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Rhyolite ( ) is the most
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is ...
-rich of volcanic rocks. It is generally
glass Glass is a non- crystalline, often transparent, amorphous solid that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most often formed by rapid cooling (quenchin ...
y or fine-grained (
aphanitic Aphanites (adj. ''aphanitic''; ) are igneous rocks that are so fine-grained that their component mineral crystals are not visible to the naked eye (in contrast to phanerites, in which the crystals are visible to the unaided eye). This ge ...
) in texture, but may be
porphyritic Porphyritic is an adjective used in geology to describe igneous rocks with a distinct difference in the size of mineral crystals, with the larger crystals known as phenocrysts. Both extrusive and intrusive rocks can be porphyritic, meaning a ...
, containing larger mineral
crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macro ...
s ( phenocrysts) in an otherwise fine-grained
groundmass The matrix or groundmass of a rock is the finer-grained mass of material in which larger grains, crystals, or clasts are embedded. The matrix of an igneous rock consists of finer-grained, often microscopic, crystals in which larger crystals, ...
. The
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...
assemblage is predominantly
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical f ...
,
sanidine Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal s ...
, and
plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more p ...
. It is the extrusive equivalent to
granite Granite () is a coarse-grained ( phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies un ...
. Rhyolitic
magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natura ...
is extremely
viscous The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the in ...
, due to its high silica content. This favors
explosive eruption In volcanology, an explosive eruption is a volcanic eruption of the most violent type. A notable example is the 1980 eruption of Mount St. Helens. Such eruptions result when sufficient gas has dissolved under pressure within a viscous magma su ...
s over
effusive eruption An effusive eruption is a type of volcanic eruption in which lava steadily flows out of a volcano onto the ground. Overview There are two major groupings of eruptions: effusive and explosive. Effusive eruption differs from explosive eruption ...
s, so this type of magma is more often erupted as
pyroclastic rock Pyroclastic rocks (derived from the el, πῦρ, links=no, meaning fire; and , meaning broken) are clastic rocks composed of rock fragments produced and ejected by explosive volcanic eruptions. The individual rock fragments are known as pyrocl ...
than as
lava flow Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or un ...
s. Rhyolitic ash-flow
tuff Tuff is a type of rock made of volcanic ash ejected from a vent during a volcanic eruption. Following ejection and deposition, the ash is lithified into a solid rock. Rock that contains greater than 75% ash is considered tuff, while rock ...
s are among the most voluminous of continental
igneous rock Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma o ...
formations. Rhyolitic tuff has been extensively used for construction.
Obsidian Obsidian () is a naturally occurring volcanic glass formed when lava extruded from a volcano cools rapidly with minimal crystal growth. It is an igneous rock. Obsidian is produced from felsic lava, rich in the lighter elements such as silicon ...
, which is rhyolitic
volcanic glass Volcanic glass is the amorphous (uncrystallized) product of rapidly cooling magma. Like all types of glass, it is a state of matter intermediate between the closely packed, highly ordered array of a crystal and the highly disordered array of ...
, has been used for tools from prehistoric times to the present day because it can be shaped to an extremely sharp edge. Rhyolitic
pumice Pumice (), called pumicite in its powdered or dust form, is a volcanic rock that consists of highly vesicular rough-textured volcanic glass, which may or may not contain crystals. It is typically light-colored. Scoria is another vesicular v ...
finds use as an abrasive, in
concrete Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most wid ...
, and as a
soil amendment A soil conditioner is a product which is added to soil to improve the soil’s physical qualities, usually its fertility (ability to provide nutrition for plants) and sometimes its mechanics. In general usage, the term "soil conditioner" is often ...
.


Description

Rhyolite is an extrusive igneous rock, formed from magma rich in
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is ...
that is extruded from a volcanic vent to cool quickly on the surface rather than slowly in the subsurface. It is generally light in color due to its low content of
mafic A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks in ...
minerals, and it is typically very fine-grained (
aphanitic Aphanites (adj. ''aphanitic''; ) are igneous rocks that are so fine-grained that their component mineral crystals are not visible to the naked eye (in contrast to phanerites, in which the crystals are visible to the unaided eye). This ge ...
) or
glassy Glassy is an adjective meaning, of or resembling glass. Glassy may also mean: * Glassy, amorphous metal * ''Glassy'', a 2021 single album, or the title song by Jo Yu-ri * Glassy phase, amorphous solid * Glassy water, amorphous ice * Glassy carbon, ...
. An extrusive igneous rock is classified as rhyolite when
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical f ...
constitutes 20% to 60% by volume of its total content of quartz,
alkali feldspar Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feldspa ...
, and
plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more p ...
( QAPF) and alkali feldspar makes up 35% to 90% of its total feldspar content.
Feldspathoid The feldspathoids are a group of tectosilicate minerals which resemble feldspars but have a different structure and much lower silica content. They occur in rare and unusual types of igneous rocks, and are usually not found in rocks containing ...
s are not present. This makes rhyolite the extrusive equivalent of granite. However, while the
IUGS The International Union of Geological Sciences (IUGS) is an international non-governmental organization devoted to international cooperation in the field of geology. About The IUGS was founded in 1961 and is a Scientific Union member of the Int ...
recommends classifying volcanic rocks on the basis of their mineral composition whenever possible, volcanic rocks are often glassy or so fine-grained that mineral identification is impractical. The rock must then be classified chemically based on its content of silica and alkali metal oxides ( K2O plus Na2O). Rhyolite is high in silica and total alkali metal oxides, placing it in the R field of the
TAS diagram The TAS classification can be used to assign names to many common types of volcanic rocks based upon the relationships between the combined alkali content and the silica content. These chemical parameters are useful, because the relative proportion ...
. The alkali feldspar in rhyolites is
sanidine Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal s ...
or, less commonly, orthoclase. It is rarely
anorthoclase The mineral anorthoclase ((Na,K)AlSi3O8) is a crystalline solid solution in the alkali feldspar series, in which the sodium-aluminium silicate member exists in larger proportion. It typically consists of between 10 and 36 percent of KAlSi3O8 and ...
. These feldspar minerals sometimes are present as phenocrysts. The plagioclase is usually
sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...
-rich (
oligoclase Oligoclase is a rock-forming mineral belonging to the plagioclase feldspars. In chemical composition and in its crystallographic and physical characters it is intermediate between albite ( Na Al Si3 O8) and anorthite ( CaAl2Si2O8). The albite: ...
or andesine).
Cristobalite Cristobalite is a mineral polymorph of silica that is formed at very high temperatures. It has the same chemical formula as quartz, SiO2, but a distinct crystal structure. Both quartz and cristobalite are polymorphs with all the members of the ...
and
trydimite Tridymite is a high-temperature polymorph of silica and usually occurs as minute tabular white or colorless pseudo-hexagonal crystals, or scales, in cavities in felsic volcanic rocks. Its chemical formula is Si O2. Tridymite was first described ...
are sometimes present along with the quartz.
Biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron- endmember annite, and the magnesium-endmember phlogopite; more ...
,
augite Augite is a common rock-forming pyroxene mineral with formula . The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees. Characteristics Augite is a solid solution in the pyroxene group ...
, fayalite, and hornblende are common accessory minerals.


Geology

Due to their high content of silica and low
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in ...
and
magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ...
contents, rhyolitic magmas form highly viscous
lava Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or ...
s. As a result, many eruptions of rhyolite are highly explosive, and rhyolite occurs more frequently as
pyroclastic rock Pyroclastic rocks (derived from the el, πῦρ, links=no, meaning fire; and , meaning broken) are clastic rocks composed of rock fragments produced and ejected by explosive volcanic eruptions. The individual rock fragments are known as pyrocl ...
than as
lava flow Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or un ...
s. Rhyolitic ash flow tuffs are the only volcanic product with volumes rivaling those of flood basalts. Rhyolites also occur as
breccia Breccia () is a rock composed of large angular broken fragments of minerals or rocks cemented together by a fine-grained matrix. The word has its origins in the Italian language, in which it means "rubble". A breccia may have a variety of ...
s or in
lava dome In volcanology, a lava dome is a circular mound-shaped protrusion resulting from the slow extrusion of viscous lava from a volcano. Dome-building eruptions are common, particularly in convergent plate boundary settings. Around 6% of eruptions ...
s,
volcanic plug A volcanic plug, also called a volcanic neck or lava neck, is a volcanic object created when magma hardens within a vent on an active volcano. When present, a plug can cause an extreme build-up of high gas pressure if rising volatile-charged ma ...
s, and
dikes Dyke (UK) or dike (US) may refer to: General uses * Dyke (slang), a slang word meaning "lesbian" * Dike (geology), a subvertical sheet-like intrusion of magma or sediment * Dike (mythology), ''Dikē'', the Greek goddess of moral justice * Dikes ...
. Rhyolitic lavas erupt at a relatively low temperature of , significantly cooler than basaltic lavas, which typically erupt at temperatures of . Rhyolites that cool too quickly to grow crystals form a natural glass or vitrophyre, also called
obsidian Obsidian () is a naturally occurring volcanic glass formed when lava extruded from a volcano cools rapidly with minimal crystal growth. It is an igneous rock. Obsidian is produced from felsic lava, rich in the lighter elements such as silicon ...
. Slower cooling forms microscopic crystals in the lava and results in textures such as flow foliations, spherulitic, nodular, and lithophysal structures. Some rhyolite is highly vesicular
pumice Pumice (), called pumicite in its powdered or dust form, is a volcanic rock that consists of highly vesicular rough-textured volcanic glass, which may or may not contain crystals. It is typically light-colored. Scoria is another vesicular v ...
. Peralkaline rhyolites (rhyolites unusually rich in alkali metals) include
comendite Comendite is a hard, peralkaline igneous rock, a type of light blue grey rhyolite. Phenocrysts are sodic sanidine with minor albite and bipyramidal quartz. Iddings, Joseph Paxson, 1913, ''Igneous rocks: composition, texture and classification' ...
and pantellerite. Peralkalinity has significant effects on lava flow morphology and
mineralogy Mineralogy is a subject of geology specializing in the scientific study of the chemistry, crystal structure, and physical (including optical) properties of minerals and mineralized artifacts. Specific studies within mineralogy include the proce ...
, such that peralkaline rhyolites can be 10–30 times more fluid than typical calc-alkaline rhyolites. As a result of their increased fluidity, they are able to form small-scale flow folds,
lava tube A lava tube, or pyroduct, is a natural conduit formed by flowing lava from a volcanic vent that moves beneath the hardened surface of a lava flow. If lava in the tube empties, it will leave a cave. Formation A lava tube is a type of lava ...
s and thin dikes. Peralkaline rhyolites erupt at relatively high temperatures of more than . They comprise
bimodal In statistics, a multimodal distribution is a probability distribution with more than one mode. These appear as distinct peaks (local maxima) in the probability density function, as shown in Figures 1 and 2. Categorical, continuous, and d ...
shield volcano A shield volcano is a type of volcano named for its low profile, resembling a warrior's shield lying on the ground. It is formed by the eruption of highly fluid (low viscosity) lava, which travels farther and forms thinner flows than the more vi ...
es at hotspots and rifts (e.g. Rainbow Range,
Ilgachuz Range The Ilgachuz Range is a name given to an extinct shield volcano in British Columbia, Canada. It is not a mountain range in the normal sense, because it was formed as a single volcano that has been eroded for the past 5 million years. It lies on t ...
and Level Mountain in
British Columbia British Columbia (commonly abbreviated as BC) is the westernmost province of Canada, situated between the Pacific Ocean and the Rocky Mountains. It has a diverse geography, with rugged landscapes that include rocky coastlines, sandy beaches, for ...
, Canada). Eruptions of rhyolite lava are relatively rare compared to eruptions of less felsic lavas. Only four eruptions of rhyolite have been recorded since the start of the 20th century: at the St. Andrew Strait volcano in
Papua New Guinea Papua New Guinea (abbreviated PNG; , ; tpi, Papua Niugini; ho, Papua Niu Gini), officially the Independent State of Papua New Guinea ( tpi, Independen Stet bilong Papua Niugini; ho, Independen Stet bilong Papua Niu Gini), is a country i ...
and Novarupta volcano in
Alaska Alaska ( ; russian: Аляска, Alyaska; ale, Alax̂sxax̂; ; ems, Alas'kaaq; Yup'ik: ''Alaskaq''; tli, Anáaski) is a state located in the Western United States on the northwest extremity of North America. A semi-exclave of the U ...
as well as at Chaitén and Cordón Caulle volcanoes in southern
Chile Chile, officially the Republic of Chile, is a country in the western part of South America. It is the southernmost country in the world, and the closest to Antarctica, occupying a long and narrow strip of land between the Andes to the eas ...
. The eruption of Novarupta in 1912 was the largest volcanic eruption of the 20th century, and began with explosive volcanism that later transitioned to effusive volcanism and the formation of a rhyolite dome in the vent.


Petrogenesis

Rhyolite magmas can be produced by
igneous differentiation In geology, igneous differentiation, or magmatic differentiation, is an umbrella term for the various processes by which magmas undergo bulk chemical change during the partial melting process, cooling, emplacement, or eruption. The sequence of ...
of a more mafic (silica-poor) magma, through fractional crystallization or by assimilation of melted crustal rock (
anatexis Anatexis (via Latin from Greek roots meaning "to melt down") is the partial melting of rocks. Traditionally, anatexis is used specifically to discuss the partial melting of crustal rocks, while the generic term " partial melting" refers to the pa ...
). Associations of
andesite Andesite () is a volcanic rock of intermediate composition. In a general sense, it is the intermediate type between silica-poor basalt and silica-rich rhyolite. It is fine-grained (aphanitic) to porphyritic in texture, and is composed predo ...
s,
dacite Dacite () is a volcanic rock formed by rapid solidification of lava that is high in silica and low in alkali metal oxides. It has a fine-grained ( aphanitic) to porphyritic texture and is intermediate in composition between andesite and rhyo ...
s, and rhyolites in similar tectonic settings and with similar chemistry suggests that the rhyolite members were formed by differentiation of mantle-derived
basalt Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90 ...
ic magmas at shallow depths. In other cases, the rhyolite appears to be a product of melting of crustal sedimentary rock. Water vapor plays an important role in lowering the melting point of silicic rock, and some rhyolitic magmas may have a water content as high as 7–8 weight percent. High-silica rhyolite (HSR), with a silica content of 75 to 77·8% , forms a distinctive subgroup within the rhyolites. HSRs are the most
evolved Evolution is change in the heritable characteristics of biological populations over successive generations. These characteristics are the expressions of genes, which are passed on from parent to offspring during reproduction. Variati ...
of all igneous rocks, with a composition very close to the water-saturated granite eutectic and with extreme enrichment in most incompatible elements. However, they are highly depleted in
strontium Strontium is the chemical element with the symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is e ...
,
barium Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. Th ...
, and
europium Europium is a chemical element with the symbol Eu and atomic number 63. Europium is the most reactive lanthanide by far, having to be stored under an inert fluid to protect it from atmospheric oxygen or moisture. Europium is also the softest lan ...
. They are interpreted as products of repeated melting and freezing of granite in the subsurface. HSRs typically erupt in large
caldera A caldera ( ) is a large cauldron-like hollow that forms shortly after the emptying of a magma chamber in a volcano eruption. When large volumes of magma are erupted over a short time, structural support for the rock above the magma chamber is ...
eruptions.


Occurrence

Rhyolite is common along convergent plate boundaries, where a slab of oceanic lithosphere is being subducted into the Earth's mantle beneath overriding oceanic or continental lithosphere. It can sometimes be the predominant igneous rock type in these settings. Rhyolite is more common when the overriding lithosphere is continental rather than oceanic. The thicker continental crust gives the rising magma more opportunity to differentiate and assimilate crustal rock. Rhyolite has been found on islands far from land, but such oceanic occurrences are rare.Farndon, John (2007) ''The Illustrated Encyclopedia of Rocks of the World''. Southwater. p. 54. The tholeiitic magmas erupted at volcanic ocean islands, such as
Iceland Iceland ( is, Ísland; ) is a Nordic island country in the North Atlantic Ocean and in the Arctic Ocean. Iceland is the most sparsely populated country in Europe. Iceland's capital and largest city is Reykjavík, which (along with its ...
, can sometimes differentiate all the way to rhyolite, and about 8% of the volcanic rock in Iceland is rhyolite. However, this is unusual, and the
Hawaiian Islands The Hawaiian Islands ( haw, Nā Mokupuni o Hawai‘i) are an archipelago of eight major islands, several atolls, and numerous smaller islets in the North Pacific Ocean, extending some from the island of Hawaii in the south to northernmost ...
(for example) have no known occurrences of rhyolite. The alkaline magmas of volcanic ocean islands will very occasionally differentiate all the way to peralkaline rhyolites, but differentiation usually ends with
trachyte Trachyte () is an extrusive igneous rock composed mostly of alkali feldspar. It is usually light-colored and aphanitic (fine-grained), with minor amounts of mafic minerals, and is formed by the rapid cooling of lava enriched with silica and al ...
. Small volumes of rhyolite are sometimes erupted in association with flood basalts, late in their history and where central volcanic complexes develop.


Name

The name rhyolite was introduced into
geology Geology () is a branch of natural science concerned with Earth and other Astronomical object, astronomical objects, the features or rock (geology), rocks of which it is composed, and the processes by which they change over time. Modern geology ...
in 1860 by the German traveler and geologist
Ferdinand von Richthofen Baron Ferdinand Freiherr von Richthofen (5 May 18336 October 1905), better known in English as was a German traveller, geographer, and scientist. He is noted for coining the terms "Seidenstraße" and "Seidenstraßen" = "Silk Road(s)" or "Silk ...
from the Greek word ''rhýax'' ("a stream of lava") and the rock name suffix "-lite".


Uses

In North American pre-historic times, rhyolite was quarried extensively in what is now eastern
Pennsylvania Pennsylvania (; ( Pennsylvania Dutch: )), officially the Commonwealth of Pennsylvania, is a state spanning the Mid-Atlantic, Northeastern, Appalachian, and Great Lakes regions of the United States. It borders Delaware to its southeast, ...
. Among the leading quarries was the Carbaugh Run Rhyolite Quarry Site in Adams County. Rhyolite was mined there starting 11,500 years ago. Tons of rhyolite were traded across the Delmarva Peninsula, because the rhyolite kept a sharp point when knapped and was used to make spear points and arrowheads. Obsidian is usually of rhyolitic composition, and it has been used for tools since prehistoric times. Obsidian scalpels have been investigated for use in delicate surgery. Pumice, also typically of rhyolitic composition, finds important uses as an abrasive, in
concrete Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most wid ...
, and as a
soil amendment A soil conditioner is a product which is added to soil to improve the soil’s physical qualities, usually its fertility (ability to provide nutrition for plants) and sometimes its mechanics. In general usage, the term "soil conditioner" is often ...
. Rhyolitic tuff was used extensively for construction in ancient Rome and has been used in construction in modern Europe.


See also

* *


References


External links


Geology.com - Rhyolite

Gemstones.com - guide and properties chart - Rhyolite
{{Volcanoes Aphanitic rocks Felsic rocks Porphyritic rocks Volcanic rocks Subvolcanic rocks Volcanology