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Riebeckite is a
sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...
-rich member of the
amphibole Amphibole () is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is ...
group of
silicate mineral Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually consid ...
s, chemical formula Na2(Fe2+3Fe3+2)Si8O22(OH)2. It forms a
solid solution A solid solution, a term popularly used for metals, is a homogenous mixture of two different kinds of atoms in solid state and have a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The wor ...
series with magnesioriebeckite. It crystallizes in the
monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic ...
system, usually as long
prismatic An optical prism is a transparent optical element with flat, polished surfaces that are designed to refract light. At least one surface must be angled — elements with two parallel surfaces are ''not'' prisms. The most familiar type of optical ...
crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macro ...
s showing a diamond-shaped cross section, but also in fibrous, bladed, acicular, columnar, and radiating forms. Its
Mohs hardness The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. The scale was introduced in 1812 by ...
is 5.0–6.0, and its
specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water at its dens ...
is 3.0–3.4. Cleavage is perfect, two directions in the shape of a
diamond Diamond is a solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Another solid form of carbon known as graphite is the chemically stable form of carbon at room temperature and pressure, b ...
; fracture is uneven, splintery. It is often translucent to nearly opaque.


Name and discovery

Riebeckite was first described in 1888 for an occurrence on
Socotra Island Socotra or Soqotra (; ar, سُقُطْرَىٰ ; so, Suqadara) is an island of the Republic of Yemen in the Indian Ocean, under the ''de facto'' control of the UAE-backed Southern Transitional Council, a secessionist participant in Yemen� ...
, Aden Governorate,
Yemen Yemen (; ar, ٱلْيَمَن, al-Yaman), officially the Republic of Yemen,, ) is a country in Western Asia. It is situated on the southern end of the Arabian Peninsula, and borders Saudi Arabia to the north and Oman to the northeast and ...
, and named for German explorer
Emil Riebeck Emil Riebeck (11 June 1853 – 22 June 1885) was a German explorer, mineralogist, ethnologist, and naturalist. He was born in Preusslitz to Carl Adolf Riebeck, an industrial magnate. He traveled to North Africa and Arabia several times, and in ...
(1853–1885). The mineral is also known as crocidolite.


Occurrence

Riebeckite typically forms dark-blue elongated to fibrous crystals in highly alkali
granite Granite () is a coarse-grained ( phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies un ...
s,
syenite Syenite is a coarse-grained intrusive igneous rock with a general composition similar to that of granite, but deficient in quartz, which, if present at all, occurs in relatively small concentrations (< 5%). Some syenites contain larger prop ...
s, rarely in
felsic In geology, felsic is a modifier describing igneous rocks that are relatively rich in elements that form feldspar and quartz.Marshak, Stephen, 2009, ''Essentials of Geology,'' W. W. Norton & Company, 3rd ed. It is contrasted with mafic rocks, wh ...
volcanics Volcanic rock (often shortened to volcanics in scientific contexts) is a rock formed from lava erupted from a volcano. In other words, it differs from other igneous rock by being of volcanic origin. Like all rock types, the concept of volcanic r ...
, granite
pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silici ...
s and
schist Schist ( ) is a medium-grained metamorphic rock showing pronounced schistosity. This means that the rock is composed of mineral grains easily seen with a low-power hand lens, oriented in such a way that the rock is easily split into thin flakes ...
. It occurs in
banded iron formation Banded iron formations (also known as banded ironstone formations or BIFs) are distinctive units of sedimentary rock consisting of alternating layers of iron oxides and iron-poor chert. They can be up to several hundred meters in thickness ...
s as the asbestiform variety ''crocidolite'' (blue
asbestos Asbestos () is a naturally occurring fibrous silicate mineral. There are six types, all of which are composed of long and thin fibrous crystals, each fibre being composed of many microscopic "fibrils" that can be released into the atmosphere b ...
). It occurs in association with
aegirine Aegirine is a member of the clino pyroxene group of inosilicate minerals. Aegirine is the sodium endmember of the aegirine-augite series. Aegirine has the chemical formula Na Fe Si2 O6 in which the iron is present as Fe3+. In the aegirine-augit ...
,
nepheline Nepheline, also called nephelite (), is a rock-forming mineral in the feldspathoid groupa silica-undersaturated aluminosilicate, Na3 K Al4 Si4 O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmati ...
,
albite Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicate ...
,
arfvedsonite Arfvedsonite () is a sodium amphibole mineral with composition: aNa2] Fe2+)4Fe3+(OH)2, Si8O22]. It crystallizes in the monoclinic prismatic crystal system and typically occurs as greenish black to bluish grey fibrous to radiating or stellate pr ...
in
igneous rock Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma o ...
s; with
tremolite Tremolite is a member of the amphibole group of silicate minerals with composition: Ca2(Mg5.0-4.5Fe2+0.0-0.5)Si8O22(OH)2. Tremolite forms by metamorphism of sediments rich in dolomite and quartz. Tremolite forms a series with actinolite and fe ...
, ferro-
actinolite Actinolite is an amphibole silicate mineral with the chemical formula . Etymology The name ''actinolite'' is derived from the Greek word ''aktis'' (), meaning "beam" or "ray", because of the mineral's fibrous nature. Mineralogy Actinolite is ...
in
metamorphic rock Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, caus ...
s; and with
grunerite Grunerite is a mineral of the amphibole group of minerals with formula Fe7 Si8 O22( OH)2. It is the iron endmember of the grunerite-cummingtonite series. It forms as fibrous, columnar or massive aggregates of crystals. The crystals are monoclini ...
,
magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With ...
,
hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
, stilpnomelane,
ankerite Ankerite is a calcium, iron, magnesium, manganese carbonate mineral of the group of rhombohedral carbonates with the chemical formula . In composition it is closely related to dolomite, but differs from this in having magnesium replaced by varyi ...
,
siderite Siderite is a mineral composed of iron(II) carbonate (FeCO3). It takes its name from the Greek word σίδηρος ''sideros,'' "iron". It is a valuable iron mineral, since it is 48% iron and contains no sulfur or phosphorus. Zinc, magnesium and ...
,
calcite Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on scratc ...
, chalcedonic
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical f ...
in iron formations.


Riebeckite granite

The riebeckite
granite Granite () is a coarse-grained ( phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies un ...
known as ''ailsite'', found on the island of
Ailsa Craig Ailsa Craig (; sco, Ailsae Craig; gd, Creag Ealasaid) is an island of in the outer Firth of Clyde, west of mainland Scotland, upon which microgranite has long been quarried to make curling stones. The now-uninhabited island comprises the ...
in western
Scotland Scotland (, ) is a country that is part of the United Kingdom. Covering the northern third of the island of Great Britain, mainland Scotland has a border with England to the southeast and is otherwise surrounded by the Atlantic Ocean to ...
, is prized for its use in the manufacture of
curling Curling is a sport in which players slide stones on a sheet of ice toward a target area which is segmented into four concentric circles. It is related to bowls, boules, and shuffleboard. Two teams, each with four players, take turns slidi ...
stones. Riebeckite granite was used for the facing stones of the
Canton Viaduct Canton Viaduct is a blind arcade cavity wall railroad viaduct in Canton, Massachusetts, built in 1834–35 for the Boston and Providence Railroad (B&P). At its completion, it was the longest () and tallest () railroad viaduct in the world; toda ...
from Moyles Quarry (a.k.a. Canton Viaduct Quarry) now part of
Borderland State Park Borderland State Park is an American history and nature preserve with public recreational features located in the towns of Easton and Sharon, Massachusetts. The state park encompasses surrounding the Ames Mansion, which was built in 1910. The ...
in
Massachusetts Massachusetts (Massachusett: ''Muhsachuweesut Massachusett_writing_systems.html" ;"title="nowiki/> məhswatʃəwiːsət.html" ;"title="Massachusett writing systems">məhswatʃəwiːsət">Massachusett writing systems">məhswatʃəwiːsət'' En ...
, US. The commonwealth's name is even taken from an Algonquian word for the
Great Blue Hill Great Blue Hill is a hill of 635 feet (194 m) located within the Blue Hills Reservation in Milton, Randolph and Canton, Massachusetts, about south of downtown Boston. It is the highest point in Norfolk County and the Greater Boston area. The ...
, which got its color from this form of granite.


Crocidolite (fibrous riebeckite)

The fibrous forms of riebeckite are known as ''crocidolite'' and are one of the six recognised types of
asbestos Asbestos () is a naturally occurring fibrous silicate mineral. There are six types, all of which are composed of long and thin fibrous crystals, each fibre being composed of many microscopic "fibrils" that can be released into the atmosphere b ...
. Often referred to as blue asbestos, it is considered the most hazardous. The association between blue asbestos and
mesothelioma Mesothelioma is a type of cancer that develops from the thin layer of tissue that covers many of the internal organs (known as the mesothelium). The most common area affected is the lining of the lungs and chest wall. Less commonly the lining ...
was established by J. C. Wager, C. A. Sleggs, and P. Marchand by 1960. Crocidolite asbestos was mined in
South Africa South Africa, officially the Republic of South Africa (RSA), is the southernmost country in Africa. It is bounded to the south by of coastline that stretch along the South Atlantic and Indian Oceans; to the north by the neighbouring coun ...
,
Bolivia , image_flag = Bandera de Bolivia (Estado).svg , flag_alt = Horizontal tricolor (red, yellow, and green from top to bottom) with the coat of arms of Bolivia in the center , flag_alt2 = 7 × 7 square p ...
, and
Wittenoom, Western Australia Wittenoom is a declared contaminated site and former townsite north-north-east of Perth, in the Hamersley Range in the Pilbara region of Western Australia. The declared contaminated site comprises , making it the "largest contaminated site i ...
. Bolivian crocidolite was used in approximately 13 billion
Kent Kent is a county in South East England and one of the home counties. It borders Greater London to the north-west, Surrey to the west and East Sussex to the south-west, and Essex to the north across the estuary of the River Thames; it faces ...
Micronite cigarette filters, manufactured from March 1952 until at least May 1956 by the
Lorillard Tobacco Company Lorillard Tobacco Company was an American tobacco company that marketed cigarettes under the brand names Newport, Maverick, Old Gold, Kent, True, Satin, and Max. The company had two operating segments: cigarettes and electronic cigarettes. Th ...
(now part of the R. J. Reynolds Tobacco Company). Blue asbestos was also used to similar effect, and hazard, in early gas masks.


See also

* *


References


External links

* {{Cite EB1911, wstitle=Crocidolite, volume=7, page=477 Amphibole group Asbestos Iron(II,III) minerals Magnesium minerals Monoclinic minerals Minerals in space group 12 Sodium minerals