale from natural gas and as a petroc ...
(), often in combination with
nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
() or
water Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as ...
().Sarah Hörs
"What in the world(s) are tholins?"
Planetary Society, July 23, 2015. Retrieved 30 Nov 2016.
Tholins are disordered polymer-like materials made of repeating chains of linked subunits and complex combinations of functional groups, typically
nitrile In organic chemistry, a nitrile is any organic compound that has a functional group. The prefix '' cyano-'' is used interchangeably with the term ''nitrile'' in industrial literature. Nitriles are found in many useful compounds, including me ...
s and
hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ...
s and their degraded forms such as
amine In chemistry, amines (, ) are compounds and functional groups that contain a basic nitrogen atom with a lone pair. Amines are formally derivatives of ammonia (), wherein one or more hydrogen atoms have been replaced by a substituent ...
s and
phenyl In organic chemistry, the phenyl group, or phenyl ring, is a cyclic group of atoms with the formula C6 H5, and is often represented by the symbol Ph. Phenyl group is closely related to benzene and can be viewed as a benzene ring, minus a hydrogen ...
s. Tholins do not form naturally on modern-day
Earth Earth is the third planet from the Sun and the only astronomical object known to harbor life. While large volumes of water can be found throughout the Solar System, only Earth sustains liquid surface water. About 71% of Earth's sur ...
, but they are found in great abundance on the surfaces of icy bodies in the outer
Solar System The Solar System Capitalization of the name varies. The International Astronomical Union, the authoritative body regarding astronomical nomenclature, specifies capitalizing the names of all individual astronomical objects but uses mixed "Solar ...
, and as reddish
aerosol An aerosol is a suspension of fine solid particles or liquid droplets in air or another gas. Aerosols can be natural or anthropogenic. Examples of natural aerosols are fog or mist, dust, forest exudates, and geyser steam. Examples of anthropogen ...
s in the atmospheres of outer Solar System planets and moons. In the presence of water, tholins could be raw materials for prebiotic chemistry (i.e., the non-living chemistry that forms the basic chemicals of which life is made). Their existence has implications for the
origins of life In biology, abiogenesis (from a- 'not' + Greek bios 'life' + genesis 'origin') or the origin of life is the natural process by which life has arisen from non-living matter, such as simple organic compounds. The prevailing scientific hypot ...
on Earth and possibly on other planets. As particles in an atmosphere, tholins scatter light, and can affect
habitability Habitability refers to the adequacy of an environment for human living. Where housing is concerned, there are generally local ordinances which define habitability. If a residence complies with those laws it is said to be habitable. In extreme e ...
. Tholins may be produced in a laboratory, and are usually studied as a heterogeneous mixture of many chemicals with many different structures and properties. Using techniques like
thermogravimetric analysis Thermogravimetric analysis or thermal gravimetric analysis (TGA) is a method of thermal analysis in which the mass of a sample is measured over time as the temperature changes. This measurement provides information about physical phenomena, such ...
, astrochemists analyze the composition of these tholin mixtures, and the exact character of the individual chemicals within them.


Overview

The term "tholin" was coined by astronomer
Carl Sagan Carl Edward Sagan (; ; November 9, 1934December 20, 1996) was an American astronomer, planetary scientist, cosmologist, astrophysicist, astrobiologist, author, and science communicator. His best known scientific contribution is research on ex ...
and his colleague
Bishun Khare Bishun Narain Khare (27 June 1933 – 20 August 2013) was a scientist who specialized in the chemistry of planetary atmospheres and of molecules relevant to biology. He published several papers on tholins, the organic molecules formed by ultrav ...
to describe the difficult-to-characterize substances they obtained in his Miller–Urey-type experiments on the methane-containing gas mixtures such as those found in Titan's atmosphere. Their paper proposing the name "tholin" said:
For the past decade we have been producing in our laboratory a variety of complex organic solids from mixtures of the cosmically abundant gases , , , , HCHO, and . The product, synthesized by ultraviolet (UV) light or spark discharge, is a brown, sometimes sticky, residue, which has been called, because of its resistance to conventional analytical chemistry, "intractable polymer". ..We propose, as a model-free descriptive term, 'tholins' (Gk Θὸλος, muddy; but also Θoλòς, vault or dome), although we were tempted by the phrase 'star-tar'.
Tholins are not one specific compound but rather are descriptive of a spectrum of molecules, including
heteropolymer In polymer chemistry, a copolymer is a polymer derived from more than one species of monomer. The polymerization of monomers into copolymers is called copolymerization. Copolymers obtained from the copolymerization of two monomer species are ...
s, that give a reddish, organic surface covering on certain planetary surfaces. Tholins are disordered polymer-like materials made of repeating chains of linked subunits and complex combinations of functional groups. Sagan and Khare note "The properties of tholins will depend on the energy source used and the initial abundances of precursors, but a general physical and chemical similarity among the various tholins is evident." Some researchers in the field prefer a narrowed definition of tholins, for example S. Hörst wrote: "Personally, I try to use the word 'tholins' only when describing the laboratory-produced samples, in part because we do not really know yet how similar the material we produce in the lab is to the material found on places like Titan or Triton (or Pluto!)." French researchers also use the term tholins only when describing the laboratory-produced samples as analogues. NASA scientists also prefer the word 'tholin' for the products of laboratory simulations, and use the term 'refractory residues' for actual observations on astronomical bodies.


Formation

Tholins may be a major constituent of the
interstellar medium In astronomy, the interstellar medium is the matter and radiation that exist in the space between the star systems in a galaxy. This matter includes gas in ionic, atomic, and molecular form, as well as dust and cosmic rays. It fills interstella ...
. On Titan, their chemistry is initiated at high altitudes and participates in the formation of solid organic particles. Their key elements are carbon, nitrogen, and hydrogen. Laboratory infrared spectroscopy analysis of experimentally synthetized tholins has confirmed earlier identifications of chemical groups present, including primary
amine In chemistry, amines (, ) are compounds and functional groups that contain a basic nitrogen atom with a lone pair. Amines are formally derivatives of ammonia (), wherein one or more hydrogen atoms have been replaced by a substituent ...
s,
nitrile In organic chemistry, a nitrile is any organic compound that has a functional group. The prefix '' cyano-'' is used interchangeably with the term ''nitrile'' in industrial literature. Nitriles are found in many useful compounds, including me ...
s, and
alkyl In organic chemistry, an alkyl group is an alkane missing one hydrogen. The term ''alkyl'' is intentionally unspecific to include many possible substitutions. An acyclic alkyl has the general formula of . A cycloalkyl is derived from a cycloa ...
portions such as / forming complex disordered macromolecular solids. Laboratory tests generated complex solids formed from exposure of : gaseous mixtures to electrical discharge in cold plasma conditions, reminiscent of the famous
Miller–Urey experiment The Miller–Urey experiment (or Miller experiment) is a famous chemistry experiment that simulated the conditions thought at the time (1952) to be present in the atmosphere of the early, prebiotic Earth, in order to test the hypothesis of the ...
conducted in 1952. As illustrated to the right, tholins are thought to form in nature through a chain of chemical reactions known as
pyrolysis The pyrolysis (or devolatilization) process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. It involves a change of chemical composition. The word is coined from the Greek-derived elements '' ...
and
radiolysis Radiolysis is the dissociation of molecules by ionizing radiation. It is the cleavage of one or several chemical bonds resulting from exposure to high-energy flux. The radiation in this context is associated with ionizing radiation; radiolysis is ...
. This begins with the dissociation and
ionization Ionization, or Ionisation is the process by which an atom or a molecule acquires a negative or positive charge by gaining or losing electrons, often in conjunction with other chemical changes. The resulting electrically charged atom or molecul ...
of molecular
nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
() and
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane ...
() by energetic particles and solar radiation. This is followed by the formation of
ethylene Ethylene (IUPAC name: ethene) is a hydrocarbon which has the formula or . It is a colourless, flammable gas with a faint "sweet and musky" odour when pure. It is the simplest alkene (a hydrocarbon with carbon-carbon double bonds). Ethylene ...
,
ethane Ethane ( , ) is an organic chemical compound with chemical formula . At standard temperature and pressure, ethane is a colorless, odorless gas. Like many hydrocarbons, ethane is isolated on an industrial scale from natural gas and as a petroc ...
,
acetylene Acetylene ( systematic name: ethyne) is the chemical compound with the formula and structure . It is a hydrocarbon and the simplest alkyne. This colorless gas is widely used as a fuel and a chemical building block. It is unstable in its pure ...
,
hydrogen cyanide Hydrogen cyanide, sometimes called prussic acid, is a chemical compound with the formula HCN and structure . It is a colorless, extremely poisonous, and flammable liquid that boils slightly above room temperature, at . HCN is produced on a ...
, and other small simple molecules and small positive ions. Further reactions form
benzene Benzene is an organic chemical compound with the molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar ring with one hydrogen atom attached to each. Because it contains only carbon and hydrogen atoms ...
and other organic molecules, and their polymerization leads to the formation of an aerosol of heavier molecules, which then condense and precipitate on the planetary surface below. Tholins formed at low pressure tend to contain nitrogen atoms in the interior of their molecules, while tholins formed at high pressure are more likely to have nitrogen atoms located in terminal positions. These atmospherically-derived substances are distinct from ''ice tholin II'', which are formed instead by irradiation (
radiolysis Radiolysis is the dissociation of molecules by ionizing radiation. It is the cleavage of one or several chemical bonds resulting from exposure to high-energy flux. The radiation in this context is associated with ionizing radiation; radiolysis is ...
) of
clathrate A clathrate is a chemical substance consisting of a lattice that traps or contains molecules. The word ''clathrate'' is derived from the Latin (), meaning ‘with bars, latticed’. Most clathrate compounds are polymeric and completely envelo ...
s of
water Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as ...
and organic compounds such as methane () or ethane (). The radiation-induced synthesis on ice are non-dependant on temperature.


Biological significance

Some researchers have speculated that Earth may have been seeded by organic compounds early in its development by tholin-rich comets, providing the raw material necessary for life to develop (see
Miller–Urey experiment The Miller–Urey experiment (or Miller experiment) is a famous chemistry experiment that simulated the conditions thought at the time (1952) to be present in the atmosphere of the early, prebiotic Earth, in order to test the hypothesis of the ...
for discussion related to this). Tholins do not exist naturally on present-day Earth due to the oxidizing properties of the free oxygen component of its atmosphere ever since the
Great Oxygenation Event The Great Oxidation Event (GOE), also called the Great Oxygenation Event, the Oxygen Catastrophe, the Oxygen Revolution, the Oxygen Crisis, or the Oxygen Holocaust, was a time interval during the Paleoproterozoic era when the Earth's atmospher ...
around 2.4 billion years ago. Laboratory experiments suggest that tholins near large pools of liquid water that might persist for thousands of years could facilitate the formation of prebiotic chemistry to take place, and has implications on the
origins of life In biology, abiogenesis (from a- 'not' + Greek bios 'life' + genesis 'origin') or the origin of life is the natural process by which life has arisen from non-living matter, such as simple organic compounds. The prevailing scientific hypot ...
on Earth and possibly other planets. Also, as particles in the atmosphere of an
exoplanet An exoplanet or extrasolar planet is a planet outside the Solar System. The first possible evidence of an exoplanet was noted in 1917 but was not recognized as such. The first confirmation of detection occurred in 1992. A different planet, init ...
, tholins affect the light scatter and act as a screen for protecting planetary surfaces from
ultraviolet Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nm (with a corresponding frequency around 30  PHz) to 400 nm (750  THz), shorter than that of visible light, but longer than X-rays. UV radiation ...
radiation, affecting
habitability Habitability refers to the adequacy of an environment for human living. Where housing is concerned, there are generally local ordinances which define habitability. If a residence complies with those laws it is said to be habitable. In extreme e ...
. Laboratory simulations found derived residues related to
amino acid Amino acids are organic compounds that contain both amino and carboxylic acid functional groups. Although hundreds of amino acids exist in nature, by far the most important are the alpha-amino acids, which comprise proteins. Only 22 alpha ...
s as well as
urea Urea, also known as carbamide, is an organic compound with chemical formula . This amide has two amino groups (–) joined by a carbonyl functional group (–C(=O)–). It is thus the simplest amide of carbamic acid. Urea serves an important ...
, with important astrobiological implications. On Earth, a wide variety of
soil bacteria Soil microbiology is the study of microorganisms in soil, their functions, and how they affect soil properties. It is believed that between two and four billion years ago, the first ancient bacteria and microorganisms came about on Earth's oceans. ...
are able to use laboratory-produced tholins as their sole source of carbon. Tholins could have been the first microbial food for
heterotroph A heterotroph (; ) is an organism that cannot produce its own food, instead taking nutrition from other sources of organic carbon, mainly plant or animal matter. In the food chain, heterotrophs are primary, secondary and tertiary consumers, but ...
ic microorganisms before
autotroph An autotroph or primary producer is an organism that produces complex organic compounds (such as carbohydrates, fats, and proteins) using carbon from simple substances such as carbon dioxide,Morris, J. et al. (2019). "Biology: How Life Wo ...
y evolved.


Occurrence

Sagan and Khare note the presence of tholins through multiple locations: "as a constituent of the Earth's primitive oceans and therefore relevant to the
origin of life In biology, abiogenesis (from a- 'not' + Greek bios 'life' + genesis 'origin') or the origin of life is the natural process by which life has arisen from non-living matter, such as simple organic compounds. The prevailing scientific hypothes ...
; as a component of red aerosols in the atmospheres of the outer planets and Titan; present in
comet A comet is an icy, small Solar System body that, when passing close to the Sun, warms and begins to release gases, a process that is called outgassing. This produces a visible atmosphere or coma, and sometimes also a tail. These phenomena ...
s, carbonaceous chondrites asteroids, and pre-planetary solar nebulae; and as a major constituent of the
interstellar medium In astronomy, the interstellar medium is the matter and radiation that exist in the space between the star systems in a galaxy. This matter includes gas in ionic, atomic, and molecular form, as well as dust and cosmic rays. It fills interstella ...
." The surfaces of comets,
centaur A centaur ( ; grc, κένταυρος, kéntauros; ), or occasionally hippocentaur, is a creature from Greek mythology with the upper body of a human and the lower body and legs of a horse. Centaurs are thought of in many Greek myths as bein ...
s, and many icy moons and Kuiper-belt objects in the outer Solar System are rich in deposits of tholins.


Moons


Titan

Titan Titan most often refers to: * Titan (moon), the largest moon of Saturn * Titans, a race of deities in Greek mythology Titan or Titans may also refer to: Arts and entertainment Fictional entities Fictional locations * Titan in fiction, fictiona ...
tholins are nitrogen-rich organic substances produced by the irradiation of the gaseous mixtures of nitrogen and methane found in the atmosphere and surface of Titan. Titan's atmosphere is about 97% nitrogen, 2.7±0.1% methane and the remaining trace amounts of other gases. In the case of Titan, the haze and orange-red color of its atmosphere are both thought to be caused by the presence of tholins.


Europa

Colored regions on Jupiter's satellite
Europa Europa may refer to: Places * Europe * Europa (Roman province), a province within the Diocese of Thrace * Europa (Seville Metro), Seville, Spain; a station on the Seville Metro * Europa City, Paris, France; a planned development * Europa Clif ...
are thought to be tholins. The morphology of Europa's impact craters and ridges is suggestive of fluidized material welling up from the fractures where
pyrolysis The pyrolysis (or devolatilization) process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. It involves a change of chemical composition. The word is coined from the Greek-derived elements '' ...
and
radiolysis Radiolysis is the dissociation of molecules by ionizing radiation. It is the cleavage of one or several chemical bonds resulting from exposure to high-energy flux. The radiation in this context is associated with ionizing radiation; radiolysis is ...
take place. In order to generate colored tholins on Europa there must be a source of materials (carbon, nitrogen, and water), and a source of energy to drive the reactions. Impurities in the water ice crust of Europa are presumed both to emerge from the interior as
cryovolcanic A cryovolcano (sometimes informally called an ice volcano) is a type of volcano that erupts volatiles such as water, ammonia or methane into an extremely cold environment that is at or below their freezing point. The process of formation is k ...
events that resurface the body, and to accumulate from space as interplanetary dust.


Rhea

The extensive dark areas on the trailing hemisphere of Saturn's moon Rhea are thought to be deposited tholins.


Triton

Neptune's moon
Triton Triton commonly refers to: * Triton (mythology), a Greek god * Triton (moon), a satellite of Neptune Triton may also refer to: Biology * Triton cockatoo, a parrot * Triton (gastropod), a group of sea snails * ''Triton'', a synonym of ''Triturus'' ...
is observed to have the reddish color characteristic of tholins. Triton's atmosphere is mostly nitrogen, with trace amounts of methane and carbon monoxide.


Dwarf planets


Pluto

Tholins occur on the
dwarf planet A dwarf planet is a small planetary-mass object that is in direct orbit of the Sun, smaller than any of the eight classical planets but still a world in its own right. The prototypical dwarf planet is Pluto. The interest of dwarf planets to ...
Pluto Pluto (minor-planet designation: 134340 Pluto) is a dwarf planet in the Kuiper belt, a ring of trans-Neptunian object, bodies beyond the orbit of Neptune. It is the ninth-largest and tenth-most-massive known object to directly orbit the S ...
and are responsible for red colors as well as the blue tint of the
atmosphere of Pluto The atmosphere of Pluto is the tenuous layer of gases surrounding Pluto. It consists mainly of nitrogen (N2), with minor amounts of methane (CH4) and carbon monoxide (CO), all of which are vaporized from their ices on Pluto's surface. It contain ...
. The reddish-brown cap of the north pole of
Charon In Greek mythology, Charon or Kharon (; grc, Χάρων) is a psychopomp, the ferryman of Hades, the Greek underworld. He carries the souls of those who have been given funeral rites across the rivers Acheron and Styx, which separate the ...
, the largest of five
moons of Pluto The dwarf planet Pluto has five natural satellites. In order of distance from Pluto, they are Charon, Styx, Nix, Kerberos, and Hydra. Charon, the largest, is mutually tidally locked with Pluto, and is massive enough that Pluto–Charon is some ...
, is thought to be composed of tholins, produced from methane, nitrogen and related gases released from the atmosphere of Pluto and transferred over about distance to the orbiting moon.


Ceres

Tholins were detected on the dwarf planet Ceres by the ''Dawn'' mission. Most of the planet's surface is extremely rich in carbon, with approximately 20% carbon by mass in its near surface. The carbon content is more than five times higher than in
carbonaceous chondrite Carbonaceous chondrites or C chondrites are a class of chondritic meteorites comprising at least 8 known groups and many ungrouped meteorites. They include some of the most primitive known meteorites. The C chondrites represent only a small prop ...
meteorites analyzed on Earth.


Makemake

Makemake Makemake (minor-planet designation 136472 Makemake) is a dwarf planet and – depending on how they are defined – the second-largest Kuiper belt object in the classical population, with a diameter approximately 60% that of Pluto. It h ...
exhibits
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane ...
, large amounts of
ethane Ethane ( , ) is an organic chemical compound with chemical formula . At standard temperature and pressure, ethane is a colorless, odorless gas. Like many hydrocarbons, ethane is isolated on an industrial scale from natural gas and as a petroc ...
and tholins, as well as smaller amounts of
ethylene Ethylene (IUPAC name: ethene) is a hydrocarbon which has the formula or . It is a colourless, flammable gas with a faint "sweet and musky" odour when pure. It is the simplest alkene (a hydrocarbon with carbon-carbon double bonds). Ethylene ...
,
acetylene Acetylene ( systematic name: ethyne) is the chemical compound with the formula and structure . It is a hydrocarbon and the simplest alkyne. This colorless gas is widely used as a fuel and a chemical building block. It is unstable in its pure ...
and high-mass
alkane In organic chemistry, an alkane, or paraffin (a historical trivial name that also has other meanings), is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in wh ...
s may be present, most likely created by
photolysis Photodissociation, photolysis, photodecomposition, or photofragmentation is a chemical reaction in which molecules of a chemical compound are broken down by photons. It is defined as the interaction of one or more photons with one target molecule. ...
of methane by solar radiation.


Kuiper belt objects and Centaurs

The reddish color typical of tholins is characteristic of many
Trans-Neptunian object A trans-Neptunian object (TNO), also written transneptunian object, is any minor planet in the Solar System that orbits the Sun at a greater average distance than Neptune, which has a semi-major axis of 30.1 astronomical units (au). Typically ...
s, including
plutino In astronomy, the plutinos are a dynamical group of trans-Neptunian objects that orbit in 2:3 mean-motion resonance with Neptune. This means that for every two orbits a plutino makes, Neptune orbits three times. The dwarf planet Pluto is the l ...
s in the outer Solar System such as
28978 Ixion 28978 Ixion (, provisional designation ) is a large trans-Neptunian object and a possible dwarf planet. It is located in the Kuiper belt, a region of icy objects orbiting beyond Neptune in the outer Solar System. Ixion is classified as a plut ...
. Spectral reflectances of
Centaurs A centaur ( ; grc, κένταυρος, kéntauros; ), or occasionally hippocentaur, is a creature from Greek mythology with the upper body of a human and the lower body and legs of a horse. Centaurs are thought of in many Greek myths as bein ...
also suggest the presence of tholins on their surfaces. The ''New Horizons'' exploration of the
classical Kuiper belt object A classical Kuiper belt object, also called a cubewano ( "QB1-o"), is a low-eccentricity Kuiper belt object (KBO) that orbits beyond Neptune and is not controlled by an orbital resonance with Neptune. Cubewanos have orbits with semi-major a ...
486958 Arrokoth Arrokoth (minor-planet designation 486958 Arrokoth; provisional designation ), formerly nicknamed Ultima Thule, is a trans-Neptunian object located in the Kuiper belt. Arrokoth became the farthest and most primitive object in the Solar System ...
revealed reddish color at its surface, suggestive of tholins.


Comets and asteroids

Tholins were detected ''in situ'' by the ''Rosetta'' mission to comet
67P/Churyumov–Gerasimenko 67P/Churyumov–Gerasimenko (abbreviated as 67P or 67P/C–G) is a Jupiter-family comet, originally from the Kuiper belt, with a current orbital period of 6.45 years, a rotation period of approximately 12.4 hours and a maximum velocity of . Chu ...
. Tholins are not typically characteristic of main-belt asteroids, but have been detected on the asteroid
24 Themis Themis (minor planet designation: 24 Themis) is one of the largest asteroids in the asteroid belt. It is also the largest member of the Themistian family. It was discovered by Annibale de Gasparis on 5 April 1853. It is named after Themis, the ...
.


Tholins beyond the Solar System

Tholins might have also been detected in the stellar system of the young star HR 4796A using the Near-Infrared Camera and Multi-Object Spectrometer (NICMOS) aboard the Hubble Space Telescope. The
HR 4796 HR 4796 is a binary star system in the southern constellation of Centaurus. Parallax measurements put it at a distance of from the Earth. The two components of this system have an angular separation of 7.7 arcseconds, which, at their ...
system is approximately 220 light years from Earth. Models show that even when far from UV radiation of a star,
cosmic ray Cosmic rays are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar System in our own ...
doses may be fully sufficient to convert carbon-containing ice grains entirely to complex organics in less than the lifetime of the typical
interstellar cloud An interstellar cloud is generally an accumulation of gas, plasma, and dust in our and other galaxies. Put differently, an interstellar cloud is a denser-than-average region of the interstellar medium, the matter and radiation that exists in the ...
.


See also

* * * * * *


References

{{Portal bar, Biology, Chemistry, Physics, Astronomy, Stars, Outer space, Solar System, Science Organic polymers Origin of life Astrochemistry Prebiotic chemistry