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Rhenium pentafluoride is a binary
inorganic compound In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemi ...
of
rhenium Rhenium is a chemical element with the symbol Re and atomic number 75. It is a silvery-gray, heavy, third-row transition metal in group 7 of the periodic table. With an estimated average concentration of 1 part per billion (ppb), rhenium is on ...
and fluorine with the chemical formula . This is a salt of rhenium and
hydrofluoric acid Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colourless, acidic and highly corrosive. It is used to make most fluorine-containing compounds; examples include the commonly used pharmaceutical antidepr ...
.


Synthesis

Rhenium pentafluoride can be synthesised by the reduction of
rhenium hexafluoride Rhenium hexafluoride, also rhenium(VI) fluoride, (ReF6) is a compound of rhenium and fluorine and one of the seventeen known binary hexafluorides. Synthesis Rhenium hexafluoride is made by combining rhenium heptafluoride with additional rheniu ...
with
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic ...
,
rhenium Rhenium is a chemical element with the symbol Re and atomic number 75. It is a silvery-gray, heavy, third-row transition metal in group 7 of the periodic table. With an estimated average concentration of 1 part per billion (ppb), rhenium is on ...
, or tungsten: :: :: ::


Physical properties

Rhenium pentafluoride forms yellow-green crystals of
orthorhombic crystal system In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a ...
, cell parameters ''a'' = 0.57 nm, ''b'' = 1.723 nm, ''c'' = 0.767 nm. Rhenium pentafluoride reacts with water. Rhenium pentafluoride is volatile. The compound consists of
dimer Dimer may refer to: * Dimer (chemistry), a chemical structure formed from two similar sub-units ** Protein dimer, a protein quaternary structure ** d-dimer * Dimer model, an item in statistical mechanics, based on ''domino tiling'' * Julius Dimer ( ...
s of composition .


References

{{fluorides Fluorides Rhenium compounds