Corn Stover Tar from Pyrolysis by Microwave Heating

Tar is a dark brown or black

viscous The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the in ...

liquid of

hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ...

s and free

carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon ma ...

, obtained from a wide variety of organic materials through

destructive distillation Destruction may refer to: Concepts * Destruktion, a term from the philosophy of Martin Heidegger * Destructive narcissism, a pathological form of narcissism * Self-destructive behaviour, a widely used phrase that ''conceptualises'' certain kind ...

. Tar can be produced from

coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when ...

wood Wood is a porous and fibrous structural tissue found in the stems and roots of trees and other woody plants. It is an organic materiala natural composite of cellulose fibers that are strong in tension and embedded in a matrix of lignin ...

petroleum Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crud ...

, or

peat Peat (), also known as turf (), is an accumulation of partially Decomposition, decayed vegetation or organic matter. It is unique to natural areas called peatlands, bogs, mires, Moorland, moors, or muskegs. The peatland ecosystem covers and ...

. "a dark brown or black bituminous usually odorous viscous liquid obtained by destructive distillation of organic material (such as wood, coal, or peat)". "tar and pitch, viscous, dark-brown to black substances obtained by the destructive distillation of coal, wood, petroleum, peat and certain other organic materials. " Mineral products resembling tar can be produced from fossil hydrocarbons, such as

Coal tar Coal tar is a thick dark liquid which is a by-product of the production of coke and coal gas from coal. It is a type of creosote. It has both medical and industrial uses. Medicinally it is a topical medication applied to skin to treat pso ...

is produced from coal as a byproduct of coke production.

Terminology

"Tar" and " pitch" can be used interchangeably;

asphalt Asphalt, also known as bitumen (, ), is a sticky, black, highly viscous liquid or semi-solid form of petroleum. It may be found in natural deposits or may be a refined product, and is classed as a pitch. Before the 20th century, the term ...

(naturally occurring pitch) may also be called either "mineral tar" or "mineral pitch". There is a tendency to use "tar" for more liquid substances and "pitch" for more solid (

viscoelastic In materials science and continuum mechanics, viscoelasticity is the property of materials that exhibit both viscous and elastic characteristics when undergoing deformation. Viscous materials, like water, resist shear flow and strain linearly ...

) substances. Both "tar" and "pitch" are applied to viscous forms of

, such as the asphalt found in naturally occurring

tar pit Tar pits, sometimes referred to as asphalt pits, are large asphalt deposits. They form in the presence of oil, which is created when decayed organic matter is subjected to pressure underground. If this crude oil seeps upward via fractures, cond ...

s (e.g., the

La Brea Tar Pits La Brea Tar Pits is an active paleontological research site in urban Los Angeles. Hancock Park was formed around a group of tar pits where natural asphalt (also called asphaltum, bitumen, or pitch; ''brea'' in Spanish) has seeped up from the gr ...

in Los Angeles). "Rangoon tar", also known as "Burmese oil" or "Burmese naphtha", is also a form of petroleum.

Oil sands Oil sands, tar sands, crude bitumen, or bituminous sands, are a type of unconventional petroleum deposit. Oil sands are either loose sands or partially consolidated sandstone containing a naturally occurring mixture of sand, clay, and wate ...

, almost exclusively produced in Alberta, Canada, are colloquially referred to as "tar sands" but are in fact composed of asphalt, also called bitumen.

Wood tar

For at least 600 years, wood tar has been used as a water repellent coating for

boat A boat is a watercraft of a large range of types and sizes, but generally smaller than a ship, which is distinguished by its larger size, shape, cargo or passenger capacity, or its ability to carry boats. Small boats are typically found on i ...

ship A ship is a large watercraft that travels the world's oceans and other sufficiently deep waterways, carrying cargo or passengers, or in support of specialized missions, such as defense, research, and fishing. Ships are generally distinguished ...

s, and

roof A roof ( : roofs or rooves) is the top covering of a building, including all materials and constructions necessary to support it on the walls of the building or on uprights, providing protection against rain, snow, sunlight, extremes of t ...

s. In Scandinavia, it was produced as a cash crop. "Peasant Tar" might be named for the district of its production. Wood tar is still used as an additive in the flavoring of

candy Candy, also called sweets (British English) or lollies (Australian English, New Zealand English), is a confection that features sugar as a principal ingredient. The category, called ''sugar confectionery'', encompasses any sweet confection, i ...

alcohol Alcohol most commonly refers to: * Alcohol (chemistry), an organic compound in which a hydroxyl group is bound to a carbon atom * Alcohol (drug), an intoxicant found in alcoholic drinks Alcohol may also refer to: Chemicals * Ethanol, one of sev ...

, and other foods. Wood tar is microbicidal. Producing tar from wood was known in

ancient Greece Ancient Greece ( el, Ἑλλάς, Hellás) was a northeastern Mediterranean civilization, existing from the Greek Dark Ages of the 12th–9th centuries BC to the end of classical antiquity ( AD 600), that comprised a loose collection of cu ...

and has probably been used in

Scandinavia Scandinavia; Sámi languages: /. ( ) is a subregion in Northern Europe, with strong historical, cultural, and linguistic ties between its constituent peoples. In English usage, ''Scandinavia'' most commonly refers to Denmark, Norway, and S ...

since the

Iron Age The Iron Age is the final epoch of the three-age division of the prehistory and protohistory of humanity. It was preceded by the Stone Age ( Paleolithic, Mesolithic, Neolithic) and the Bronze Age ( Chalcolithic). The concept has been mostly ...

. Production and trade in pine-derived tar was a major contributor in the economies of

Northern Europe The northern region of Europe has several definitions. A restrictive definition may describe Northern Europe as being roughly north of the southern coast of the Baltic Sea, which is about 54°N, or may be based on other geographical factors ...

and

Colonial America The colonial history of the United States covers the history of European colonization of North America from the early 17th century until the incorporation of the Thirteen Colonies into the United States after the Revolutionary War. In the ...

. Its main use was in preserving wooden sailing vessels against rot. For centuries, dating back at least to the 14th century, tar was among

Sweden Sweden, formally the Kingdom of Sweden,The United Nations Group of Experts on Geographical Names states that the country's formal name is the Kingdom of SwedenUNGEGN World Geographical Names, Sweden./ref> is a Nordic countries, Nordic c ...

's most important exports. Sweden exported 13,000 barrels of tar in 1615 and 227,000 barrels in the peak year of 1863. The largest user was the

Royal Navy The Royal Navy (RN) is the United Kingdom's naval warfare force. Although warships were used by English and Scottish kings from the early medieval period, the first major maritime engagements were fought in the Hundred Years' War against Fr ...

of the

United Kingdom The United Kingdom of Great Britain and Northern Ireland, commonly known as the United Kingdom (UK) or Britain, is a country in Europe, off the north-western coast of the continental mainland. It comprises England, Scotland, Wales and ...

. Demand for tar declined with the advent of iron and steel ships. Production nearly stopped in the early 20th century, when other chemicals replaced tar, and wooden ships were replaced by steel ships. Traditional wooden boats are still sometimes tarred. The heating ( dry distilling) of

pine A pine is any conifer tree or shrub in the genus ''Pinus'' () of the family (biology), family Pinaceae. ''Pinus'' is the sole genus in the subfamily Pinoideae. The World Flora Online created by the Royal Botanic Gardens, Kew and Missouri Botanic ...

wood causes

tar Tar is a dark brown or black viscous liquid of hydrocarbons and free carbon, obtained from a wide variety of organic materials through destructive distillation. Tar can be produced from coal, wood, petroleum, or peat. "a dark brown or black bi ...

and pitch to drip away from the wood and leave behind charcoal.

Birch bark Birch bark or birchbark is the bark of several Eurasian and North American birch trees of the genus ''Betula''. The strong and water-resistant cardboard-like bark can be easily cut, bent, and sewn, which has made it a valuable building, craftin ...

is used to make particularly fine tar, known as "

Russia Russia (, , ), or the Russian Federation, is a transcontinental country spanning Eastern Europe and Northern Asia. It is the largest country in the world, with its internationally recognised territory covering , and encompassing one-ei ...

n oil", suitable for

leather Leather is a strong, flexible and durable material obtained from the tanning, or chemical treatment, of animal skins and hides to prevent decay. The most common leathers come from cattle, sheep, goats, equine animals, buffalo, pigs and hog ...

protection. The by-products of wood tar are

turpentine Turpentine (which is also called spirit of turpentine, oil of turpentine, terebenthene, terebinthine and (colloquially) turps) is a fluid obtained by the distillation of resin harvested from living trees, mainly pines. Mainly used as a special ...

and

charcoal Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, ...

. When

deciduous In the fields of horticulture and Botany, the term ''deciduous'' () means "falling off at maturity" and "tending to fall off", in reference to trees and shrubs that seasonally shed leaves, usually in the autumn; to the shedding of petals, ...

tree woods are subjected to

, the products are

methanol Methanol (also called methyl alcohol and wood spirit, amongst other names) is an organic chemical and the simplest aliphatic alcohol, with the formula C H3 O H (a methyl group linked to a hydroxyl group, often abbreviated as MeOH). It is ...

(wood alcohol) and

. Tar kilns ( sv, tjärmila, da, tjæremile, no, tjæremile, fi, tervahauta) are dry distillation ovens, historically used in Scandinavia for producing tar from wood. They were built close to the forest, from

limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms w ...

or from more primitive holes in the ground. The bottom is sloped into an outlet hole to allow the tar to pour out. The wood is split into dimensions of a finger, stacked densely, and finally covered tight with earth and moss. If oxygen can enter, the wood might catch fire, and the production would be ruined. On top of this, a fire is stacked and lit. After a few hours, the tar starts to pour out and continues to do so for a few days.

Uses

Tar was used as seal for roofing

shingles Shingles, also known as zoster or herpes zoster, is a viral disease characterized by a painful skin rash with blisters in a localized area. Typically the rash occurs in a single, wide mark either on the left or right side of the body or fac ...

and

tar paper Tar paper is a heavy-duty paper used in construction. Tar paper is made by impregnating paper or fiberglass mat with tar, producing a waterproof material useful for roof construction. Tar paper is distinguished from roofing felt, which is impreg ...

and to seal the hulls of ships and boats. For millennia, wood tar was used to waterproof

sail A sail is a tensile structure—which is made from fabric or other membrane materials—that uses wind power to propel sailing craft, including sailing ships, sailboats, windsurfers, ice boats, and even sail-powered land vehicles. Sails ma ...

s and boats, but today, sails made from inherently waterproof synthetic substances have reduced the demand for tar. Wood tar is still used to seal traditional wooden boats and the roofs of historic, shingle-roofed churches, as well as painting exterior walls of log buildings. Tar is also a general disinfectant. Pine tar oil, or wood tar oil, is used for the surface treatment of wooden shingle roofs, boats, buckets, and tubs and in the medicine, soap, and rubber industries. Pine tar has good penetration on the rough wood. An old wood tar oil recipe for the treatment of wood is one-third each genuine wood tar, balsam turpentine, and boiled or raw linseed oil or Chinese tung oil. Tervavene 1910

Finland Finland ( fi, Suomi ; sv, Finland ), officially the Republic of Finland (; ), is a Nordic country in Northern Europe. It shares land borders with Sweden to the northwest, Norway to the north, and Russia to the east, with the Gulf of Bot ...

, wood tar was once considered a

panacea In Greek mythology, Panacea (Greek ''Πανάκεια'', Panakeia), a goddess of universal remedy, was the daughter of Asclepius and Epione. Panacea and her four sisters each performed a facet of Apollo's art: * Panacea (the goddess of univers ...

reputed to heal "even those cut in twain through their midriff". A Finnish proverb states that "if

sauna A sauna (, ), or sudatory, is a small room or building designed as a place to experience dry or wet heat sessions, or an establishment with one or more of these facilities. The steam and high heat make the bathers perspire. A thermometer in a ...

vodka Vodka ( pl, wódka , russian: водка , sv, vodka ) is a clear distilled alcoholic beverage. Different varieties originated in Poland, Russia, and Sweden. Vodka is composed mainly of water and ethanol but sometimes with traces of impuriti ...

and tar won't help, the disease is fatal." Wood tar is used in traditional Finnish medicine because of its microbicidal properties. Wood tar is also available diluted as

tar water Tar-water was a medieval medicine consisting of pine tar and water. As it was foul-tasting, it slowly dropped in popularity, but was revived in the Victorian era. It is used both as a tonic and as a substitute to get rid of "strong spirits". Both ...

, which has numerous uses: *As a flavoring for candies (e.g., Terva Leijona) and alcohol (Terva Viina). *As a spice for food, like meat. *As a scent for

s. Tar water is mixed into water, which is turned into steam in the sauna. *As an anti-

dandruff Dandruff is a skin condition that mainly affects the scalp. Symptoms include flaking and sometimes mild itchiness. It can result in social or self-esteem problems. A more severe form of the condition, which includes inflammation of the skin ...

agent in

shampoo Shampoo () is a hair care product, typically in the form of a viscous liquid, that is used for cleaning hair. Less commonly, shampoo is available in solid bar format. Shampoo is used by applying it to wet hair, massaging the product into the ...

. *As a component of cosmetics. Mixing tar with

linseed oil Linseed oil, also known as flaxseed oil or flax oil (in its edible form), is a colourless to yellowish oil obtained from the dried, ripened seeds of the flax plant (''Linum usitatissimum''). The oil is obtained by pressing, sometimes followed by ...

varnish Varnish is a clear transparent hard protective coating or film. It is not a stain. It usually has a yellowish shade from the manufacturing process and materials used, but it may also be pigmented as desired, and is sold commercially in variou ...

produces tar paint. Tar paint has a translucent brownish hue and can be used to saturate and tone wood and protect it from weather. Tar paint can also be toned with various pigments, producing translucent colors and preserving the wood texture. Tar was once used for

public humiliation Public humiliation or public shaming is a form of punishment whose main feature is dishonoring or disgracing a person, usually an offender or a prisoner, especially in a public place. It was regularly used as a form of judicially sanctioned puni ...

, known as

tarring and feathering Tarring and feathering is a form of public torture and punishment used to enforce unofficial justice or revenge. It was used in feudal Europe and its colonies in the early modern period, as well as the early American frontier, mostly as a ty ...

. By pouring hot wood tar onto somebody's bare skin and waiting for it to cool, they would remain stuck in one position. From there, people would attach feathers to the tar, which would remain stuck on the tarred person for the duration of the punishment. That person would then become a public example for the rest of the day. Macarony Boston NMAH2003-25005

Tar was used in 9th-century

Baghdad Baghdad (; ar, بَغْدَاد , ) is the capital of Iraq and the second-largest city in the Arab world after Cairo. It is located on the Tigris near the ruins of the ancient city of Babylon and the Sassanid Persian capital of Ctesiphon ...

, which had streets paved with tar, derived from petroleum that became accessible from natural fields in the region.

Coal tar

Coal tar was formerly one of the products of

gasworks A gasworks or gas house is an industrial plant for the production of flammable gas. Many of these have been made redundant in the developed world by the use of natural gas, though they are still used for storage space. Early gasworks Coal ...

. Tar made from coal or petroleum is considered

toxic Toxicity is the degree to which a chemical substance or a particular mixture of substances can damage an organism. Toxicity can refer to the effect on a whole organism, such as an animal, bacterium, or plant, as well as the effect on a sub ...

and

carcinogenic A carcinogen is any substance, radionuclide, or radiation that promotes carcinogenesis (the formation of cancer). This may be due to the ability to damage the genome or to the disruption of cellular metabolic processes. Several radioactive sub ...

because of its high

benzene Benzene is an organic chemical compound with the molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar ring with one hydrogen atom attached to each. Because it contains only carbon and hydrogen atoms ...

content, though

coal tar Coal tar is a thick dark liquid which is a by-product of the production of coke and coal gas from coal. It is a type of creosote. It has both medical and industrial uses. Medicinally it is a topical medication applied to skin to treat pso ...

in low concentrations is used as a

topical A topical medication is a medication that is applied to a particular place on or in the body. Most often topical medication means application to body surfaces such as the skin or mucous membranes to treat ailments via a large range of classes ...

medicine. Coal and petroleum tar has a pungent odour. Coal tar is listed at number 1999 in the United Nations list of

dangerous goods Dangerous goods, abbreviated DG, are substances that when transported are a risk to health, safety, property or the environment. Certain dangerous goods that pose risks even when not being transported are known as hazardous materials ( syllabi ...

References

External links