Slush hydrogen
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Slush hydrogen is a combination of
liquid hydrogen Liquid hydrogen (LH2 or LH2) is the liquid state of the element hydrogen. Hydrogen is found naturally in the molecular H2 form. To exist as a liquid, H2 must be cooled below its critical point of 33  K. However, for it to be in a fully li ...
and
solid hydrogen Solid hydrogen is the solid state of the element hydrogen, achieved by decreasing the temperature below hydrogen's melting point of . It was collected for the first time by James Dewar in 1899 and published with the title "Sur la solidification de ...
at the
triple point In thermodynamics, the triple point of a substance is the temperature and pressure at which the three phases (gas, liquid, and solid) of that substance coexist in thermodynamic equilibrium.. It is that temperature and pressure at which the subli ...
with a lower temperature and a higher density than
liquid hydrogen Liquid hydrogen (LH2 or LH2) is the liquid state of the element hydrogen. Hydrogen is found naturally in the molecular H2 form. To exist as a liquid, H2 must be cooled below its critical point of 33  K. However, for it to be in a fully li ...
. It is commonly formed by repeating a freeze-thaw process. This is most easily done by bringing liquid hydrogen near its boiling point and then reducing pressure using a vacuum pump. The decrease in pressure causes the liquid hydrogen to vaporize/boil - which removes latent heat, and ultimately decreases the temperature of the liquid hydrogen. Solid hydrogen is formed on the surface of the boiling liquid (between the gas/liquid interface) as the liquid is cooled and reaches its triple point. The vacuum pump is stopped, causing an increase of pressure, the solid hydrogen formed on the surface partially melts and begins to sink. The solid hydrogen is agitated in the liquid and the process is repeated. The resulting hydrogen slush has an increased density of 16–20% when compared to liquid hydrogen. It is proposed as a
rocket fuel Rocket propellant is the reaction mass of a rocket. This reaction mass is ejected at the highest achievable velocity from a rocket engine to produce thrust. The energy required can either come from the propellants themselves, as with a chemical ...
in place of liquid hydrogen in order to use smaller fuel tanks and thus reduce the
dry weight Vehicle weight is a measurement of wheeled motor vehicles; either an actual measured weight of the vehicle under defined conditions or a gross weight rating for its weight carrying capacity. Curb or kerb weight Curb weight (U.S. English) or kerb ...
of the vehicle.


Production

The continuous freeze technique used for slush hydrogen involves pulling a continuous vacuum over triple point liquid and using a solid hydrogen mechanical ice-breaker to disrupt the surface of the freezing hydrogen.A.S. Rapial and D.E. Daney (May 1969)
1966 – Preparation and characterization of slush hydrogen and nitrogen gels
Cryogenics Division. Institute for Basic Standards National Bureau of Standards, Boulder, Colorado (report for NASA). Retrieved on 2012-12-29.
*Fuel density: 0.085 g/cm3 *
Melting point The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends ...
: −259
°C The degree Celsius is the unit of temperature on the Celsius scale (originally known as the centigrade scale outside Sweden), one of two temperature scales used in the International System of Units (SI), the other being the Kelvin scale. The ...
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Boiling point The boiling point of a substance is the temperature at which the vapor pressure of a liquid equals the pressure surrounding the liquid and the liquid changes into a vapor. The boiling point of a liquid varies depending upon the surrounding envir ...
: −253
°C The degree Celsius is the unit of temperature on the Celsius scale (originally known as the centigrade scale outside Sweden), one of two temperature scales used in the International System of Units (SI), the other being the Kelvin scale. The ...


See also

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Compressed hydrogen Compressed hydrogen (CH2, CGH2 or CGH2) is the gaseous state of the element hydrogen kept under pressure. Compressed hydrogen in hydrogen tanks at 350 bar (5,000 psi) and 700 bar (10,000 psi) is used for mobile hydrogen storage in hydrogen vehicles ...
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Hydrogen safety Hydrogen safety covers the safe production, handling and use of hydrogen, particularly hydrogen gas fuel and liquid hydrogen. Hydrogen possesses the NFPA 704's highest rating of 4 on the flammability scale because it is flammable when mixed even i ...
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Metallic hydrogen Metallic hydrogen is a phase of hydrogen in which it behaves like an electrical conductor. This phase was predicted in 1935 on theoretical grounds by Eugene Wigner and Hillard Bell Huntington. At high pressure and temperatures, metallic hydroge ...
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Timeline of hydrogen technologies This is a timeline of the history of hydrogen technology. Timeline 16th century * c. 1520 – First recorded observation of hydrogen by Paracelsus through dissolution of metals (iron, zinc, and tin) in sulfuric acid. 17th century * 1625 – Fi ...
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Liquefaction of gases Liquefaction of gases is physical conversion of a gas into a liquid state ( condensation). The liquefaction of gases is a complicated process that uses various compressions and expansions to achieve high pressures and very low temperatures, using ...


References

{{reflist, 2 Hydrogen physics Hydrogen technologies Hydrogen storage Liquid fuels Rocket fuels Coolants Cryogenics