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Richard Chace Tolman (March 4, 1881 – September 5, 1948) was an American
mathematical physicist Mathematical physics refers to the development of mathematical methods for application to problems in physics. The ''Journal of Mathematical Physics'' defines the field as "the application of mathematics to problems in physics and the developmen ...
and
physical chemist Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mech ...
who made many contributions to statistical mechanics. He also made important contributions to theoretical cosmology in the years soon after Einstein's discovery of
general relativity General relativity, also known as the general theory of relativity and Einstein's theory of gravity, is the geometric theory of gravitation published by Albert Einstein in 1915 and is the current description of gravitation in modern physics ...
. He was a professor of
physical chemistry Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistica ...
and
mathematical physics Mathematical physics refers to the development of mathematical methods for application to problems in physics. The '' Journal of Mathematical Physics'' defines the field as "the application of mathematics to problems in physics and the developme ...
at the
California Institute of Technology The California Institute of Technology (branded as Caltech or CIT)The university itself only spells its short form as "Caltech"; the institution considers other spellings such a"Cal Tech" and "CalTech" incorrect. The institute is also occasional ...
(Caltech).


Biography

Tolman was born in
West Newton, Massachusetts West Newton is one of the thirteen villages within the city of Newton in Middlesex County, Massachusetts, United States. Among the oldest of the thirteen Newton villages, the West Newton Village Center is a National Register Historic District. ...
and studied
chemical engineering Chemical engineering is an engineering field which deals with the study of operation and design of chemical plants as well as methods of improving production. Chemical engineers develop economical commercial processes to convert raw materials int ...
at the
Massachusetts Institute of Technology The Massachusetts Institute of Technology (MIT) is a private land-grant research university in Cambridge, Massachusetts. Established in 1861, MIT has played a key role in the development of modern technology and science, and is one of the ...
, receiving his
bachelor's degree A bachelor's degree (from Middle Latin ''baccalaureus'') or baccalaureate (from Modern Latin ''baccalaureatus'') is an undergraduate academic degree awarded by colleges and universities upon completion of a course of study lasting three to six ...
in 1903 and PhD in 1910 under A. A. Noyes. He married Ruth Sherman Tolman in 1924. In 1912, he conceived of the concept of
relativistic mass The word "mass" has two meanings in special relativity: '' invariant mass'' (also called rest mass) is an invariant quantity which is the same for all observers in all reference frames, while the relativistic mass is dependent on the velocity o ...
, writing that "the expression m_0 \left(1 - \frac \right)^ is best suited for the mass of a moving body." In a 1916 experiment with Thomas Dale Stewart, Tolman demonstrated that
electricity Electricity is the set of physical phenomena associated with the presence and motion of matter that has a property of electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as describ ...
consists of
electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no ...
s flowing through a
metal A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall ...
lic conductor. A by-product of this experiment was a measured value of the mass of the electron. Overall, however, he was primarily known as a theorist. Tolman was a member of the
Technical Alliance The Technical Alliance was a group of engineers, scientists, and technicians based in New York City, formed towards the end of 1919 by American engineer Howard Scott. The Alliance started an ''Energy Survey of North America'', aimed at documenting t ...
in 1919, a forerunner of the
Technocracy movement The technocracy movement was a social movement active in the United States and Canada in the 1930s which favored technocracy as a system of government over representative democracy and concomitant partisan politics. Historians associate the move ...
where he helped conduct an energy survey analyzing the possibility of applying science to social and industrial affairs. Tolman was elected a Fellow of the
American Academy of Arts and Sciences The American Academy of Arts and Sciences (abbreviation: AAA&S) is one of the oldest learned societies in the United States. It was founded in 1780 during the American Revolution by John Adams, John Hancock, James Bowdoin, Andrew Oliver, a ...
in 1922. The same year, he joined the faculty of the
California Institute of Technology The California Institute of Technology (branded as Caltech or CIT)The university itself only spells its short form as "Caltech"; the institution considers other spellings such a"Cal Tech" and "CalTech" incorrect. The institute is also occasional ...
, where he became professor of physical chemistry and mathematical physics and later dean of the graduate school. One of Tolman's early students at Caltech was the theoretical chemist Linus Pauling, to whom Tolman taught the
old quantum theory The old quantum theory is a collection of results from the years 1900–1925 which predate modern quantum mechanics. The theory was never complete or self-consistent, but was rather a set of heuristic corrections to classical mechanics. The theory ...
. In 1927, Tolman published a text on statistical mechanics whose background was the old quantum theory of
Max Planck Max Karl Ernst Ludwig Planck (, ; 23 April 1858 – 4 October 1947) was a German theoretical physicist whose discovery of energy quanta won him the Nobel Prize in Physics in 1918. Planck made many substantial contributions to theoretical p ...
,
Niels Bohr Niels Henrik David Bohr (; 7 October 1885 – 18 November 1962) was a Danish physicist who made foundational contributions to understanding atomic structure and quantum theory, for which he received the Nobel Prize in Physics in 1922 ...
and Arnold Sommerfeld. In 1938, he published a new detailed work that covered the application of statistical mechanics to classical and quantum systems. It was the standard work on the subject for many years and remains of interest today. In the later years of his career, Tolman became increasingly interested in the application of
thermodynamics Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of th ...
to relativistic systems and
cosmology Cosmology () is a branch of physics and metaphysics dealing with the nature of the universe. The term ''cosmology'' was first used in English in 1656 in Thomas Blount's ''Glossographia'', and in 1731 taken up in Latin by German philosopher ...
. An important monograph he published in 1934 titled ''Relativity, Thermodynamics, and Cosmology'' demonstrated how
black body A black body or blackbody is an idealized physical body that absorbs all incident electromagnetic radiation, regardless of frequency or angle of incidence. The name "black body" is given because it absorbs all colors of light. A black body ...
radiation in an expanding universe cools but remains
thermal A thermal column (or thermal) is a rising mass of buoyant air, a convective current in the atmosphere, that transfers heat energy vertically. Thermals are created by the uneven heating of Earth's surface from solar radiation, and are an example ...
a key pointer toward the properties of the
cosmic microwave background In Big Bang cosmology the cosmic microwave background (CMB, CMBR) is electromagnetic radiation that is a remnant from an early stage of the universe, also known as "relic radiation". The CMB is faint cosmic background radiation filling all spac ...
. (See
Edward Tryon Edward P. Tryon (September 4, 1940 – December 11, 2019) was an American scientist and a professor emeritus of physics at Hunter College of the City University of New York (CUNY). He was the first physicist to propose that our universe originated ...
.)
Also in this monograph, Tolman was the first person to document and explain how a closed universe could equal zero energy. He explained how all mass energy is positive and all gravitational energy is negative and they cancel each other out, leading to a universe of zero energy. His investigation of the oscillatory universe hypothesis, which
Alexander Friedmann Alexander Alexandrovich Friedmann (also spelled Friedman or Fridman ; russian: Алекса́ндр Алекса́ндрович Фри́дман) (June 16 .S. 4 1888 – September 16, 1925) was a Russian and Soviet physicist and mathematician ...
had proposed in 1922, drew attention to difficulties as regards
entropy Entropy is a scientific concept, as well as a measurable physical property, that is most commonly associated with a state of disorder, randomness, or uncertainty. The term and the concept are used in diverse fields, from classical thermodynam ...
and resulted in its demise until the late 1960s. During
World War II World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the vast majority of the world's countries—including all of the great powers—forming two opposing ...
, Tolman served as scientific advisor to General
Leslie Groves Lieutenant General Leslie Richard Groves Jr. (17 August 1896 – 13 July 1970) was a United States Army Corps of Engineers officer who oversaw the construction of the Pentagon and directed the Manhattan Project, a top secret research project ...
on the
Manhattan Project The Manhattan Project was a research and development undertaking during World War II that produced the first nuclear weapons. It was led by the United States with the support of the United Kingdom and Canada. From 1942 to 1946, the project w ...
. At the time of his death in
Pasadena Pasadena ( ) is a city in Los Angeles County, California, northeast of downtown Los Angeles. It is the most populous city and the primary cultural center of the San Gabriel Valley. Old Pasadena is the city's original commercial district. ...
, he was chief advisor to Bernard Baruch, the U.S. representative to the
United Nations Atomic Energy Commission The United Nations Atomic Energy Commission (UNAEC) was founded on 24 January 1946 by the very first resolution of the United Nations General Assembly "to deal with the problems raised by the discovery of atomic energy." The General Assembly asked ...
. Each year, the
southern California Southern California (commonly shortened to SoCal) is a geographic and cultural region that generally comprises the southern portion of the U.S. state of California. It includes the Los Angeles metropolitan area, the second most populous urban a ...
section of the
American Chemical Society The American Chemical Society (ACS) is a scientific society based in the United States that supports scientific inquiry in the field of chemistry. Founded in 1876 at New York University, the ACS currently has more than 155,000 members at all ...
honors Tolman by awarding its Tolman Medal "in recognition of outstanding contributions to chemistry."


Family

Tolman's brother was the
behavioral psychologist Behaviorism is a systematic approach to understanding the behavior of humans and animals. It assumes that behavior is either a reflex evoked by the pairing of certain antecedent stimuli in the environment, or a consequence of that individual ...
Edward Chace Tolman Edward Chace Tolman (April 14, 1886 – November 19, 1959) was an American psychologist and a professor of psychology at the University of California, Berkeley. Through Tolman's theories and works, he founded what is now a branch of psychology know ...
.


See also

*
List of textbooks in thermodynamics and statistical mechanics A list of notable textbooks in thermodynamics and statistical mechanics, arranged by category and date. Only or mainly thermodynamics * * * * * * Both thermodynamics and statistical mechanics * * * 2e Kittel, Charles; and Kroemer, Herb ...
* Tolman length * Tolman surface brightness test * Tolman's paradox * Tolman's H theorem * Tolman–Ehrenfest effect * Tolman–Oppenheimer–Volkoff equation * Tolman–Oppenheimer–Volkoff limit *
Lemaître–Tolman metric In physics, the Lemaître–Tolman metric, also known as the Lemaître–Tolman–Bondi metric or the Tolman metric, is a Lorentzian metric based on an exact solution of Einstein's field equations; it describes an isotropic and expanding (or co ...
* Lewis–Tolman paradox * Stewart–Tolman effect * Oscillatory universe * Static spherically symmetric perfect fluid * Thin Man (nuclear bomb)


References


Books by Tolman

* * Reissued (1987) New York: Dover . * Reissued (1979) New York: Dover .


External links


Short biography
from the Online Archive of California
Short biography
from the "Tolman Award" page of the Southern California Section of the American Chemical Society. * *
Biographical memoir
National Academy of Sciences. Includes a complete bibliography of Tolman's writings. Retrieved July 14, 2017. {{DEFAULTSORT:Tolman, Richard Chace 1881 births 1948 deaths 20th-century American physicists California Institute of Technology faculty American cosmologists Fellows of the American Academy of Arts and Sciences Manhattan Project people MIT School of Engineering alumni People from Newton, Massachusetts American relativity theorists American physical chemists