Stickies (papermaking)
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When recycling post-consumer paper, stickies are tacky substances contained in the
paper pulp Pulp is a fibrous lignocellulosic material prepared by chemically, semi-chemically, or mechanically isolating the cellulosic fibers of wood, fiber crops, waste paper, or rags. Mixed with water and other chemicals or plant-based additives, pul ...
and process water systems of
paper machine A paper machine (or paper-making machine) is an industrial machine which is used in the pulp and paper industry to create paper in large quantities at high speed. Modern paper-making machines are based on the principles of the Fourdrinier Machin ...
s. Stickies have the potential to contaminate the components either within or around the equipment necessary in the Stages of Manufacturing that a
Paper Mill A paper mill is a factory devoted to making paper from vegetable fibres such as wood pulp, old rags, and other ingredients. Prior to the invention and adoption of the Fourdrinier machine and other types of paper machine that use an endless belt ...
follows in its Developed Process, but would have otherwise excluded it in its routine cleaning and maintenance procedures.
Contamination Contamination is the presence of a constituent, impurity, or some other undesirable element that renders something unsuitable, unfit or harmful for the physical body, natural environment, workplace, etc. Types of contamination Within the scien ...
s of
paper Paper is a thin sheet material produced by mechanically or chemically processing cellulose fibres derived from wood, Textile, rags, poaceae, grasses, Feces#Other uses, herbivore dung, or other vegetable sources in water. Once the water is dra ...
that are classified as tacky are also called stickies. The main sources for stickies are
recycled paper The recycling of paper is the process by which waste paper is turned into new paper products. It has several important benefits: It saves waste paper from occupying the homes of people and producing methane as it breaks down. Because paper fibr ...
, waxes, and soft adhesives.


Composition

Stickies are an indefinite mixture of
organic compound Some chemical authorities define an organic compound as a chemical compound that contains a carbon–hydrogen or carbon–carbon bond; others consider an organic compound to be any chemical compound that contains carbon. For example, carbon-co ...
s, with the main part being different
ester In chemistry, an ester is a compound derived from an acid (either organic or inorganic) in which the hydrogen atom (H) of at least one acidic hydroxyl group () of that acid is replaced by an organyl group (R). These compounds contain a distin ...
s. The components might stem from: *Printing
ink Ink is a gel, sol, or solution that contains at least one colorant, such as a dye or pigment, and is used to color a surface to produce an image, text, or design. Ink is used for drawing or writing with a pen, brush, reed pen, or quill. ...
s *Coating binders (synthetic
latex Latex is an emulsion (stable dispersion) of polymer microparticles in water. Latices are found in nature, but synthetic latices are common as well. In nature, latex is found as a wikt:milky, milky fluid, which is present in 10% of all floweri ...
) *
Waxes Waxes are a diverse class of organic compounds that are lipophilic, malleable solids near ambient temperatures. They include higher alkanes and lipids, typically with melting points above about 40 Â°C (104 Â°F), melting to give low ...
* Hot melt adhesive and unsupported
pressure-sensitive adhesive Pressure-sensitive adhesive (PSA, self-adhesive, self-stick adhesive) is a type of nonreactive adhesive which forms a bond when pressure is applied to bond the adhesive with a surface. No solvent, water, or heat is needed to activate the adhesive ...
s *
Plastics Plastics are a wide range of synthetic or semisynthetic materials composed primarily of polymers. Their defining characteristic, plasticity, allows them to be molded, extruded, or pressed into a diverse range of solid forms. This adaptab ...
*
Wet strength The wet strength of paper and paperboard is a measure of how well the web of fibers holding the paper together can resist a force of rupture when the paper is wet. Wet strength is routinely expressed as the ratio of wet to dry tensile force at bre ...
resin A resin is a solid or highly viscous liquid that can be converted into a polymer. Resins may be biological or synthetic in origin, but are typically harvested from plants. Resins are mixtures of organic compounds, predominantly terpenes. Commo ...
s * Pitch *
Papermaking Papermaking is the manufacture of paper and cardboard, which are used widely for printing, writing, and packaging, among many other purposes. Today almost all paper is Pulp and paper industry, made using industrial machinery, while handmade pape ...
additives


Properties

Stickies that pass through a slotted plate screen of 0.10 - 0.15 mm are called ''micro stickies''. Micro stickies can be finely dispersed (100
μm The micrometre (Commonwealth English as used by the International Bureau of Weights and Measures; SI symbol: μm) or micrometer (American English), also commonly known by the non-SI term micron, is a unit of length in the International System ...
- 100 nm), colloidal (100 - 10 nm) or molecularly dissolved (< 10 nm). Macro stickies are those which are retained as screening residue. The reason for this classification is that macro stickies are easy to remove from the
deinked pulp Pulp is a fibrous lignocellulosic material prepared by chemically, semi-chemically, or mechanically isolating the cellulosic fibers of wood, fiber crops, waste paper, or rags. Mixed with water and other chemicals or plant-based additives, pul ...
during the
deinking Deinking is the industrial process of removing printing ink from paperfibers of recycled paper to make deinked pulp. The key in the deinking process is the ability to detach ink from the fibers. This is achieved by a combination of mechanical a ...
process by means of filtration. Micro stickies are transported with the pulp to the
paper machine A paper machine (or paper-making machine) is an industrial machine which is used in the pulp and paper industry to create paper in large quantities at high speed. Modern paper-making machines are based on the principles of the Fourdrinier Machin ...
and might
agglomerate Agglomerate (from the Latin ''agglomerare'' meaning "to form into a ball") is a coarse accumulation of large blocks of volcanic material that contains at least 75% bombs. Volcanic bombs differ from volcanic blocks in that their shape records flui ...
and cause problematic
deposits A deposit account is a bank account maintained by a financial institution in which a customer can deposit and withdraw money. Deposit accounts can be savings accounts, current accounts or any of several other types of accounts explained below. ...
there. Stickies often have
thermoplastic A thermoplastic, or thermosoftening plastic, is any plastic polymer material that becomes pliable or moldable at a certain elevated temperature and solidifies upon cooling. Most thermoplastics have a high molecular weight. The polymer chains as ...
properties. Chemical-physical alterations like pH,
temperature Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making ...
and
charge Charge or charged may refer to: Arts, entertainment, and media Films * ''Charge, Zero Emissions/Maximum Speed'', a 2011 documentary Music * ''Charge'' (David Ford album) * ''Charge'' (Machel Montano album) * '' Charge!!'', an album by The Aqu ...
changes might cause colloidal destabilization and
agglomeration Agglomeration may refer to: * Urban agglomeration, in standard English * Megalopolis, in Chinese English, as defined in China's ''Standard for basic terminology of urban planning'' (GB/T 50280—98). Also known as "city cluster". * Economies of agg ...
of micro stickies.


Stickies control

Several control methods are used: *Alteration of the physical properties, like using recycling-friendly paper coatings *Avoidance of troublesome components that cause stickies *Removal by more effective
deinking Deinking is the industrial process of removing printing ink from paperfibers of recycled paper to make deinked pulp. The key in the deinking process is the ability to detach ink from the fibers. This is achieved by a combination of mechanical a ...
processes, like improved screening, cleaning, washing and flotation *Passivation with process additives like fixation agents *Prevention by washing wires or protecting equipment parts with chemicals. *Measuring stickies using TAPPI method T274 and T277


References

{{Paper Papermaking Paper recycling