Tungsten Pentoxide
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Tungsten pentoxide () was reported in early literature but proved to have the
stoichiometry Stoichiometry () is the relationships between the masses of reactants and Product (chemistry), products before, during, and following chemical reactions. Stoichiometry is based on the law of conservation of mass; the total mass of reactants must ...
W18O49.Wells A.F. (1984) ''Structural Inorganic Chemistry'' 5th edition Oxford Science Publications Sometimes called mineral blue, it is a blue solid formed by the reaction of tungsten trioxide, WO3, and
tungsten Tungsten (also called wolfram) is a chemical element; it has symbol W and atomic number 74. It is a metal found naturally on Earth almost exclusively in compounds with other elements. It was identified as a distinct element in 1781 and first ...
metal at 700 °C.


Intermediate oxides of tungsten

There are a number of these unusual intermediate oxides formed from reacting metal and trioxide, including W20O58 and W24O70. W18O49 contains both octahedral and pentagonal bipyramidal co-ordination of the metal
atom Atoms are the basic particles of the chemical elements. An atom consists of a atomic nucleus, nucleus of protons and generally neutrons, surrounded by an electromagnetically bound swarm of electrons. The chemical elements are distinguished fr ...
s by
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
.


See also

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Tungsten(III) oxide Tungsten(III) oxide (W2O3) is a compound of tungsten and oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, ...
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Tungsten(IV) oxide Tungsten(IV) oxide is the chemical compound with the formula W O2. The bronze-colored solid crystallizes in a monoclinic cell. The rutile-like structure features distorted octahedral WO6 centers with alternate short W–W bonds (248 pm). ...
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Tungsten(VI) oxide Tungsten(VI) oxide, also known as tungsten trioxide is a chemical compound of oxygen and the transition metal tungsten, with formula WO3. The compound is also called tungstic anhydride, reflecting its relation to tungstic acid . It is a light ...


References

Tungsten(V) compounds Transition metal oxides {{inorganic-compound-stub