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The Stern–Gerlach experiment demonstrated that the spatial orientation of
angular momentum In physics, angular momentum (rarely, moment of momentum or rotational momentum) is the rotational analog of linear momentum. It is an important physical quantity because it is a conserved quantity—the total angular momentum of a closed syst ...
is quantized. Thus an atomic-scale system was shown to have intrinsically quantum properties. In the original experiment, silver atoms were sent through a spatially varying magnetic field, which deflected them before they struck a detector screen, such as a glass slide. Particles with non-zero
magnetic moment In electromagnetism, the magnetic moment is the magnetic strength and orientation of a magnet or other object that produces a magnetic field. Examples of objects that have magnetic moments include loops of electric current (such as electroma ...
are deflected, due to the magnetic field
gradient In vector calculus, the gradient of a scalar-valued differentiable function of several variables is the vector field (or vector-valued function) \nabla f whose value at a point p is the "direction and rate of fastest increase". If the gr ...
, from a straight path. The screen reveals discrete points of accumulation, rather than a continuous distribution, owing to their quantized
spin Spin or spinning most often refers to: * Spinning (textiles), the creation of yarn or thread by twisting fibers together, traditionally by hand spinning * Spin, the rotation of an object around a central axis * Spin (propaganda), an intentionally ...
. Historically, this experiment was decisive in convincing physicists of the reality of angular-momentum quantization in all atomic-scale systems. After its conception by
Otto Stern :''Otto Stern was also the pen name of German women's rights activist Louise Otto-Peters (1819–1895)''. Otto Stern (; 17 February 1888 – 17 August 1969) was a German-American physicist and Nobel laureate in physics. He was the second most ...
in 1921, the experiment was first successfully conducted by Walther Gerlach in early 1922.


Description

The Stern–Gerlach experiment involves sending a beam of
silver Silver is a chemical element with the symbol Ag (from the Latin ', derived from the Proto-Indo-European ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, white, lustrous transition metal, it exhibits the highest electrical ...
atoms through an
inhomogeneous Homogeneity and heterogeneity are concepts often used in the sciences and statistics relating to the uniformity of a substance or organism. A material or image that is homogeneous is uniform in composition or character (i.e. color, shape, size, ...
magnetic field A magnetic field is a vector field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to ...
and observing their deflection. The results show that particles possess an intrinsic
angular momentum In physics, angular momentum (rarely, moment of momentum or rotational momentum) is the rotational analog of linear momentum. It is an important physical quantity because it is a conserved quantity—the total angular momentum of a closed syst ...
that is closely analogous to the angular momentum of a classically spinning object, but that takes only certain quantized values. Another important result is that only one component of a particle's spin can be measured at one time, meaning that the measurement of the spin along the z-axis destroys information about a particle's spin along the x and y axis. The experiment is normally conducted using electrically neutral particles such as silver atoms. This avoids the large deflection in the path of a charged particle moving through a magnetic field and allows spin-dependent effects to dominate. If the particle is treated as a classical spinning magnetic dipole, it will
precess Precession is a change in the orientation of the rotational axis of a rotating body. In an appropriate reference frame it can be defined as a change in the first Euler angle, whereas the third Euler angle defines the rotation itself. In othe ...
in a magnetic field because of the torque that the magnetic field exerts on the dipole (see torque-induced precession). If it moves through a homogeneous magnetic field, the forces exerted on opposite ends of the dipole cancel each other out and the trajectory of the particle is unaffected. However, if the magnetic field is inhomogeneous then the force on one end of the dipole will be slightly greater than the opposing force on the other end, so that there is a net force which deflects the particle's trajectory. If the particles were classical spinning objects, one would expect the distribution of their spin angular momentum vectors to be
random In common usage, randomness is the apparent or actual lack of pattern or predictability in events. A random sequence of events, symbols or steps often has no order and does not follow an intelligible pattern or combination. Individual ran ...
and
continuous Continuity or continuous may refer to: Mathematics * Continuity (mathematics), the opposing concept to discreteness; common examples include ** Continuous probability distribution or random variable in probability and statistics ** Continuous g ...
. Each particle would be deflected by an amount proportional to the
dot product In mathematics, the dot product or scalar productThe term ''scalar product'' means literally "product with a scalar as a result". It is also used sometimes for other symmetric bilinear forms, for example in a pseudo-Euclidean space. is an alg ...
of its magnetic moment with the external field gradient, producing some density distribution on the detector screen. Instead, the particles passing through the Stern–Gerlach apparatus are deflected either up or down by a specific amount. This was a measurement of the quantum observable now known as
spin Spin or spinning most often refers to: * Spinning (textiles), the creation of yarn or thread by twisting fibers together, traditionally by hand spinning * Spin, the rotation of an object around a central axis * Spin (propaganda), an intentionally ...
angular momentum, which demonstrated possible outcomes of a measurement where the observable has a discrete set of values or point spectrum. Although some discrete quantum phenomena, such as atomic spectra, were observed much earlier, the Stern–Gerlach experiment allowed scientists to directly observe separation between discrete quantum states for the first time in the history of science. Theoretically, quantum angular momentum ''of any kind'' has a discrete spectrum, which is sometimes briefly expressed as "angular momentum is quantized".


Experiment using particles with + or − spin

If the experiment is conducted using charged particles like electrons, there will be a
Lorentz force In physics (specifically in electromagnetism) the Lorentz force (or electromagnetic force) is the combination of electric and magnetic force on a point charge due to electromagnetic fields. A particle of charge moving with a velocity in an elect ...
that tends to bend the trajectory in a circle. This force can be cancelled by an electric field of appropriate magnitude oriented transverse to the charged particle's path. Electrons are spin- particles. These have only two possible spin angular momentum values measured along any axis, +\frac or -\frac, a purely quantum mechanical phenomenon. Because its value is always the same, it is regarded as an intrinsic property of electrons, and is sometimes known as "intrinsic angular momentum" (to distinguish it from orbital angular momentum, which can vary and depends on the presence of other particles). If one measures the spin along a vertical axis, electrons are described as "spin up" or "spin down", based on the magnetic moment pointing up or down, respectively. To mathematically describe the experiment with spin +\frac particles, it is easiest to use Dirac's
bra–ket notation In quantum mechanics, bra–ket notation, or Dirac notation, is used ubiquitously to denote quantum states. The notation uses angle brackets, and , and a vertical bar , to construct "bras" and "kets". A ket is of the form , v \rangle. Mathem ...
. As the particles pass through the Stern–Gerlach device, they are deflected either up or down, and observed by the detector which resolves to either spin up or spin down. These are described by the angular momentum quantum number j, which can take on one of the two possible allowed values, either +\frac or -\frac. The act of observing (measuring) the momentum along the z axis corresponds to the operator J_z. In mathematical terms, the initial state of the particles is :, \psi\rangle = c_1\left, \psi_\right\rangle + c_2\left, \psi_\right\rangle where constants c_1 and c_2 are complex numbers. This initial state spin can point in any direction. The squares of the
absolute value In mathematics, the absolute value or modulus of a real number x, is the non-negative value without regard to its sign. Namely, , x, =x if is a positive number, and , x, =-x if x is negative (in which case negating x makes -x positive), ...
s , c_1, ^2 and , c_2, ^2 determine the probabilities that for a system in the initial state , \psi\rangle one of the two possible values of j is found after the measurement is made. The constants c_1 and c_2 must also be normalized in order that the probability of finding either one of the values be unity, that is we must ensure that , c_1, ^2 + , c_2, ^2 = 1. However, this information is not sufficient to determine the values of c_1 and c_2, because they are complex numbers. Therefore, the measurement yields only the squared magnitudes of the constants, which are interpreted as probabilities.


Sequential experiments

If we link multiple Stern–Gerlach apparatuses (the rectangles containing ''S-G''), we can clearly see that they do not act as simple selectors, i.e. filtering out particles with one of the states (pre-existing to the measurement) and blocking the others. Instead they alter the state by observing it (as in light polarization). In the figure below, x and z name the directions of the (inhomogenous) magnetic field, with the x-z-plane being orthogonal to the particle beam. In the three S-G systems shown below, the cross-hatched squares denote the blocking of a given output, i.e. each of the S-G systems with a blocker allows only particles with one of two states to enter the next S-G apparatus in the sequence.


Experiment 1

The top illustration shows that when a second, identical, S-G apparatus is placed at the exit of the first apparatus, only z+ is seen in the output of the second apparatus. This result is expected since all neutrons at this point are expected to have z+ spin, as only the z+ beam from the first apparatus entered the second apparatus.


Experiment 2

The middle system shows what happens when a different S-G apparatus is placed at the exit of the z+ beam resulting of the first apparatus, the second apparatus measuring the deflection of the beams on the x axis instead of the z axis. The second apparatus produces x+ and x- outputs. Now classically we would expect to have one beam with the x characteristic oriented + and the z characteristic oriented +, and another with the x characteristic oriented - and the z characteristic oriented +.


Experiment 3

The bottom system contradicts that expectation. The output of the third apparatus which measures the deflection on the z axis again shows an output of z- as well as z+. Given that the input to the second S-G apparatus consisted only of z+, it can be inferred that a S-G apparatus must be altering the states of the particles that pass through it. This experiment can be interpreted to exhibit the
uncertainty principle In quantum mechanics, the uncertainty principle (also known as Heisenberg's uncertainty principle) is any of a variety of mathematical inequalities asserting a fundamental limit to the accuracy with which the values for certain pairs of physic ...
: since the angular momentum cannot be measured on two perpendicular directions at the same time, the measurement of the angular momentum on the x direction destroys the previous determination of the angular momentum in the z direction. That's why the third apparatus measures renewed z+ and z- beams like the x measurement really made a clean slate of the z+ output.


History

The Stern–Gerlach experiment was conceived by
Otto Stern :''Otto Stern was also the pen name of German women's rights activist Louise Otto-Peters (1819–1895)''. Otto Stern (; 17 February 1888 – 17 August 1969) was a German-American physicist and Nobel laureate in physics. He was the second most ...
in 1921 and performed by him and Walther Gerlach in
Frankfurt Frankfurt, officially Frankfurt am Main (; Hessian: , " Frank ford on the Main"), is the most populous city in the German state of Hesse. Its 791,000 inhabitants as of 2022 make it the fifth-most populous city in Germany. Located on it ...
in 1922. At the time, Stern was an assistant to
Max Born Max Born (; 11 December 1882 – 5 January 1970) was a German physicist and mathematician who was instrumental in the development of quantum mechanics. He also made contributions to solid-state physics and optics and supervised the work of a ...
at the University of Frankfurt's Institute for Theoretical Physics, and Gerlach was an assistant at the same university's Institute for Experimental Physics. At the time of the experiment, the most prevalent model for describing the
atom Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas, a ...
was the
Bohr model In atomic physics, the Bohr model or Rutherford–Bohr model, presented by Niels Bohr and Ernest Rutherford in 1913, is a system consisting of a small, dense nucleus surrounded by orbiting electrons—similar to the structure of the Solar Syst ...
, which described
electrons The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have n ...
as going around the positively charged
nucleus Nucleus ( : nuclei) is a Latin word for the seed inside a fruit. It most often refers to: * Atomic nucleus, the very dense central region of an atom *Cell nucleus, a central organelle of a eukaryotic cell, containing most of the cell's DNA Nucl ...
only in certain discrete
atomic orbital In atomic theory and quantum mechanics, an atomic orbital is a function describing the location and wave-like behavior of an electron in an atom. This function can be used to calculate the probability of finding any electron of an atom in any ...
s or
energy levels A quantum mechanical system or particle that is bound—that is, confined spatially—can only take on certain discrete values of energy, called energy levels. This contrasts with classical particles, which can have any amount of energy. The ...
. Since the electron was quantized to be only in certain positions in space, the separation into distinct orbits was referred to as space quantization. The Stern–Gerlach experiment was meant to test the Bohr–Sommerfeld hypothesis that the direction of the angular momentum of a silver atom is quantized. Note that the experiment was performed several years before Uhlenbeck and Goudsmit formulated their hypothesis of the existence of the electron spin. Even though the result of the Stern−Gerlach experiment has later turned out to be in agreement with the predictions of quantum mechanics for a spin- particle, the experiment should be seen as a corroboration of the Bohr–Sommerfeld theory. In 1927, T.E. Phipps and J.B. Taylor reproduced the effect using
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-to ...
atoms in their
ground state The ground state of a quantum-mechanical system is its stationary state of lowest energy; the energy of the ground state is known as the zero-point energy of the system. An excited state is any state with energy greater than the ground state. ...
, thereby eliminating any doubts that may have been caused by the use of
silver Silver is a chemical element with the symbol Ag (from the Latin ', derived from the Proto-Indo-European ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, white, lustrous transition metal, it exhibits the highest electrical ...
atoms. However, in 1926 the non-relativistic
Schrödinger equation The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of th ...
had incorrectly predicted the
magnetic moment In electromagnetism, the magnetic moment is the magnetic strength and orientation of a magnet or other object that produces a magnetic field. Examples of objects that have magnetic moments include loops of electric current (such as electroma ...
of hydrogen to be zero in its ground state. To correct this problem
Wolfgang Pauli Wolfgang Ernst Pauli (; ; 25 April 1900 – 15 December 1958) was an Austrian theoretical physicist and one of the pioneers of quantum physics. In 1945, after having been nominated by Albert Einstein, Pauli received the Nobel Prize in Physics ...
introduced "by hand", so to speak, the 3
Pauli matrices In mathematical physics and mathematics, the Pauli matrices are a set of three complex matrices which are Hermitian, involutory and unitary. Usually indicated by the Greek letter sigma (), they are occasionally denoted by tau () when used ...
which now bear his name, but which were later shown by
Paul Dirac Paul Adrien Maurice Dirac (; 8 August 1902 – 20 October 1984) was an English theoretical physicist who is regarded as one of the most significant physicists of the 20th century. He was the Lucasian Professor of Mathematics at the Univer ...
in 1928 to be intrinsic in his relativistic equation. The experiment was first performed with an electromagnet that allowed the non-uniform magnetic field to be turned on gradually from a null value. When the field was null, the silver atoms were deposited as a single band on the detecting glass slide. When the field was made stronger, the middle of the band began to widen and eventually to split into two, so that the glass-slide image looked like a lip-print, with an opening in the middle, and closure at either end. In the middle, where the magnetic field was strong enough to split the beam into two, statistically half of the silver atoms had been deflected by the non-uniformity of the field.


Importance

The Stern–Gerlach experiment strongly influenced later developments in
modern physics Modern physics is a branch of physics that developed in the early 20th century and onward or branches greatly influenced by early 20th century physics. Notable branches of modern physics include quantum mechanics, special relativity and general ...
: *In the decade that followed, scientists showed using similar techniques, that the nuclei of some atoms also have quantized angular momentum. It is the interaction of this nuclear angular momentum with the spin of the electron that is responsible for the
hyperfine structure In atomic physics, hyperfine structure is defined by small shifts in otherwise degenerate energy levels and the resulting splittings in those energy levels of atoms, molecules, and ions, due to electromagnetic multipole interaction between the n ...
of the spectroscopic lines. *In the 1930s, using an extended version of the Stern–Gerlach apparatus, Isidor Rabi and colleagues showed that by using a varying magnetic field, one can force the magnetic moment to go from one state to the other. The series of experiments culminated in 1937 when they discovered that state transitions could be induced using time varying fields or RF fields. The so-called
Rabi oscillation In physics, the Rabi cycle (or Rabi flop) is the cyclic behaviour of a two-level quantum system in the presence of an oscillatory driving field. A great variety of physical processes belonging to the areas of quantum computing, condensed matter ...
is the working mechanism for the
Magnetic Resonance Imaging Magnetic resonance imaging (MRI) is a medical imaging technique used in radiology to form pictures of the anatomy and the physiological processes of the body. MRI scanners use strong magnetic fields, magnetic field gradients, and radio wave ...
equipment found in hospitals. *
Norman F. Ramsey Norman Foster Ramsey Jr. (August 27, 1915 – November 4, 2011) was an American physicist who was awarded the 1989 Nobel Prize in Physics, for the invention of the separated oscillatory field method, which had important applications in the const ...
later modified the Rabi apparatus to increase the interaction time with the field. The extreme sensitivity due to the frequency of the radiation makes this very useful for keeping accurate time, and it is still used today in
atomic clock An atomic clock is a clock that measures time by monitoring the resonant frequency of atoms. It is based on atoms having different energy levels. Electron states in an atom are associated with different energy levels, and in transitions betwe ...
s. * In the early sixties, Ramsey and Daniel Kleppner used a Stern–Gerlach system to produce a beam of polarized hydrogen as the source of energy for the hydrogen maser, which is still one of the most popular frequency standards. * The direct observation of the spin is the most direct evidence of quantization in quantum mechanics. * The Stern–Gerlach experiment has become a prototype for '' quantum measurement'', demonstrating the observation of a single, real value (''
eigenvalue In linear algebra, an eigenvector () or characteristic vector of a linear transformation is a nonzero vector that changes at most by a scalar factor when that linear transformation is applied to it. The corresponding eigenvalue, often denote ...
)'' of an initially unknown physical property. Entering the Stern-Gerlach magnet, the direction of the silver atom’s magnetic moment is indefinite, but it is observed to be either parallel, or anti-parallel to the direction of the magnetic field, B, at the exit of the magnet. Atoms with a magnetic moment parallel to B have been accelerated in that direction by the magnetic field gradient; those with anti-parallel moments were accelerated the opposite way. So, each atom traversing the magnet will strike the detector ((5) in the diagram) at just one of the two spots. According to '' quantum measurement theory,'' the wave function representing the atom’s magnetic moment is in a '' superposition'' of those two directions entering the magnet. A single, spin-direction
eigenvalue In linear algebra, an eigenvector () or characteristic vector of a linear transformation is a nonzero vector that changes at most by a scalar factor when that linear transformation is applied to it. The corresponding eigenvalue, often denote ...
is recorded when a momentum quantum is transferred, from the magnetic field, to the atom, initiating acceleration, and displacement, in that momentum direction.


See also

* Photon polarization *
Stern–Gerlach Medal The Stern–Gerlach Medal is the most prestigious German Award for experimental physicists, named after the scientists of the Stern–Gerlach experiment, Otto Stern and Walther Gerlach. The prize, awarded annually since 1993, is awarded by the De ...
* German inventors and discoverers


References


Further reading

*

* * * * *
Use of ions


External links




Stern–Gerlach Experiment Flash Model




at plato.stanford.edu
Animation, applications and research linked to the spin
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