Quaterpyridine
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Quaterpyridine refers to a family of
pyridine Pyridine is a basic (chemistry), basic heterocyclic compound, heterocyclic organic compound with the chemical formula . It is structurally related to benzene, with one methine group replaced by a nitrogen atom . It is a highly flammable, weak ...
derivatives with the formula (NC5H4-C5H3N)2. These compounds can also be viewed as
bipyridine Bipyridines are a family of organic compounds with the formula (C5H4N)2, consisting of two pyridyl (C5H4N) rings. Pyridine is an aromatic nitrogen-containing heterocycle. The bipyridines are all colourless solids, which are soluble in organic sol ...
decorated with two pyridyl substituents. Several isomers are known. All are colorless solids. One particular isomer, 2,2':6',2'':6'',2-quaterpyridine, a derivative of
2,2'-bipyridine The comma is a punctuation mark that appears in several variants in different languages. Some typefaces render it as a small line, slightly curved or straight, but inclined from the vertical; others give it the appearance of a miniature fille ...
has attracted interest because it is a potential
tetradentate In chemistry, tetradentate ligands are ligands that bind four donor atoms to a central atom to form a coordination complex. This number of donor atoms that bind is called denticity and is a method of classifying ligands. Tetradentate ligands are ...
ligand In coordination chemistry, a ligand is an ion or molecule with a functional group that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one or more of the ligand's el ...
in
coordination chemistry A coordination complex is a chemical compound consisting of a central atom or ion, which is usually metallic and is called the ''coordination centre'', and a surrounding array of chemical bond, bound molecules or ions, that are in turn known as ' ...
.{{cite journal , doi=10.1021/acs.chemrev.6b00377, title=Quaterpyridines as Scaffolds for Functional Metallosupramolecular Materials , year=2016 , last1=Gorczyński , first1=Adam , last2=Harrowfield , first2=Jack M. , last3=Patroniak , first3=Violetta , last4=Stefankiewicz , first4=Artur R. , journal=Chemical Reviews , volume=116 , issue=23 , pages=14620–14674 , pmid=27960268


Related compounds

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terpyridine Terpyridine (2,2';6',2"-terpyridine, often abbreviated to Terpy or Tpy) is a heterocyclic compound derived from pyridine. It is a white solid that is soluble in most organic solvents. The compound is mainly used as a ligand in coordination chemist ...


References

Chelating agents Pyridines Bipyridines