Smart materials, also called intelligent or responsive materials, are designed materials that have one or more properties that can be significantly changed in a controlled fashion by external stimuli, such as
stress, moisture,
electric
Electricity is the set of physical phenomena associated with the presence and motion of matter that has a property of electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described b ...
or
magnetic
Magnetism is the class of physical attributes that are mediated by a magnetic field, which refers to the capacity to induce attractive and repulsive phenomena in other entities. Electric currents and the magnetic moments of elementary particles ...
fields, light,
temperature
Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer.
Thermometers are calibrated in various temperature scales that historically have relied on ...
,
pH, or chemical compounds. Smart materials are the basis of many applications, including
sensors
A sensor is a device that produces an output signal for the purpose of sensing a physical phenomenon.
In the broadest definition, a sensor is a device, module, machine, or subsystem that detects events or changes in its environment and sends ...
and
actuators
An actuator is a component of a machine that is responsible for moving and controlling a mechanism or system, for example by opening a valve. In simple terms, it is a "mover".
An actuator requires a control device (controlled by control signal) ...
, or
artificial muscles, particularly as
electroactive polymers
file:EAP-example2.png, (a) Cartoon drawing of an EAP gripping device.(b) A voltage is applied and the EAP fingers deform in order to release the ball.(c) When the voltage is removed, the EAP fingers return to their original shape and grip the ball
...
(EAPs).
Terms used to describe smart materials include shape memory material (SMM) and shape memory technology (SMT).
Types
There are a number of types of smart material, of which are already common. Some examples are as following:
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Piezoelectric
Piezoelectricity (, ) is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied mechanical stress. The word ' ...
materials are materials that produce a voltage when stress is applied. Since this effect also applies in a reverse manner, a voltage across the sample will produce stress within sample. Suitably designed structures made from these materials can, therefore, be made that bend, expand or contract when a voltage is applied.
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Shape-memory alloy
In metallurgy, a shape-memory alloy (SMA) is an alloy that can be deformed when cold but returns to its pre-deformed ("remembered") shape when heated. It may also be called memory metal, memory alloy, smart metal, smart alloy, or muscle wire.
P ...
s and
shape-memory polymer
Shape-memory polymers (SMPs) are polymeric smart materials that have the ability to return from a deformed state (temporary shape) to their original (permanent) shape when induced by an external stimulus (trigger), such as temperature change.
P ...
s are materials in which large deformation can be induced and recovered through temperature changes or stress changes (
pseudoelasticity Pseudoelasticity, sometimes called superelasticity, is an elastic (reversible) response to an applied stress, caused by a phase transformation between the austenitic and martensitic phases of a crystal. It is exhibited in shape-memory alloys.
Ov ...
). The shape memory effect results due to respectively martensitic phase change and induced elasticity at higher temperatures.
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Photovoltaic
Photovoltaics (PV) is the conversion of light into electricity using semiconducting materials that exhibit the photovoltaic effect, a phenomenon studied in physics, photochemistry, and electrochemistry. The photovoltaic effect is commercially ...
materials or
optoelectronics
Optoelectronics (or optronics) is the study and application of electronic devices and systems that find, detect and control light, usually considered a sub-field of photonics. In this context, ''light'' often includes invisible forms of radiati ...
convert light to electrical current.
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Electroactive polymers
file:EAP-example2.png, (a) Cartoon drawing of an EAP gripping device.(b) A voltage is applied and the EAP fingers deform in order to release the ball.(c) When the voltage is removed, the EAP fingers return to their original shape and grip the ball
...
(EAPs) change their volume by voltage or electric fields.
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Magnetostrictive
Magnetostriction (cf. electrostriction) is a property of magnetic materials that causes them to change their shape or dimensions during the process of magnetization. The variation of materials' magnetization due to the applied magnetic field chang ...
materials exhibit a change in shape under the influence of magnetic field and also exhibit a change in their magnetization under the influence of mechanical stress.
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Magnetic shape memory Magnetic shape memory alloys (MSMAs), also called ferromagnetic shape memory alloys (FSMA), are particular shape memory alloys which produce forces and deformations in response to a magnetic field. The thermal shape memory effect has been obtained ...
alloys are materials that change their shape in response to a significant change in the magnetic field.
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Smart inorganic polymers
Smart inorganic polymers (SIPs) are hybrid or fully inorganic polymers with tunable (smart) properties such as stimuli responsive physical properties (shape, conductivity, rheology, bioactivity, self-repair, sensing etc.). While organic polymers ar ...
showing tunable and responsive properties.
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pH-sensitive polymers
pH sensitive or pH responsive polymers are materials which will respond to the changes in the pH of the surrounding medium by varying their dimensions. Materials may swell, collapse, or change depending on the pH of their environment. This behavio ...
are materials that change in volume when the pH of the surrounding medium changes.
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Temperature-responsive polymers
Temperature-responsive polymers or thermoresponsive polymers are polymers that exhibit drastic and discontinuous changes in their physical properties with temperature. The term is commonly used when the property concerned is solubility in a given ...
are materials which undergo changes upon temperature.
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Halochromic materials are commonly used materials that change their color as a result of changing acidity. One suggested application is for paints that can change color to indicate
corrosion
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engi ...
in the metal underneath them.
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Chromogenic systems change color in response to electrical, optical or thermal changes. These include
electrochromic
Electrochromism is a phenomenon in which a material displays changes in color or opacity in response to an electrical stimulus.
In this way, a smart window made of an electrochromic material can block specific wavelengths of ultraviolet, visib ...
materials, which change their colour or opacity on the application of a voltage (e.g.,
liquid crystal display
A liquid-crystal display (LCD) is a flat-panel display or other electronically modulated optical device that uses the light-modulating properties of liquid crystals combined with polarizers. Liquid crystals do not emit light directly but ...
s),
thermochromic
Thermochromism is the property of substances to change color due to a change in temperature. A mood ring is an excellent example of this phenomenon, but thermochromism also has more practical uses, such as baby bottles which change to a differen ...
materials change in colour depending on their temperature, and
photochromic
Photochromism is the reversible transformation of a chemical species (photoswitch) between two forms by the absorption of electromagnetic radiation (photoisomerization), where the two forms have different absorption spectra. In plain language, th ...
materials, which change colour in response to light—for example, light-sensitive
sunglasses
Sunglasses or sun glasses (informally called shades or sunnies; more names below) are a form of protective eyewear designed primarily to prevent bright sunlight and high-energy visible light from damaging or discomforting the eyes. They can ...
that darken when exposed to bright sunlight.
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Ferrofluid
Ferrofluid is a liquid that is attracted to the poles of a magnet. It is a colloidal liquid made of nanoscale ferromagnetic or ferrimagnetic particles suspended in a carrier fluid (usually an organic solvent or water). Each magnetic par ...
s are magnetic fluids (affected by magnets and magnetic fields).
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Photomechanical materials change shape under exposure to light.
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Polycaprolactone
Polycaprolactone (PCL) is a biodegradable polyester with a low melting point of around 60 °C and a glass transition temperature of about −60 °C. The most common use of polycaprolactone is in the production of speciality polyuret ...
(polymorph) can be molded by immersion in hot water.
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Self-healing material
Self-healing materials are artificial or synthetically created substances that have the built-in ability to automatically repair damages to themselves without any external diagnosis of the problem or human intervention. Generally, materials will ...
s have the intrinsic ability to repair damage due to normal usage, thus expanding the material's lifetime.
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Dielectric elastomers
Dielectric elastomers (DEs) are smart material systems that produce large strains. They belong to the group of electroactive polymers (EAP). DE actuators (DEA) transform electric energy into mechanical work. They are lightweight and have a high ...
(DEs) are smart material systems which produce large strains (up to 500%) under the influence of an external electric field.
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Magnetocaloric materials are compounds that undergo a reversible change in temperature upon exposure to a changing magnetic field.
* Smart self-healing coatings heal without human intervention.
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Thermoelectric materials
Thermoelectric materials show the thermoelectric effect in a strong or convenient form.
The ''thermoelectric effect'' refers to phenomena by which either a temperature difference creates an electric potential or an electric current creates a te ...
are used to build devices that
convert temperature differences into electricity and vice versa.
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Chemoresponsive materials change size or volume under the influence of external chemical or biological compound.
[''Chemoresponsive Materials /Stimulation by Chemical and Biological Signals'', Schneider, H.-J.; Ed:, (2015)''The Royal Society of Chemistry,'' Cambridge https://dx.doi.org/10.1039/97817828822420]
Smart materials have properties that react to changes in their environment. This means that one of their properties can be changed by an external condition, such as temperature, light, pressure, electricity, voltage, pH, or chemical compounds. This change is reversible and can be repeated many times.
There is a wide range of different smart materials. Each offer different properties that can be changed. Some materials are very good and cover a huge range of the scales.
See also
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Smart polymer
Smart polymers, stimuli-responsive polymers or functional polymers are high-performance polymers that change according to the environment they are in. Such materials can be sensitive to a number of factors, such as temperature, humidity, pH, chem ...
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Programmable matter
Programmable matter is matter which has the ability to change its physical properties (shape, density, moduli, conductivity, optical properties, etc.) in a programmable fashion, based upon user input or autonomous sensing. Programmable matter is ...
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Sensors
A sensor is a device that produces an output signal for the purpose of sensing a physical phenomenon.
In the broadest definition, a sensor is a device, module, machine, or subsystem that detects events or changes in its environment and sends ...
*
Actuators
An actuator is a component of a machine that is responsible for moving and controlling a mechanism or system, for example by opening a valve. In simple terms, it is a "mover".
An actuator requires a control device (controlled by control signal) ...
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Artificial muscles
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Thermally induced shape-memory effect (polymers)
The thermally induced unidirectional shape-shape-memory effect is an effect classified within the new so-called smart materials. Polymers with thermally induced shape-memory effect are new materials, whose applications are recently being studied ...
References
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External links
Smart Materials Book Series Royal Society of Chemistry
Artificial materials