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The Schottky diode (named after the German physicist
Walter H. Schottky Walter Hans Schottky (23 July 1886 – 4 March 1976) was a German physicist who played a major early role in developing the theory of electron and ion emission phenomena, invented the screen-grid vacuum tube in 1915 while working at Siemen ...
), also known as Schottky barrier diode or hot-carrier diode, is a semiconductor
diode A diode is a two-terminal electronic component that conducts current primarily in one direction (asymmetric conductance); it has low (ideally zero) resistance in one direction, and high (ideally infinite) resistance in the other. A diod ...
formed by the junction of a
semiconductor A semiconductor is a material which has an electrical conductivity value falling between that of a conductor, such as copper, and an insulator, such as glass. Its resistivity falls as its temperature rises; metals behave in the opposite way ...
with a metal. It has a low
forward voltage Forward is a relative direction, the opposite of backward. Forward may also refer to: People * Forward (surname) Sports * Forward (association football) * Forward (basketball), including: ** Point forward ** Power forward (basketball) ** ...
drop and a very fast switching action. The
cat's-whisker detector A crystal detector is an obsolete electronic component used in some early 20th century radio receivers that consists of a piece of crystalline mineral which rectifies the alternating current radio signal. It was employed as a detector ( d ...
s used in the early days of
wireless Wireless communication (or just wireless, when the context allows) is the transfer of information between two or more points without the use of an electrical conductor, optical fiber or other continuous guided medium for the transfer. The most ...
and
metal rectifier A metal rectifier is an early type of semiconductor rectifier in which the semiconductor is copper oxide, germanium or selenium. They were used in power applications to convert alternating current to direct current in devices such as radios and ...
s used in early power applications can be considered primitive Schottky diodes. When sufficient forward voltage is applied, a current flows in the forward direction. A silicon p–n diode has a typical forward voltage of 600–700 mV, while the Schottky's forward voltage is 150–450 mV. This lower forward voltage requirement allows higher switching speeds and better system efficiency.


History

Walter H. Schottky (1886–1976) in 1914, discovered an irregularity in the emission of thermions in a vacuum tube, now known as the Schottky effect.


Construction

A
metal–semiconductor junction In solid-state physics, a metal–semiconductor (M–S) junction is a type of electrical junction in which a metal comes in close contact with a semiconductor material. It is the oldest practical semiconductor device. M–S junctions can either ...
is formed between a metal and a semiconductor, creating a
Schottky barrier A Schottky barrier, named after Walter H. Schottky, is a potential energy barrier for electrons formed at a metal–semiconductor junction. Schottky barriers have rectifying characteristics, suitable for use as a diode. One of the primary ch ...
(instead of a semiconductor–semiconductor junction as in conventional diodes). Typical metals used are molybdenum, platinum, chromium or tungsten, and certain
silicide A silicide is a type of chemical compound that combines silicon and a (usually) more electropositive element. Silicon is more electropositive than carbon. Silicides are structurally closer to borides than to carbides. Similar to borides and carb ...
s (e.g., palladium silicide and
platinum silicide Platinum silicide, also known as platinum monosilicide, is the inorganic compound with the formula PtSi. It is a semiconductor that turns into a superconductor when cooled to 0.8 K. Structure and bonding The crystal structure of PtSi is orthorh ...
), whereas the semiconductor would typically be n-type silicon. The metal side acts as the
anode An anode is an electrode of a polarized electrical device through which conventional current enters the device. This contrasts with a cathode, an electrode of the device through which conventional current leaves the device. A common mnemonic is ...
, and n-type semiconductor acts as the
cathode A cathode is the electrode from which a conventional current leaves a polarized electrical device. This definition can be recalled by using the mnemonic ''CCD'' for ''Cathode Current Departs''. A conventional current describes the direction in whi ...
of the diode; meaning
conventional current An electric current is a stream of charged particles, such as electrons or ions, moving through an electrical conductor or space. It is measured as the net rate of flow of electric charge through a surface or into a control volume. The moving ...
can flow from the metal side to the semiconductor side, but not in the opposite direction. This Schottky barrier results in both very fast switching and low forward voltage drop. The choice of the combination of the metal and semiconductor determines the forward voltage of the diode. Both n- and p-type semiconductors can develop Schottky barriers. However, the p-type typically has a much lower forward voltage. As the reverse leakage current increases dramatically with lowering the forward voltage, it cannot be too low, so the usually employed range is about 0.5–0.7 V, and p-type semiconductors are employed only rarely.
Titanium silicide Titanium is a chemical element with the symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in s ...
and other refractory silicides, which are able to withstand the temperatures needed for source/drain annealing in CMOS processes, usually have too low a forward voltage to be useful, so processes using these silicides therefore usually do not offer Schottky diodes. With increased doping of the semiconductor, the width of the depletion region drops. Below a certain width, the charge carriers can tunnel through the depletion region. At very high doping levels, the junction does not behave as a rectifier any more and becomes an ohmic contact. This can be used for the simultaneous formation of ohmic contacts and diodes, as a diode will form between the silicide and lightly doped n-type region, and an ohmic contact will form between the silicide and the heavily doped n- or p-type region. Lightly doped p-type regions pose a problem, as the resulting contact has too high a resistance for a good ohmic contact, but too low a forward voltage and too high a reverse leakage to make a good diode. As the edges of the Schottky contact are fairly sharp, a high electric field gradient occurs around them, which limits how large the reverse breakdown voltage threshold can be. Various strategies are used, from guard rings to overlaps of metallization to spread out the field gradient. The guard rings consume valuable die area and are used primarily for larger higher-voltage diodes, while overlapping metallization is employed primarily with smaller low-voltage diodes. Schottky diodes are often used as antisaturation clamps in
Schottky transistor A Schottky transistor is a combination of a transistor and a Schottky diode that prevents the transistor from saturating by diverting the excessive input current. It is also called a Schottky-clamped transistor. Mechanism Standard transistor ...
s. Schottky diodes made from palladium silicide (PdSi) are excellent due to their lower forward voltage (which has to be lower than the forward voltage of the base-collector junction). The Schottky temperature coefficient is lower than the coefficient of the B–C junction, which limits the use of PdSi at higher temperatures. For power Schottky diodes, the parasitic resistances of the buried n+ layer and the epitaxial n-type layer become important. The resistance of the epitaxial layer is more important than it is for a transistor, as the current must cross its entire thickness. However, it serves as a distributed ballasting resistor over the entire area of the junction and, under usual conditions, prevents localized thermal runaway. In comparison with the power p–n diodes, the Schottky diodes are less rugged. The junction is in direct contact with the thermally sensitive metallization; a Schottky diode can therefore dissipate less power than an equivalent-size p–n counterpart with a deep-buried junction before failing (especially during reverse breakdown). The relative advantage of the lower forward voltage of Schottky diodes is diminished at higher forward currents, where the voltage drop is dominated by the series resistance.


Reverse recovery time

The most important difference between the p–n diode and the Schottky diode is the reverse recovery time (trr) when the diode switches from the conducting to the non-conducting state. In a p–n diode, the reverse recovery time can be in the order of several microseconds to less than 100 ns for fast diodes, and it is mainly limited by the
diffusion capacitance Diffusion Capacitance is the capacitance that happens due to transport of charge carriers between two terminals of a device, for example, the diffusion of carriers from anode to cathode in a forward biased diode or from emitter to baseforward-biase ...
caused by minority carriers accumulated in the diffusion region during the conducting state. Schottky diodes are significantly faster since they are unipolar devices and their speed is only limited by the junction capacitance. The switching time is ~100 ps for the small-signal diodes, and up to tens of nanoseconds for special high-capacity power diodes. With p–n-junction switching, there is also a reverse recovery current, which in high-power semiconductors brings increased
EMI EMI Group Limited (originally an initialism for Electric and Musical Industries, also referred to as EMI Records Ltd. or simply EMI) was a British Transnational corporation, transnational Conglomerate (company), conglomerate founded in March 1 ...
noise. With Schottky diodes, switching is essentially "instantaneous" with only a slight capacitive loading, which is much less of a concern. This "instantaneous" switching is not always the case. In higher voltage Schottky devices, in particular, the guard ring structure needed to control breakdown field geometry creates a parasitic p–n diode with the usual recovery time attributes. As long as this guard ring diode is not forward biased, it adds only capacitance. If the Schottky junction is driven hard enough however, the forward voltage eventually will bias both diodes forward and actual trr will be greatly impacted. It is often said that the Schottky diode is a "
majority carrier In physics, a charge carrier is a particle or quasiparticle that is free to move, carrying an electric charge, especially the particles that carry electric charges in electrical conductors. Examples are electrons, ions and holes. The term is use ...
" semiconductor device. This means that if the semiconductor body is a doped n-type, only the n-type carriers (mobile
electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have n ...
s) play a significant role in the normal operation of the device. The majority carriers are quickly injected into the conduction band of the metal contact on the other side of the diode to become free moving electrons. Therefore, no slow random recombination of n and p-type carriers is involved, so that this diode can cease conduction faster than an ordinary p–n rectifier
diode A diode is a two-terminal electronic component that conducts current primarily in one direction (asymmetric conductance); it has low (ideally zero) resistance in one direction, and high (ideally infinite) resistance in the other. A diod ...
. This property, in turn, allows a smaller device area, which also makes for a faster transition. This is another reason why Schottky diodes are useful in switch-mode power converters: the high speed of the diode means that the circuit can operate at frequencies in the range 200 kHz to 2 MHz, allowing the use of small
inductor An inductor, also called a coil, choke, or reactor, is a passive two-terminal electrical component that stores energy in a magnetic field when electric current flows through it. An inductor typically consists of an insulated wire wound into a c ...
s and
capacitor A capacitor is a device that stores electrical energy in an electric field by virtue of accumulating electric charges on two close surfaces insulated from each other. It is a passive electronic component with two terminals. The effect of ...
s with greater efficiency than would be possible with other diode types. Small-area Schottky diodes are the heart of RF
detectors A sensor is a device that produces an output signal for the purpose of sensing a physical phenomenon. In the broadest definition, a sensor is a device, module, machine, or subsystem that detects events or changes in its environment and sends ...
and mixers, which often operate at frequencies up to 50 GHz.


Limitations

The most evident limitations of Schottky diodes are their relatively low reverse voltage ratings, and their relatively high
reverse leakage current Reverse leakage current in a semiconductor device is the current from that semiconductor device when the device is reverse biased. When a semiconductor device is reverse biased it should not conduct any current, however, due to an increased ba ...
. For silicon-metal Schottky diodes, the reverse voltage is typically 50 V or less. Some higher-voltage designs are available (200 V is considered a high reverse voltage). Reverse leakage current, since it increases with temperature, leads to a thermal instability issue. This often limits the useful reverse voltage to well below the actual rating. While higher reverse voltages are achievable, they would present a higher forward voltage, comparable to other types of standard diodes. Such Schottky diodes would have no advantage unless great switching speed is required.


Silicon carbide Schottky diode

Schottky diodes constructed from
silicon carbide Silicon carbide (SiC), also known as carborundum (), is a hard chemical compound containing silicon and carbon. A semiconductor, it occurs in nature as the extremely rare mineral moissanite, but has been mass-produced as a powder and crystal s ...
have a much lower reverse leakage current than
silicon Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic ...
Schottky diodes, as well as higher forward voltage (about 1.4–1.8 V at 25 °C) and reverse voltage. they were available from manufacturers in variants up to 1700 V of reverse voltage. Silicon carbide has a high thermal conductivity, and temperature has little influence on its switching and thermal characteristics. With special packaging, silicon carbide Schottky diodes can operate at junction temperatures of over 500  K (about 200 °C), which allows passive radiative cooling in
aerospace Aerospace is a term used to collectively refer to the atmosphere and outer space. Aerospace activity is very diverse, with a multitude of commercial, industrial and military applications. Aerospace engineering consists of aeronautics and ast ...
applications.


Applications


Voltage clamping

While standard silicon diodes have a forward voltage drop of about 0.7 V and germanium diodes 0.3 V, Schottky diodes' voltage drop at forward biases of around 1 mA is in the range of 0.15 V to 0.46 V (see the 1N5817 and 1N5711), which makes them useful in voltage clamping applications and prevention of transistor saturation. This is due to the higher
current density In electromagnetism, current density is the amount of charge per unit time that flows through a unit area of a chosen cross section. The current density vector is defined as a vector whose magnitude is the electric current per cross-sectional a ...
in the Schottky diode.


Reverse current and discharge protection

Because of a Schottky diode's low forward voltage drop, less energy is wasted as heat, making them the most efficient choice for applications sensitive to efficiency. For instance, they are used in stand-alone ("off-grid")
photovoltaic Photovoltaics (PV) is the conversion of light into electricity using semiconducting materials that exhibit the photovoltaic effect, a phenomenon studied in physics, photochemistry, and electrochemistry. The photovoltaic effect is commercially ...
(PV) systems to prevent
batteries Battery most often refers to: * Electric battery, a device that provides electrical power * Battery (crime), a crime involving unlawful physical contact Battery may also refer to: Energy source *Automotive battery, a device to provide power t ...
from discharging through the solar panels at night, called "blocking diodes". They are also used in grid-connected systems with multiple strings connected in parallel, in order to prevent reverse current flowing from adjacent strings through shaded strings if the "bypass diodes" have failed.


Switched-mode power supplies

Schottky diodes are also used as
rectifiers A rectifier is an electrical device that converts alternating current (AC), which periodically reverses direction, to direct current (DC), which flows in only one direction. The reverse operation (converting DC to AC) is performed by an inve ...
in
switched-mode power supplies A switched-mode power supply (switching-mode power supply, switch-mode power supply, switched power supply, SMPS, or switcher) is an electronic power supply that incorporates a switching regulator to convert electrical power efficiently. Like ...
. The low forward voltage and fast recovery time leads to increased efficiency. They can also be used in power supply " OR"ing circuits in products that have both an internal
battery Battery most often refers to: * Electric battery, a device that provides electrical power * Battery (crime), a crime involving unlawful physical contact Battery may also refer to: Energy source *Automotive battery, a device to provide power t ...
and a mains adapter input, or similar. However, the high reverse leakage current presents a problem in this case, as any high-impedance voltage sensing circuit (e.g., monitoring the battery voltage or detecting whether a mains adapter is present) will see the voltage from the other power source through the diode leakage.


Sample-and-hold circuits

Schottky diodes can be used in diode-bridge based
sample and hold In electronics, a sample and hold (also known as sample and follow) circuit is an analog device that samples (captures, takes) the voltage of a continuously varying analog signal and holds (locks, freezes) its value at a constant level for a ...
circuits. When compared to regular
p–n junction A p–n junction is a boundary or interface between two types of semiconductor materials, p-type and n-type, inside a single crystal of semiconductor. The "p" (positive) side contains an excess of holes, while the "n" (negative) side contai ...
based diode bridges, Schottky diodes can offer advantages. A forward-biased Schottky diode does not have any minority carrier charge storage. This allows them to switch more quickly than regular diodes, resulting in lower transition time from the sample to the hold step. The absence of minority carrier charge storage also results in a lower hold step or sampling error, resulting in a more accurate sample at the output.


Charge control

Due to its efficient electric field control, Schottky diodes can be used to accurately load or unload single electrons in semiconductor nanostructures such as quantum wells or quantum dots.


Designation

Commonly encountered Schottky diodes include the 1N58xx series rectifiers, such as the 1N581x (1 A) and 1N582x (3 A) through-hole parts, and the SS1x (1 A) and SS3x (3 A) surface-mount parts. Schottky rectifiers are available in numerous surface-mount package styles. Small-signal Schottky diodes such as the 1N5711, 1N6263, 1SS106, 1SS108, and the BAT41–43, 45–49 series are widely used in high-frequency applications as detectors, mixers and nonlinear elements, and have superseded germanium diodes. They are also suitable for
electrostatic discharge Electrostatic discharge (ESD) is a sudden and momentary flow of electric current between two electrically charged objects caused by contact, an electrical short or dielectric breakdown. A buildup of static electricity can be caused by tribochar ...
(ESD) protection of sensitive devices such as III-V-semiconductor devices,
laser diode The laser diode chip removed and placed on the eye of a needle for scale A laser diode (LD, also injection laser diode or ILD, or diode laser) is a semiconductor device similar to a light-emitting diode in which a diode pumped directly with ...
s and, to a lesser extent, exposed lines of
CMOS Complementary metal–oxide–semiconductor (CMOS, pronounced "sea-moss", ) is a type of metal–oxide–semiconductor field-effect transistor (MOSFET) fabrication process that uses complementary and symmetrical pairs of p-type and n-type MOSF ...
circuitry. Schottky metal–semiconductor junctions are featured in the successors to the 7400
TTL TTL may refer to: Photography * Through-the-lens metering, a camera feature * Zenit TTL, an SLR film camera named for its TTL metering capability Technology * Time to live, a computer data lifespan-limiting mechanism * Transistor–transistor lo ...
family of logic devices, the 74S, 74LS and 74ALS series, where they are employed as
Baker clamp Baker clamp is a generic name for a class of electronic circuits that reduce the storage time of a switching bipolar junction transistor (BJT) by applying a nonlinear negative feedback through various kinds of diodes. The reason for slow turn-off t ...
s in parallel with the collector-base junctions of the
bipolar transistor A bipolar junction transistor (BJT) is a type of transistor that uses both electrons and electron holes as charge carriers. In contrast, a unipolar transistor, such as a field-effect transistor, uses only one kind of charge carrier. A bipolar t ...
s to prevent their saturation, thereby greatly reducing their turn-off delays.


Alternatives

When less power dissipation is desired, a
MOSFET The metal–oxide–semiconductor field-effect transistor (MOSFET, MOS-FET, or MOS FET) is a type of field-effect transistor (FET), most commonly fabricated by the controlled oxidation of silicon. It has an insulated gate, the voltage of which d ...
and a control circuit can be used instead, in an operation mode known as
active rectification Active rectification, or synchronous rectification, is a technique for improving the efficiency of rectification by replacing diodes with actively controlled switches, usually power MOSFETs or power bipolar junction transistors (BJT). Whereas norm ...
. A
super diode The precision rectifier is a configuration obtained with an operational amplifier in order to have a circuit behave like an ideal diode and rectifier.Paul Horowitz and Winfield Hill, ''The Art of Electronics''. 2nd ed. Cambridge University Press ...
consisting of a pn-diode or Schottky diode and an
operational amplifier An operational amplifier (often op amp or opamp) is a DC-coupled high-gain electronic voltage amplifier with a differential input and, usually, a single-ended output. In this configuration, an op amp produces an output potential (relative to c ...
provides an almost perfect diode characteristic due to the effect of negative feedback, although its use is restricted to frequencies the operational amplifier used can handle.


Electrowetting

Electrowetting Electrowetting is the modification of the wetting properties of a surface (which is typically hydrophobic) with an applied electric field. History The electrowetting of mercury and other liquids on variably charged surfaces was probably first ex ...
can be observed when a Schottky diode is formed using a
droplet A drop or droplet is a small column of liquid, bounded completely or almost completely by free surfaces. A drop may form when liquid accumulates at the lower end of a tube or other surface boundary, producing a hanging drop called a pendant ...
of liquid metal, e.g. mercury, in contact with a semiconductor, e.g.
silicon Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic ...
. Depending on the doping type and density in the semiconductor, the droplet spreading depends on the magnitude and sign of the voltage applied to the mercury droplet. This effect has been termed ‘Schottky electrowetting’.


See also

*
Schottky barrier A Schottky barrier, named after Walter H. Schottky, is a potential energy barrier for electrons formed at a metal–semiconductor junction. Schottky barriers have rectifying characteristics, suitable for use as a diode. One of the primary ch ...
*
Schottky effect The Schottky effect or field enhanced thermionic emission is a phenomenon in condensed matter physics named after Walter H. Schottky. In electron emission devices, especially electron guns, the thermionic electron emitter will be biased negative ...
(Schottky emission) *
Heterostructure barrier varactor The heterostructure barrier varactor (HBV) is a semiconductor device which shows a variable capacitance with voltage bias, similar to a varactor diode. Unlike a diode, it has an anti-symmetric current-voltage relationship and a symmetric capacitan ...
diode *
Active rectification Active rectification, or synchronous rectification, is a technique for improving the efficiency of rectification by replacing diodes with actively controlled switches, usually power MOSFETs or power bipolar junction transistors (BJT). Whereas norm ...
*
Baker clamp Baker clamp is a generic name for a class of electronic circuits that reduce the storage time of a switching bipolar junction transistor (BJT) by applying a nonlinear negative feedback through various kinds of diodes. The reason for slow turn-off t ...
and
Schottky transistor A Schottky transistor is a combination of a transistor and a Schottky diode that prevents the transistor from saturating by diverting the excessive input current. It is also called a Schottky-clamped transistor. Mechanism Standard transistor ...
*
1N58xx Schottky diodes The 1N58xx is a series of medium power, fast, low voltage Schottky diodes, which consists of part number numbers 1N5817 through 1N5825. Overview The 1N581''x'' are typically packaged in the DO-41 axial through-hole case, and in many cases are ...
*
Electrowetting Electrowetting is the modification of the wetting properties of a surface (which is typically hydrophobic) with an applied electric field. History The electrowetting of mercury and other liquids on variably charged surfaces was probably first ex ...


References


External links


"Characteristics of Schottky Diodes"
– PowerGuru
"Introduction to Schottky Rectifiers"

"Is the lowest forward voltage drop of real schottky diodes always the best choice?"
Technical application,
IXYS Corporation IXYS Corporation is an American company based in Milpitas, California. IXYS focuses on power semiconductors, radio-frequency (RF) power semiconductors, and digital and analog integrated circuits (ICs). History Dr. Nathan Zommer founded IXYS Cor ...
.
"Schottky diode" in ''Electronics Notes''
{{Authority control Diodes