The stretched exponential function
is obtained by inserting a fractional
power law
In statistics, a power law is a Function (mathematics), functional relationship between two quantities, where a Relative change and difference, relative change in one quantity results in a proportional relative change in the other quantity, inde ...
into the
exponential function.
In most applications, it is meaningful only for arguments between 0 and +∞. With , the usual exponential function is recovered. With a ''stretching exponent'' ''β'' between 0 and 1, the graph of log ''f'' versus ''t'' is characteristically ''stretched'', hence the name of the function. The compressed exponential function (with ) has less practical importance, with the notable exception of , which gives the
normal distribution.
In mathematics, the stretched exponential is also known as the
complementary cumulative Weibull distribution. The stretched exponential is also the
characteristic function, basically the
Fourier transform
A Fourier transform (FT) is a mathematical transform that decomposes functions into frequency components, which are represented by the output of the transform as a function of frequency. Most commonly functions of time or space are transformed, ...
, of the
Lévy symmetric alpha-stable distribution.
In physics, the stretched exponential function is often used as a phenomenological description of
relaxation in disordered systems. It was first introduced by
Rudolf Kohlrausch in 1854 to describe the discharge of a capacitor; thus it is also known as the Kohlrausch function. In 1970, G. Williams and D.C. Watts used the
Fourier transform
A Fourier transform (FT) is a mathematical transform that decomposes functions into frequency components, which are represented by the output of the transform as a function of frequency. Most commonly functions of time or space are transformed, ...
of the stretched exponential to describe
dielectric spectra of polymers; in this context, the stretched exponential or its Fourier transform are also called the Kohlrausch–Williams–Watts (KWW) function.
In phenomenological applications, it is often not clear whether the stretched exponential function should be used to describe the differential or the integral distribution function—or neither.
In each case, one gets the same asymptotic decay, but a different power law prefactor, which makes fits more ambiguous than for simple exponentials. In a few cases, it can be shown that the asymptotic decay is a stretched exponential, but the prefactor is usually an unrelated power.
Mathematical properties
Moments
Following the usual physical interpretation, we interpret the function argument ''t'' as time, and ''f''
β(''t'') is the differential distribution. The area under the curve
can thus be interpreted as a ''mean relaxation time''. One finds
where is the
gamma function
In mathematics, the gamma function (represented by , the capital letter gamma from the Greek alphabet) is one commonly used extension of the factorial function to complex numbers. The gamma function is defined for all complex numbers except ...
. For exponential decay, is recovered.
The higher
moments of the stretched exponential function are
Distribution function
In physics, attempts have been made to explain stretched exponential behaviour as a linear superposition of simple exponential decays. This requires a nontrivial distribution of relaxation times, ''ρ''(''u''), which is implicitly defined by
Alternatively, a distribution
is used.
''ρ'' can be computed from the series expansion:
For rational values of ''β'', ''ρ''(''u'') can be calculated in terms of elementary functions. But the expression is in general too complex to be useful except for the case where
Figure 2 shows the same results plotted in both a
linear and a
log representation. The curves converge to a
Dirac delta function
In mathematics, the Dirac delta distribution ( distribution), also known as the unit impulse, is a generalized function or distribution over the real numbers, whose value is zero everywhere except at zero, and whose integral over the entire ...
peaked at as ''β'' approaches 1, corresponding to the simple exponential function.
The moments of the original function can be expressed as
The first logarithmic moment of the distribution of simple-exponential relaxation times is
where Eu is the
Euler constant.
Fourier transform
To describe results from spectroscopy or inelastic scattering, the sine or cosine Fourier transform of the stretched exponential is needed. It must be calculated either by numeric integration, or from a series expansion. The series here as well as the one for the distribution function are special cases of the
Fox–Wright function. For practical purposes, the Fourier transform may be approximated by the
Havriliak–Negami function, though nowadays the numeric computation can be done so efficiently that there is no longer any reason not to use the Kohlrausch–Williams–Watts function in the frequency domain.
History and further applications
As said in the introduction, the stretched exponential was introduced by the
German physicist Rudolf Kohlrausch in 1854 to describe the discharge of a capacitor (
Leyden jar) that used glass as dielectric medium. The next documented usage is by
Friedrich Kohlrausch, son of Rudolf, to describe torsional relaxation.
A. Werner
A is the first letter of the Latin and English alphabet.
A may also refer to:
Science and technology Quantities and units
* ''a'', a measure for the attraction between particles in the Van der Waals equation
* ''A'' value, a measure of ...
used it in 1907 to describe complex luminescence decays;
Theodor Förster in 1949 as the fluorescence decay law of electronic energy donors.
Outside condensed matter physics, the stretched exponential has been used to describe the removal rates of small, stray bodies in the solar system, the diffusion-weighted MRI signal in the brain, and the production from unconventional gas wells.
In probability,
If the integrated distribution is a stretched exponential, the normalized
probability density function is given by
Note that confusingly some authors have been known to use the name "stretched exponential" to refer to the
Weibull distribution.
Modified functions
A modified stretched exponential function
with a slowly ''t''-dependent exponent ''β'' has been used for biological survival curves.
Wireless Communications
In wireless communications, a scaled version of the stretched exponential function has been shown to appear in the Laplace Transform for the interference power
when the transmitters' locations are modeled as a 2D
Poisson Point Process with no exclusion region around the receiver.
The
Laplace Transform can be written for arbitrary
fading
In wireless communications, fading is variation of the attenuation of a signal with various variables. These variables include time, geographical position, and radio frequency. Fading is often modeled as a random process. A fading channel is a ...
distribution as follows:
where
is the power of the fading,
is the
path loss exponent,
is the density of the 2D Poisson Point Process,
is the Gamma function, and