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Robert Minard Garrels (August 24, 1916 – March 8, 1988) was an American geochemist. Garrels applied experimental
physical chemistry Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mech ...
data and techniques to
geology Geology (). is a branch of natural science concerned with the Earth and other astronomical objects, the rocks of which they are composed, and the processes by which they change over time. Modern geology significantly overlaps all other Earth ...
and
geochemistry Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the e ...
problems. The book ''Solutions, Minerals, and Equilibria'' co-authored in 1965 by Garrels and Charles L. Christ revolutionized aqueous geochemistry. Garrels earned a bachelor's degree in geology from the
University of Michigan The University of Michigan (U-M, U of M, or Michigan) is a public university, public research university in Ann Arbor, Michigan, United States. Founded in 1817, it is the oldest institution of higher education in the state. The University of Mi ...
in 1937. He went on to earn an M.S. degree from
Northwestern University Northwestern University (NU) is a Private university, private research university in Evanston, Illinois, United States. Established in 1851 to serve the historic Northwest Territory, it is the oldest University charter, chartered university in ...
in 1939, his thesis work was on iron ores of
Newfoundland Newfoundland and Labrador is the easternmost province of Canada, in the country's Atlantic region. The province comprises the island of Newfoundland and the continental region of Labrador, having a total size of . As of 2025 the population ...
in 1938. His Ph.D. was awarded in 1941 based on lab studies of complex formation between
lead Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...
and
chloride The term chloride refers to a compound or molecule that contains either a chlorine anion (), which is a negatively charged chlorine atom, or a non-charged chlorine atom covalently bonded to the rest of the molecule by a single bond (). The pr ...
ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
s in
aqueous solution An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, also known as sodium chloride (NaCl), in water ...
.


Life and career

Garrels worked for the
United States Geological Survey The United States Geological Survey (USGS), founded as the Geological Survey, is an agency of the U.S. Department of the Interior whose work spans the disciplines of biology, geography, geology, and hydrology. The agency was founded on Mar ...
during
World War II World War II or the Second World War (1 September 1939 – 2 September 1945) was a World war, global conflict between two coalitions: the Allies of World War II, Allies and the Axis powers. World War II by country, Nearly all of the wo ...
and returned to teach at Northwestern until 1952. Also in 1952, he published a technical paper, "Origin and Classification of Chemical Sediments in Terms of pH and Oxidation-Reduction Potentials" with William C. Krumbein, which was to become a classic study of sedimentary rocks from a physical chemistry viewpoint. This and following works revolutionized sedimentary and aqueous geochemistry. He joined the
United States Geological Survey The United States Geological Survey (USGS), founded as the Geological Survey, is an agency of the U.S. Department of the Interior whose work spans the disciplines of biology, geography, geology, and hydrology. The agency was founded on Mar ...
again for a time, but returned to academia at
Harvard University Harvard University is a Private university, private Ivy League research university in Cambridge, Massachusetts, United States. Founded in 1636 and named for its first benefactor, the History of the Puritans in North America, Puritan clergyma ...
in 1955. He became a full professor in 1957 and later department chair. His work and the lab he supervised at Harvard produced many classic works, including the ''Solutions, Minerals, and Equilibria'' text. Here, between 1960 and 1962, he, along with his colleagues, published the classic studies: * "Oxidation of Pyrite by Iron Sulfate Solutions" * "Stability of Some Carbonates at 25°C and One Atmosphere Total Pressure" * "Control of Carbonate Solubility by Carbonate Complexes" * "A Chemical Model for Sea Water at 25°C and One Atmosphere Total Pressure" He returned to
Northwestern University Northwestern University (NU) is a Private university, private research university in Evanston, Illinois, United States. Established in 1851 to serve the historic Northwest Territory, it is the oldest University charter, chartered university in ...
in 1965 and conducted influential studies on the
silicate A silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is also used ...
and
carbonate A carbonate is a salt of carbonic acid, (), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word "carbonate" may also refer to a carbonate ester, an organic compound containing the carbonate group ...
buffering of seawaters, the genesis of groundwaters and the theoretical treatment of irreversible reactions in
geochemical processes Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the e ...
. In 1969, he moved to the
Scripps Institution of Oceanography Scripps Institution of Oceanography (SIO) is the center for oceanography and Earth science at the University of California, San Diego. Its main campus is located in La Jolla, with additional facilities in Point Loma. Founded in 1903 and incorpo ...
and later to the
University of Hawaiʻi at Mānoa The University of Hawaii at Mānoa is a Public university, public Land-grant university, land-grant research university in Honolulu, Hawaii, United States. It is the flagship campus of the University of Hawaiʻi system and houses the main offic ...
. During this time he worked on thermodynamic properties of silicate minerals and also published "Cycling of Carbon, Sulfur, and Oxygen through Geologic Time" with Ed Perry in 1974. In 1974, he returned to
Northwestern University Northwestern University (NU) is a Private university, private research university in Evanston, Illinois, United States. Established in 1851 to serve the historic Northwest Territory, it is the oldest University charter, chartered university in ...
and published important studies on the sulfur and carbon isotopic compositions of
Phanerozoic The Phanerozoic is the current and the latest of the four eon (geology), geologic eons in the Earth's geologic time scale, covering the time period from 538.8 million years ago to the present. It is the eon during which abundant animal and ...
rocks with Abraham Lerman and Frederick T. Mackenzie. Garrels had broad interests beyond geology. He enjoyed travel and wine. He was athletic, holding the world high jump record for men over 57 years of age. He was a poet-scientist: ''Cycle of P''
by Robert M. Garrels : I put some P into the sea
the biomass did swell : But settling down soon overcame
and P went down toward Hell : From Purgatory soon released
it moved up to the land : To make a perfect rose for thee
to carry in thy hand : But roses wilt and die you know
then P falls on the ground : Gobbled up as ferric P
a nasty brown compound : The world is moral still you know
and Nature's wheels do grind : Put ferric P into the sea
and a rose someday you'll find He moved to the
University of South Florida The University of South Florida (USF) is a Public university, public research university with its main campus located in Tampa, Florida, Tampa, Florida, United States, and other campuses in St. Petersburg, Florida, St. Petersburg and Sarasota, ...
at St. Petersburg in 1979, holding the St. Petersburg Progress Chair in Marine Science, and spent summers at the Université Louis Pasteur, Strasbourg; the Université Libre, Brussels; and
Yale Yale University is a private Ivy League research university in New Haven, Connecticut, United States. Founded in 1701, Yale is the third-oldest institution of higher education in the United States, and one of the nine colonial colleges ch ...
, where he held an adjunct professorship. During this time he published "The Carbonate–Silicate Geochemical Cycle and Its Effect on Atmospheric
Carbon Dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
over the Past 100 Million Years" in 1983. This concerned the BLAG model, named for the collaborators including Tony Lasaga and Robert Berner. He continued to be active while fighting cancer, publishing "Modeling Atmospheric O2 in the Global Sedimentary Redox Cycle" (1986) and "A Model for the Deposition of the Microbanded Precambrian Iron Formations." (1987)


Awards and honors

* 1961 – Election to the
National Academy of Sciences The National Academy of Sciences (NAS) is a United States nonprofit, NGO, non-governmental organization. NAS is part of the National Academies of Sciences, Engineering, and Medicine, along with the National Academy of Engineering (NAE) and the ...
* 1962 – President of the
Geochemical Society The Geochemical Society is a nonprofit scientific organization founded to encourage the application of chemistry to solve problems involving geology and cosmology. The society promotes understanding of geochemistry through the annual Goldschmidt Co ...
* 1966 – Received the Arthur L. Day Medal of the
Geological Society of America The Geological Society of America (GSA) is a nonprofit organization dedicated to the advancement of the geosciences. History The society was founded in Ithaca, New York, in 1888 by Alexander Winchell, John J. Stevenson, Charles H. Hi ...
* 1969 – Honorary doctorate from the Université Libre de Bruxelles * 1973 – Received the V. M. Goldschmidt Award of the
Geochemical Society The Geochemical Society is a nonprofit scientific organization founded to encourage the application of chemistry to solve problems involving geology and cosmology. The society promotes understanding of geochemistry through the annual Goldschmidt Co ...
* 1976 – Honorary doctorate from the Université Louis Pasteur, Strasbourg, France * 1978 – Received the Penrose Medal of the Geological Society of America * 1980 – Honorary doctorate from the University of Michigan, Ann Arbor, Michigan, US * 1981 – Received the
Wollaston Medal The Wollaston Medal is a scientific award for geology and the highest award granted by the Geological Society of London, the oldest geological society in the world. The medal is named after William Hyde Wollaston, and was first awarded in 1831. I ...
of the
Geological Society of London The Geological Society of London, known commonly as the Geological Society, is a learned society based in the United Kingdom. It is the oldest national geological society in the world and the largest in Europe, with more than 12,000 Fellows. Fe ...
* 1981 – Received the
Roebling Medal The Roebling Medal is the highest award of the Mineralogical Society of America for scientific eminence as represented primarily by scientific publication of outstanding original research in mineralogy. The award is named for Colonel Washington A. ...
of the
Mineralogical Society of America The Mineralogical Society of America (MSA) is a scientific membership organization. MSA was founded in 1919 for the advancement of mineralogy, crystallography, geochemistry, and petrology, and promotion of their uses in other sciences, industry, ...


Selected publications

* ''A Textbook of Geology,'' Harper's Geoscience Series (1951) *
Behavior of Colorado Plateau uranium minerals during oxidation
' U.S. Geological Survey Trace Elements Investigations Report No. 588 (1956) * ''Mineral Equilibria at Low Temperature and Pressure,'' Harper (1960) * ''Solutions, Minerals, and Equilibria'' with Charles L. Christ (1965) (2nd ed. Freeman Cooper Co, 1982 and revised ed 1990) (1990 ed.) * ''Evolution of Sedimentary Rocks'' with Fred Mackenzie; Norton, (1971) () * ''Water the Web of Life'' with Cynthia Garrels; Norton (1972) () * ''Chemical cycles and the global environment: Assessing human influences'' with Cynthia Garrels and F. T. Mackenzie W.; Kaufmann (1975) () * ''Thermodynamic Values at Low Temperature for Natural Inorganic Materials: An Uncritical Summary,'' with Terri L. Woods; Oxford University Press (1986)


References


External links



* ttp://findingaids.library.northwestern.edu/catalog/inu-ead-nua-archon-565 Robert M. Garrels Papers, 1938-1992, Northwestern University Archive, Evanston, Illinois {{DEFAULTSORT:Garrels, Robert 1916 births 1988 deaths 20th-century American chemists Members of the United States National Academy of Sciences American geochemists Wollaston Medal winners University of Michigan College of Literature, Science, and the Arts alumni Northwestern University alumni Harvard University faculty University of Hawaiʻi at Mānoa faculty Penrose Medal winners United States Geological Survey personnel American physical chemists Presidents of the Geochemical Society Recipients of the V. M. Goldschmidt Award