Sodium Compounds

Sodium atoms have 11 electrons, one more than the stable configuration of the noble gas neon. As a result, sodium usually forms ionic compounds involving the Na⁺ cation. Sodium is a reactive alkali metal and is much more stable in ionic compounds. It can also form intermetallic compounds and organosodium compounds. Sodium compounds are often soluble in water.

Metallic sodium

Metallic sodium is generally less reactive than potassium and more reactive than lithium. Sodium metal is highly reducing, with the standard reduction potential for the Na⁺/Na couple being −2.71 volts, though potassium and lithium have even more negative potentials.
The thermal, fluidic, chemical, and nuclear properties of molten sodium metal have caused it to be one of the main coolants of choice for the fast breeder reactor. Such nuclear reactors are seen as a crucial step for the production of clean energy.

Salts and oxides

Sodium compounds are of immense commercial importance, being particularly central to industries producing glass, paper, soap, and textiles.Alfred Klemm, Gabriele Hartmann, Ludwig Lange, "Sodium and Sodium Alloys" in Ullmann's Encyclopedia of Industrial Chemistry 2005, Wiley-VCH, Weinheim. The most important sodium compounds are table salt (Na Cl), soda ash (Na₂ CO₃), baking soda (Na HCO₃), caustic soda (NaOH), sodium nitrate (Na NO₃), di- and tri- sodium phosphates, sodium thiosulfate (Na₂ S₂O₃·5H₂O), and borax (Na₂ B₄O₇·10H₂O). In compounds, sodium is usually ionically bonded to water and anions and is viewed as a hard Lewis acid.

Most soaps are sodium salts of fatty acids. Sodium soaps have a higher melting temperature (and seem "harder") than potassium soaps. Sodium containing mixed oxides are promising catalysts and photocatalysts. Photochemically intercalated sodium ion enhances the photoelectrocatalytic activity of WO₃.

Like all the alkali metals, sodium reacts exothermically with water. The reaction produces caustic soda (sodium hydroxide) and flammable hydrogen gas. When burned in air, it forms primarily sodium peroxide with some sodium oxide.Greenwood and Earnshaw, p. 84

Aqueous solutions

Sodium tends to form water-soluble compounds, such as halides, sulfates, nitrates, carboxylates and carbonates. The main aqueous species are the aquo complexes a(H₂O)_''n''sup>+, where ''n'' = 4–8; with ''n'' = 6 indicated from X-ray diffraction data and computer simulations.

Direct precipitation of sodium salts from aqueous solutions is rare because sodium salts typically have a high affinity for water. An exception is sodium bismuthate (NaBiO₃). Because of the high solubility of its compounds, sodium salts are usually isolated as solids by evaporation or by precipitation with an organic antisolvent, such as ethanol; for example, only 0.35 g/L of sodium chloride will dissolve in ethanol. Crown ethers, like 15-crown-5, may be used as a phase-transfer catalyst.

Sodium content of samples is determined by atomic absorption spectrophotometry or by potentiometry using ion-selective electrodes.

Electrides and sodides

Like the other alkali metals, sodium dissolves in ammonia and some amines to give deeply colored solutions; evaporation of these solutions leaves a shiny film of metallic sodium. The solutions contain the coordination complex (Na(NH₃)₆)⁺, with the positive charge counterbalanced by electrons as anions; cryptands permit the isolation of these complexes as crystalline solids. Sodium forms complexes with crown ethers, cryptands and other ligands.

For example, 15-crown-5 has a high affinity for sodium because the cavity size of 15-crown-5 is 1.7–2.2 Å, which is enough to fit the sodium ion (1.9 Å). Cryptands, like crown ethers and other ionophores, also have a high affinity for the sodium ion; derivatives of the alkalide Na⁻ are obtainable by the addition of cryptands to solutions of sodium in ammonia via disproportionation.

Organosodium compounds

Many organosodium compounds have been prepared. Because of the high polarity of the C-Na bonds, they behave like sources of carbanions (salts with organic anions). Some well-known derivatives include sodium cyclopentadienide (NaC₅H₅) and trityl sodium ((C₆H₅)₃CNa). Sodium naphthalene, Na⁺ ₁₀H₈•sup>−, a strong reducing agent, forms upon mixing Na and naphthalene in ethereal solutions.

Intermetallic compounds

Sodium forms alloys with many metals, such as potassium, calcium, lead, and the group 11 and 12 elements. Sodium and potassium form KNa₂ and NaK. NaK is 40–90% potassium and it is liquid at ambient temperature. It is an excellent thermal and electrical conductor. Sodium-calcium alloys are by-products of the electrolytic production of sodium from a binary salt mixture of NaCl-CaCl₂ and ternary mixture NaCl-CaCl₂-BaCl₂. Calcium is only partially miscible with sodium, and the 1-2% of it dissolved in the sodium obtained from said mixtures can be precipitated by cooling to 120 °C and filtering.

In a liquid state, sodium is completely miscible with lead. There are several methods to make sodium-lead alloys. One is to melt them together and another is to deposit sodium electrolytically on molten lead cathodes. NaPb₃, NaPb, Na₉Pb₄, Na₅Pb₂, and Na₁₅Pb₄ are some of the known sodium-lead alloys. Sodium also forms alloys with gold (NaAu₂) and silver (NaAg₂). Group 12 metals (zinc, cadmium and mercury) are known to make alloys with sodium. NaZn₁₃ and NaCd₂ are alloys of zinc and cadmium. Sodium and mercury form NaHg, NaHg₄, NaHg₂, Na₃Hg₂, and Na₃Hg.

See also

* Lithium compounds
* Magnesium compounds

References

{{Sodium compounds

Sodium
Sodium compounds
Chemical compounds by element