Naturally occurring
samarium
Samarium is a chemical element; it has symbol Sm and atomic number 62. It is a moderately hard silvery metal that slowly oxidizes in air. Being a typical member of the lanthanide series, samarium usually has the oxidation state +3. Compounds of s ...
(
62Sm) is composed of five stable
isotope
Isotopes are distinct nuclear species (or ''nuclides'') of the same chemical element. They have the same atomic number (number of protons in their Atomic nucleus, nuclei) and position in the periodic table (and hence belong to the same chemica ...
s,
144Sm,
149Sm,
150Sm,
152Sm and
154Sm, and two extremely long-lived
radioisotope
A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess numbers of either neutrons or protons, giving it excess nuclear energy, and making it unstable. This excess energy can be used in one of three ...
s,
147Sm (half life: 1.066 y) and
148Sm (6.3 y), with
152Sm being the most abundant (26.75%
natural abundance
In physics, natural abundance (NA) refers to the abundance of isotopes of a chemical element as naturally found on a planet. The relative atomic mass (a weighted average, weighted by mole-fraction abundance figures) of these isotopes is the ato ...
).
146Sm (9.20 y)
is also fairly long-lived, but is not long-lived enough to have survived in significant quantities from the formation of the Solar System on Earth, although it remains useful in radiometric dating in the Solar System as an
extinct radionuclide
An extinct radionuclide is a radionuclide that was formed by nucleosynthesis before the formation of the Solar System, about 4.6 billion years ago, but has since decayed to virtually zero abundance and is no longer detectable as a primordial nu ...
. It is the longest-lived nuclide that has not yet been confirmed to be
primordial. Its instability is due to having 84 neutrons (two more than 82, which is a
magic number corresponding to a stable neutron configuration), and so it may emit an
alpha particle
Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay but may also be produce ...
(which has 2 neutrons) to form neodymium-142 with 82 neutrons.
Other than the naturally occurring isotopes, the longest-lived radioisotopes are
151Sm, which has a
half-life Half-life is a mathematical and scientific description of exponential or gradual decay.
Half-life, half life or halflife may also refer to:
Film
* Half-Life (film), ''Half-Life'' (film), a 2008 independent film by Jennifer Phang
* ''Half Life: ...
of 94.6 years, and
145Sm, which has a half-life of 340 days. All of the remaining radioisotopes, which range from
129Sm to
168Sm, have half-lives that are less than two days, and the majority of these have half-lives that are less than 48 seconds. This element also has twelve known
isomers
In chemistry, isomers are molecules or polyatomic ions with identical molecular formula – that is, the same number of atoms of each element – but distinct arrangements of atoms in space. ''Isomerism'' refers to the existence or possibili ...
with the most stable being
141mSm (t
1/2 22.6 minutes),
143m1Sm (t
1/2 66 seconds) and
139mSm (t
1/2 10.7 seconds).
The long lived isotopes,
146Sm,
147Sm, and
148Sm, primarily decay by
alpha decay
Alpha decay or α-decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle (helium nucleus). The parent nucleus transforms or "decays" into a daughter product, with a mass number that is reduced by four and an a ...
to
isotopes of neodymium
Naturally occurring neodymium (60Nd) is composed of five stable isotopes, 142Nd, 143Nd, 145Nd, 146Nd and 148Nd, with 142Nd being the most abundant (27.2% natural abundance), and two long-lived radioisotopes, 144Nd and 150Nd. In all, 35 radioisotop ...
. Lighter unstable isotopes of samarium primarily decay by
electron capture
Electron capture (K-electron capture, also K-capture, or L-electron capture, L-capture) is a process in which the proton-rich nucleus of an electrically neutral atom absorbs an inner atomic electron, usually from the K or L electron shells. Th ...
to
isotopes of promethium, while heavier ones decay by
beta decay
In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which an atomic nucleus emits a beta particle (fast energetic electron or positron), transforming into an isobar of that nuclide. For example, beta decay of a neutron ...
to
isotopes of europium. A 2012 paper
revising the estimated half-life of
146Sm from 10.3(5)×10
7 y to 6.8(7)×10
7 y was retracted in 2023.
Isotopes of samarium are used in
samarium–neodymium dating for determining the age relationships of rocks and meteorites.
151Sm is a
medium-lived fission product
Long-lived fission products (LLFPs) are radioactive materials with a long half-life (more than 200,000 years) produced by nuclear fission of uranium and plutonium. Because of their persistent Ionizing radiation, radiotoxicity, it is necessary to is ...
and acts as a
neutron poison
In applications such as nuclear reactors, a neutron poison (also called a neutron absorber or a nuclear poison) is a substance with a large neutron absorption cross-section. In such applications, absorbing neutrons is normally an undesirable ef ...
in the
nuclear fuel cycle
The nuclear fuel cycle, also known as the nuclear fuel chain, describes the series of stages that nuclear fuel undergoes during its production, use, and recycling or disposal. It consists of steps in the ''front end'', which are the preparation o ...
. The stable
fission product
Nuclear fission products are the atomic fragments left after a large atomic nucleus undergoes nuclear fission. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons, the releas ...
149Sm is also a neutron poison.
Samarium is theoretically the lightest element with even
atomic number
The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of its atomic nucleus. For ordinary nuclei composed of protons and neutrons, this is equal to the proton number (''n''p) or the number of pro ...
with no stable isotopes (all isotopes of it can theoretically go either
alpha decay
Alpha decay or α-decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle (helium nucleus). The parent nucleus transforms or "decays" into a daughter product, with a mass number that is reduced by four and an a ...
or
beta decay
In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which an atomic nucleus emits a beta particle (fast energetic electron or positron), transforming into an isobar of that nuclide. For example, beta decay of a neutron ...
or
double beta decay
In nuclear physics, double beta decay is a type of radioactive decay in which two neutrons are simultaneously transformed into two protons, or vice versa, inside an atomic nucleus. As in single beta decay, this process allows the atom to move cl ...
), other such elements are those with atomic numbers > 66 (
dysprosium
Dysprosium is a chemical element; it has symbol Dy and atomic number 66. It is a rare-earth element in the lanthanide series with a metallic silver luster. Dysprosium is never found in nature as a free element, though, like other lanthanides, it ...
, which is the heaviest theoretically stable nuclide).
List of isotopes
, -id=Samarium-129
, rowspan=2,
129Sm
, rowspan=2 style="text-align:right" , 62
, rowspan=2 style="text-align:right" , 67
, rowspan=2, 128.95456(54)#
, rowspan=2, 550(100) ms
,
β+ (?%)
,
129Pm
, rowspan=2, (1/2+,3/2+)
, rowspan=2,
, rowspan=2,
, -
, β
+, p (?%)
,
128Nd
, -id=Samarium-130
,
130Sm
, style="text-align:right" , 62
, style="text-align:right" , 68
, 129.94879(43)#
, 1# s
,
,
, 0+
,
,
, -id=Samarium-131
, rowspan=2,
131Sm
, rowspan=2 style="text-align:right" , 62
, rowspan=2 style="text-align:right" , 69
, rowspan=2, 130.94602(43)#
, rowspan=2, 1.2(2) s
, β
+
,
131Pm
, rowspan=2, 5/2+#
, rowspan=2,
, rowspan=2,
, -
, β
+, p (?%)
,
130Nd
, -id=Samarium-132
,
132Sm
, style="text-align:right" , 62
, style="text-align:right" , 70
, 131.94081(32)#
, 4.0(3) s
, β
+
,
132Pm
, 0+
,
,
, -id=Samarium-133
, rowspan=2,
133Sm
, rowspan=2 style="text-align:right" , 62
, rowspan=2 style="text-align:right" , 71
, rowspan=2, 132.93856(32)#
, rowspan=2, 2.89(16) s
, β
+ (?%)
,
133Pm
, rowspan=2, (5/2+)
, rowspan=2,
, rowspan=2,
, -
, β
+, p (?%)
,
132Nd
, -id=Samarium-133m
, style="text-indent:1em" ,
133mSm
, colspan="3" style="text-indent:2em" , 120(60)# keV
, 3.5(4) s
, β
+
,
133Pm
, (1/2−)
,
,
, -id=Samarium-134
,
134Sm
, style="text-align:right" , 62
, style="text-align:right" , 72
, 133.93411(21)#
, 9.5(8) s
, β
+
,
134Pm
, 0+
,
,
, -id=Samarium-135
, rowspan=2,
135Sm
, rowspan=2 style="text-align:right" , 62
, rowspan=2 style="text-align:right" , 73
, rowspan=2, 134.93252(17)
, rowspan=2, 10.3(5) s
, β
+ (99.98%)
,
135Pm
, rowspan=2, (7/2+)
, rowspan=2,
, rowspan=2,
, -
, β
+, p (0.02%)
,
134Nd
, -id=Samarium-136
,
136Sm
, style="text-align:right" , 62
, style="text-align:right" , 74
, 135.928276(13)
, 47(2) s
, β
+
,
136Pm
, 0+
,
,
, -id=Samarium-136m
, style="text-indent:1em" ,
136mSm
, colspan="3" style="text-indent:2em" , 2264.7(11) keV
, 15(1) μs
, IT
,
136Sm
, (8−)
,
,
, -id=Samarium-137
,
137Sm
, style="text-align:right" , 62
, style="text-align:right" , 75
, 136.927008(31)
, 45(1) s
, β
+
,
137Pm
, (9/2−)
,
,
, -id=Samarium-138
,
138Sm
, style="text-align:right" , 62
, style="text-align:right" , 76
, 137.923244(13)
, 3.1(2) min
, β
+
,
138Pm
, 0+
,
,
, -id=Samarium-139
,
139Sm
, style="text-align:right" , 62
, style="text-align:right" , 77
, 138.922297(12)
, 2.57(10) min
, β
+
,
139Pm
, 1/2+
,
,
, -id=Samarium-139m
, rowspan=2 style="text-indent:1em" ,
139mSm
, rowspan=2 colspan="3" style="text-indent:2em" , 457.38(23) keV
, rowspan=2, 10.7(6) s
,
IT (93.7%)
,
139Sm
, rowspan=2, 11/2−
, rowspan=2,
, rowspan=2,
, -
, β
+ (6.3%)
,
139Pm
, -id=Samarium-140
,
140Sm
, style="text-align:right" , 62
, style="text-align:right" , 78
, 139.918995(13)
, 14.82(12) min
, β
+
,
140Pm
, 0+
,
,
, -id=Samarium-141
,
141Sm
, style="text-align:right" , 62
, style="text-align:right" , 79
, 140.9184815(92)
, 10.2(2) min
, β
+
,
141Pm
, 1/2+
,
,
, -id=Samarium-141m
, rowspan=2 style="text-indent:1em" ,
141mSm
, rowspan=2 colspan="3" style="text-indent:2em" , 175.9(3) keV
, rowspan=2, 22.6(2) min
, β
+ (99.69%)
,
141Pm
, rowspan=2, 11/2−
, rowspan=2,
, rowspan=2,
, -
, IT (0.31%)
,
141Sm
, -id=Samarium-142
, rowspan=2,
142Sm
, rowspan=2 style="text-align:right" , 62
, rowspan=2 style="text-align:right" , 80
, rowspan=2, 141.9152094(20)
, rowspan=2, 72.49(5) min
, EC (>95%)
, rowspan=2,
142Pm
, rowspan=2, 0+
, rowspan=2,
, rowspan=2,
, -
, β
+ (<5%)
, -id=Samarium-142m1
, style="text-indent:1em" ,
142m1Sm
, colspan="3" style="text-indent:2em" , 2372.1(4) keV
, 170(2) ns
, IT
,
142Sm
, 7−
,
,
, -id=Samarium-142m2
, style="text-indent:1em" ,
142m2Sm
, colspan="3" style="text-indent:2em" , 3662.2(7) keV
, 480(60) ns
, IT
,
142Sm
, 10+
,
,
, -id=Samarium-143
, rowspan=2,
143Sm
, rowspan=2 style="text-align:right" , 62
, rowspan=2 style="text-align:right" , 81
, rowspan=2, 142.9146348(30)
, rowspan=2, 8.75(6) min
, EC (60.0%)
,
143Pm
, rowspan=2, 3/2+
, rowspan=2,
, rowspan=2,
, -
, β
+ (40.0%)
,
143Pm
, -id=Samarium-143m1
, rowspan=2 style="text-indent:1em" ,
143m1Sm
, rowspan=2 colspan="3" style="text-indent:2em" , 753.99(16) keV
, rowspan=2, 66(2) s
, IT (99.76%)
,
143Sm
, rowspan=2, 11/2−
, rowspan=2,
, rowspan=2,
, -
, β
+ (0.24%)
,
143Pm
, -id=Samarium-143m2
, style="text-indent:1em" ,
143m2Sm
, colspan="3" style="text-indent:2em" , 2793.8(13) keV
, 30(3) ms
, IT
,
143Sm
, 23/2−
,
,
, -id=Samarium-144
,
144Sm
, style="text-align:right" , 62
, style="text-align:right" , 82
, 143.9120063(16)
, colspan=3 align=center,
Observationally stable
Stable nuclides are isotopes of a chemical element whose nucleons are in a configuration that does not permit them the surplus energy required to produce a radioactive emission. The nuclei of such isotopes are not radioactive and unlike radionuc ...
, 0+
, 0.0308(4)
,
, -id=Samarium-144m
, style="text-indent:1em" ,
144mSm
, colspan="3" style="text-indent:2em" , 2323.60(8) keV
, 880(25) ns
, IT
,
144Sm
, 6+
,
,
, -id=Samarium-145
,
145Sm
, style="text-align:right" , 62
, style="text-align:right" , 83
, 144.9134172(16)
, 340(3) d
,
EC
,
145Pm
, 7/2−
,
,
, -id=Samarium-145m
, style="text-indent:1em" ,
145mSm
, colspan="3" style="text-indent:2em" , 8815(1) keV
, 3.52(16) μs
, IT
,
145Sm
, 49/2+
,
,
, -id=Samarium-146
,
146Sm
, style="text-align:right" , 62
, style="text-align:right" , 84
, 145.9130468(33)
, 9.20(26) y
[
, α
, 142Nd
, 0+
, Trace
,
, -
, 147Sm][ Primordial ]radioisotope
A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess numbers of either neutrons or protons, giving it excess nuclear energy, and making it unstable. This excess energy can be used in one of three ...
Fission product
Nuclear fission products are the atomic fragments left after a large atomic nucleus undergoes nuclear fission. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons, the releas ...
[Used in Samarium–neodymium dating]
, style="text-align:right" , 62
, style="text-align:right" , 85
, 146.9149044(14)
, 1.066(5) y
, α
, 143Nd
, 7/2−
, 0.1500(14)
,
, -id=Samarium-148
, 148Sm
, style="text-align:right" , 62
, style="text-align:right" , 86
, 147.9148292(13)
, 6.3(13) y
, α
, ''144Nd''
, 0+
, 0.1125(9)
,
, -
, 149SmNeutron poison
In applications such as nuclear reactors, a neutron poison (also called a neutron absorber or a nuclear poison) is a substance with a large neutron absorption cross-section. In such applications, absorbing neutrons is normally an undesirable ef ...
in reactors
, style="text-align:right" , 62
, style="text-align:right" , 87
, 148.9171912(12)
, colspan=3 align=center, Observationally stable
, 7/2−
, 0.1382(10)
,
, -id=Samarium-150
, 150Sm
, style="text-align:right" , 62
, style="text-align:right" , 88
, 149.9172820(12)
, colspan=3 align=center, Observationally stable
, 0+
, 0.0737(9)
,
, -
, 151Sm
, style="text-align:right" , 62
, style="text-align:right" , 89
, 150.9199389(12)
, 94.6(6) y
, β−
, ''151Eu''
, 5/2−
,
,
, -id=Samarium-151m
, style="text-indent:1em" , 151mSm
, colspan="3" style="text-indent:2em" , 261.13(4) keV
, 1.4(1) μs
, IT
, 151Sm
, (11/2)−
,
,
, -id=Samarium-152
, 152Sm
, style="text-align:right" , 62
, style="text-align:right" , 90
, 151.9197386(11)
, colspan=3 align=center, Observationally stable
, 0+
, 0.2674(9)
,
, -
, 153Sm
, style="text-align:right" , 62
, style="text-align:right" , 91
, 152.9221036(11)
, 46.2846(23) h
, β−
, 153Eu
, 3/2+
,
,
, -id=Samarium-153m
, style="text-indent:1em" , 153mSm
, colspan="3" style="text-indent:2em" , 98.39(10) keV
, 10.6(3) ms
, IT
, 153Sm
, 11/2−
,
,
, -id=Samarium-154
, 154Sm
, style="text-align:right" , 62
, style="text-align:right" , 92
, 153.9222158(14)
, colspan=3 align=center, Observationally stable
, 0+
, 0.2274(14)
,
, -id=Samarium-155
, 155Sm
, style="text-align:right" , 62
, style="text-align:right" , 93
, 154.9246466(14)
, 22.18(6) min
, β−
, 155Eu
, 3/2−
,
,
, -id=Samarium-155m1
, style="text-indent:1em" , 155m1Sm
, colspan="3" style="text-indent:2em" , 16.5467(19) keV
, 2.8(5) μs
, IT
, 155Sm
, 5/2+
,
,
, -id=Samarium-155m2
, style="text-indent:1em" , 155m2Sm
, colspan="3" style="text-indent:2em" , 538.03(19) keV
, 1.00(8) μs
, IT
, 155Sm
, 11/2−
,
,
, -id=Samarium-156
, 156Sm
, style="text-align:right" , 62
, style="text-align:right" , 94
, 155.9255382(91)
, 9.4(2) h
, β−
, 156Eu
, 0+
,
,
, -id=Samarium-156m
, style="text-indent:1em" , 156mSm
, colspan="3" style="text-indent:2em" , 1397.55(9) keV
, 185(7) ns
, IT
, 156Sm
, 5−
,
,
, -id=Samarium-157
, 157Sm
, style="text-align:right" , 62
, style="text-align:right" , 95
, 156.9284186(48)
, 8.03(7) min
, β−
, 157Eu
, 3/2−#
,
,
, -id=Samarium-158
, 158Sm
, style="text-align:right" , 62
, style="text-align:right" , 96
, 157.9299493(51)
, 5.30(3) min
, β−
, 158Eu
, 0+
,
,
, -id=Samarium-159
, 159Sm
, style="text-align:right" , 62
, style="text-align:right" , 97
, 158.9332171(64)
, 11.37(15) s
, β−
, 159Eu
, 5/2−
,
,
, -id=Samarium-159m
, style="text-indent:1em" , 159mSm
, colspan="3" style="text-indent:2em" , 1276.5(8) keV
, 116(8) ns
, IT
, 159Sm
, (15/2+)
,
,
, -id=Samarium-160
, 160Sm
, style="text-align:right" , 62
, style="text-align:right" , 98
, 159.9353370(21)
, 9.6(3) s
, β−
, 160Eu
, 0+
,
,
, -id=Samarium-160m1
, style="text-indent:1em" , 160m1Sm
, colspan="3" style="text-indent:2em" , 1361.3(4) keV
, 120(46) ns
, IT
, 160Sm
, (5−)
,
,
, -id=Samarium-160m2
, style="text-indent:1em" , 160m2Sm
, colspan="3" style="text-indent:2em" , 2757.3(4) keV
, 1.8(4) μs
, IT
, 160Sm
, (11+)
,
,
, -id=Samarium-161
, 161Sm
, style="text-align:right" , 62
, style="text-align:right" , 99
, 160.9391601(73)
,
, β−
, 161Eu
, 7/2+#
,
,
, -id=Samarium-161m
, style="text-indent:1em" , 161mSm
, colspan="3" style="text-indent:2em" , 1388.1(6) keV
, 2.6(4) μs
, IT
, 161Sm
, (17/2−)
,
,
, -id=Samarium-162
, 162Sm
, style="text-align:right" , 62
, style="text-align:right" , 100
, 161.9416217(38)
, [
, β−
, 162Eu
, 0+
,
,
, -id=Samarium-162m
, style="text-indent:1em" , 162mSm
, colspan="3" style="text-indent:2em" , 1009.4(5) keV
, 1.78(7) μs
, IT
, 162Sm
, (4−)
,
,
, -id=Samarium-163
, rowspan=2, 163Sm
, rowspan=2 style="text-align:right" , 62
, rowspan=2 style="text-align:right" , 101
, rowspan=2, 162.9456791(79)
, rowspan=2, ][
, β−
, 163Eu
, rowspan=2, 1/2−#
, rowspan=2,
, rowspan=2,
, -
, β−, n (<0.1%)
, 162Eu
, -id=Samarium-164
, rowspan=2, 164Sm
, rowspan=2 style="text-align:right" , 62
, rowspan=2 style="text-align:right" , 102
, rowspan=2, 163.9485501(44)
, rowspan=2, ][
, β−
, 164Eu
, rowspan=2, 0+
, rowspan=2,
, rowspan=2,
, -
, β−, n (<0.7%)
, 163Eu
, -id=Samarium-164m
, style="text-indent:1em" , 164mSm
, colspan="3" style="text-indent:2em" , 1485.5(12) keV
, 600(140) ns
, IT
, 164Sm
, (6−)
,
,
, -id=Samarium-165
, rowspan=2, 165Sm
, rowspan=2 style="text-align:right" , 62
, rowspan=2 style="text-align:right" , 103
, rowspan=2, 164.95329(43)#
, rowspan=2, ][
, β− (98.64%)
, 165Eu
, rowspan=2, 5/2−#
, rowspan=2,
, rowspan=2,
, -
, β−, n (1.36%)
, 164Eu
, -id=Samarium-166
, rowspan=2, 166Sm
, rowspan=2 style="text-align:right" , 62
, rowspan=2 style="text-align:right" , 104
, rowspan=2, 165.95658(43)#
, rowspan=2, ][
, β− (95.62%)
, 166Eu
, rowspan=2, 0+
, rowspan=2,
, rowspan=2,
, -
, β−, n (4.38%)
, 165Eu
, -id=Samarium-167
, rowspan=2, 167Sm
, rowspan=2 style="text-align:right" , 62
, rowspan=2 style="text-align:right" , 105
, rowspan=2, 166.96207(54)#
, rowspan=2, ][
, β−
, 167Eu
, rowspan=2, 7/2−#
, rowspan=2,
, rowspan=2,
, -
, β−, n (<16%)
, 166Eu
, -id=Samarium-168
, rowspan=2, 168Sm
, rowspan=2 style="text-align:right" , 62
, rowspan=2 style="text-align:right" , 106
, rowspan=2, 167.96603(32)#
, rowspan=2, ][
, β−
, 168Eu
, rowspan=2, 0+#
, rowspan=2,
, rowspan=2,
, -
, β−, n (<21%)
, 167Eu
]
Samarium-149
Samarium-149 (149Sm) is an observationally stable isotope of samarium
Samarium is a chemical element; it has symbol Sm and atomic number 62. It is a moderately hard silvery metal that slowly oxidizes in air. Being a typical member of the lanthanide series, samarium usually has the oxidation state +3. Compounds of s ...
(predicted to decay, but no decays have ever been observed, giving it a half-life at least several orders of magnitude longer than the age of the universe), and a product of the decay chain from the fission product
Nuclear fission products are the atomic fragments left after a large atomic nucleus undergoes nuclear fission. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons, the releas ...
149Nd (yield 1.0888%). 149Sm is a neutron
The neutron is a subatomic particle, symbol or , that has no electric charge, and a mass slightly greater than that of a proton. The Discovery of the neutron, neutron was discovered by James Chadwick in 1932, leading to the discovery of nucle ...
-absorbing nuclear poison
In applications such as nuclear reactors, a neutron poison (also called a neutron absorber or a nuclear poison) is a substance with a large neutron absorption cross-section. In such applications, absorbing neutrons is normally an undesirable ef ...
with significant effect on nuclear reactor
A nuclear reactor is a device used to initiate and control a Nuclear fission, fission nuclear chain reaction. They are used for Nuclear power, commercial electricity, nuclear marine propulsion, marine propulsion, Weapons-grade plutonium, weapons ...
operation, second only to 135Xe. Its neutron cross section
In nuclear physics, the concept of a neutron cross section is used to express the likelihood of interaction between an incident neutron and a target nucleus. The neutron cross section σ can be defined as the area in cm2 for which the number of ...
is 40140 barn
A barn is an agricultural building usually on farms and used for various purposes. In North America, a barn refers to structures that house livestock, including cattle and horses, as well as equipment and fodder, and often grain.Allen G ...
s for thermal neutron
The neutron detection temperature, also called the neutron energy, indicates a free neutron's kinetic energy, usually given in electron volts. The term ''temperature'' is used, since hot, thermal and cold neutrons are moderated in a medium wit ...
s.
The equilibrium concentration (and thus the poisoning effect) builds to an equilibrium value in about 500 hours (about 20 days) of reactor operation, and since 149Sm is stable, the concentration remains essentially constant during further reactor operation. This contrasts with xenon-135
Xenon-135 (135Xe) is an Isotope#Radioactive, primordial, and stable isotopes, unstable isotope of xenon with a half-life of about 9.2 hours. 135Xe is a fission product of uranium and it is the most powerful known neutron-absorbing nuclear poison ...
, which accumulates from the beta decay of iodine-135
There are 40 known isotopes of iodine (53I) from 108I to 147I; all undergo radioactive decay except 127I, which is stable. Iodine is thus a monoisotopic element.
Its longest-lived radioactive isotope, 129I, has a half-life of 16.14 million yea ...
(a short lived fission product
Nuclear fission products are the atomic fragments left after a large atomic nucleus undergoes nuclear fission. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons, the releas ...
) and has a high neutron cross section, but itself decays with a half-life of 9.2 hours (so does not remain in constant concentration long after the reactor shutdown), causing the so-called xenon pit.
Samarium-151
Samarium-151 (151Sm) has a half-life Half-life is a mathematical and scientific description of exponential or gradual decay.
Half-life, half life or halflife may also refer to:
Film
* Half-Life (film), ''Half-Life'' (film), a 2008 independent film by Jennifer Phang
* ''Half Life: ...
of 94.6 years, undergoing low-energy beta decay, and has a fission product yield
Nuclear fission splits a heavy nucleus such as uranium or plutonium into two lighter nuclei, which are called fission products. Yield refers to the fraction of a fission product produced per fission.
Yield can be broken down by:
# Individual i ...
of 0.4203% for thermal neutrons and 235U, about 39% of 149Sm's yield. The yield is somewhat higher for 239Pu.
Its neutron absorption cross section
Cross section may refer to:
* Cross section (geometry)
** Cross-sectional views in architecture and engineering 3D
*Cross section (geology)
* Cross section (electronics)
* Radar cross section, measure of detectability
* Cross section (physics)
**A ...
for thermal neutron
The neutron detection temperature, also called the neutron energy, indicates a free neutron's kinetic energy, usually given in electron volts. The term ''temperature'' is used, since hot, thermal and cold neutrons are moderated in a medium wit ...
s is high at 15200 barn
A barn is an agricultural building usually on farms and used for various purposes. In North America, a barn refers to structures that house livestock, including cattle and horses, as well as equipment and fodder, and often grain.Allen G ...
s, about 38% of 149Sm's absorption cross section, or about 20 times that of 235U. Since the ratios between the production and absorption rates of 151Sm and 149Sm are almost equal, the two isotopes should reach similar equilibrium concentrations. Since 149Sm reaches equilibrium in about 500 hours (20 days), 151Sm should reach equilibrium in about 50 days.
Since nuclear fuel is used for several years (burnup
In nuclear power technology, burnup is a measure of how much energy is extracted from a given amount of nuclear fuel. It may be measured as the fraction of fuel atoms that underwent fission in %FIMA (fissions per initial heavy metal atom) or %FIF ...
) in a nuclear power plant
A nuclear power plant (NPP), also known as a nuclear power station (NPS), nuclear generating station (NGS) or atomic power station (APS) is a thermal power station in which the heat source is a nuclear reactor. As is typical of thermal power st ...
, the final amount of 151Sm in the spent nuclear fuel
Spent nuclear fuel, occasionally called used nuclear fuel, is nuclear fuel that has been irradiated in a nuclear reactor (usually at a nuclear power plant). It is no longer useful in sustaining a nuclear reaction in an ordinary thermal reactor and ...
at discharge is only a small fraction of the total 151Sm produced during the use of the fuel.
According to one study, the mass fraction of 151Sm in spent fuel is about 0.0025 for heavy loading of MOX fuel
Mixed oxide fuel (MOX fuel) is nuclear fuel that contains more than one oxide of fissile material, usually consisting of plutonium blended with natural uranium, reprocessed uranium, or depleted uranium. MOX fuel is an alternative to the low-enr ...
and about half that for uranium fuel, which is roughly two orders of magnitude less than the mass fraction of about 0.15 for the medium-lived fission product
Long-lived fission products (LLFPs) are radioactive materials with a long half-life (more than 200,000 years) produced by nuclear fission of uranium and plutonium. Because of their persistent Ionizing radiation, radiotoxicity, it is necessary to is ...
137Cs.[ Figure 2, page 6] The decay energy
The decay energy is the energy change of a nucleus having undergone a radioactive decay. Radioactive decay is the process in which an unstable atomic nucleus loses energy by emitting ionizing particles and radiation. This decay, or loss of energ ...
of 151Sm is also about an order of magnitude less than that of 137Cs. The low yield, low survival rate, and low decay energy
The decay energy is the energy change of a nucleus having undergone a radioactive decay. Radioactive decay is the process in which an unstable atomic nucleus loses energy by emitting ionizing particles and radiation. This decay, or loss of energ ...
mean that 151Sm has insignificant nuclear waste
Radioactive waste is a type of hazardous waste that contains radioactive material. It is a result of many activities, including nuclear medicine, nuclear research, nuclear power generation, nuclear decommissioning, rare-earth mining, and nuclear ...
impact compared to the two main medium-lived fission product
Long-lived fission products (LLFPs) are radioactive materials with a long half-life (more than 200,000 years) produced by nuclear fission of uranium and plutonium. Because of their persistent Ionizing radiation, radiotoxicity, it is necessary to is ...
s 137Cs and 90Sr.
ANL factsheet
Samarium-153
Samarium-153 (153Sm) has a half-life of 46.3 hours, undergoing β− decay into 153Eu. As a component of samarium lexidronam, it is used in palliation of bone cancer
A bone tumor is an neoplastic, abnormal growth of tissue in bone, traditionally classified as benign, noncancerous (benign) or malignant, cancerous (malignant). Cancerous bone tumors usually originate from a cancer in another part of the body su ...
. It is treated by the body in a similar manner to calcium, and it localizes selectively to bone
A bone is a rigid organ that constitutes part of the skeleton in most vertebrate animals. Bones protect the various other organs of the body, produce red and white blood cells, store minerals, provide structure and support for the body, ...
.
See also
Daughter products other than samarium
* Isotopes of europium
* Isotopes of promethium
* Isotopes of neodymium
Naturally occurring neodymium (60Nd) is composed of five stable isotopes, 142Nd, 143Nd, 145Nd, 146Nd and 148Nd, with 142Nd being the most abundant (27.2% natural abundance), and two long-lived radioisotopes, 144Nd and 150Nd. In all, 35 radioisotop ...
References
{{Navbox element isotopes
Samarium
Samarium
Samarium is a chemical element; it has symbol Sm and atomic number 62. It is a moderately hard silvery metal that slowly oxidizes in air. Being a typical member of the lanthanide series, samarium usually has the oxidation state +3. Compounds of s ...