Sea ice
Sea ice arises as seawater freezes. Because ice is less density, dense than water, it floats on the ocean's surface (as does fresh water ice). Sea ice covers about 7% of the Earth's surface and about 12% of the world's oceans. Much of the world' ...
is a complex composite composed primarily of pure ice in various states of
crystallization
Crystallization is a process that leads to solids with highly organized Atom, atoms or Molecule, molecules, i.e. a crystal. The ordered nature of a crystalline solid can be contrasted with amorphous solids in which atoms or molecules lack regu ...
, but including air bubbles and pockets of
brine
Brine (or briny water) is a high-concentration solution of salt (typically sodium chloride or calcium chloride) in water. In diverse contexts, ''brine'' may refer to the salt solutions ranging from about 3.5% (a typical concentration of seawat ...
. Understanding its growth processes is important for
climate modellers and
remote sensing
Remote sensing is the acquisition of information about an physical object, object or phenomenon without making physical contact with the object, in contrast to in situ or on-site observation. The term is applied especially to acquiring inform ...
specialists, since the composition and microstructural properties of the ice affect how it reflects or absorbs sunlight.

Sea ice growth models for predicting the
ice distribution and extent are also valuable for shipping. An ice growth model can be combined with
remote sensing
Remote sensing is the acquisition of information about an physical object, object or phenomenon without making physical contact with the object, in contrast to in situ or on-site observation. The term is applied especially to acquiring inform ...
measurements in an
assimilation model as a means of generating more accurate
ice charts.
Overview
Several formation mechanisms of sea ice have been identified. At its earliest stages, sea ice consists of elongated, randomly oriented
crystals
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macrosc ...
. This is called
frazil, and mixed with water in the unconsolidated state is known as
grease ice. If wave and wind conditions are calm these crystals will consolidate at the surface, and by selective pressure begin to grow preferentially in the downward direction, forming
nilas
Sea ice arises as seawater freezes. Because ice is less dense than water, it floats on the ocean's surface (as does fresh water ice). Sea ice covers about 7% of the Earth's surface and about 12% of the world's oceans. Much of the world's sea ic ...
. In more turbulent conditions, the frazil will consolidate by mechanical action to form
pancake ice, which has a more random structure.
[
][
] Another common formation mechanism, especially in the
Antarctic
The Antarctic (, ; commonly ) is the polar regions of Earth, polar region of Earth that surrounds the South Pole, lying within the Antarctic Circle. It is antipodes, diametrically opposite of the Arctic region around the North Pole.
The Antar ...
where
precipitation
In meteorology, precipitation is any product of the condensation of atmospheric water vapor that falls from clouds due to gravitational pull. The main forms of precipitation include drizzle, rain, rain and snow mixed ("sleet" in Commonwe ...
over sea ice is high, is from snow deposition: on thin ice the snow will weigh down the ice enough to cause flooding. Subsequent freezing will form ice with a much more granular structure.
[
][
]
One of the more interesting processes to occur within consolidated ice packs is changes in
the
saline content. As the ice freezes, most of the
salt
In common usage, salt is a mineral composed primarily of sodium chloride (NaCl). When used in food, especially in granulated form, it is more formally called table salt. In the form of a natural crystalline mineral, salt is also known as r ...
content gets rejected and forms highly
saline
brine
Brine (or briny water) is a high-concentration solution of salt (typically sodium chloride or calcium chloride) in water. In diverse contexts, ''brine'' may refer to the salt solutions ranging from about 3.5% (a typical concentration of seawat ...
inclusions between the
crystals
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macrosc ...
. With decreasing temperatures in the ice sheet, the
size of the brine pockets decreases while the salt content goes up. Since ice is less
dense
Density (volumetric mass density or specific mass) is the ratio of a substance's mass to its volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' (or ''d'') can also be use ...
than
water, increasing
pressure
Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and eve ...
causes some of the brine to be ejected from both the top and bottom,
producing the characteristic C-shaped salinity profile of first-year ice.
[
]
Brine will also drain through vertical channels, particularly in the melt season. Thus
multi-year ice will tend
to have both lower salinity and lower density than first-year ice.
[ ] Sea-ice density is relatively stable during winter with values close to 910 kg/m
3, but may decrease up to 720 kg/m
3 during warming mainly due to increase in air volume. Air volume of sea ice in can be as high as 15% in summer and 4% in late autumn.
The main physical processes of sea-ice desalination are gravity drainage and flushing of surface
meltwater
Meltwater (or melt water) is water released by the melting of snow or ice, including glaciers, glacial ice, tabular icebergs and ice shelf, ice shelves over oceans. Meltwater is often found during early spring (season), spring when snow packs a ...
and
melt ponds. During winter, desalination is governed mostly by gravity drainage, while flushing becomes important during summer. Gravity drainage can be triggered both by atmospheric heat and bottom melt from oceanic heat. A typical salinity of first-year ice by the end of winter season is 4–6, while typical salinities of multiyear ice is 2–3. Snowmelt, surface flooding, and the presence of under-ice meltwater may affect sea-ice salinity. During the melt season, the only process of ice growth is related to the formation of
false bottoms.
Vertical growth
The downward growth of consolidated ice under the assumption of zero heat flux from the ocean is determined by the rate of conductive
heat flux
In physics and engineering, heat flux or thermal flux, sometimes also referred to as heat flux density, heat-flow density or heat-flow rate intensity, is a flow of energy per unit area per unit time (physics), time. Its SI units are watts per sq ...
, ''Q
*'', at the ice-water interface. The ocean heat fluxes substantially vary spatially and temporally and strongly contribute to the summer sea ice melt and the absence of sea ice in some parts of the Arctic Ocean. If we also assume a linear temperature profile within ice and no effect from ice thermal inertia, we can determine latent heat flux ''Q
*'' by solving the following equation:
:
where ''T
si'' is the snow-ice interface temperature, ''T
s'' is the air-snow interface temperature, ''h
i'' and ''h
s'' are the ice and snow thicknesses. The water temperature ''T
w'' is assumed to be at or near
freezing
Freezing is a phase transition in which a liquid turns into a solid when its temperature is lowered below its freezing point.
For most substances, the melting and freezing points are the same temperature; however, certain substances possess dif ...
(
Stefan problem
In mathematics and its applications, particularly to phase transitions in matter, a Stefan problem is a particular kind of boundary value problem for a system of partial differential equations (PDE), in which the boundary between the phases can ...
). We can approximate the ice and snow
thermal conductivities ''k
i'' and ''k
s'', as an average over the layers. The surface heat budget defines the snow surface temperature ''T
s'' and includes four atmospheric heat fluxes:
:
which are latent, sensible, longwave and shortwave radiation fluxes, respectively. For a description of the approximate
parameterization
In mathematics, and more specifically in geometry, parametrization (or parameterization; also parameterisation, parametrisation) is the process of finding parametric equations of a curve, a surface (mathematics), surface, or, more generally, a ma ...
s, see
determining surface flux under
sea ice thickness. The equation can be solved using a numerical
root-finding algorithm
In numerical analysis, a root-finding algorithm is an algorithm for finding zeros, also called "roots", of continuous functions. A zero of a function is a number such that . As, generally, the zeros of a function cannot be computed exactly nor ...
such as
bisection
In geometry, bisection is the division of something into two equal or congruent parts (having the same shape and size). Usually it involves a bisecting line, also called a ''bisector''. The most often considered types of bisectors are the ''s ...
: the functional dependencies on surface temperature are given, with ''e'' being the
equilibrium vapor pressure
Vapor pressure or equilibrium vapor pressure is the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases (solid or liquid) at a given temperature in a closed system. The equilibrium vapor pressure is an indicati ...
. Shortwave radiation may increase ocean surface temperatures and corresponding ocean heat fluxes, affecting heat balance at the ice-ocean interface. This process is a part of
Ice–albedo feedback
Ice–albedo feedback is a climate change feedback, where a change in the area of ice caps, glaciers, and sea ice alters the albedo and surface temperature of a planet. Because ice is very reflective, it reflects far more solar energy back to spac ...
.
While Cox and Weeks assume thermal equilibrium,
[
] Tonboe uses a more complex thermodynamic model based on
numerical solution
Numerical analysis is the study of algorithms that use numerical approximation (as opposed to symbolic manipulations) for the problems of mathematical analysis (as distinguished from discrete mathematics). It is the study of numerical methods t ...
of the
heat equation
In mathematics and physics (more specifically thermodynamics), the heat equation is a parabolic partial differential equation. The theory of the heat equation was first developed by Joseph Fourier in 1822 for the purpose of modeling how a quanti ...
.
[
] This would be appropriate when the ice is thick or the weather conditions are changing rapidly.
The rate of ice growth can be calculated from heat flux by the following equation:
:
where ''L'' is the
latent heat
Latent heat (also known as latent energy or heat of transformation) is energy released or absorbed, by a body or a thermodynamic system, during a constant-temperature process—usually a first-order phase transition, like melting or condensation. ...
of fusion for water and
is the density of ice (for pure ice). For sea ice, ''L'' is the effective latent heat of sea ice and
is the density of sea ice. These two parameters depend on sea-ice salinity, temperature, and volumetric gas fraction, as well as sea-ice thermal conductivity. The growth rate of sea ice in turn determines the saline content of the newly frozen ice. Empirical equations for determining the initial brine entrapment in sea ice have been derived by Cox and Weeks
and Nakawo and Sinha
[
] and take the form:
:
where ''S'' is ice salinity, ''S
0'' is the salinity of the parent water, and ''f'' is an empirical function of ice growth rate, e.g.:
:
where ''g'' is in cm/s.
Salt content
Brine entrapped in sea ice will always be at or near freezing, since any departure will either cause some of the water in the brine to freeze, or melt some of the surrounding ice. Thus, brine salinity is variable and can be determined based strictly on temperature—see
freezing point depression. There are empirical formulas relating sea ice temperature to brine salinity.
The relative brine volume, ''V
b'', is defined as the fraction of brine relative to the total volume. It too is highly variable, however its value is more difficult to determine since changes in temperature may cause some of the brine to be ejected or move within the layers, particularly in new ice. Writing equations relating the salt content of the brine, the total salt content, the brine volume, the density of the brine and the density of the ice and solving for brine volume produces the following relation:
:
where ''S'' is sea ice salinity, ''S
b'' is brine salinity,
is the density of the ice and
is brine density. Compare with this empirical formula from Frankenstein and Garner:
:
where ''T'' is ice temperature in degrees
Celsius
The degree Celsius is the unit of temperature on the Celsius temperature scale "Celsius temperature scale, also called centigrade temperature scale, scale based on 0 ° for the melting point of water and 100 ° for the boiling point ...
and ''S'' is ice salinity in
parts per thousand
In science and engineering, the parts-per notation is a set of pseudo-units to describe the small values of miscellaneous dimensionless quantities, e.g. mole fraction or mass fraction.
Since these fractions are quantity-per-quantity measures ...
.
In new ice, the amount of brine ejected as the ice cools can be determined by assuming that the total volume stays constant and subtracting the volume increase from the brine volume. Note that this is only applicable to newly formed ice: any warming will tend to generate air pockets as the brine volume will increase more slowly than the ice volume decreases, again due to the density difference. Cox and Weeks provide the following formula determining the ratio of total ice salinity between temperatures, ''T
1'' and ''T
2'' where ''T
2'' < ''T
1'':
:
where ''c''=0.8 kg m
−3 is a constant. As the ice goes through constant warming and cooling cycles it becomes progressively more
porous
Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
, through ejection of the brine and drainage through the resulting channels.
The figure above shows a
scatter plot
A scatter plot, also called a scatterplot, scatter graph, scatter chart, scattergram, or scatter diagram, is a type of plot or mathematical diagram using Cartesian coordinates to display values for typically two variables for a set of dat ...
of salinity versus ice thickness for ice cores taken from the
Weddell Sea
The Weddell Sea is part of the Southern Ocean and contains the Weddell Gyre. Its land boundaries are defined by the bay formed from the coasts of Coats Land and the Antarctic Peninsula. The easternmost point is Cape Norvegia at Princess Martha C ...
,
Antarctica
Antarctica () is Earth's southernmost and least-populated continent. Situated almost entirely south of the Antarctic Circle and surrounded by the Southern Ocean (also known as the Antarctic Ocean), it contains the geographic South Pole. ...
, with an exponential fit of the form,
, overlaid, where ''h'' is ice thickness and ''a'' and ''b'' are constants.
Horizontal motion
The horizontal motion of sea ice is quite difficult to model because ice is a
non-Newtonian fluid.
Sea ice will deform primarily at
fracture
Fracture is the appearance of a crack or complete separation of an object or material into two or more pieces under the action of stress (mechanics), stress. The fracture of a solid usually occurs due to the development of certain displacemen ...
points which in turn will form at the points of greatest
stress and lowest
strength
Strength may refer to:
Personal trait
*Physical strength, as in people or animals
*Character strengths like those listed in the Values in Action Inventory
*The exercise of willpower
Physics
* Mechanical strength, the ability to withstand ...
, or where the ratio between the two is a maximum. Ice thickness, salinity and
porosity
Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
will all affect the strength of the ice. The motion of the ice is driven primarily by ocean currents, though to a lesser extent by wind. Note that stresses will not be in the direction of the winds or currents, but rather will be shifted by
Coriolis Coriolis may refer to:
* Gaspard-Gustave de Coriolis (1792–1843), French mathematician, mechanical engineer and scientist
* Coriolis force
In physics, the Coriolis force is a pseudo force that acts on objects in motion within a frame of ref ...
effects—see, for instance,
Ekman spiral
Ekman transport is part of Ekman motion theory, first investigated in 1902 by Vagn Walfrid Ekman. Winds are the main source of energy for ocean circulation, and Ekman transport is a component of wind-driven ocean current. Ekman transport occurs ...
.
See also
*
Sea ice
Sea ice arises as seawater freezes. Because ice is less density, dense than water, it floats on the ocean's surface (as does fresh water ice). Sea ice covers about 7% of the Earth's surface and about 12% of the world's oceans. Much of the world' ...
*
Sea ice thickness
*
Sea ice concentration
*
Sea ice emissivity modelling
References
Sea ice
Climatology